DE69010922T2 - Enzym und Enzymstabilisationssystem enthaltendes flüssiges Waschmittel. - Google Patents
Enzym und Enzymstabilisationssystem enthaltendes flüssiges Waschmittel.Info
- Publication number
- DE69010922T2 DE69010922T2 DE69010922T DE69010922T DE69010922T2 DE 69010922 T2 DE69010922 T2 DE 69010922T2 DE 69010922 T DE69010922 T DE 69010922T DE 69010922 T DE69010922 T DE 69010922T DE 69010922 T2 DE69010922 T2 DE 69010922T2
- Authority
- DE
- Germany
- Prior art keywords
- acid
- enzyme
- liquid detergent
- aqueous liquid
- composition according
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- 239000003599 detergent Substances 0.000 title claims description 67
- 102000004190 Enzymes Human genes 0.000 title claims description 36
- 108090000790 Enzymes Proteins 0.000 title claims description 36
- 239000007788 liquid Substances 0.000 title claims description 31
- 230000006641 stabilisation Effects 0.000 title description 5
- 238000011105 stabilization Methods 0.000 title description 5
- 239000000203 mixture Substances 0.000 claims description 71
- 229940088598 enzyme Drugs 0.000 claims description 34
- 239000002253 acid Substances 0.000 claims description 22
- -1 peroxide compound Chemical class 0.000 claims description 21
- 150000001875 compounds Chemical class 0.000 claims description 14
- 239000007844 bleaching agent Substances 0.000 claims description 13
- 239000002245 particle Substances 0.000 claims description 12
- 150000002978 peroxides Chemical class 0.000 claims description 11
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 claims description 9
- 108091005804 Peptidases Proteins 0.000 claims description 9
- 239000004365 Protease Substances 0.000 claims description 9
- WNLRTRBMVRJNCN-UHFFFAOYSA-N adipic acid Chemical compound OC(=O)CCCCC(O)=O WNLRTRBMVRJNCN-UHFFFAOYSA-N 0.000 claims description 8
- 239000003381 stabilizer Substances 0.000 claims description 8
- 150000007513 acids Chemical class 0.000 claims description 7
- 239000004094 surface-active agent Substances 0.000 claims description 7
- 102100037486 Reverse transcriptase/ribonuclease H Human genes 0.000 claims description 6
- 150000001735 carboxylic acids Chemical class 0.000 claims description 6
- XBDQKXXYIPTUBI-UHFFFAOYSA-N dimethylselenoniopropionate Natural products CCC(O)=O XBDQKXXYIPTUBI-UHFFFAOYSA-N 0.000 claims description 6
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- IUVKMZGDUIUOCP-BTNSXGMBSA-N quinbolone Chemical compound O([C@H]1CC[C@H]2[C@H]3[C@@H]([C@]4(C=CC(=O)C=C4CC3)C)CC[C@@]21C)C1=CCCC1 IUVKMZGDUIUOCP-BTNSXGMBSA-N 0.000 claims description 3
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- OSWFIVFLDKOXQC-UHFFFAOYSA-N 4-(3-methoxyphenyl)aniline Chemical compound COC1=CC=CC(C=2C=CC(N)=CC=2)=C1 OSWFIVFLDKOXQC-UHFFFAOYSA-N 0.000 description 4
- XSVSPKKXQGNHMD-UHFFFAOYSA-N 5-bromo-3-methyl-1,2-thiazole Chemical compound CC=1C=C(Br)SN=1 XSVSPKKXQGNHMD-UHFFFAOYSA-N 0.000 description 4
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- 229910052708 sodium Inorganic materials 0.000 description 4
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- 150000003871 sulfonates Chemical class 0.000 description 4
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- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 3
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- 125000001931 aliphatic group Chemical group 0.000 description 3
- HXDRSFFFXJISME-UHFFFAOYSA-N butanedioic acid;2,3-dihydroxybutanedioic acid Chemical compound OC(=O)CCC(O)=O.OC(=O)C(O)C(O)C(O)=O HXDRSFFFXJISME-UHFFFAOYSA-N 0.000 description 3
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- 239000003795 chemical substances by application Substances 0.000 description 3
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- 229940090960 diethylenetriamine pentamethylene phosphonic acid Drugs 0.000 description 3
- DUYCTCQXNHFCSJ-UHFFFAOYSA-N dtpmp Chemical compound OP(=O)(O)CN(CP(O)(O)=O)CCN(CP(O)(=O)O)CCN(CP(O)(O)=O)CP(O)(O)=O DUYCTCQXNHFCSJ-UHFFFAOYSA-N 0.000 description 3
- 239000006260 foam Substances 0.000 description 3
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- 235000019832 sodium triphosphate Nutrition 0.000 description 3
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- KDYFGRWQOYBRFD-UHFFFAOYSA-N succinic acid Chemical compound OC(=O)CCC(O)=O KDYFGRWQOYBRFD-UHFFFAOYSA-N 0.000 description 3
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- IKCBAZNFHUGPRO-KVVVOXFISA-N 2-hydroxypropane-1,2,3-tricarboxylic acid;(z)-octadec-9-enoic acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O.CCCCCCCC\C=C/CCCCCCCC(O)=O IKCBAZNFHUGPRO-KVVVOXFISA-N 0.000 description 2
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- FEWJPZIEWOKRBE-JCYAYHJZSA-N Dextrotartaric acid Chemical compound OC(=O)[C@H](O)[C@@H](O)C(O)=O FEWJPZIEWOKRBE-JCYAYHJZSA-N 0.000 description 2
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- OFOBLEOULBTSOW-UHFFFAOYSA-N Malonic acid Chemical compound OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 2
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- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 description 2
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- XJRBAMWJDBPFIM-UHFFFAOYSA-N methyl vinyl ether Chemical compound COC=C XJRBAMWJDBPFIM-UHFFFAOYSA-N 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 150000002763 monocarboxylic acids Chemical class 0.000 description 1
- DNIAPMSPPWPWGF-UHFFFAOYSA-N monopropylene glycol Natural products CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 1
- 230000003472 neutralizing effect Effects 0.000 description 1
- MGFYIUFZLHCRTH-UHFFFAOYSA-N nitrilotriacetic acid Chemical compound OC(=O)CN(CC(O)=O)CC(O)=O MGFYIUFZLHCRTH-UHFFFAOYSA-N 0.000 description 1
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(O)=O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 229960003540 oxyquinoline Drugs 0.000 description 1
- 239000012188 paraffin wax Substances 0.000 description 1
- 229960003330 pentetic acid Drugs 0.000 description 1
- 150000004976 peroxydisulfates Chemical class 0.000 description 1
- 125000005342 perphosphate group Chemical group 0.000 description 1
- JRKICGRDRMAZLK-UHFFFAOYSA-L persulfate group Chemical group S(=O)(=O)([O-])OOS(=O)(=O)[O-] JRKICGRDRMAZLK-UHFFFAOYSA-L 0.000 description 1
- XYFCBTPGUUZFHI-UHFFFAOYSA-O phosphonium Chemical compound [PH4+] XYFCBTPGUUZFHI-UHFFFAOYSA-O 0.000 description 1
- 239000011574 phosphorus Substances 0.000 description 1
- 229910052698 phosphorus Inorganic materials 0.000 description 1
- 229920000435 poly(dimethylsiloxane) Polymers 0.000 description 1
- 229920001444 polymaleic acid Polymers 0.000 description 1
- 229920002223 polystyrene Polymers 0.000 description 1
- 235000013772 propylene glycol Nutrition 0.000 description 1
- 150000003856 quaternary ammonium compounds Chemical class 0.000 description 1
- 125000001453 quaternary ammonium group Chemical group 0.000 description 1
- MCJGNVYPOGVAJF-UHFFFAOYSA-N quinolin-8-ol Chemical compound C1=CN=C2C(O)=CC=CC2=C1 MCJGNVYPOGVAJF-UHFFFAOYSA-N 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 150000004671 saturated fatty acids Chemical class 0.000 description 1
- 235000003441 saturated fatty acids Nutrition 0.000 description 1
- 229920002545 silicone oil Polymers 0.000 description 1
- 239000002002 slurry Substances 0.000 description 1
- 150000003384 small molecules Chemical class 0.000 description 1
- 229910000029 sodium carbonate Inorganic materials 0.000 description 1
- 235000019812 sodium carboxymethyl cellulose Nutrition 0.000 description 1
- 229920001027 sodium carboxymethylcellulose Polymers 0.000 description 1
- FQENQNTWSFEDLI-UHFFFAOYSA-J sodium diphosphate Chemical compound [Na+].[Na+].[Na+].[Na+].[O-]P([O-])(=O)OP([O-])([O-])=O FQENQNTWSFEDLI-UHFFFAOYSA-J 0.000 description 1
- 229960001922 sodium perborate Drugs 0.000 description 1
- 239000012418 sodium perborate tetrahydrate Substances 0.000 description 1
- 229940045872 sodium percarbonate Drugs 0.000 description 1
- PFUVRDFDKPNGAV-UHFFFAOYSA-N sodium peroxide Chemical compound [Na+].[Na+].[O-][O-] PFUVRDFDKPNGAV-UHFFFAOYSA-N 0.000 description 1
- 229940048086 sodium pyrophosphate Drugs 0.000 description 1
- 229940079864 sodium stannate Drugs 0.000 description 1
- IBDSNZLUHYKHQP-UHFFFAOYSA-N sodium;3-oxidodioxaborirane;tetrahydrate Chemical compound O.O.O.O.[Na+].[O-]B1OO1 IBDSNZLUHYKHQP-UHFFFAOYSA-N 0.000 description 1
- YKLJGMBLPUQQOI-UHFFFAOYSA-M sodium;oxidooxy(oxo)borane Chemical compound [Na+].[O-]OB=O YKLJGMBLPUQQOI-UHFFFAOYSA-M 0.000 description 1
- 230000007928 solubilization Effects 0.000 description 1
- 238000005063 solubilization Methods 0.000 description 1
- 125000001424 substituent group Chemical group 0.000 description 1
- 239000001384 succinic acid Substances 0.000 description 1
- 150000005846 sugar alcohols Polymers 0.000 description 1
- 230000019635 sulfation Effects 0.000 description 1
- 238000005670 sulfation reaction Methods 0.000 description 1
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 description 1
- 235000019818 tetrasodium diphosphate Nutrition 0.000 description 1
- 239000001577 tetrasodium phosphonato phosphate Substances 0.000 description 1
- 235000021122 unsaturated fatty acids Nutrition 0.000 description 1
- 150000004670 unsaturated fatty acids Chemical class 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/04—Water-soluble compounds
- C11D3/08—Silicates
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/38—Products with no well-defined composition, e.g. natural products
- C11D3/386—Preparations containing enzymes, e.g. protease or amylase
- C11D3/38663—Stabilised liquid enzyme compositions
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/39—Organic or inorganic per-compounds
- C11D3/3947—Liquid compositions
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Detergent Compositions (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB898900496A GB8900496D0 (en) | 1989-01-10 | 1989-01-10 | Liquid detergent composition containing enzyme and enzyme stabilization system |
| EP90870197A EP0482274A1 (en) | 1989-01-10 | 1990-10-22 | Liquid detergent compositions containing a suspended peroxygen bleach |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| DE69010922D1 DE69010922D1 (de) | 1994-09-01 |
| DE69010922T2 true DE69010922T2 (de) | 1995-03-16 |
Family
ID=40149609
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE69010922T Expired - Fee Related DE69010922T2 (de) | 1989-01-10 | 1990-01-05 | Enzym und Enzymstabilisationssystem enthaltendes flüssiges Waschmittel. |
Country Status (17)
| Country | Link |
|---|---|
| EP (2) | EP0378261B1 (pt) |
| JP (2) | JP2749416B2 (pt) |
| CN (2) | CN1027080C (pt) |
| AR (1) | AR244323A1 (pt) |
| AT (1) | ATE109201T1 (pt) |
| AU (2) | AU638961B2 (pt) |
| CA (2) | CA2007381C (pt) |
| DE (1) | DE69010922T2 (pt) |
| FI (1) | FI900130A (pt) |
| GB (1) | GB8900496D0 (pt) |
| IE (2) | IE900097L (pt) |
| MX (2) | MX172149B (pt) |
| MY (1) | MY108663A (pt) |
| NZ (2) | NZ232055A (pt) |
| PT (2) | PT92820A (pt) |
| TR (1) | TR25347A (pt) |
| WO (1) | WO1992007055A1 (pt) |
Families Citing this family (33)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE69029190T2 (de) * | 1989-11-30 | 1997-03-20 | Clorox Co | Stabiles wässeriges Oxidationswaschmittel |
| CA2073445A1 (en) * | 1990-02-08 | 1991-08-09 | Johannes Cornelis Van De Pas | Liquid bleach composition |
| EP0476726A1 (en) * | 1990-07-27 | 1992-03-25 | Unilever N.V. | Protease-containing liquid detergent compositions |
| EP0471410A3 (en) * | 1990-08-15 | 1992-07-01 | Unilever Nv | Structured liquid detergent compositions containing subtilisin mutants |
| US5264142A (en) * | 1991-11-25 | 1993-11-23 | Lever Brothers Company, Division Of Conopco, Inc. | Stabilization of peroxygen bleach in enzyme-containing heavy duty liquids |
| WO1994018314A1 (en) | 1993-02-11 | 1994-08-18 | Genencor International, Inc. | Oxidatively stable alpha-amylase |
| EP2199386A1 (en) | 1993-10-08 | 2010-06-23 | Novozymes A/S | Amylase variants |
| US5691295A (en) * | 1995-01-17 | 1997-11-25 | Cognis Gesellschaft Fuer Biotechnologie Mbh | Detergent compositions |
| EP0769047B1 (en) * | 1994-07-01 | 1999-03-10 | Warwick International Group Limited | Bleaching compositions |
| CN1153526A (zh) * | 1994-07-21 | 1997-07-02 | 美国3M公司 | 稀释时能增加粘度的浓缩清洗剂组合物 |
| DE19515072A1 (de) * | 1995-04-28 | 1996-10-31 | Cognis Bio Umwelt | Cellulasehaltiges Waschmittel |
| DE19605688A1 (de) * | 1996-02-16 | 1997-08-21 | Henkel Kgaa | Übergangsmetallkomplexe als Aktivatoren für Persauerstoffverbindungen |
| US5958739A (en) * | 1996-06-06 | 1999-09-28 | Genencor International Inc. | Mutant α-amylase |
| EP0816247B1 (en) * | 1996-06-26 | 2001-08-16 | The Procter & Gamble Company | Venting container containing a liquid product with particulate solids |
| US6548134B1 (en) | 1996-06-26 | 2003-04-15 | The Procter & Gamble Company | Vented container containing a liquid product with particulate solids |
| ATE238408T1 (de) * | 1996-11-13 | 2003-05-15 | Procter & Gamble | Wässerige alkalische peroxidbleichmittel enthaltende zusammensetzungen |
| US6080568A (en) * | 1997-08-19 | 2000-06-27 | Genencor International, Inc. | Mutant α-amylase comprising modification at residues corresponding to A210, H405 and/or T412 in Bacillus licheniformis |
| DE50107849D1 (de) | 2000-07-28 | 2005-12-01 | Henkel Kgaa | Neues amylolytisches enzym aus bacillus sp. a 7-7 (dsm 12368) sowie wasch- und reinigungsmittel mit diesem neuen amylolytischen enzym |
| JP2002129189A (ja) * | 2000-10-26 | 2002-05-09 | Teepol Ltd | 界面活性剤の可溶化方法およびそれによって得られる界面活性剤可溶化溶液、並びにそれを用いた液体洗浄剤組成物 |
| US7888104B2 (en) | 2000-11-28 | 2011-02-15 | Henkel Ag & Co. Kgaa | Cyclodextrin glucanotransferase (CGTase), obtained from<I>Bacillus agaradherens<λ>(DSM 9948) and detergents and cleaning agents containing said novel cyclodextrin glucanotransferase |
| JP4567334B2 (ja) | 2001-10-22 | 2010-10-20 | ヘンケル・アクチェンゲゼルシャフト・ウント・コムパニー・コマンディットゲゼルシャフト・アウフ・アクチェン | 綿活性汚れ除去性ウレタン系ポリマー |
| DE10153792A1 (de) | 2001-10-31 | 2003-05-22 | Henkel Kgaa | Neue Alkalische Protease-Varianten und Wasch- und Reinigungsmittel enthaltend diese neuen Alkalischen Protease-Varianten |
| DE10162727A1 (de) | 2001-12-20 | 2003-07-10 | Henkel Kgaa | Neue Alkalische Protease aus Bacillus gibsonii (DSM 14391) und Wasch-und Reinigungsmittel enthaltend diese neue Alkalische Protease |
| DE10162728A1 (de) | 2001-12-20 | 2003-07-10 | Henkel Kgaa | Neue Alkalische Protease aus Bacillus gibsonii (DSM 14393) und Wasch-und Reinigungsmittel enthaltend diese neue Alkalische Protease |
| DE10163884A1 (de) | 2001-12-22 | 2003-07-10 | Henkel Kgaa | Neue Alkalische Protease aus Bacillus sp. (DSM 14392) und Wasch- und Reinigungsmittel enthaltend diese neue Alkalische Protease |
| DE10257387A1 (de) | 2002-12-06 | 2004-06-24 | Henkel Kgaa | Mehrkomponenten-Flüssigwaschmittel |
| GB2392167A (en) * | 2002-08-22 | 2004-02-25 | Reckitt Benckiser Inc | Composition containing an acid with anionic and nonionic surfactants |
| DE10303130A1 (de) * | 2003-01-28 | 2004-07-29 | Clariant Gmbh | Wässrige Flüssigwaschmittel-Dispersionen |
| EP2383330A1 (en) | 2006-03-31 | 2011-11-02 | Novozymes A/S | A stabilized liquid enzyme composition |
| US8071345B2 (en) | 2006-03-31 | 2011-12-06 | Novozymes A/S | Stabilized subtilisin composition |
| DE102007011236A1 (de) | 2007-03-06 | 2008-09-11 | Henkel Ag & Co. Kgaa | Carboxylgruppen tragende Benzophenon-oderBenzoesäureanilid-Derivate als Enzymstabilisatoren |
| JP5436199B2 (ja) * | 2009-12-28 | 2014-03-05 | ライオン株式会社 | 液体洗浄剤組成物の製造方法 |
| EP3083925A4 (en) * | 2013-12-18 | 2017-08-02 | Arkema Inc. | Stable liquid compositions containing enzymes and peroxides |
Family Cites Families (14)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR2140822A5 (en) * | 1971-06-09 | 1973-01-19 | Air Liquide | Bleaching liquids - contg hydrogen peroxide or persalts in alkaline medium with stabilisers |
| CA1104451A (en) * | 1978-02-28 | 1981-07-07 | Manuel Juan De Luque | Detergent bleach composition and process |
| US4377489A (en) * | 1981-03-16 | 1983-03-22 | Ceil Clean Corporation, Inc. | Inorganic persulfate cleaning solution for acoustic materials |
| DE3364292D1 (en) * | 1982-02-03 | 1986-08-07 | Procter & Gamble | Oxygen-bleach-containing liquid detergent compositions |
| US4529525A (en) * | 1982-08-30 | 1985-07-16 | Colgate-Palmolive Co. | Stabilized enzyme-containing detergent compositions |
| GB8311314D0 (en) * | 1983-04-26 | 1983-06-02 | Unilever Plc | Aqueous enzyme-containing compositions |
| US4689167A (en) * | 1985-07-11 | 1987-08-25 | The Procter & Gamble Company | Detergency builder system |
| JPS62253697A (ja) * | 1986-04-02 | 1987-11-05 | 花王株式会社 | 漂白剤組成物 |
| GB8712430D0 (en) * | 1987-05-27 | 1987-07-01 | Procter & Gamble | Liquid detergent |
| GB8713756D0 (en) * | 1987-06-12 | 1987-07-15 | Procter & Gamble | Liquid detergent |
| FR2630454B1 (fr) * | 1988-04-22 | 1990-08-10 | Air Liquide | Lessives liquides aqueuses blanchissantes stables au stockage et procede de lavage |
| CA1314186C (en) * | 1988-04-29 | 1993-03-09 | Frederik Jan Schepers | Liquid cleaning products |
| GB8826458D0 (en) * | 1988-11-11 | 1988-12-14 | Ici Plc | Bleach formulation & aqueous detergent compositions |
| GB8900525D0 (en) * | 1989-01-10 | 1989-03-08 | Procter & Gamble | Liquid detergent composition containing enzyme and enzyme stabilization system |
-
1989
- 1989-01-10 GB GB898900496A patent/GB8900496D0/en active Pending
-
1990
- 1990-01-05 AT AT90200026T patent/ATE109201T1/de not_active IP Right Cessation
- 1990-01-05 DE DE69010922T patent/DE69010922T2/de not_active Expired - Fee Related
- 1990-01-05 EP EP90200026A patent/EP0378261B1/en not_active Expired - Lifetime
- 1990-01-09 CA CA002007381A patent/CA2007381C/en not_active Expired - Fee Related
- 1990-01-09 TR TR90/0095A patent/TR25347A/xx unknown
- 1990-01-09 NZ NZ232055A patent/NZ232055A/xx unknown
- 1990-01-10 CN CN90100768.4A patent/CN1027080C/zh not_active Expired - Fee Related
- 1990-01-10 IE IE900097A patent/IE900097L/xx unknown
- 1990-01-10 AU AU47871/90A patent/AU638961B2/en not_active Ceased
- 1990-01-10 JP JP2003298A patent/JP2749416B2/ja not_active Expired - Fee Related
- 1990-01-10 PT PT92820A patent/PT92820A/pt not_active Application Discontinuation
- 1990-01-10 FI FI900130A patent/FI900130A/fi not_active Application Discontinuation
- 1990-01-10 MX MX019083A patent/MX172149B/es unknown
- 1990-10-22 EP EP90870197A patent/EP0482274A1/en not_active Withdrawn
-
1991
- 1991-10-15 CA CA002094604A patent/CA2094604C/en not_active Expired - Fee Related
- 1991-10-15 AU AU89523/91A patent/AU662501B2/en not_active Ceased
- 1991-10-15 WO PCT/US1991/007606 patent/WO1992007055A1/en active Application Filing
- 1991-10-15 JP JP3518590A patent/JPH06502440A/ja active Pending
- 1991-10-21 NZ NZ240293A patent/NZ240293A/en unknown
- 1991-10-21 IE IE368591A patent/IE913685A1/en not_active Application Discontinuation
- 1991-10-21 MX MX9101678A patent/MX9101678A/es unknown
- 1991-10-21 AR AR91320962A patent/AR244323A1/es active
- 1991-10-22 MY MYPI91001948A patent/MY108663A/en unknown
- 1991-10-22 PT PT99296A patent/PT99296A/pt not_active Application Discontinuation
- 1991-10-22 CN CN91111077.1A patent/CN1030333C/zh not_active Expired - Lifetime
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| 8363 | Opposition against the patent | ||
| 8365 | Fully valid after opposition proceedings | ||
| 8339 | Ceased/non-payment of the annual fee |