IE913685A1 - Liquid detergent compositions containing a suspended¹peroxygen bleach - Google Patents
Liquid detergent compositions containing a suspended¹peroxygen bleachInfo
- Publication number
- IE913685A1 IE913685A1 IE368591A IE368591A IE913685A1 IE 913685 A1 IE913685 A1 IE 913685A1 IE 368591 A IE368591 A IE 368591A IE 368591 A IE368591 A IE 368591A IE 913685 A1 IE913685 A1 IE 913685A1
- Authority
- IE
- Ireland
- Prior art keywords
- water
- liquid detergent
- composition according
- solid
- acid
- Prior art date
Links
- 239000000203 mixture Substances 0.000 title claims abstract description 69
- 239000003599 detergent Substances 0.000 title claims abstract description 33
- 239000007788 liquid Substances 0.000 title claims abstract description 25
- 239000007844 bleaching agent Substances 0.000 title claims description 17
- 150000001875 compounds Chemical class 0.000 claims description 26
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical group CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 23
- 239000002245 particle Substances 0.000 claims description 15
- 239000007787 solid Substances 0.000 claims description 15
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 14
- 239000003960 organic solvent Substances 0.000 claims description 13
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 claims description 11
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 9
- 239000007791 liquid phase Substances 0.000 claims description 9
- 229910052760 oxygen Inorganic materials 0.000 claims description 9
- 239000001301 oxygen Substances 0.000 claims description 9
- 150000004682 monohydrates Chemical class 0.000 claims description 5
- 150000004685 tetrahydrates Chemical class 0.000 claims description 5
- 125000001931 aliphatic group Chemical group 0.000 claims description 3
- 238000001953 recrystallisation Methods 0.000 claims description 3
- MWNQXXOSWHCCOZ-UHFFFAOYSA-L sodium;oxido carbonate Chemical compound [Na+].[O-]OC([O-])=O MWNQXXOSWHCCOZ-UHFFFAOYSA-L 0.000 claims description 2
- 102000004190 Enzymes Human genes 0.000 abstract description 8
- 108090000790 Enzymes Proteins 0.000 abstract description 8
- 150000001732 carboxylic acid derivatives Chemical class 0.000 abstract 1
- 150000001735 carboxylic acids Chemical class 0.000 abstract 1
- 230000006641 stabilisation Effects 0.000 abstract 1
- 238000011105 stabilization Methods 0.000 abstract 1
- 230000000087 stabilizing effect Effects 0.000 abstract 1
- 125000004432 carbon atom Chemical group C* 0.000 description 16
- 125000000217 alkyl group Chemical group 0.000 description 12
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 12
- -1 mono-long chain quaternary ammonium compounds Chemical class 0.000 description 11
- 239000004094 surface-active agent Substances 0.000 description 11
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 10
- 150000003839 salts Chemical class 0.000 description 9
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 8
- 239000003945 anionic surfactant Substances 0.000 description 8
- 239000004435 Oxo alcohol Substances 0.000 description 7
- 239000007859 condensation product Substances 0.000 description 7
- 150000002191 fatty alcohols Chemical class 0.000 description 7
- 150000004760 silicates Chemical class 0.000 description 7
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 6
- 239000000654 additive Substances 0.000 description 6
- 229940088598 enzyme Drugs 0.000 description 6
- 239000002736 nonionic surfactant Substances 0.000 description 6
- 239000012071 phase Substances 0.000 description 6
- 239000003381 stabilizer Substances 0.000 description 6
- JSPLKZUTYZBBKA-UHFFFAOYSA-N trioxidane Chemical class OOO JSPLKZUTYZBBKA-UHFFFAOYSA-N 0.000 description 6
- 125000000129 anionic group Chemical group 0.000 description 5
- 239000004615 ingredient Substances 0.000 description 5
- 229910052708 sodium Inorganic materials 0.000 description 5
- 239000011734 sodium Substances 0.000 description 5
- BAERPNBPLZWCES-UHFFFAOYSA-N (2-hydroxy-1-phosphonoethyl)phosphonic acid Chemical compound OCC(P(O)(O)=O)P(O)(O)=O BAERPNBPLZWCES-UHFFFAOYSA-N 0.000 description 4
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 4
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 description 4
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 4
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 4
- 239000002253 acid Substances 0.000 description 4
- 229910052681 coesite Inorganic materials 0.000 description 4
- 229910052906 cristobalite Inorganic materials 0.000 description 4
- 235000014113 dietary fatty acids Nutrition 0.000 description 4
- 239000000194 fatty acid Substances 0.000 description 4
- 229930195729 fatty acid Natural products 0.000 description 4
- 230000002209 hydrophobic effect Effects 0.000 description 4
- 239000000377 silicon dioxide Substances 0.000 description 4
- 235000012239 silicon dioxide Nutrition 0.000 description 4
- 239000002904 solvent Substances 0.000 description 4
- 229910052682 stishovite Inorganic materials 0.000 description 4
- 150000003871 sulfonates Chemical class 0.000 description 4
- 150000003467 sulfuric acid derivatives Chemical class 0.000 description 4
- 229910052905 tridymite Inorganic materials 0.000 description 4
- WVDDGKGOMKODPV-UHFFFAOYSA-N Benzyl alcohol Chemical compound OCC1=CC=CC=C1 WVDDGKGOMKODPV-UHFFFAOYSA-N 0.000 description 3
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 3
- 239000004280 Sodium formate Substances 0.000 description 3
- 150000004996 alkyl benzenes Chemical class 0.000 description 3
- 239000003093 cationic surfactant Substances 0.000 description 3
- 150000001768 cations Chemical class 0.000 description 3
- 238000002425 crystallisation Methods 0.000 description 3
- 230000008025 crystallization Effects 0.000 description 3
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 description 3
- 238000004090 dissolution Methods 0.000 description 3
- 239000003792 electrolyte Substances 0.000 description 3
- 230000002255 enzymatic effect Effects 0.000 description 3
- 150000004665 fatty acids Chemical class 0.000 description 3
- 238000011065 in-situ storage Methods 0.000 description 3
- 239000000463 material Substances 0.000 description 3
- 238000000034 method Methods 0.000 description 3
- 239000000047 product Substances 0.000 description 3
- HLBBKKJFGFRGMU-UHFFFAOYSA-M sodium formate Chemical compound [Na+].[O-]C=O HLBBKKJFGFRGMU-UHFFFAOYSA-M 0.000 description 3
- 235000019254 sodium formate Nutrition 0.000 description 3
- 239000000725 suspension Substances 0.000 description 3
- 239000003760 tallow Substances 0.000 description 3
- DNIAPMSPPWPWGF-GSVOUGTGSA-N (R)-(-)-Propylene glycol Chemical compound C[C@@H](O)CO DNIAPMSPPWPWGF-GSVOUGTGSA-N 0.000 description 2
- QDCPNGVVOWVKJG-VAWYXSNFSA-N 2-[(e)-dodec-1-enyl]butanedioic acid Chemical compound CCCCCCCCCC\C=C\C(C(O)=O)CC(O)=O QDCPNGVVOWVKJG-VAWYXSNFSA-N 0.000 description 2
- SVTBMSDMJJWYQN-UHFFFAOYSA-N 2-methylpentane-2,4-diol Chemical compound CC(O)CC(C)(C)O SVTBMSDMJJWYQN-UHFFFAOYSA-N 0.000 description 2
- CIWBSHSKHKDKBQ-JLAZNSOCSA-N Ascorbic acid Chemical compound OC[C@H](O)[C@H]1OC(=O)C(O)=C1O CIWBSHSKHKDKBQ-JLAZNSOCSA-N 0.000 description 2
- LSNNMFCWUKXFEE-UHFFFAOYSA-M Bisulfite Chemical compound OS([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-M 0.000 description 2
- 235000013162 Cocos nucifera Nutrition 0.000 description 2
- 244000060011 Cocos nucifera Species 0.000 description 2
- LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical compound CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 description 2
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 2
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 2
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 description 2
- 150000001336 alkenes Chemical class 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- 238000004061 bleaching Methods 0.000 description 2
- 150000007942 carboxylates Chemical class 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- 235000019864 coconut oil Nutrition 0.000 description 2
- 239000003240 coconut oil Substances 0.000 description 2
- WJJMNDUMQPNECX-UHFFFAOYSA-N dipicolinic acid Chemical compound OC(=O)C1=CC=CC(C(O)=O)=N1 WJJMNDUMQPNECX-UHFFFAOYSA-N 0.000 description 2
- 238000007046 ethoxylation reaction Methods 0.000 description 2
- 150000002430 hydrocarbons Chemical class 0.000 description 2
- 125000004435 hydrogen atom Chemical group [H]* 0.000 description 2
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 2
- 125000002768 hydroxyalkyl group Chemical group 0.000 description 2
- 229960004592 isopropanol Drugs 0.000 description 2
- BDAGIHXWWSANSR-UHFFFAOYSA-N methanoic acid Natural products OC=O BDAGIHXWWSANSR-UHFFFAOYSA-N 0.000 description 2
- SECPZKHBENQXJG-FPLPWBNLSA-N palmitoleic acid Chemical compound CCCCCC\C=C/CCCCCCCC(O)=O SECPZKHBENQXJG-FPLPWBNLSA-N 0.000 description 2
- 239000002304 perfume Substances 0.000 description 2
- 229920000058 polyacrylate Polymers 0.000 description 2
- 229920001223 polyethylene glycol Polymers 0.000 description 2
- 229910052700 potassium Inorganic materials 0.000 description 2
- 239000011591 potassium Substances 0.000 description 2
- BDERNNFJNOPAEC-UHFFFAOYSA-N propan-1-ol Chemical compound CCCO BDERNNFJNOPAEC-UHFFFAOYSA-N 0.000 description 2
- 238000005185 salting out Methods 0.000 description 2
- 241000894007 species Species 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- KDYFGRWQOYBRFD-UHFFFAOYSA-N succinic acid Chemical class OC(=O)CCC(O)=O KDYFGRWQOYBRFD-UHFFFAOYSA-N 0.000 description 2
- WRIDQFICGBMAFQ-UHFFFAOYSA-N (E)-8-Octadecenoic acid Natural products CCCCCCCCCC=CCCCCCCC(O)=O WRIDQFICGBMAFQ-UHFFFAOYSA-N 0.000 description 1
- LNFLHXZJCVGTSO-UHFFFAOYSA-N 1-(3-butoxypropoxy)propan-1-ol Chemical compound CCCCOCCCOC(O)CC LNFLHXZJCVGTSO-UHFFFAOYSA-N 0.000 description 1
- IDQBJILTOGBZCR-UHFFFAOYSA-N 1-butoxypropan-1-ol Chemical compound CCCCOC(O)CC IDQBJILTOGBZCR-UHFFFAOYSA-N 0.000 description 1
- XNWFRZJHXBZDAG-UHFFFAOYSA-N 2-METHOXYETHANOL Chemical compound COCCO XNWFRZJHXBZDAG-UHFFFAOYSA-N 0.000 description 1
- POAOYUHQDCAZBD-UHFFFAOYSA-N 2-butoxyethanol Chemical compound CCCCOCCO POAOYUHQDCAZBD-UHFFFAOYSA-N 0.000 description 1
- ZNQVEEAIQZEUHB-UHFFFAOYSA-N 2-ethoxyethanol Chemical compound CCOCCO ZNQVEEAIQZEUHB-UHFFFAOYSA-N 0.000 description 1
- LQJBNNIYVWPHFW-UHFFFAOYSA-N 20:1omega9c fatty acid Natural products CCCCCCCCCCC=CCCCCCCCC(O)=O LQJBNNIYVWPHFW-UHFFFAOYSA-N 0.000 description 1
- OSWFIVFLDKOXQC-UHFFFAOYSA-N 4-(3-methoxyphenyl)aniline Chemical compound COC1=CC=CC(C=2C=CC(N)=CC=2)=C1 OSWFIVFLDKOXQC-UHFFFAOYSA-N 0.000 description 1
- XSVSPKKXQGNHMD-UHFFFAOYSA-N 5-bromo-3-methyl-1,2-thiazole Chemical compound CC=1C=C(Br)SN=1 XSVSPKKXQGNHMD-UHFFFAOYSA-N 0.000 description 1
- 239000005725 8-Hydroxyquinoline Substances 0.000 description 1
- QSBYPNXLFMSGKH-UHFFFAOYSA-N 9-Heptadecensaeure Natural products CCCCCCCC=CCCCCCCCC(O)=O QSBYPNXLFMSGKH-UHFFFAOYSA-N 0.000 description 1
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 1
- 102000013142 Amylases Human genes 0.000 description 1
- 108010065511 Amylases Proteins 0.000 description 1
- 239000004215 Carbon black (E152) Substances 0.000 description 1
- 102000005575 Cellulases Human genes 0.000 description 1
- 108010084185 Cellulases Proteins 0.000 description 1
- RWSOTUBLDIXVET-UHFFFAOYSA-N Dihydrogen sulfide Chemical class S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 description 1
- 239000004367 Lipase Substances 0.000 description 1
- 102000004882 Lipase Human genes 0.000 description 1
- 108090001060 Lipase Proteins 0.000 description 1
- 239000005642 Oleic acid Substances 0.000 description 1
- ZQPPMHVWECSIRJ-UHFFFAOYSA-N Oleic acid Natural products CCCCCCCCC=CCCCCCCCC(O)=O ZQPPMHVWECSIRJ-UHFFFAOYSA-N 0.000 description 1
- 229910019142 PO4 Inorganic materials 0.000 description 1
- 235000021319 Palmitoleic acid Nutrition 0.000 description 1
- 102000035195 Peptidases Human genes 0.000 description 1
- 108091005804 Peptidases Proteins 0.000 description 1
- 239000002202 Polyethylene glycol Substances 0.000 description 1
- 239000004111 Potassium silicate Substances 0.000 description 1
- GOOHAUXETOMSMM-UHFFFAOYSA-N Propylene oxide Chemical compound CC1CO1 GOOHAUXETOMSMM-UHFFFAOYSA-N 0.000 description 1
- 239000004365 Protease Substances 0.000 description 1
- 239000004115 Sodium Silicate Substances 0.000 description 1
- VMHLLURERBWHNL-UHFFFAOYSA-M Sodium acetate Chemical compound [Na+].CC([O-])=O VMHLLURERBWHNL-UHFFFAOYSA-M 0.000 description 1
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 1
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 1
- YDONNITUKPKTIG-UHFFFAOYSA-N [Nitrilotris(methylene)]trisphosphonic acid Chemical compound OP(O)(=O)CN(CP(O)(O)=O)CP(O)(O)=O YDONNITUKPKTIG-UHFFFAOYSA-N 0.000 description 1
- 239000003082 abrasive agent Substances 0.000 description 1
- 230000002378 acidificating effect Effects 0.000 description 1
- 150000001252 acrylic acid derivatives Chemical class 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 229910052783 alkali metal Inorganic materials 0.000 description 1
- 150000001340 alkali metals Chemical class 0.000 description 1
- 125000002877 alkyl aryl group Chemical group 0.000 description 1
- 150000008051 alkyl sulfates Chemical class 0.000 description 1
- 229910000323 aluminium silicate Inorganic materials 0.000 description 1
- 125000003368 amide group Chemical group 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
- 235000019418 amylase Nutrition 0.000 description 1
- 229940025131 amylases Drugs 0.000 description 1
- 230000000844 anti-bacterial effect Effects 0.000 description 1
- 125000003118 aryl group Chemical group 0.000 description 1
- 235000010323 ascorbic acid Nutrition 0.000 description 1
- 229960005070 ascorbic acid Drugs 0.000 description 1
- 239000011668 ascorbic acid Substances 0.000 description 1
- 239000003899 bactericide agent Substances 0.000 description 1
- 229940077388 benzenesulfonate Drugs 0.000 description 1
- 235000019445 benzyl alcohol Nutrition 0.000 description 1
- 229960004217 benzyl alcohol Drugs 0.000 description 1
- 229910021538 borax Inorganic materials 0.000 description 1
- CMFFZBGFNICZIS-UHFFFAOYSA-N butanedioic acid;2,3-dihydroxybutanedioic acid Chemical compound OC(=O)CCC(O)=O.OC(=O)CCC(O)=O.OC(=O)C(O)C(O)C(O)=O CMFFZBGFNICZIS-UHFFFAOYSA-N 0.000 description 1
- HXDRSFFFXJISME-UHFFFAOYSA-N butanedioic acid;2,3-dihydroxybutanedioic acid Chemical compound OC(=O)CCC(O)=O.OC(=O)C(O)C(O)C(O)=O HXDRSFFFXJISME-UHFFFAOYSA-N 0.000 description 1
- 239000004202 carbamide Substances 0.000 description 1
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 1
- 239000003054 catalyst Substances 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 239000007795 chemical reaction product Substances 0.000 description 1
- SECPZKHBENQXJG-UHFFFAOYSA-N cis-palmitoleic acid Natural products CCCCCCC=CCCCCCCCC(O)=O SECPZKHBENQXJG-UHFFFAOYSA-N 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 238000009833 condensation Methods 0.000 description 1
- 230000005494 condensation Effects 0.000 description 1
- 229920001577 copolymer Polymers 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- 210000003298 dental enamel Anatomy 0.000 description 1
- SZXQTJUDPRGNJN-UHFFFAOYSA-N dipropylene glycol Chemical compound OCCCOCCCO SZXQTJUDPRGNJN-UHFFFAOYSA-N 0.000 description 1
- 238000004851 dishwashing Methods 0.000 description 1
- 239000012153 distilled water Substances 0.000 description 1
- DUYCTCQXNHFCSJ-UHFFFAOYSA-N dtpmp Chemical compound OP(=O)(O)CN(CP(O)(O)=O)CCN(CP(O)(=O)O)CCN(CP(O)(O)=O)CP(O)(O)=O DUYCTCQXNHFCSJ-UHFFFAOYSA-N 0.000 description 1
- 239000000975 dye Substances 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000011067 equilibration Methods 0.000 description 1
- 150000002170 ethers Chemical class 0.000 description 1
- 125000001301 ethoxy group Chemical group [H]C([H])([H])C([H])([H])O* 0.000 description 1
- 239000004744 fabric Substances 0.000 description 1
- 235000019253 formic acid Nutrition 0.000 description 1
- 229910052736 halogen Inorganic materials 0.000 description 1
- 150000002367 halogens Chemical class 0.000 description 1
- 229940051250 hexylene glycol Drugs 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- QXJSBBXBKPUZAA-UHFFFAOYSA-N isooleic acid Natural products CCCCCCCC=CCCCCCCCCC(O)=O QXJSBBXBKPUZAA-UHFFFAOYSA-N 0.000 description 1
- 235000019421 lipase Nutrition 0.000 description 1
- ZDGGJQMSELMHLK-UHFFFAOYSA-N m-Trifluoromethylhippuric acid Chemical compound OC(=O)CNC(=O)C1=CC=CC(C(F)(F)F)=C1 ZDGGJQMSELMHLK-UHFFFAOYSA-N 0.000 description 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- DNIAPMSPPWPWGF-UHFFFAOYSA-N monopropylene glycol Natural products CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 1
- 230000003472 neutralizing effect Effects 0.000 description 1
- MGFYIUFZLHCRTH-UHFFFAOYSA-N nitrilotriacetic acid Chemical compound OC(=O)CN(CC(O)=O)CC(O)=O MGFYIUFZLHCRTH-UHFFFAOYSA-N 0.000 description 1
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 1
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(O)=O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 description 1
- 239000003605 opacifier Substances 0.000 description 1
- 229960003540 oxyquinoline Drugs 0.000 description 1
- 239000012188 paraffin wax Substances 0.000 description 1
- 150000004976 peroxydisulfates Chemical class 0.000 description 1
- 125000005342 perphosphate group Chemical group 0.000 description 1
- JRKICGRDRMAZLK-UHFFFAOYSA-L persulfate group Chemical group S(=O)(=O)([O-])OOS(=O)(=O)[O-] JRKICGRDRMAZLK-UHFFFAOYSA-L 0.000 description 1
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 1
- 239000010452 phosphate Substances 0.000 description 1
- XYFCBTPGUUZFHI-UHFFFAOYSA-O phosphonium Chemical compound [PH4+] XYFCBTPGUUZFHI-UHFFFAOYSA-O 0.000 description 1
- NNHHDJVEYQHLHG-UHFFFAOYSA-N potassium silicate Chemical compound [K+].[K+].[O-][Si]([O-])=O NNHHDJVEYQHLHG-UHFFFAOYSA-N 0.000 description 1
- 235000019353 potassium silicate Nutrition 0.000 description 1
- 229910052913 potassium silicate Inorganic materials 0.000 description 1
- 235000013772 propylene glycol Nutrition 0.000 description 1
- 150000003856 quaternary ammonium compounds Chemical class 0.000 description 1
- MCJGNVYPOGVAJF-UHFFFAOYSA-N quinolin-8-ol Chemical compound C1=CN=C2C(O)=CC=CC2=C1 MCJGNVYPOGVAJF-UHFFFAOYSA-N 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 238000005070 sampling Methods 0.000 description 1
- 150000004671 saturated fatty acids Chemical class 0.000 description 1
- 235000003441 saturated fatty acids Nutrition 0.000 description 1
- 238000002791 soaking Methods 0.000 description 1
- 239000001632 sodium acetate Substances 0.000 description 1
- 235000017281 sodium acetate Nutrition 0.000 description 1
- 235000012217 sodium aluminium silicate Nutrition 0.000 description 1
- 229910000029 sodium carbonate Inorganic materials 0.000 description 1
- FQENQNTWSFEDLI-UHFFFAOYSA-J sodium diphosphate Chemical compound [Na+].[Na+].[Na+].[Na+].[O-]P([O-])(=O)OP([O-])([O-])=O FQENQNTWSFEDLI-UHFFFAOYSA-J 0.000 description 1
- NVIFVTYDZMXWGX-UHFFFAOYSA-N sodium metaborate Chemical compound [Na+].[O-]B=O NVIFVTYDZMXWGX-UHFFFAOYSA-N 0.000 description 1
- 229960001922 sodium perborate Drugs 0.000 description 1
- 239000012418 sodium perborate tetrahydrate Substances 0.000 description 1
- 229940048086 sodium pyrophosphate Drugs 0.000 description 1
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 description 1
- 229910052911 sodium silicate Inorganic materials 0.000 description 1
- 239000004328 sodium tetraborate Substances 0.000 description 1
- 235000010339 sodium tetraborate Nutrition 0.000 description 1
- 235000019832 sodium triphosphate Nutrition 0.000 description 1
- IBDSNZLUHYKHQP-UHFFFAOYSA-N sodium;3-oxidodioxaborirane;tetrahydrate Chemical compound O.O.O.O.[Na+].[O-]B1OO1 IBDSNZLUHYKHQP-UHFFFAOYSA-N 0.000 description 1
- YKLJGMBLPUQQOI-UHFFFAOYSA-M sodium;oxidooxy(oxo)borane Chemical compound [Na+].[O-]OB=O YKLJGMBLPUQQOI-UHFFFAOYSA-M 0.000 description 1
- 239000011343 solid material Substances 0.000 description 1
- 239000007790 solid phase Substances 0.000 description 1
- 125000001424 substituent group Chemical group 0.000 description 1
- 150000005846 sugar alcohols Polymers 0.000 description 1
- 230000001180 sulfating effect Effects 0.000 description 1
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 description 1
- 235000019818 tetrasodium diphosphate Nutrition 0.000 description 1
- 239000001577 tetrasodium phosphonato phosphate Substances 0.000 description 1
- 230000009974 thixotropic effect Effects 0.000 description 1
- 238000004448 titration Methods 0.000 description 1
- 235000021122 unsaturated fatty acids Nutrition 0.000 description 1
- 150000004670 unsaturated fatty acids Chemical class 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
- 239000003021 water soluble solvent Substances 0.000 description 1
- 239000010457 zeolite Substances 0.000 description 1
- 239000002888 zwitterionic surfactant Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/04—Water-soluble compounds
- C11D3/08—Silicates
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/38—Products with no well-defined composition, e.g. natural products
- C11D3/386—Preparations containing enzymes, e.g. protease or amylase
- C11D3/38663—Stabilised liquid enzyme compositions
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/39—Organic or inorganic per-compounds
- C11D3/3947—Liquid compositions
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Detergent Compositions (AREA)
Abstract
Stabilization systems for aqueous liquid detergent compositions containing detergent enzymes and peroxygen bleaches are disclosed. The detergent compositions contain a carboxylic acid or a mixture of carboxylic acids as an enzyme stabilizing system.
Description
LIQUID DETERGENT COMPOSITIONS CONTAINING A SUSPENDED PEROXYGEN BLEACH Technical Field The invention relates to liquid detergent compositions which contain a suspending solid peroxygen compound, and low levels of silicate.
Background Answering the long-felt need for bleach-containing aqueous liquid detergent compositions, European Patent Application 293 040 and 294 904, have described aqueous detergent compositions having a pH above 8, containing an anionic surfactant at conventional levels, and a solid - 2 peroxygen bleach, suspended in a specific water/solvent medium, which medium was found to give the required chemical stability to the composition.
In such compositions however, particular attention has to be given to the physical stability of suspended particles in the liquid medium.
One option is represented by e.g. copending U.K. Application No. 8926620.9, describing liquid detergent compositions in which solid particles, in particular particles of a peroxygen compound, are suspended by means of a structured surfactant phase (surfactant neat phase). There is a need, however, for suspending systems which involve easier processing, compared to structured surfactant phases.
Although not for the purpose of suspending peroxygen bleach particles, structured surfactant phases have been described in various patent documents; In particular EP-A-79 646, EP-A-86 614, EP-A-203 660 and EP-A-295 021 describe liquid detergent compositions containing suspended builder particles where one or more salting-out electrolytes, or surfactant desolubilizing electrolytes are used, to build structured phases with the surfactant materials; Such electrolytes include, among many other substances, silicates, and need to be used at substantial levels, i.e. above 5%, in order to perform their salting-out effect.
Other patent documents disclosing the use of silicates in cleaning/detergent compositions of the suspending type include GB-A-2031455, and GB-A-1342612 wherein the solid materials to be suspended include abrasives and - 3 water-insoluble phosphate builder salts, but do not encompass peroxygen bleach particles; actually, GB-A-2158453 which mentions perborate as a possible bleaching ingredient in liquid compositions of the suspending type specifically advocates that the compositions must be free of silicate, and instead must contain a carboxylic antigelling agent.
Silicates have also been widely described as alkalinity-building ingredients of aqueous thixotropic liquid compositions used for e.g. automatic dishwashing purposes. Representative of this art is EP 315 024, disclosing levels of silicate in the range of 25% to 40%.
It has now surprisingly been found that low levels of silicate can efficiently suspend peroxygen-bleach particles in liquid detergent compositions of the type described in EP-A-293 040, with only a moderate increase in the viscosity of the composition.
The present suspension system does not involve any specific processing difficulty; furthermore the presence of silicate brings such advantages as increased alkaiity and increased washing-machine compatibility.
The present invention therefore provides perfectly phase-stable aqueous liquid detergent compositions containing a solid peroxygen bleach compound, a liquid phase consisting of water and a water-miscible organic solvent, and low levels of silicate to suspend the peroxygen bleach particles in the liquid phase. - 4 Summary The present invention relates to stable liquid detergent compositions having a pH of at least 8 and less than about 11, comprising a solid, water-soluble peroxygen compound suspended in a liquid phase containing water and at least one water-miscible organic solvent, the amount of the solid water-soluble peroxygen compound being such that the amount of available oxygen provided by said peroxygen compound is from 0.5% to 3%, said compositions containing from 0.5% to 5%, preferably 1% to 3%, by weight of silicate.
Detailed Description The water-soluble peroxyqen compound The water-soluble solid peroxygen compound is present in the compositions herein preferably at levels of from 5 to 50% by weight of the total composition, more preferably from 5 to 40%, even more preferably from 5% to 30%, most preferably from 10% to 30% by weight.
Examples of suitable water-soluble solid peroxygen compounds include the perborates, persulfates, peroxydisulfates, perphosphates and the crystalline peroxyhydrates formed by reacting hydrogen peroxide with sodium carbonate (forming percarbonate) or urea. Preferred peroxygen bleach compounds are perborates and percarbonates.
Most preferred in the present context is a perborate bleach in the form of particles having a weight-average an - 5 average particle diameter of from 0.5 to 20 micrometers, preferably 3 to 15 micrometers.
The small average particle size can best be achieved by in-situ crystallization, typically of perborate monohydrate.
In-situ crystallization encompasses processes involving dissolution and recrystallization, as in the dissolution of perborate monohydrate and subsequent formation of perborate tetrahydrate. Recrystallization may also take place by allowing perborate monohydrate to take up crystal water, whereby the monohydrate directly recrystallizes into the tetrahydrate, without dissolution step.
In-situ crystallization also encompasses processes involving chemical reactions, as when sodium perborate is formed by reacting stoichiometric amounts of hydrogen peroxide and sodium metaborate or borax.
The water-miscible organic solvent The suspension system for the solid peroxygen component herein consists in a liquid phase that comprises water and a water-miscible organic solvent. This makes it possible to incorporate in the liquid detergent compositions herein a high amount of solid water-soluble peroxygen compound, while keeping the amount of available oxygen in solution below 0.5% by weight of the liquid phase, preferably below 0.1%. Less than one tenth of the total amount of peroxygen compound is dissolved in the liquid phase; the low level of available oxygen in solution is in fact critical for the stability of the system. - 6 The standard iodometric method (as described for instance in Methoden der Organischen Chemie, Houben Weyl, 1953, Vo. 2, page 562) is suitable to determine the available oxygen (AVO) content of the composition.
In order to ensure complete equilibration between liquid and solid phases, the compositions are to be kept after mixing for three days at room temperature before the AVO titration. Before measuring the products are thoroughly shaken in order to ensure correct sampling.
For the determination of the available oxygen (AVO) in the liquid phase, samples of the compositions are centrifuged for 10 minutes at 10.000 rpm. The liquid is then separated from the solid and titrated for available oxygen.
It is not necessary that the organic solvent be fully miscible with water, provided that enough of the solvent mixes with the water of the composition to affect the solubility of the peroxygen compound in the described manner. Fully water-soluble solvents are preferred for use herein.
The water-miscible organic solvent must, of course, be compatible with the peroxygen bleach compound at the pH that is used. Therefore, polyalcohols having vicinal hydroxy groups (e.g. 1,2-propanediol and glycerol) are less desirable when the peroxygen bleach compound is perborate.
Examples of suitable water-miscible organic solvents include the lower aliphatic monoalcohols; ethers of diethylene glycol and lower monoaliphatic monoalcohols; specifically ethanol, n-propanol; iso-propanol; butanol; - 7 polyethylene glycol (e.g., PEG 150, 200, 300, 400); dipropylene glycol; hexylene glycol; methoxyethanol; ethoxyethanol; butoxyethanol; ethyldiglycolether; benzylalcohol; butoxypropanol; butoxypropoxypropanol; and mixtures thereof. Preferred solvents include ethanol; isopropanol, l-methoxy-2-propanol and butyldiglycolether.
A preferred solvent system is ethanol. Ethanol may be preferably present in a water:ethanol ratio of 8:1 to 1:3.
Although the presence or absence of other ingredients plays a role, the amount of available oxygen in solution is largely determined by the ratio water:organic solvent. It is not necessary however to use more organic solvent than is needed to keep the amount of available oxygen in solution below 0.5%, preferably below 0.1%.
In practical terms, the ratio water:organic solvent is, for most systems, in the range from 5:1 to 1:3, preferably from 4:1 to 1:2.
The silicate The silicates are present in the present composition at levels of from 0.5% to 5%, preferably from 1% to 3%. The addition of silicates at such low levels cannot promote the formation of a structured surfactant phase, but surprisingly allows for an efficient and stable suspension of the peroxygen bleach particles, with only a moderate increase in the viscosity of the composition.
The silicate materials for use herein can be natural silicates with a ratio of SiO2 to Na20 of from 1:1 to 4:1, preferably 1:1 (metasilicate), 1.6:1 or 2:1. - 8 Preferred is sodium silicate, while potassium silicate can also be used.
Synthetic silicates can be used for the purpose of the present invention, such as Sydej^l20, with a ratio of SiO2 to MgO of 3.5:1.
The present liquid detergent compositions with bleach exhibit a pH (1% solution in distilled water) of at least 8 and less than about 11, preferably of at least 9, more preferably at least 9.5. The alkaline pH allows good bleaching action of the peroxygen compound, particularly when the peroxygen is a perborate.
Surfactants The compositions herein preferably contain a nonionic or cationic surfactant, or a mixture thereof, at total levels of from 1% to 20%, most preferably from 3% to 10%.
The nonionic surfactants are conventionally produced by condensing ethylene oxide with a hydrocarbon having a reactive hydrogen atom, e.g., a hydroxyl, carboxyl, or amido group, in the presence of an acidic or basic catalyst, and include compounds having the general formula RA(CH2CH2O)nH wherein R represents the hydrophobic moiety, A represents the group carrying the reactive hydrogen atom and n represents the average number of ethylene oxide moieties. R typically contains from about 8 to 22 carbon atoms. They can also be formed by the condensation of propylene oxide with a lower molecular weight compound, n usually varies from about 2 to about 24. - 9 The hydrophobic moiety of the nonionic compound is preferably a primary or secondary, straight or branched, aliphatic alcohol having from about 8 to about 24, preferably from about 12 to about 20 carbon atoms. A more complete disclosure of suitable nonionic surfactants can be found in U.S. Patent 4,111,855. Mixtures of nonionic surfactants can be desirable.
A preferred class of nonionic ethoxylates is represented by the condensation product of a fatty alcohol having from 12 to 15 carbon atoms and from about 4 to 10 moles of ethylene oxide per mole of fatty alcohol.
Suitable species of this class of ethoxylates include : the condensation product of C12-C15 oxo-alcohols and 7 moles of ethylene oxide per mole of alcohol; the condensation product of narrow cut C14-C15 oxo-alcohols and 7 or 9 moles of ethylene oxide per mole of fatty(oxo)alcohol; the condensation product of a narrow cut c12-c13 fattY(oxo)alc°hol and 6,5 moles of ethylene oxide per mole of fatty alcohol; and the condensation products of a C10-C14 coconut fatty alcohol with a degree of ethoxylation (moles EO/mole fatty alcohol) in the range from 5 to 8. The fatty oxo-alcohols while mainly linear can have, depending upon the processing conditions and raw material olefins, a certain degree of branching, particularly short chain such as methyl branching.
A degree of branching in the range from 15% to 50% (weight %) is frequently found in commercial oxo alcohols.
Preferred nonionic ethoxylated components can also be represented by a mixture of 2 separately ethoxylated nonionic surfactants having a different degree of ethoxylation. For example, the nonionic ethoxylate - 10 surfactant containing from 3 to 7 moles of ethylene oxide per mole of hydrophobic moiety and a second ethoxylated species having from 8 to 14 moles of ethylene oxide per mole of hydrophobic moiety. A preferred nonionic ethoxylated mixture contains a lower ethoxylate which is the condensation product of a Ci2-C15 oxo-alc°hol, with up to 50% (wt) branching, and from about 3 to 7 moles of ethylene oxide per mole of fatty oxo-alcohol, and a higher ethoxylate which is the condensation product of a C16-C19 oxo-alcohol with more than 50% (wt) branching and from about 8 to 14 moles of ethylene oxide per mole of branched oxo-alcohol.
Semi-polar nonionic surfactants include water-soluble amine oxides containing one alkyl or hydroxy alkyl moiety of from about 8 to about 28 carbon atoms and two moieties selected from the group consisting of alkyl groups and hydroxy alkyl groups, containing from 1 to about 3 carbon atoms which can optionally be joined into ring structures.
The liquid detergent compositions of the present invention optionally contain a cationic surfactant, preferably from 0.1% to 10%, more preferably 0.1% to 5%, by weight of the composition.
Examples of suitable cationic surfactants include quaternary ammonium compounds of the formula R1R2R3R4N+X_' where^n Rl is C12_C2O alkY1 or hydroxyalkyi; R2 is Cj-C^ alkyl or hydroxyalkyi or c12c20 or hydroxyalkyi or Cj-C4 hydroxyalkyi; R3 and R4 are each C3-C4 alkyl or hydroxyalkyi, or C6-CQ aryl or alkylaryl;. and X- is halogen. Preferred are mono-long chain quaternary ammonium compounds (i.e., compounds of the above formula wheren R2 is Cq-C4 alkyl or hydroxyalkyi).
- Il Zwitterionic surfactants which could be used in the compositions of the present invention include derivatives of aliphatic quaternary ammonium, phosphonium, and sulphonium compounds in which the aliphatic moiety can be straight or branched chain and wherein one of the aliphatic substituents contains from about 8 to about 24 carbon atoms and another substituent contains, at least, an anionic water-solubilizing group. Particularly preferred zwitterionic materials are the ethoxylated ammonium sulfonates and sulfates disclosed in U.S. Patents 3,925,262, Laughlin et al., issued December 9, 1975 and 3,929,678, Laughlin et al., issued December 30, 1975.
The compositions herein may also contain anionic surfactants. The anionic detergents are well-known in the detergent arts and have found wide-spread application in commercial detergents. Suitable anionic synthetic surface-active salts are selected from the group of sulfonates and sulfates. Preferred anionic synthetic water-soluble sulfonate or sulfate salts have in their molecular structure an alkyl radical containing from about 8 to about 22 carbon atoms.
Accordingly, anionic surfactants, if used, are present at levels up to 40% by weight, preferably from 1% to 30% by weight, even more preferably from 5% to 20% by weight.
Synthetic anionic surfactants, can be represented by the general formula R1SO3M wherein R^ represents a hydrocarbon group selected from the group consisting of straight or branched alkyl radicals containing from about 8 to about 24 carbon atoms and alkyl phenyl radicals containing from about 9 to about 15 carbon atoms in the alkyl group. M is a salt forming cation which typically is - 12 selected from the group consisting of sodium, potassium, ammonium, and mixtures thereof.
A preferred synthetic anionic surfactant is a water-soluble salt of an alkylbenzene sulfonic acid containing from 9 to 15 carbon atoms in the alkyl group. Another preferred synthetic anionic surfactant is a water-soluble salt of an alkyl sulfate or an alkyl polyethoxylate ether sulfate wherein the alkyl group contains from about 8 to about 24, preferably from about 10 to about 20 carbon atoms, and preferably from about 1 to about 12 ethoxy groups. Other suitable anionic surfactants are disclosed in U.S. Patent 4,170,565, Flesher et al., issued October 9, 1979.
Examples of such preferred anionic surfactant salts are the reaction products obtained by sulfating Cg-C18 fatty alcohols derived from tallow and coconut oil; alkylbenzene sulfonates wherein the alkyl group contains from about 9 to 15 carbon atoms; sodium alkylglyceryl ether sulfonates; ether sulfates of fatty alcohols derived from tallow and coconut oils; coconut fatty acid monoglyceride sulfates and sulfonates; and water-soluble salts of paraffin sulfonates having from about 8 to about 22 carbon atoms in the alkyl chain. Sulfonated olefin surfactants as more fully described in e.g. U.S. Patent Specification 3,332,880 can also be used. The neutralizing cation for the anionic synthetic sulfonates and/or sulfates is represented by conventional cations which are widely used in detergent technology such as sodium and potassium.
A particularly preferred anionic synthetic surfactant component herein is represented by the water-soluble salts of an alkylbenzene sulfonic acid, preferably sodium - 13 IE 913685 alkylbenzene sulfonates having from about 10 to 13 carbon atoms in the alkyl group.
Builders The present compositions may contain a builder, preferably at a level no more than 50%, more preferably at a level of from 5% to 40% of the total composition.
If present, such builders can consist of the inorganic or organic types already described in the art.
The liquid detergent compositions herein optionally may contain, as a builder, a fatty acid component. Preferably, however, the amount of fatty acid is less than 10% by weight of the composition, more preferably less than 4%.
Preferred saturated fatty acids have from 10 to 16, more preferably 12 to 14 carbon atoms. Preferred unsaturated fatty acids are oleic acid and palmitoleic acid.
Examples of inorganic builders include the phosphourus-based builders, e.g., sodium tripolyphosphate, sodium pyrophosphate, and aluminosilicates (zeolites).
Examples of organic builders are represented by polyacids such as citric acid, nitrilotriacetic acid, and mixtures of tartrate monosuccinate with tartrate disuccinate. Preferred builders for use herein are citric acid and alk(en)yl-substituted succinic acid compounds, wherein alk(en)yl contains from 10 to 16 carbon atoms. An example of this group of compounds is dodecenyl succinic acid. Polymeric carboxylate builders inclusive of polyacrylates, polyhydroxy acrylates and polyacrylates/polymaleates copolymers can also be used, - 14 preferably in combination with the preferred builders above, i.e. citric acid and akl(en)yl substituted succinic acid compounds.
Other components/additives The compositions herein may also contain other components and/or additives at a level preferably less than about 5%. Non-limiting examples of such additives, which can more preferably be used at levels from 0.05% to 2%, include polyaminocarboxylate additives such as ethylenediaminotetracetic acid, diethylenetriamino-pentacetic acid, ethylenediamino disuccinic acid or the water-soluble alkali metals thereof. Other additives useful at these levels include organo-phosphonic acids; particularly preferred are ethylenediamino tetramethylenephosphonic acid, diethylenetriamino pentamethylenephosphonic acid and aminotrimethylenephosphonic acid, hydroxyethylidene diphosphonic acid. Bleach stabilizers such as ascorbic acid, dipicolinic acid, sodium stannates, 8-hydroxyquinoline, hydroxyethylidene diphosphonic acid (HEDP), and diethylenetriamine penta(methylene phosphonic acid) can also be included in these compositions at these levels, more preferably at levels from between 0.01 to 1%.
The compositions herein can contain a series of further optional ingredients which are mostly used in additive levels, usually below about 5%. Examples of the like include : polyacids, enzymes and enzymatic stabilizing agents, suds regulants, opacifiers, agents to improve the machine compatibility in relation to enamel-coated surfaces, bactericides, dyes, perfumes, brighteners, softeners and the like. - 15 As described above, detergent enzymes can be used in the liquid detergent compositions of this invention. In fact, one of the desirable features of the present compositions is that they are compatible with such detergent enzymes. Suitable enzymes include the detergent proteases, amylases, lipases and cellulases. Enzymatic stabilizing agents for use in liquid detergents are well known. Enzyme stabilizing agents, if used, are preferably in a range of from about 0.5% to 5%. Preferred enzymatic stabilizing agents for use herein are formic acid, acetic acid, and salts thereof, e.g. sodium formate and sodium acetate. More preferred stabilizing agents are sodium formate and acetic acid.
Use of the Compositions The present compositions are mainly intended to be used in the wash cycle of a washing machine? however, other uses can be contemplated, such as pretreatment product for heavily-soiled fabrics, or soaking product; the use is not necessarily limited to the washing-machine context, and the compositions of the present invention can be used alone or in combination with compatible handwash compositions.
Some typical liquid detergent compositions of the present invention have the following formulae : - 16 EXAMPLES Ingredients Composition wt% I II Ill IV V VI Linear alkyl benzene sulfonate 10 12 10 8 10 12c13"Ci5 alcohol ethoxylated (EO3) 5 0 0 10 5 3c13_c15 alc°hol ethoxylated (E07) 0 7 5 0 2 4 Citric Acid 2.5 3.5 4 1 2.5 3 Dodecenyl succinic acid 8.5 7 6.5 10 8.5 8 Polymeric carboxylate builder 1.5 1.5 2 1.5 1.5 1 Tallow fatty acid - 1.5 2 - - 1 Diethylenetriamino penta(methylene phosphonic acid) 0.5 0.5 0.4 0.5 0.5 0. Hydroxyethylidene diphosphonic acid 0.2 0.2 0.3 0.2 0.3 0. Sodium formate 1.5 1 1.5 1.5 1 2 Acetic acid 1.4 1.5 1.4 1.4 2 - Ethanol 8 10 12 10 14 14 Sodium perborate monohydrate 14 - 14 - - 14 Sodium perborate tetrahydrate - 20 - 22 20 - Silicate SiO2 to Na20 ratio 1.6 1 3 - - - - Silicate SiO2 to Na20 ratio 2.0 - - 1.5 3 - - Sydec® 120 - - - - 1 4 Sodium hydroxyde up pH 9.5 - Water + minors (perfume, brightener, enzymes,...) --------- balance to 100
Claims (9)
1. CIAIMS 1A stable liquid detergent composition having a pH of at least 8 and less than about 11, comprising a solid, water-soluble peroxygen compound suspended in a liquid phase containing water and at least one water-miscible organic solvent, the amount of the solid water-soluble peroxygen compound being such that the amount of available oxygen provided by said peroxygen compound is from 0.5% to 3%, said composition containing from 0.5% to 5% by weight of silicate.
2. A detergent composition, according to claim 1, wherein the silicate is present at a level of from 1% to 3%.
3. A liquid detergent composition according to claims 1 and 2, wherein the water-miscible organic solvent is an aliphatic monoalcohol.
4. A liquid detergent composition according to claim 2 wherein the water-miscible organic solvent is ethanol, and the water:ethanol ratio of from 8:1 to 1:3, preferably
5. :1 to 1:2. 4. A liquid detergent composition according to claims 1-3, wherein the solid, water-soluble peroxygen compound is perborate tetrahydrate, and present at levels of from 5% to 30% by weight of the total composition.
6. A composition according to claim 4 wherein the perborate tetrahydrate bleach is in the form of particles having a weight-average particle diameter of from 0.5 micrometer to 20 micrometer. -187.
7.A composition according to claim 5 wherein the perborate tetrahydrate particles have been formed by recrystallization of a perborate monohydrate.
8. A composition according to claims 1-3, wherein the solid, water-soluble peroxygen compound is a percarbonate.
9. A composition according to claim 1, substantially as hereinbefore described and exemplified.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB898900496A GB8900496D0 (en) | 1989-01-10 | 1989-01-10 | Liquid detergent composition containing enzyme and enzyme stabilization system |
EP90870197A EP0482274A1 (en) | 1989-01-10 | 1990-10-22 | Liquid detergent compositions containing a suspended peroxygen bleach |
Publications (1)
Publication Number | Publication Date |
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IE913685A1 true IE913685A1 (en) | 1992-04-22 |
Family
ID=40149609
Family Applications (2)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
IE900097A IE900097L (en) | 1989-01-10 | 1990-01-10 | Liquid detergent composition containing enzyme and enzyme¹stabilization system |
IE368591A IE913685A1 (en) | 1989-01-10 | 1991-10-21 | Liquid detergent compositions containing a suspended¹peroxygen bleach |
Family Applications Before (1)
Application Number | Title | Priority Date | Filing Date |
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IE900097A IE900097L (en) | 1989-01-10 | 1990-01-10 | Liquid detergent composition containing enzyme and enzyme¹stabilization system |
Country Status (17)
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EP (2) | EP0378261B1 (en) |
JP (2) | JP2749416B2 (en) |
CN (2) | CN1027080C (en) |
AR (1) | AR244323A1 (en) |
AT (1) | ATE109201T1 (en) |
AU (2) | AU638961B2 (en) |
CA (2) | CA2007381C (en) |
DE (1) | DE69010922T2 (en) |
FI (1) | FI900130A (en) |
GB (1) | GB8900496D0 (en) |
IE (2) | IE900097L (en) |
MX (2) | MX172149B (en) |
MY (1) | MY108663A (en) |
NZ (2) | NZ232055A (en) |
PT (2) | PT92820A (en) |
TR (1) | TR25347A (en) |
WO (1) | WO1992007055A1 (en) |
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DE10163884A1 (en) | 2001-12-22 | 2003-07-10 | Henkel Kgaa | New alkaline protease from Bacillus sp. (DSM 14392) and detergents and cleaning agents containing this new alkaline protease |
DE10257387A1 (en) | 2002-12-06 | 2004-06-24 | Henkel Kgaa | Dispensing bottle, used for applying toilet or hard surface cleaner, disinfectant, laundry or dish-washing detergent or corrosion inhibitor, has separate parts holding different active liquids mixing only after discharge from nozzles |
GB2392167A (en) * | 2002-08-22 | 2004-02-25 | Reckitt Benckiser Inc | Composition containing an acid with anionic and nonionic surfactants |
DE10303130A1 (en) * | 2003-01-28 | 2004-07-29 | Clariant Gmbh | Aqueous liquid detergent dispersion useful as a laundry detergent comprises anionic surfactant, builder and quaternary alkyl hydroxyethyl ammonium salt |
WO2007113241A1 (en) * | 2006-03-31 | 2007-10-11 | Novozymes A/S | A stabilized liquid enzyme composition |
US8071345B2 (en) | 2006-03-31 | 2011-12-06 | Novozymes A/S | Stabilized subtilisin composition |
DE102007011236A1 (en) * | 2007-03-06 | 2008-09-11 | Henkel Ag & Co. Kgaa | Carboxyl-bearing benzophenone or benzoic acid anilide derivatives as enzyme stabilizers |
JP5436199B2 (en) * | 2009-12-28 | 2014-03-05 | ライオン株式会社 | Method for producing liquid detergent composition |
CN105829519B (en) * | 2013-12-18 | 2020-10-02 | 阿科玛股份有限公司 | Stable liquid compositions comprising enzymes and peroxides |
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FR2140822A5 (en) * | 1971-06-09 | 1973-01-19 | Air Liquide | Bleaching liquids - contg hydrogen peroxide or persalts in alkaline medium with stabilisers |
CA1104451A (en) * | 1978-02-28 | 1981-07-07 | Manuel Juan De Luque | Detergent bleach composition and process |
US4377489A (en) * | 1981-03-16 | 1983-03-22 | Ceil Clean Corporation, Inc. | Inorganic persulfate cleaning solution for acoustic materials |
DE3364292D1 (en) * | 1982-02-03 | 1986-08-07 | Procter & Gamble | Oxygen-bleach-containing liquid detergent compositions |
US4529525A (en) * | 1982-08-30 | 1985-07-16 | Colgate-Palmolive Co. | Stabilized enzyme-containing detergent compositions |
GB8311314D0 (en) * | 1983-04-26 | 1983-06-02 | Unilever Plc | Aqueous enzyme-containing compositions |
US4689167A (en) * | 1985-07-11 | 1987-08-25 | The Procter & Gamble Company | Detergency builder system |
JPS62253697A (en) * | 1986-04-02 | 1987-11-05 | 花王株式会社 | Bleaching composition |
GB8712430D0 (en) * | 1987-05-27 | 1987-07-01 | Procter & Gamble | Liquid detergent |
GB8713756D0 (en) * | 1987-06-12 | 1987-07-15 | Procter & Gamble | Liquid detergent |
FR2630454B1 (en) * | 1988-04-22 | 1990-08-10 | Air Liquide | STORAGE-STABLE AQUEOUS AQUEOUS LIQUID LIQUIDS AND WASHING METHOD |
CA1314186C (en) * | 1988-04-29 | 1993-03-09 | Frederik Jan Schepers | Liquid cleaning products |
GB8826458D0 (en) * | 1988-11-11 | 1988-12-14 | Ici Plc | Bleach formulation & aqueous detergent compositions |
GB8900525D0 (en) * | 1989-01-10 | 1989-03-08 | Procter & Gamble | Liquid detergent composition containing enzyme and enzyme stabilization system |
-
1989
- 1989-01-10 GB GB898900496A patent/GB8900496D0/en active Pending
-
1990
- 1990-01-05 EP EP90200026A patent/EP0378261B1/en not_active Expired - Lifetime
- 1990-01-05 DE DE69010922T patent/DE69010922T2/en not_active Expired - Fee Related
- 1990-01-05 AT AT90200026T patent/ATE109201T1/en not_active IP Right Cessation
- 1990-01-09 CA CA002007381A patent/CA2007381C/en not_active Expired - Fee Related
- 1990-01-09 NZ NZ232055A patent/NZ232055A/en unknown
- 1990-01-09 TR TR90/0095A patent/TR25347A/en unknown
- 1990-01-10 PT PT92820A patent/PT92820A/en not_active Application Discontinuation
- 1990-01-10 FI FI900130A patent/FI900130A/en not_active Application Discontinuation
- 1990-01-10 IE IE900097A patent/IE900097L/en unknown
- 1990-01-10 AU AU47871/90A patent/AU638961B2/en not_active Ceased
- 1990-01-10 CN CN90100768.4A patent/CN1027080C/en not_active Expired - Fee Related
- 1990-01-10 MX MX019083A patent/MX172149B/en unknown
- 1990-01-10 JP JP2003298A patent/JP2749416B2/en not_active Expired - Fee Related
- 1990-10-22 EP EP90870197A patent/EP0482274A1/en not_active Withdrawn
-
1991
- 1991-10-15 JP JP3518590A patent/JPH06502440A/en active Pending
- 1991-10-15 AU AU89523/91A patent/AU662501B2/en not_active Ceased
- 1991-10-15 CA CA002094604A patent/CA2094604C/en not_active Expired - Fee Related
- 1991-10-15 WO PCT/US1991/007606 patent/WO1992007055A1/en active Application Filing
- 1991-10-21 AR AR91320962A patent/AR244323A1/en active
- 1991-10-21 MX MX9101678A patent/MX9101678A/en unknown
- 1991-10-21 IE IE368591A patent/IE913685A1/en not_active Application Discontinuation
- 1991-10-21 NZ NZ240293A patent/NZ240293A/en unknown
- 1991-10-22 MY MYPI91001948A patent/MY108663A/en unknown
- 1991-10-22 PT PT99296A patent/PT99296A/en not_active Application Discontinuation
- 1991-10-22 CN CN91111077.1A patent/CN1030333C/en not_active Expired - Lifetime
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