DE60311930D1 - Filterkatalysator für die Reinigung von Dieselabgasen und Herstellungsverfahren dafür - Google Patents
Filterkatalysator für die Reinigung von Dieselabgasen und Herstellungsverfahren dafürInfo
- Publication number
- DE60311930D1 DE60311930D1 DE60311930T DE60311930T DE60311930D1 DE 60311930 D1 DE60311930 D1 DE 60311930D1 DE 60311930 T DE60311930 T DE 60311930T DE 60311930 T DE60311930 T DE 60311930T DE 60311930 D1 DE60311930 D1 DE 60311930D1
- Authority
- DE
- Germany
- Prior art keywords
- purification
- manufacturing process
- exhaust gases
- diesel exhaust
- process therefor
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- 239000003054 catalyst Substances 0.000 title 1
- 239000007789 gas Substances 0.000 title 1
- 238000004519 manufacturing process Methods 0.000 title 1
- 238000000746 purification Methods 0.000 title 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/92—Chemical or biological purification of waste gases of engine exhaust gases
- B01D53/94—Chemical or biological purification of waste gases of engine exhaust gases by catalytic processes
- B01D53/9445—Simultaneously removing carbon monoxide, hydrocarbons or nitrogen oxides making use of three-way catalysts [TWC] or four-way-catalysts [FWC]
- B01D53/945—Simultaneously removing carbon monoxide, hydrocarbons or nitrogen oxides making use of three-way catalysts [TWC] or four-way-catalysts [FWC] characterised by a specific catalyst
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/50—Catalysts, in general, characterised by their form or physical properties characterised by their shape or configuration
- B01J35/56—Foraminous structures having flow-through passages or channels, e.g. grids or three-dimensional monoliths
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/92—Chemical or biological purification of waste gases of engine exhaust gases
- B01D53/94—Chemical or biological purification of waste gases of engine exhaust gases by catalytic processes
- B01D53/9404—Removing only nitrogen compounds
- B01D53/9409—Nitrogen oxides
- B01D53/9413—Processes characterised by a specific catalyst
- B01D53/9422—Processes characterised by a specific catalyst for removing nitrogen oxides by NOx storage or reduction by cyclic switching between lean and rich exhaust gases (LNT, NSC, NSR)
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
- B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/56—Platinum group metals
- B01J23/58—Platinum group metals with alkali- or alkaline earth metals
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/02—Impregnation, coating or precipitation
- B01J37/024—Multiple impregnation or coating
- B01J37/0244—Coatings comprising several layers
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B38/00—Porous mortars, concrete, artificial stone or ceramic ware; Preparation thereof
- C04B38/0006—Honeycomb structures
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
- F01N—GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
- F01N3/00—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust
- F01N3/02—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for cooling, or for removing solid constituents of, exhaust
- F01N3/021—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for cooling, or for removing solid constituents of, exhaust by means of filters
- F01N3/022—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for cooling, or for removing solid constituents of, exhaust by means of filters characterised by specially adapted filtering structure, e.g. honeycomb, mesh or fibrous
- F01N3/0222—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for cooling, or for removing solid constituents of, exhaust by means of filters characterised by specially adapted filtering structure, e.g. honeycomb, mesh or fibrous the structure being monolithic, e.g. honeycombs
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
- F01N—GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
- F01N3/00—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust
- F01N3/02—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for cooling, or for removing solid constituents of, exhaust
- F01N3/021—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for cooling, or for removing solid constituents of, exhaust by means of filters
- F01N3/033—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for cooling, or for removing solid constituents of, exhaust by means of filters in combination with other devices
- F01N3/035—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for cooling, or for removing solid constituents of, exhaust by means of filters in combination with other devices with catalytic reactors, e.g. catalysed diesel particulate filters
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2255/00—Catalysts
- B01D2255/10—Noble metals or compounds thereof
- B01D2255/102—Platinum group metals
- B01D2255/1021—Platinum
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2255/00—Catalysts
- B01D2255/10—Noble metals or compounds thereof
- B01D2255/102—Platinum group metals
- B01D2255/1023—Palladium
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2255/00—Catalysts
- B01D2255/20—Metals or compounds thereof
- B01D2255/202—Alkali metals
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2255/00—Catalysts
- B01D2255/20—Metals or compounds thereof
- B01D2255/204—Alkaline earth metals
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2255/00—Catalysts
- B01D2255/90—Physical characteristics of catalysts
- B01D2255/91—NOx-storage component incorporated in the catalyst
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2255/00—Catalysts
- B01D2255/90—Physical characteristics of catalysts
- B01D2255/92—Dimensions
- B01D2255/9202—Linear dimensions
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/02—Impregnation, coating or precipitation
- B01J37/024—Multiple impregnation or coating
- B01J37/0242—Coating followed by impregnation
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/02—Impregnation, coating or precipitation
- B01J37/024—Multiple impregnation or coating
- B01J37/0248—Coatings comprising impregnated particles
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
- C04B2111/00474—Uses not provided for elsewhere in C04B2111/00
- C04B2111/00793—Uses not provided for elsewhere in C04B2111/00 as filters or diaphragms
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
- C04B2111/00474—Uses not provided for elsewhere in C04B2111/00
- C04B2111/0081—Uses not provided for elsewhere in C04B2111/00 as catalysts or catalyst carriers
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02T—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO TRANSPORTATION
- Y02T10/00—Road transport of goods or passengers
- Y02T10/10—Internal combustion engine [ICE] based vehicles
- Y02T10/12—Improving ICE efficiencies
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Combustion & Propulsion (AREA)
- Organic Chemistry (AREA)
- Materials Engineering (AREA)
- Biomedical Technology (AREA)
- General Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Analytical Chemistry (AREA)
- Mechanical Engineering (AREA)
- General Engineering & Computer Science (AREA)
- Environmental & Geological Engineering (AREA)
- Health & Medical Sciences (AREA)
- Ceramic Engineering (AREA)
- Structural Engineering (AREA)
- Catalysts (AREA)
- Exhaust Gas Treatment By Means Of Catalyst (AREA)
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2002268245A JP3874270B2 (ja) | 2002-09-13 | 2002-09-13 | 排ガス浄化フィルタ触媒及びその製造方法 |
JP2002268245 | 2002-09-13 |
Publications (2)
Publication Number | Publication Date |
---|---|
DE60311930D1 true DE60311930D1 (de) | 2007-04-05 |
DE60311930T2 DE60311930T2 (de) | 2007-10-25 |
Family
ID=31884809
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
DE60311930T Expired - Fee Related DE60311930T2 (de) | 2002-09-13 | 2003-09-05 | Filterkatalysator für die Reinigung von Dieselabgasen und Herstellungsverfahren dafür |
Country Status (6)
Country | Link |
---|---|
US (1) | US7306771B2 (de) |
EP (1) | EP1398081B1 (de) |
JP (1) | JP3874270B2 (de) |
KR (1) | KR100545299B1 (de) |
CN (1) | CN1309940C (de) |
DE (1) | DE60311930T2 (de) |
Families Citing this family (80)
Publication number | Priority date | Publication date | Assignee | Title |
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EP1655274B1 (de) * | 2003-07-25 | 2013-11-27 | NGK Insulators, Ltd. | Poröser keramikkörper und verfahren zur evaluierung seiner permeabilität |
US7229597B2 (en) | 2003-08-05 | 2007-06-12 | Basfd Catalysts Llc | Catalyzed SCR filter and emission treatment system |
US7387829B2 (en) | 2004-01-13 | 2008-06-17 | Ibiden Co., Ltd. | Honeycomb structure, porous body, pore forming material for the porous body, and methods for manufacturing the pore forming material, the porous body and the honeycomb structure |
JP4429756B2 (ja) * | 2004-02-10 | 2010-03-10 | 株式会社キャタラー | フィルタ触媒 |
JP4526276B2 (ja) | 2004-02-10 | 2010-08-18 | 株式会社キャタラー | フィルタ触媒およびその触媒層の解析方法 |
JP2005296935A (ja) * | 2004-03-17 | 2005-10-27 | Toyota Central Res & Dev Lab Inc | 排ガスフィルタおよびその製造方法、並びに、排ガス処理装置 |
KR100766357B1 (ko) * | 2004-03-23 | 2007-10-15 | 니뽄 가이시 가부시키가이샤 | 세라믹 필터 |
WO2005120687A1 (en) * | 2004-06-05 | 2005-12-22 | Umicore Ag & Co. Kg | Particle filter provided with a catalytic coating |
JP2006046200A (ja) * | 2004-08-05 | 2006-02-16 | Hitachi Ltd | ディーゼル内燃機関用排ガス浄化フィルタとその製造方法及び排ガス浄化装置 |
DE102004040548A1 (de) * | 2004-08-21 | 2006-02-23 | Umicore Ag & Co. Kg | Verfahren zum Beschichten eines Wandflußfilters mit feinteiligen Feststoffen und damit erhaltenes Partikelfilter und seine Verwendung |
DE102004040551A1 (de) * | 2004-08-21 | 2006-02-23 | Umicore Ag & Co. Kg | Verfahren zur Beschichtung eines Wandflußfilters mit einer Beschichtungszusammensetzung |
DE102004040549B4 (de) * | 2004-08-21 | 2017-03-23 | Umicore Ag & Co. Kg | Katalytisch beschichtetes Partikelfilter und seine Verwendung |
FR2875149B1 (fr) * | 2004-09-15 | 2006-12-15 | Rhodia Chimie Sa | Procede de fabrication d'un filtre a particules catalyse et filtre ainsi obtenu |
CN101056692B (zh) * | 2004-10-14 | 2010-08-25 | 田中贵金属工业株式会社 | 降低柴油机微粒过滤器上颗粒物起燃温度的不含铂族金属的催化剂 |
JP2006110485A (ja) * | 2004-10-15 | 2006-04-27 | Johnson Matthey Japan Inc | 排気ガス触媒およびそれを用いた排気ガス処理装置 |
JP4161957B2 (ja) * | 2004-10-21 | 2008-10-08 | トヨタ自動車株式会社 | 排気浄化触媒および排気浄化触媒の製造方法 |
JP4907860B2 (ja) | 2004-11-11 | 2012-04-04 | 株式会社キャタラー | フィルタ触媒 |
WO2006103963A1 (ja) * | 2005-03-29 | 2006-10-05 | Ngk Insulators, Ltd. | ハニカム構造体 |
JP4963799B2 (ja) * | 2005-06-13 | 2012-06-27 | 株式会社キャタラー | 排ガス浄化用触媒 |
JP2006346656A (ja) * | 2005-06-20 | 2006-12-28 | Toyota Motor Corp | 排ガス浄化用触媒とその製造方法 |
JP4907108B2 (ja) * | 2005-06-28 | 2012-03-28 | 株式会社キャタラー | スラリーの粘度の調整方法および排ガス浄化触媒用コーティングスラリー |
JP4844029B2 (ja) * | 2005-07-14 | 2011-12-21 | トヨタ自動車株式会社 | 排気浄化装置 |
EP1920839A4 (de) | 2005-08-31 | 2012-01-25 | Ngk Insulators Ltd | Katalytische wabenstruktur, vorbeschichteter träger zur erzeugung einer katalytischen wabenstruktur und verfahren zur herstellung einer katalytischen wabenstruktur |
US7754160B2 (en) | 2005-08-31 | 2010-07-13 | Ngk Insulators | Honeycomb catalytic body and process for manufacturing honeycomb catalytic body |
EP1935489A4 (de) * | 2005-08-31 | 2012-01-25 | Ngk Insulators Ltd | Wabenförmiger katalytischer körper und zugehöriges herstellungsverfahren |
JP4785470B2 (ja) * | 2005-09-08 | 2011-10-05 | 本田技研工業株式会社 | 排ガス浄化フィルタおよびその製造方法 |
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CN101330961A (zh) * | 2005-12-16 | 2008-12-24 | 康宁股份有限公司 | 低压降的涂覆的柴油机废气过滤器 |
JP5233026B2 (ja) * | 2006-03-06 | 2013-07-10 | Dowaエレクトロニクス株式会社 | Dpfの製造法 |
JP2007275704A (ja) * | 2006-04-03 | 2007-10-25 | Johnson Matthey Japan Inc | 排気ガス触媒およびそれを用いた排気ガス処理装置 |
KR100766725B1 (ko) | 2006-05-24 | 2007-10-12 | 에스케이에너지 주식회사 | 배기가스 재순환 라인을 구비한 디젤 엔진의 배기가스 정화장치 |
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CN101479023A (zh) * | 2006-06-29 | 2009-07-08 | 乌米科雷股份两合公司 | 三元催化剂 |
JP2008023501A (ja) * | 2006-07-25 | 2008-02-07 | Toyota Motor Corp | 排ガス浄化用触媒 |
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JP5150132B2 (ja) * | 2007-04-27 | 2013-02-20 | 日本碍子株式会社 | ハニカムフィルタシステム |
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ATE457813T1 (de) * | 2007-09-28 | 2010-03-15 | Umicore Ag & Co Kg | Entfernung von partikeln aus dem abgas von mit überwiegend stöchiometrischem luft/kraftstoff- gemisch betriebenen verbrennungsmotoren |
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KR101427912B1 (ko) * | 2008-10-31 | 2014-08-11 | 현대자동차 주식회사 | 촉매여과필터 |
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EP4119224A1 (de) * | 2009-05-29 | 2023-01-18 | Corning Incorporated | Partikelfilter mit niedriger russbeladener beschichtung |
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US8978360B2 (en) * | 2009-09-15 | 2015-03-17 | Ford Global Technologies, Llc | Hydrocarbon and NOx trap |
JP5726414B2 (ja) * | 2009-11-18 | 2015-06-03 | 日本碍子株式会社 | 触媒担持フィルタ、及び排ガス浄化システム |
JP5518518B2 (ja) * | 2010-02-15 | 2014-06-11 | 日本碍子株式会社 | ハニカムフィルタの製造方法 |
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DE10048511A1 (de) * | 2000-09-29 | 2002-04-18 | Omg Ag & Co Kg | Verfahren zur Verminderung von Kohlenmonoxid, Kohlenwasserstoffen und Partikel im mageren Abgas von Verbrennungsmotoren |
US6777370B2 (en) * | 2001-04-13 | 2004-08-17 | Engelhard Corporation | SOx tolerant NOx trap catalysts and methods of making and using the same |
-
2002
- 2002-09-13 JP JP2002268245A patent/JP3874270B2/ja not_active Expired - Fee Related
-
2003
- 2003-09-05 EP EP03020190A patent/EP1398081B1/de not_active Expired - Lifetime
- 2003-09-05 DE DE60311930T patent/DE60311930T2/de not_active Expired - Fee Related
- 2003-09-08 KR KR1020030062533A patent/KR100545299B1/ko not_active IP Right Cessation
- 2003-09-12 US US10/660,707 patent/US7306771B2/en not_active Expired - Fee Related
- 2003-09-15 CN CNB031569501A patent/CN1309940C/zh not_active Expired - Fee Related
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JP3874270B2 (ja) | 2007-01-31 |
DE60311930T2 (de) | 2007-10-25 |
EP1398081B1 (de) | 2007-02-21 |
US7306771B2 (en) | 2007-12-11 |
CN1309940C (zh) | 2007-04-11 |
US20040053781A1 (en) | 2004-03-18 |
KR100545299B1 (ko) | 2006-01-24 |
CN1490500A (zh) | 2004-04-21 |
EP1398081A1 (de) | 2004-03-17 |
KR20040024483A (ko) | 2004-03-20 |
JP2004105792A (ja) | 2004-04-08 |
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