DE60303154T2 - Verfahren zur Herstellung von ungesättigten Aldehyden und/oder Carbonsäuren mittels Gasphasenoxidation unter Verwendung eines Mo-Bi-Fe Katalysators - Google Patents

Verfahren zur Herstellung von ungesättigten Aldehyden und/oder Carbonsäuren mittels Gasphasenoxidation unter Verwendung eines Mo-Bi-Fe Katalysators Download PDF

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Publication number
DE60303154T2
DE60303154T2 DE60303154T DE60303154T DE60303154T2 DE 60303154 T2 DE60303154 T2 DE 60303154T2 DE 60303154 T DE60303154 T DE 60303154T DE 60303154 T DE60303154 T DE 60303154T DE 60303154 T2 DE60303154 T2 DE 60303154T2
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catalyst
catalysts
reaction
reaction zone
diameter
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DE60303154T
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German (de)
English (en)
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DE60303154D1 (de
Inventor
Hiromi Himeji-shi Yunoki
Michio Himeji-shi Tanimoto
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Nippon Shokubai Co Ltd
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Nippon Shokubai Co Ltd
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    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/16—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation
    • C07C51/21—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/27—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation
    • C07C45/32—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen
    • C07C45/37—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of >C—O—functional groups to >C=O groups
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/002—Mixed oxides other than spinels, e.g. perovskite
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/85—Chromium, molybdenum or tungsten
    • B01J23/888—Tungsten
    • B01J23/8885—Tungsten containing also molybdenum
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/40—Catalysts, in general, characterised by their form or physical properties characterised by dimensions, e.g. grain size
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/27—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation
    • C07C45/32—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/27—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation
    • C07C45/32—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen
    • C07C45/33—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of CHx-moieties
    • C07C45/34—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of CHx-moieties in unsaturated compounds
    • C07C45/35—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of CHx-moieties in unsaturated compounds in propene or isobutene
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/16—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation
    • C07C51/21—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen
    • C07C51/25—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of unsaturated compounds containing no six-membered aromatic ring
    • C07C51/252—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of unsaturated compounds containing no six-membered aromatic ring of propene, butenes, acrolein or methacrolein
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/85—Chromium, molybdenum or tungsten
    • B01J23/88—Molybdenum
    • B01J23/887—Molybdenum containing in addition other metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/8876—Arsenic, antimony or bismuth
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/85—Chromium, molybdenum or tungsten
    • B01J23/88—Molybdenum
    • B01J23/887—Molybdenum containing in addition other metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/8877—Vanadium, tantalum, niobium or polonium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/0009—Use of binding agents; Moulding; Pressing; Powdering; Granulating; Addition of materials ameliorating the mechanical properties of the product catalyst
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/0236—Drying, e.g. preparing a suspension, adding a soluble salt and drying

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Catalysts (AREA)
DE60303154T 2002-04-03 2003-03-20 Verfahren zur Herstellung von ungesättigten Aldehyden und/oder Carbonsäuren mittels Gasphasenoxidation unter Verwendung eines Mo-Bi-Fe Katalysators Expired - Lifetime DE60303154T2 (de)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
JP2002101773 2002-04-03
JP2002101773 2002-04-03

Publications (2)

Publication Number Publication Date
DE60303154D1 DE60303154D1 (de) 2006-04-06
DE60303154T2 true DE60303154T2 (de) 2006-08-03

Family

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Family Applications (1)

Application Number Title Priority Date Filing Date
DE60303154T Expired - Lifetime DE60303154T2 (de) 2002-04-03 2003-03-20 Verfahren zur Herstellung von ungesättigten Aldehyden und/oder Carbonsäuren mittels Gasphasenoxidation unter Verwendung eines Mo-Bi-Fe Katalysators

Country Status (7)

Country Link
US (1) US7045657B2 (enExample)
EP (1) EP1350566B1 (enExample)
KR (1) KR20030079685A (enExample)
CN (1) CN1259301C (enExample)
BR (1) BR0300753B1 (enExample)
DE (1) DE60303154T2 (enExample)
TW (1) TW200402414A (enExample)

Families Citing this family (15)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP3892244B2 (ja) * 2001-03-21 2007-03-14 株式会社日本触媒 不飽和アルデヒドおよび不飽和カルボン酸製造用触媒の製造方法
JP5607865B2 (ja) * 2003-08-29 2014-10-15 三菱レイヨン株式会社 メタクリル酸の製造方法
TWI342877B (en) 2003-12-26 2011-06-01 Lg Chemical Ltd Method of producing unsaturated aldehyde and/or unsaturated acid
KR100714606B1 (ko) * 2005-02-25 2007-05-07 주식회사 엘지화학 불포화 알데히드 및/또는 불포화 산의 제조방법
KR100677051B1 (ko) 2005-03-18 2007-02-01 주식회사 엘지화학 올레핀으로부터 불포화산을 제조하는 방법
WO2007105523A1 (ja) * 2006-03-10 2007-09-20 Mitsubishi Rayon Co., Ltd. 不飽和アルデヒド及び不飽和カルボン酸の製造方法
US7897813B2 (en) 2006-07-19 2011-03-01 Nippon Shokubai Co., Ltd. Reactor for gas phase catalytic oxidation and a process for producing acrylic acid using it
CN101385978B (zh) * 2007-09-12 2011-04-20 上海华谊丙烯酸有限公司 一种合成甲基丙烯醛的催化剂及其制备方法
DE102008044946B4 (de) * 2008-08-29 2022-06-15 Evonik Superabsorber Gmbh Einsatz von Schaumkörpern in Oxidations-Reaktoren zur Herstellung ungesättigter Carbonsäuren
CN103772172B (zh) * 2012-10-23 2016-02-10 中国石油天然气股份有限公司 一种丙烯选择性氧化生产丙烯醛的方法
CN104781221B (zh) * 2012-11-07 2016-10-05 三菱丽阳株式会社 异丁烯醛和甲基丙烯酸的制造方法
US9724680B2 (en) * 2012-12-07 2017-08-08 Exxonmobil Research And Engineering Company Fiber reinforced zeolite extrudates with enhanced physical properties
JP2016539936A (ja) 2013-11-11 2016-12-22 ビーエーエスエフ ソシエタス・ヨーロピアＢａｓｆ Ｓｅ 不飽和アルデヒド及び／又は不飽和カルボン酸の製造法
US9115067B1 (en) 2014-12-22 2015-08-25 Novus International, Inc. Process for the manufacture of acrolein
SG11202109109YA (en) * 2019-03-29 2021-11-29 Nippon Kayaku Kk Method for producing unsaturated aldehyde

Family Cites Families (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE2056614C3 (de) 1970-11-18 1981-04-16 Basf Ag, 6700 Ludwigshafen Verfahren zur Herstellung von Acrylsäure aus Propylen
JPS55113730A (en) 1979-02-26 1980-09-02 Mitsubishi Petrochem Co Ltd Preparation of acrolein and acrylic acid
JPS5946132A (ja) * 1982-09-06 1984-03-15 Nippon Shokubai Kagaku Kogyo Co Ltd メタクロレイン合成用触媒
ES2092557T3 (es) 1989-12-06 1996-12-01 Nippon Catalytic Chem Ind Procedimiento para producir metalocreina y acido metacrilico.
JP2659839B2 (ja) 1990-01-26 1997-09-30 株式会社日本触媒 メタクロレインおよびメタクリル酸の製造方法
US5206431A (en) 1990-02-08 1993-04-27 Nippon Shokubai Kagaku Kogyo Co., Ltd. Process for producing methacrylic acid
JPH0784400B2 (ja) 1990-04-03 1995-09-13 株式会社日本触媒 不飽和アルデヒドおよび不飽和酸の製造方法
JP2809476B2 (ja) 1990-04-11 1998-10-08 株式会社日本触媒 アクロレインおよびアクリル酸の製造方法
DE4307509A1 (de) 1993-03-10 1994-09-15 Basf Ag Verfahren zur Herstellung von 3 bis 5 C-Atome aufweisenden alpha,beta-monoethylenisch ungesättigten Aldehyden, Carbonsäuren oder Nitrilen
JP3139285B2 (ja) 1994-06-20 2001-02-26 住友化学工業株式会社 アクロレインおよびアクリル酸の製造方法
JP3537253B2 (ja) 1996-03-06 2004-06-14 株式会社日本触媒 アクリル酸の製造方法
JP3775872B2 (ja) 1996-12-03 2006-05-17 日本化薬株式会社 アクロレイン及びアクリル酸の製造方法
JP3943284B2 (ja) 1999-05-27 2007-07-11 株式会社日本触媒 アクリル酸の製造方法
JP3943311B2 (ja) * 2000-05-19 2007-07-11 株式会社日本触媒 不飽和アルデヒドおよび不飽和カルボン酸の製造方法

Also Published As

Publication number Publication date
US20030191343A1 (en) 2003-10-09
KR20030079685A (ko) 2003-10-10
DE60303154D1 (de) 2006-04-06
EP1350566B1 (en) 2006-01-11
TW200402414A (en) 2004-02-16
US7045657B2 (en) 2006-05-16
CN1448381A (zh) 2003-10-15
EP1350566A2 (en) 2003-10-08
EP1350566A3 (en) 2004-01-14
TWI328001B (enExample) 2010-08-01
BR0300753A (pt) 2004-09-14
BR0300753B1 (pt) 2012-12-11
CN1259301C (zh) 2006-06-14

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