DE60303154D1 - Verfahren zur Herstellung von ungesättigten Aldehyden und/oder Carbonsäuren mittels Gasphasenoxidation unter Verwendung eines Mo-Bi-Fe Katalysators - Google Patents

Verfahren zur Herstellung von ungesättigten Aldehyden und/oder Carbonsäuren mittels Gasphasenoxidation unter Verwendung eines Mo-Bi-Fe Katalysators

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Publication number
DE60303154D1
DE60303154D1 DE60303154T DE60303154T DE60303154D1 DE 60303154 D1 DE60303154 D1 DE 60303154D1 DE 60303154 T DE60303154 T DE 60303154T DE 60303154 T DE60303154 T DE 60303154T DE 60303154 D1 DE60303154 D1 DE 60303154D1
Authority
DE
Germany
Prior art keywords
catalyst
preparation
gas phase
carboxylic acids
phase oxidation
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
DE60303154T
Other languages
English (en)
Other versions
DE60303154T2 (de
Inventor
Hiromi Yunoki
Michio Tanimoto
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Nippon Shokubai Co Ltd
Original Assignee
Nippon Shokubai Co Ltd
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Filing date
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Application filed by Nippon Shokubai Co Ltd filed Critical Nippon Shokubai Co Ltd
Application granted granted Critical
Publication of DE60303154D1 publication Critical patent/DE60303154D1/de
Publication of DE60303154T2 publication Critical patent/DE60303154T2/de
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/16—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation
    • C07C51/21—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/27—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation
    • C07C45/32—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen
    • C07C45/37—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of >C—O—functional groups to >C=O groups
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/002—Mixed oxides other than spinels, e.g. perovskite
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/85—Chromium, molybdenum or tungsten
    • B01J23/888—Tungsten
    • B01J23/8885—Tungsten containing also molybdenum
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/40—Catalysts, in general, characterised by their form or physical properties characterised by dimensions, e.g. grain size
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/27—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation
    • C07C45/32—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/27—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation
    • C07C45/32—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen
    • C07C45/33—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of CHx-moieties
    • C07C45/34—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of CHx-moieties in unsaturated compounds
    • C07C45/35—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of CHx-moieties in unsaturated compounds in propene or isobutene
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/16—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation
    • C07C51/21—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen
    • C07C51/25—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of unsaturated compounds containing no six-membered aromatic ring
    • C07C51/252—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of unsaturated compounds containing no six-membered aromatic ring of propene, butenes, acrolein or methacrolein
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/85—Chromium, molybdenum or tungsten
    • B01J23/88—Molybdenum
    • B01J23/887—Molybdenum containing in addition other metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/8876—Arsenic, antimony or bismuth
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/85—Chromium, molybdenum or tungsten
    • B01J23/88—Molybdenum
    • B01J23/887—Molybdenum containing in addition other metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/8877—Vanadium, tantalum, niobium or polonium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/0009—Use of binding agents; Moulding; Pressing; Powdering; Granulating; Addition of materials ameliorating the mechanical properties of the product catalyst
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/0236—Drying, e.g. preparing a suspension, adding a soluble salt and drying

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Catalysts (AREA)
DE60303154T 2002-04-03 2003-03-20 Verfahren zur Herstellung von ungesättigten Aldehyden und/oder Carbonsäuren mittels Gasphasenoxidation unter Verwendung eines Mo-Bi-Fe Katalysators Expired - Lifetime DE60303154T2 (de)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
JP2002101773 2002-04-03
JP2002101773 2002-04-03

Publications (2)

Publication Number Publication Date
DE60303154D1 true DE60303154D1 (de) 2006-04-06
DE60303154T2 DE60303154T2 (de) 2006-08-03

Family

ID=28035940

Family Applications (1)

Application Number Title Priority Date Filing Date
DE60303154T Expired - Lifetime DE60303154T2 (de) 2002-04-03 2003-03-20 Verfahren zur Herstellung von ungesättigten Aldehyden und/oder Carbonsäuren mittels Gasphasenoxidation unter Verwendung eines Mo-Bi-Fe Katalysators

Country Status (7)

Country Link
US (1) US7045657B2 (de)
EP (1) EP1350566B1 (de)
KR (1) KR20030079685A (de)
CN (1) CN1259301C (de)
BR (1) BR0300753B1 (de)
DE (1) DE60303154T2 (de)
TW (1) TW200402414A (de)

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP3892244B2 (ja) * 2001-03-21 2007-03-14 株式会社日本触媒 不飽和アルデヒドおよび不飽和カルボン酸製造用触媒の製造方法
KR100694950B1 (ko) * 2003-08-29 2007-03-14 미츠비시 레이온 가부시키가이샤 메타크릴산의 제조방법
US7326389B2 (en) 2003-12-26 2008-02-05 Lg Chem, Ltd. Method of producing unsaturated aldehyde and/or unsaturated acid
KR100714606B1 (ko) * 2005-02-25 2007-05-07 주식회사 엘지화학 불포화 알데히드 및/또는 불포화 산의 제조방법
TWI349001B (en) 2005-03-18 2011-09-21 Lg Chemical Ltd Method of producing unsaturated acid from olefin
KR101332123B1 (ko) * 2006-03-10 2013-11-21 미츠비시 레이온 가부시키가이샤 불포화 알데하이드 및 불포화 카복실산의 제조방법
US7897813B2 (en) 2006-07-19 2011-03-01 Nippon Shokubai Co., Ltd. Reactor for gas phase catalytic oxidation and a process for producing acrylic acid using it
CN101385978B (zh) * 2007-09-12 2011-04-20 上海华谊丙烯酸有限公司 一种合成甲基丙烯醛的催化剂及其制备方法
DE102008044946B4 (de) * 2008-08-29 2022-06-15 Evonik Superabsorber Gmbh Einsatz von Schaumkörpern in Oxidations-Reaktoren zur Herstellung ungesättigter Carbonsäuren
CN103772172B (zh) * 2012-10-23 2016-02-10 中国石油天然气股份有限公司 一种丙烯选择性氧化生产丙烯醛的方法
CN104781221B (zh) * 2012-11-07 2016-10-05 三菱丽阳株式会社 异丁烯醛和甲基丙烯酸的制造方法
US9724680B2 (en) * 2012-12-07 2017-08-08 Exxonmobil Research And Engineering Company Fiber reinforced zeolite extrudates with enhanced physical properties
EP3068754B1 (de) * 2013-11-11 2018-01-31 Basf Se Verfahren zur herstellung eines ungesättigten aldehyds und/oder einer ungesättigten carbonsäure
US9115067B1 (en) 2014-12-22 2015-08-25 Novus International, Inc. Process for the manufacture of acrolein
SG11202109109YA (en) * 2019-03-29 2021-11-29 Nippon Kayaku Kk Method for producing unsaturated aldehyde

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DE2056614C3 (de) 1970-11-18 1981-04-16 Basf Ag, 6700 Ludwigshafen Verfahren zur Herstellung von Acrylsäure aus Propylen
JPS55113730A (en) 1979-02-26 1980-09-02 Mitsubishi Petrochem Co Ltd Preparation of acrolein and acrylic acid
JPS5946132A (ja) * 1982-09-06 1984-03-15 Nippon Shokubai Kagaku Kogyo Co Ltd メタクロレイン合成用触媒
JP2659839B2 (ja) 1990-01-26 1997-09-30 株式会社日本触媒 メタクロレインおよびメタクリル酸の製造方法
ES2130297T3 (es) 1989-12-06 1999-07-01 Nippon Catalytic Chem Ind Procedimiento para producir metacroleina y acido metacrilico.
US5206431A (en) 1990-02-08 1993-04-27 Nippon Shokubai Kagaku Kogyo Co., Ltd. Process for producing methacrylic acid
JPH0784400B2 (ja) 1990-04-03 1995-09-13 株式会社日本触媒 不飽和アルデヒドおよび不飽和酸の製造方法
JP2809476B2 (ja) 1990-04-11 1998-10-08 株式会社日本触媒 アクロレインおよびアクリル酸の製造方法
DE4307509A1 (de) 1993-03-10 1994-09-15 Basf Ag Verfahren zur Herstellung von 3 bis 5 C-Atome aufweisenden alpha,beta-monoethylenisch ungesättigten Aldehyden, Carbonsäuren oder Nitrilen
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JP3537253B2 (ja) 1996-03-06 2004-06-14 株式会社日本触媒 アクリル酸の製造方法
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JP3943284B2 (ja) 1999-05-27 2007-07-11 株式会社日本触媒 アクリル酸の製造方法
JP3943311B2 (ja) * 2000-05-19 2007-07-11 株式会社日本触媒 不飽和アルデヒドおよび不飽和カルボン酸の製造方法

Also Published As

Publication number Publication date
EP1350566B1 (de) 2006-01-11
TWI328001B (de) 2010-08-01
CN1448381A (zh) 2003-10-15
EP1350566A3 (de) 2004-01-14
BR0300753B1 (pt) 2012-12-11
BR0300753A (pt) 2004-09-14
CN1259301C (zh) 2006-06-14
EP1350566A2 (de) 2003-10-08
DE60303154T2 (de) 2006-08-03
TW200402414A (en) 2004-02-16
KR20030079685A (ko) 2003-10-10
US7045657B2 (en) 2006-05-16
US20030191343A1 (en) 2003-10-09

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