DE60109575D1 - Makrocyclische polyester oligomere und ihre polymerisations-verfahren - Google Patents

Makrocyclische polyester oligomere und ihre polymerisations-verfahren

Info

Publication number
DE60109575D1
DE60109575D1 DE60109575T DE60109575T DE60109575D1 DE 60109575 D1 DE60109575 D1 DE 60109575D1 DE 60109575 T DE60109575 T DE 60109575T DE 60109575 T DE60109575 T DE 60109575T DE 60109575 D1 DE60109575 D1 DE 60109575D1
Authority
DE
Germany
Prior art keywords
macrocyclic polyester
water
suspension
polyester oligomer
polymerization catalyst
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
DE60109575T
Other languages
English (en)
Other versions
DE60109575T2 (de
Inventor
J Winckler
Tohru Takekoshi
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Cyclics Corp
Original Assignee
Cyclics Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from US09/535,132 external-priority patent/US6369157B1/en
Application filed by Cyclics Corp filed Critical Cyclics Corp
Publication of DE60109575D1 publication Critical patent/DE60109575D1/de
Application granted granted Critical
Publication of DE60109575T2 publication Critical patent/DE60109575T2/de
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C67/00—Shaping techniques not covered by groups B29C39/00 - B29C65/00, B29C70/00 or B29C73/00
    • B29C67/24—Shaping techniques not covered by groups B29C39/00 - B29C65/00, B29C70/00 or B29C73/00 characterised by the choice of material
    • B29C67/246—Moulding high reactive monomers or prepolymers, e.g. by reaction injection moulding [RIM], liquid injection moulding [LIM]
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29B—PREPARATION OR PRETREATMENT OF THE MATERIAL TO BE SHAPED; MAKING GRANULES OR PREFORMS; RECOVERY OF PLASTICS OR OTHER CONSTITUENTS OF WASTE MATERIAL CONTAINING PLASTICS
    • B29B15/00—Pretreatment of the material to be shaped, not covered by groups B29B7/00 - B29B13/00
    • B29B15/08—Pretreatment of the material to be shaped, not covered by groups B29B7/00 - B29B13/00 of reinforcements or fillers
    • B29B15/10—Coating or impregnating independently of the moulding or shaping step
    • B29B15/12—Coating or impregnating independently of the moulding or shaping step of reinforcements of indefinite length
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29B—PREPARATION OR PRETREATMENT OF THE MATERIAL TO BE SHAPED; MAKING GRANULES OR PREFORMS; RECOVERY OF PLASTICS OR OTHER CONSTITUENTS OF WASTE MATERIAL CONTAINING PLASTICS
    • B29B15/00—Pretreatment of the material to be shaped, not covered by groups B29B7/00 - B29B13/00
    • B29B15/08—Pretreatment of the material to be shaped, not covered by groups B29B7/00 - B29B13/00 of reinforcements or fillers
    • B29B15/10—Coating or impregnating independently of the moulding or shaping step
    • B29B15/12—Coating or impregnating independently of the moulding or shaping step of reinforcements of indefinite length
    • B29B15/122—Coating or impregnating independently of the moulding or shaping step of reinforcements of indefinite length with a matrix in liquid form, e.g. as melt, solution or latex
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29B—PREPARATION OR PRETREATMENT OF THE MATERIAL TO BE SHAPED; MAKING GRANULES OR PREFORMS; RECOVERY OF PLASTICS OR OTHER CONSTITUENTS OF WASTE MATERIAL CONTAINING PLASTICS
    • B29B15/00—Pretreatment of the material to be shaped, not covered by groups B29B7/00 - B29B13/00
    • B29B15/08—Pretreatment of the material to be shaped, not covered by groups B29B7/00 - B29B13/00 of reinforcements or fillers
    • B29B15/10—Coating or impregnating independently of the moulding or shaping step
    • B29B15/12—Coating or impregnating independently of the moulding or shaping step of reinforcements of indefinite length
    • B29B15/122—Coating or impregnating independently of the moulding or shaping step of reinforcements of indefinite length with a matrix in liquid form, e.g. as melt, solution or latex
    • B29B15/125—Coating or impregnating independently of the moulding or shaping step of reinforcements of indefinite length with a matrix in liquid form, e.g. as melt, solution or latex by dipping
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C41/00—Shaping by coating a mould, core or other substrate, i.e. by depositing material and stripping-off the shaped article; Apparatus therefor
    • B29C41/02—Shaping by coating a mould, core or other substrate, i.e. by depositing material and stripping-off the shaped article; Apparatus therefor for making articles of definite length, i.e. discrete articles
    • B29C41/04—Rotational or centrifugal casting, i.e. coating the inside of a mould by rotating the mould
    • B29C41/06—Rotational or centrifugal casting, i.e. coating the inside of a mould by rotating the mould about two or more axes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
    • C08G63/78—Preparation processes
    • C08G63/82—Preparation processes characterised by the catalyst used
    • C08G63/85—Germanium, tin, lead, arsenic, antimony, bismuth, titanium, zirconium, hafnium, vanadium, niobium, tantalum, or compounds thereof
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/31504—Composite [nonstructural laminate]
    • Y10T428/31786—Of polyester [e.g., alkyd, etc.]

Landscapes

  • Mechanical Engineering (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Polymers & Plastics (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Organic Chemistry (AREA)
  • Polyesters Or Polycarbonates (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Heterocyclic Compounds That Contain Two Or More Ring Oxygen Atoms (AREA)
  • Processes Of Treating Macromolecular Substances (AREA)
  • Reinforced Plastic Materials (AREA)
  • Moulding By Coating Moulds (AREA)
DE2001609575 2000-01-21 2001-01-19 Makrocyclische polyester oligomere und ihre polymerisations-verfahren Expired - Lifetime DE60109575T2 (de)

Applications Claiming Priority (7)

Application Number Priority Date Filing Date Title
US17772700P 2000-01-21 2000-01-21
US177727P 2000-01-21
US09/535,132 US6369157B1 (en) 2000-01-21 2000-03-24 Blend material including macrocyclic polyester oligomers and processes for polymerizing the same
US535132 2000-03-24
US09/754,943 US6420047B2 (en) 2000-01-21 2001-01-04 Macrocyclic polyester oligomers and processes for polymerizing the same
US754943 2001-01-04
PCT/US2001/002064 WO2001053379A1 (en) 2000-01-21 2001-01-19 Macrocyclic polyester oligomers and processes for polymerizing the same

Publications (2)

Publication Number Publication Date
DE60109575D1 true DE60109575D1 (de) 2005-04-28
DE60109575T2 DE60109575T2 (de) 2006-02-09

Family

ID=27390858

Family Applications (1)

Application Number Title Priority Date Filing Date
DE2001609575 Expired - Lifetime DE60109575T2 (de) 2000-01-21 2001-01-19 Makrocyclische polyester oligomere und ihre polymerisations-verfahren

Country Status (6)

Country Link
US (4) US6420047B2 (de)
EP (1) EP1250374B1 (de)
JP (1) JP2003520875A (de)
AT (1) ATE291602T1 (de)
DE (1) DE60109575T2 (de)
WO (1) WO2001053379A1 (de)

Families Citing this family (78)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20050137333A1 (en) * 2003-12-19 2005-06-23 Cyclics Corporation Processes for dispersing an impact modifier in a macrocyclic polyester oligomer
US7256241B2 (en) * 2000-01-21 2007-08-14 Cyclics Corporation Methods for polymerizing macrocyclic polyester oligomers using catalyst promoters
US6906147B2 (en) * 2002-03-20 2005-06-14 Cyclics Corporation Catalytic systems
US7151143B2 (en) * 2000-01-21 2006-12-19 Cyclics Corporation Blends containing macrocyclic polyester oligomer and high molecular weight polymer
US6960626B2 (en) * 2000-01-21 2005-11-01 Cyclics Corporation Intimate physical mixtures containing macrocyclic polyester oligomer and filler
US6420047B2 (en) * 2000-01-21 2002-07-16 Cyclics Corporation Macrocyclic polyester oligomers and processes for polymerizing the same
US20050282952A1 (en) * 2000-01-21 2005-12-22 Cyclics Corporation Graphite-polyester composites made from macrocyclic polyester oligomers
US7223359B2 (en) * 2002-11-05 2007-05-29 Northwestern University Method of producing an exfoliated polymer-clay nanocomposite through solid-state shear pulverization
US20040010066A1 (en) * 2000-06-30 2004-01-15 Devine Stephen J Flame retardant dispersible powders on a wax, polymer, or organic carrier
US7750109B2 (en) 2000-09-01 2010-07-06 Cyclics Corporation Use of a residual oligomer recyclate in the production of macrocyclic polyester oligomer
AU2001288663A1 (en) * 2000-09-01 2002-03-13 Cyclics Corporation Methods for converting linear polyesters to macrocyclic oligoester compositions and macrocyclic oligoesters
US7767781B2 (en) 2000-09-01 2010-08-03 Cyclics Corporation Preparation of low-acid polyalkylene terephthalate and preparation of macrocyclic polyester oligomer therefrom
US6436548B1 (en) 2000-09-12 2002-08-20 Cyclics Corporation Species modification in macrocyclic polyester oligomers, and compositions prepared thereby
US6420048B1 (en) * 2001-06-05 2002-07-16 Cyclics Corporation High molecular weight copolyesters from macrocyclic oligoesters and cyclic esters
JP3952706B2 (ja) * 2001-06-14 2007-08-01 富士ゼロックス株式会社 高分子化合物及びその製造方法、成形体及びその製造方法
DE60206508T2 (de) * 2001-06-27 2006-07-06 Cyclics Corp. Isolierung, formulierung und informbringen von makrocyclischen oligoestern
US7304123B2 (en) * 2001-06-27 2007-12-04 Cyclics Corporation Processes for shaping macrocyclic oligoesters
US6436549B1 (en) * 2001-07-16 2002-08-20 Cyclics Corporation Block copolymers from macrocyclic oligoesters and dihydroxyl-functionalized polymers
US6787632B2 (en) * 2001-10-09 2004-09-07 Cyclics Corporation Organo-titanate catalysts for preparing pure macrocyclic oligoesters
US6831138B2 (en) * 2002-01-07 2004-12-14 Cyclics Corporation Polymer-containing organo-metal catalysts
US6806346B2 (en) * 2002-07-12 2004-10-19 E. I. Du Pont De Nemours And Company Copolymerization of cyclic ester oligomers
EP1415793A1 (de) * 2002-11-04 2004-05-06 Alcan Technology & Management Ltd. Verfahren zur Herstellung von Bauteilen aus Faserverbundkunststoffen
US20040106713A1 (en) * 2002-12-03 2004-06-03 Avakian Roger W. Use of additives in compounds containing macrocyclic poly(alkylene dicarboxylate) oligomers
US7078451B2 (en) * 2002-12-19 2006-07-18 Owens Corning Fiberglas Technology, Inc. Formulation and process for compression molded component parts
AU2003297330A1 (en) * 2002-12-20 2004-07-22 Cyclics Corporation Purification of macrocyclic oligoesters
CN100392006C (zh) * 2002-12-20 2008-06-04 陶氏环球技术公司 聚合的大环低聚物纳米复合材料组合物
JP2007521341A (ja) * 2002-12-23 2007-08-02 ダウ グローバル テクノロジーズ インコーポレイティド Ｓｍｃ成形方法
CA2509699A1 (en) * 2002-12-23 2004-07-15 Dow Global Technologies Inc. Electrically conductive polymerized macrocyclic oligomer carbon nanofiber compositions
WO2004113058A1 (en) * 2003-06-25 2004-12-29 Joseph Steven Egan Method of construction of moulded products
US20050095415A1 (en) * 2003-10-30 2005-05-05 Raghavendran Venkat K. Glass mat thermoplastic composite
US7351769B2 (en) * 2004-01-26 2008-04-01 Freudenberg-Nok General Partnership Dynamic vulcanization of elastomers with in-situ polymerization
EP1570976A1 (de) * 2004-03-04 2005-09-07 Alcan Technology & Management Ltd. Verarbeitung von zyklischen Oligomeren zu thermoplastischen PBT-Kunststoffen
EP1570977A1 (de) * 2004-03-05 2005-09-07 Alcan Technology & Management Ltd. Verfahren zur kontinuierlichen Herstellung von faserverstärkten Kunststoffplatten
EP1580246A1 (de) * 2004-03-24 2005-09-28 The Dow Chemical Company Reaktiver Schmelzkleber
USRE44893E1 (en) 2004-03-26 2014-05-13 Hanwha Azdel, Inc. Fiber reinforced thermoplastic sheets with surface coverings
US7196160B2 (en) * 2004-04-22 2007-03-27 Dow Global Technologies Inc Catalysts and methods for polymerizing macrocyclic oligomers
JP2008503613A (ja) * 2004-06-18 2008-02-07 ダウ グローバル テクノロジーズ インコーポレイティド 分散された充填剤を含む重合性大環状オリゴマーマスターバッチ
JP2008503614A (ja) * 2004-06-18 2008-02-07 ダウ グローバル テクノロジーズ インコーポレイティド 大環状オリゴマーのポリマー中の複合体のための触媒含有クレイ材料
JP2008503610A (ja) * 2004-06-18 2008-02-07 ダウ グローバル テクノロジーズ インコーポレイティド 遅延作用触媒及び大環状オリゴマーの重合方法
US20060067055A1 (en) * 2004-09-30 2006-03-30 Heffner Kenneth H Thermally conductive composite and uses for microelectronic packaging
US20080007890A1 (en) * 2004-09-30 2008-01-10 Harmon Julianne P Thermally conductive composite and uses for microelectronic packaging
US7557157B2 (en) * 2004-11-09 2009-07-07 E. I. Du Pont De Nemours And Company Polymerization of macrocyclic polyester oligomers at elevated temperature using rare earth element catalysts
WO2006053070A1 (en) * 2004-11-09 2006-05-18 E.I. Dupont De Nemours And Company Polymerization of macrocyclic polyester oligomers using metal amide and metal alkoxide catalysts
US7622543B2 (en) * 2004-11-09 2009-11-24 E.I. Du Pont De Nemours And Company Polymerization of macrocyclic polyester oligomers using N-heterocyclic carbene catalysts
US7488772B2 (en) * 2004-11-09 2009-02-10 E.I. Du Pont De Nemours And Company Polymerization of macrocyclic polyester oligomers using N-heterocyclic carbene and metal amide or metal alkoxide catalyst
US7642028B2 (en) * 2005-03-17 2010-01-05 Xerox Corporation Imaging members
DE102005018450B3 (de) * 2005-04-20 2006-10-12 Heraeus Kulzer Gmbh Verwendung von Butylenterephtalat zur Herstellung thermoplastischen Zahnersatzes
US20070173630A1 (en) * 2005-12-02 2007-07-26 Cyclics Corporation Macrocyclic polyester oligomers as flow modifier additives for thermoplastics
US7745561B2 (en) 2006-01-31 2010-06-29 Cyclics Corporation Processes for making copolymers using macrocyclic oligoesters, and copolymers therefrom
US7730996B2 (en) * 2006-04-12 2010-06-08 Ocv Intellectual Capital, Llc Long fiber thermoplastic composite muffler system with integrated crash management
US7942237B2 (en) * 2006-04-12 2011-05-17 Ocv Intellectual Capital, Llc Long fiber thermoplastic composite muffler system with integrated reflective chamber
US7934580B2 (en) * 2006-04-12 2011-05-03 Ocv Intellectual Capital, Llc Long fiber thermoplastic composite muffler system
WO2008021035A1 (en) * 2006-08-10 2008-02-21 Dow Global Technologies, Inc. Polymers of macrocyclic oligomers containing highly expanded graphite
CA2668428A1 (en) 2006-11-06 2008-05-15 Michael W. Eknoian Cosmetic device comprising discrete elements
FR2918081B1 (fr) * 2007-06-27 2009-09-18 Cabinet Hecke Sa Procede d'impregnation de fibres continues par une matrice polymerique composite renfermant un polymere thermoplastique
WO2009055598A1 (en) * 2007-10-23 2009-04-30 Cyclics Corporation Processes for reducing acid content of a polyalkylene terephthalate product and using such in the production of macrocyclic polyester oligomer
US7686862B1 (en) * 2008-09-22 2010-03-30 Peerless Mfg. Co. Composite vane and method of manufacture
US8946335B2 (en) * 2008-10-30 2015-02-03 Kaneka Corporation Highly thermally conductive thermoplastic resin composition and thermoplastic resin
BR112012000563A2 (pt) 2009-06-19 2016-11-16 Polyone Corp terpolímeros limpadores de oxigênio.
CN102498149B (zh) 2009-09-16 2013-11-27 株式会社钟化 有机导热性添加剂、树脂组合物及硬化物
CN102844351B (zh) 2010-04-19 2014-11-19 株式会社钟化 高导热性热塑性树脂
EP2562200B1 (de) 2010-04-19 2016-10-19 Kaneka Corporation Thermoplastisches harz mit hoher wärmeleitfähigkeit
ES2378129B1 (es) * 2010-04-30 2013-03-25 Airbus Operations, S.L. Proceso de aplicación de resina sobre una superficie tratada con sustancias desmoldeantes de un útil base de moldeo para obtener cuerpos de material compuesto.
WO2013030103A1 (de) * 2011-08-26 2013-03-07 Basf Se Verfahren zur herstellung von formteilen
EP2855556A4 (de) 2012-05-25 2016-02-10 Polyone Corp Sauerstoffabsorbierende copolymere aus cyclischen aliphatischen monomeren
US9725558B2 (en) * 2013-03-15 2017-08-08 Sulzer Chemtech Ag Process to prepare a cyclic oligomer and a cyclic oligomer obtainable thereby
US20160102182A1 (en) * 2013-06-11 2016-04-14 Johns Manville Fiber-reinforced composite articles and methods of making them
US9855680B2 (en) * 2013-06-11 2018-01-02 Johns Manville Fiber-reinforced composite articles and methods of making them
US9115266B2 (en) 2013-07-31 2015-08-25 E I Du Pont De Nemours And Company Carbon nanotube-polymer composite and process for making same
JP6121978B2 (ja) * 2014-12-10 2017-04-26 株式会社 サン・テクトロ プリプレグ製造装置
US20160230412A1 (en) * 2015-02-09 2016-08-11 Keenan & Associates Fence And Deck Post Cap
CN107530908B (zh) * 2015-05-01 2021-11-05 昭和电工材料株式会社 Frp前体的制造方法及其制造装置
WO2018060241A1 (en) * 2016-09-29 2018-04-05 Sulzer Chemtech Ag A process to prepare a polyester polymer and a polyester polymer obtainable thereby
JP6411677B1 (ja) * 2017-06-02 2018-10-24 株式会社ジャムコ 複合材部品の製造方法、および、複合材部品製造装置
US10717245B2 (en) 2018-04-03 2020-07-21 Johns Manville System for producing a fully impregnated thermoplastic prepreg
EP3643736A1 (de) * 2018-10-26 2020-04-29 Johns Manville System zur herstellung eines vollständig imprägnierten thermoplastischen prepregs
WO2020226660A1 (en) * 2019-05-09 2020-11-12 Dustin Eplee Fluidized bed rotational molding
US11117292B2 (en) 2019-05-09 2021-09-14 Dustin Eplee Fluidized bed rotational molding

Family Cites Families (131)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2628171A (en) 1950-02-23 1953-02-10 Du Pont Solvent-soluble water-repellency compositions
US3018272A (en) 1955-06-30 1962-01-23 Du Pont Sulfonate containing polyesters dyeable with basic dyes
US3875275A (en) * 1958-05-05 1975-04-01 Jerome H Lemelson Method for molding composite bodies
US3090753A (en) 1960-08-02 1963-05-21 Exxon Research Engineering Co Ester oil compositions containing acid anhydride
GB991020A (en) 1960-11-29 1965-05-05 Martin Marietta Corp Esterification of iso- and terephthalic acids
GB957841A (en) 1961-04-10 1964-05-13 Ici Ltd The preparation of organo-tin compounds and their use as catalysts in the productionof polymethanes
GB1108921A (en) 1964-04-10 1968-04-10 Du Pont Improvements relating to polyethers
AT265646B (de) 1965-02-25 1968-10-25 Metallgesellschaft Ag Verfahren zur Erhöhung des Molekulargewichtes eines faser- und filmbildenden Polyesters
US3528935A (en) * 1967-11-30 1970-09-15 Sinclair Research Inc Package stable,low viscosity,high solids,thermosetting coating compositions with latent curing catalyst
US3786067A (en) 1972-02-18 1974-01-15 Ashland Oil Inc Cyclic organometallic compounds
US4111899A (en) 1977-07-20 1978-09-05 The Dow Chemical Company Heat stabilized thermoplastic resins containing compounds with phosphorus to phosphorus bonds
US4559262A (en) * 1981-01-21 1985-12-17 Imperial Chemical Industries, Plc Fibre reinforced compositions and methods for producing such compositions
SU1077893A1 (ru) 1981-11-27 1984-03-07 Всесоюзный научно-исследовательский институт синтетических и натуральных душистых веществ Способ получени макроциклических диэфиров
US4740583A (en) 1984-05-11 1988-04-26 General Electric Company Method for converting cyclic polycarbonate oligomer mixtures to linear polycarbonate, and composition resulting therefrom
US4644053A (en) 1984-05-11 1987-02-17 General Electric Company Cyclic polycarbonate oligomers and methods for their preparation and use
US4568703A (en) 1984-07-27 1986-02-04 Bp Chemicals Limited Process for the production of polymers containing isocyanurate and or oxazolidone linkages
US4638077A (en) 1984-11-29 1987-01-20 General Electric Company Method for the preparation of chloroformate compositions
US4590259A (en) 1984-11-30 1986-05-20 General Electric Company High molecular weight linear polyesters and method for their preparation
US4727134A (en) 1985-02-22 1988-02-23 General Electric Company Method for preparing cyclic polycarbonate oligomer mixtures
US4605731A (en) 1985-04-16 1986-08-12 General Electric Company Method for preparing linear polycarbonate from cyclic oligomer with aryl carbanion generating catalyst
US4680345A (en) 1985-06-05 1987-07-14 Toyo Boseki Kabushiki Kaisha Continuous production of elastic polyesters
US5039717A (en) 1985-07-25 1991-08-13 Amoco Corporation Copolyesters
JPS6275547A (ja) 1985-09-30 1987-04-07 Canon Inc 静電荷像現像用電荷付与材
US4616077A (en) 1985-11-22 1986-10-07 General Electric Company Method for preparing cyclic polycarbonate oligomer from bischloroformate composition
US4888411A (en) 1985-11-25 1989-12-19 General Electric Company Crosslinkable polycyclic polycarbonate oligomer and methods for their preparation and use
DE3607627A1 (de) 1986-03-07 1987-09-10 Bayer Ag Thermoplastische blockcopolymere auf der basis von cyclischen carbonaten oder estern
US4803288A (en) 1986-03-20 1989-02-07 Nisso Petrochemical Industries Co., Ltd. Process for producing macrocyclic ester compounds
USRE34431E (en) 1986-07-21 1993-11-02 General Electric Company Macrocyclic oligomers containing spiro(bis)indane moieties
US4757132A (en) 1986-10-20 1988-07-12 General Electric Company Cyclic polyester oligomer polymerization
US4980453A (en) 1986-07-21 1990-12-25 General Electric Company Macrocyclic oligomers containing spiro(bis)indane moietes
US4785060A (en) 1986-08-28 1988-11-15 Colgate-Palmolive Company Soil release promoting pet-poet copolymer, method of producing same and use thereof in detergent composition having soil release promoting property
JPS6372513A (ja) * 1986-09-16 1988-04-02 Nippon Carbide Ind Co Ltd 繊維強化樹脂成形品の成形方法およびそれに使用する不飽和ポリエステル樹脂組成物
US4829144A (en) 1986-10-20 1989-05-09 General Electric Company Cyclic polyester oligomer and method for their preparation
US4831001A (en) 1986-10-30 1989-05-16 General Electric Company Cyclic polycarbonate oligomers: inhibition and control of polymerization to linear polycarbonates
US4816548A (en) 1986-10-30 1989-03-28 General Electric Company Cyclic polycarbonate oligomers: inhibition and control of polymerization to linear polycarbonates
US4904810A (en) 1987-01-16 1990-02-27 General Electric Company Bischoloroformate preparation method with phosgene removal and monochloroformate conversion
US4900706A (en) 1987-03-17 1990-02-13 Sumitomo Chemical Company, Limited Process for producing olefin polymers and catalyst used therein
DE3737047A1 (de) 1987-10-31 1989-05-11 Huels Troisdorf Zubereitung auf basis von titan-chelaten von diolen und von titanacylaten
US5202386A (en) 1987-12-14 1993-04-13 Akzo Nv Modification of (co)polymers employing organic peroxides
EP0338115A3 (en) * 1988-02-05 1991-02-27 Basf Aktiengesellschaft Process for preparing a void-free pre-impregnated material comprising a thermoplastic polymer
DE3831886A1 (de) 1988-09-20 1990-03-29 Bayer Ag Verfahren zur herstellung von aromatischen polycarbonaten
DE3838752A1 (de) 1988-11-16 1990-05-17 Bayer Ag Verfahren zur herstellung von cyclischen kohlensaeureestern
US5097008A (en) 1989-06-01 1992-03-17 General Electric Company Preparation of branched polycarbonate from oligomeric cyclic polycarbonate and polyhydric phenol
US5191038A (en) 1989-06-01 1993-03-02 General Electric Company Preparation of branched polycarbonate composition from cyclic aromatic polycarbonate oligomer, polyhydric phenol and polycarbonate
US5006637A (en) 1989-06-12 1991-04-09 General Electric Company Method for preparing copolyestercarbonates from cyclic oligomers
US4970288A (en) 1989-09-22 1990-11-13 Atochem North America, Inc. Non-toxic polyester compositions made with organotin esterification catalysts
US5071711A (en) 1989-09-28 1991-12-10 The Dow Chemical Company Preforms for molding processes
US4992228A (en) 1989-09-28 1991-02-12 The Dow Chemical Company Method for preparing preforms for molding processes
DE4000173A1 (de) 1990-01-05 1991-07-11 Bayer Ag Waermeformbestaendige, gut verarbeitbare und thermostabile polycarbonat-formmassen
US5241880A (en) 1990-02-07 1993-09-07 Nippon Cable System, Inc. Control cable
US5116900A (en) 1990-02-13 1992-05-26 Owens-Corning Fiberglas Corporation Coating composition for fibers
US5207850A (en) 1990-07-17 1993-05-04 General Electric Company Process for making thermoplastic composites with cyclics oligomers and composites made thereby
NL9001641A (nl) 1990-07-19 1992-02-17 Stamicarbon Werkwijze voor het maken van polymere producten van cyclische esters.
US6353030B1 (en) 1990-08-01 2002-03-05 Novartis Ag Relating to organic compounds
US5095088A (en) 1990-08-13 1992-03-10 Shell Oil Company Cyclic polycarbonate oligomer containing spiro diLactam moieties
US5264548A (en) 1990-09-20 1993-11-23 General Electric Company Low melting cyclic polycarbonate composition
DE4034574A1 (de) 1990-10-31 1992-05-07 Bayer Ag Thermoplastmischungen
US5466744A (en) 1990-11-05 1995-11-14 General Electric Company Polymerization of macrocyclic poly(alkylene dicarboxylate) oligomers
US5039783A (en) 1990-11-05 1991-08-13 General Electric Company Method for preparing and polymerizing macrocyclic poly(alkylene discarboxylate) oligomers
US5136018A (en) 1990-11-19 1992-08-04 General Electric Company Macrocyclic polyarylate compositions of decreased crystallinity
JP3072334B2 (ja) 1991-03-11 2000-07-31 ヘンケル・コーポレーション 低分子量生成物を製造するための原料物質の解重合制御法
US5654395A (en) 1991-05-03 1997-08-05 Eastman Chemical Company Reinforced polyester compositions and method of making same
US5191013A (en) 1991-05-16 1993-03-02 General Electric Company Macrocyclic filled compositions convertible to polyester composites
US5214158A (en) 1991-06-03 1993-05-25 General Electric Company Method for preparation of macrocyclic poly(alkylene dicarboxylate) oligomers
KR940010346B1 (ko) 1991-06-12 1994-10-22 한국과학기술연구원 폴리부틸렌테레프탈레이트계 중합체의 제조방법
US5200496A (en) 1991-07-02 1993-04-06 The Dow Chemical Company Process for preparing polycarbonate having reduced carbonate byproduct content
US5128439A (en) 1991-10-11 1992-07-07 Exxon Research And Engineering Company Saturated polyesters and crosslinked membranes therefrom for aromatics/saturates separation
US5340909A (en) 1991-12-18 1994-08-23 Hoechst Celanese Corporation Poly(1,3-propylene terephthalate)
US5281669A (en) 1992-04-13 1994-01-25 General Electric Company Blends of linear polymers with macrocyclic oligomers
US5300392A (en) 1992-06-29 1994-04-05 Xerox Corporation Imaging member with polycarbonate obtained from cyclic oligomers
US5300393A (en) 1992-08-14 1994-04-05 Xerox Corporation Imaging members and processes for the preparation thereof
US5314779A (en) 1992-08-24 1994-05-24 Xerox Corporation Imaging members and processes for the preparation thereof
US5302484A (en) 1992-08-24 1994-04-12 Xerox Corporation Imaging members and processes for the preparation thereof
EP0589640A1 (de) 1992-09-24 1994-03-30 General Electric Company Makrocyklische Formmassen
US5830541A (en) 1992-09-30 1998-11-03 The Dow Chemical Company Process for electrostatically painting polymers containing a non-volatile metal salt conductivity inducing material
US5231161A (en) 1992-10-22 1993-07-27 General Electric Company Method for preparation of macrocyclic poly(alkylene dicarboxylate) oligomers from bis(hydroxyalkyl) dicarboxylates
US5321117A (en) 1992-11-19 1994-06-14 General Electric Company Macrocyclic polyester oligomer preparation with Lewis acid as catalyst
US5300590A (en) * 1992-11-30 1994-04-05 General Electric Company Macrocyclic polyester compositions convertible to linear polyesters of improved integrity
DE4244008C2 (de) 1992-12-24 1997-04-24 Bayer Ag Verfahren zur Herstellung von aliphatisch-aromatischen Polycarbonaten
ES2142379T3 (es) 1993-07-22 2000-04-16 Gen Electric Fosfitos ciclicos como estabilizadores de polimeros.
US5420226A (en) 1993-08-11 1995-05-30 Xerox Corporation Method of making photoreceptor charge transport layers
EP0655476A1 (de) 1993-11-29 1995-05-31 General Electric Company Faservorformlinge enthaltende zyklische Polyesteroligomere
US5968642A (en) 1993-12-22 1999-10-19 Dupont-Mitsui Fluorochemicals Co., Ltd. Article having a water-repellent fluororesin surface, and method for manufacturing the same
US5348985A (en) 1994-01-18 1994-09-20 General Electric Company Process for making thermoplastic polyester foams
US5356984A (en) 1994-02-14 1994-10-18 General Electric Company Method for molding magnets and compositions for use therein
GB9409293D0 (en) 1994-05-10 1994-06-29 Ici Plc Polyesters
US5389719A (en) 1994-06-20 1995-02-14 General Electric Company Method for polymerizing macrocyclic poly(alkylene dicarboxylate) oligomers
US5387666A (en) 1994-06-20 1995-02-07 General Electric Company Branched polyesters prepared from macrocyclic poly(Alkylene Dicarboxylate) oligomers
US5386037A (en) * 1994-06-20 1995-01-31 General Electric Company Trisstannoxanes useful for polymerizing macrocyclic poly(alkylene dicarboxylate) oligomers
US5407984A (en) 1994-08-31 1995-04-18 General Electric Company Process for preparing macrocyclic polyester oligomers
US5646454A (en) * 1994-09-24 1997-07-08 Robert Bosch Gmbh Electronic safety device for vehicle occupants including a memory device for storing fault conditions and associated control commands
US5446122A (en) 1994-11-30 1995-08-29 General Electric Company Process for preparing macrocyclic polyesters
US5434244A (en) 1994-12-09 1995-07-18 General Electric Company Process for isolating macrocyclic polyester oligomers
US5527976A (en) * 1995-01-12 1996-06-18 General Electric Company Method for polymerizing macrocyclic poly(alkylene dicarboxylate) oligomers
US5530052A (en) 1995-04-03 1996-06-25 General Electric Company Layered minerals and compositions comprising the same
US5693722A (en) 1995-05-22 1997-12-02 Bayer Corporation Method for modifying the backbone of polymeric resins
US5605979A (en) 1995-05-22 1997-02-25 Bayer Corporation Method for modifying the backbone of polymeric resins
JPH08323748A (ja) * 1995-05-29 1996-12-10 Toho Rayon Co Ltd 成形材料及びその製造方法
US5519108A (en) 1995-06-07 1996-05-21 Industrial Technology Research Institute Catalytic compositions containing tetrabutyl titanate and a mixture of cocatalysts for the preparation of poly(butylene terephthalate)
US5498651A (en) 1995-06-19 1996-03-12 General Electric Company Method for polymerizing macrocyclic polyester oligomers
US5663282A (en) 1995-11-13 1997-09-02 General Electric Company Method for producing polyesters
DE19546500A1 (de) * 1995-12-13 1997-06-19 Hoechst Ag Verfahren zur Herstellung eines Cycloolefincopolymeren
US5648454A (en) 1996-02-14 1997-07-15 General Electric Company Process for producing high ductile polyesters
US5710086A (en) 1996-03-20 1998-01-20 General Electric Company Titanate catalysts
US5668186A (en) 1996-03-20 1997-09-16 General Electric Company Process for depolymerizing polyesters
US5661214A (en) 1996-08-05 1997-08-26 General Electric Company Titanate esters useful as polymerization initiators for macrocylic polyester oligomers
US5700888A (en) 1996-11-07 1997-12-23 Bridgestone Corporation Synthesis of macrocyclic polymers having low hysteresis compounded properties
US5795423A (en) 1996-12-05 1998-08-18 Ford Global Technologies, Inc. Method for manufacturing a fiber reinforced article
US6395865B2 (en) * 1997-12-05 2002-05-28 Continental Pet Technologies Inc Process for making pen/pet blends and transparent articles therefrom
DE19651445A1 (de) 1996-12-11 1998-06-18 Bayer Ag Mischungen amidgruppenhaltiger Polycarbonatpolycyclen und ihre Herstellung
US5760161A (en) 1997-02-10 1998-06-02 Albemarle Corporation Process for making unsaturated, thermosetting, brominated phthalic anhydride/polyol polyester resins
DE19727271A1 (de) 1997-06-26 1999-01-07 Basf Ag Funktionalisierte Kohlenmonoxidcopolymere
US6432486B1 (en) * 1997-11-17 2002-08-13 Delta Airlines, Inc. Surface treatments for articles and vehicles
JP3373164B2 (ja) * 1997-12-26 2003-02-04 住友ベークライト株式会社 プリプレグ及び積層板の製造方法
US6124412A (en) 1997-12-29 2000-09-26 Saudi Basic Industries Corporation Alumoxane-enhanced, supported ziegler-natta polymerization catalysts, methods of making same, processes of using same and polymers produced therefrom
DE19808843C2 (de) 1998-03-03 2003-10-02 Degussa Verfahren zur Herstellung von makrocyclischen Estern
US6297330B1 (en) 1998-08-28 2001-10-02 E. I. Du Pont De Nemours And Company Polymerizations based on cyclic oligomer
US6080834A (en) 1999-04-16 2000-06-27 E. I. Du Pont De Nemours And Company Titanium-containing catalyst composition and processes therefor and therewith
JP2001031846A (ja) 1999-07-19 2001-02-06 Unitika Ltd ポリエステル組成物及びその製造法
US6376026B1 (en) 1999-12-20 2002-04-23 Rohm And Haas Company Method of coating with powders comprising macrocyclic oligomers
US6369157B1 (en) * 2000-01-21 2002-04-09 Cyclics Corporation Blend material including macrocyclic polyester oligomers and processes for polymerizing the same
US6420047B2 (en) * 2000-01-21 2002-07-16 Cyclics Corporation Macrocyclic polyester oligomers and processes for polymerizing the same
DE10041198B4 (de) * 2000-08-23 2004-01-15 Symrise Gmbh & Co. Kg Verfahren zur Herstellung makrocyclischer Ester
AU2001288663A1 (en) * 2000-09-01 2002-03-13 Cyclics Corporation Methods for converting linear polyesters to macrocyclic oligoester compositions and macrocyclic oligoesters
US6436548B1 (en) * 2000-09-12 2002-08-20 Cyclics Corporation Species modification in macrocyclic polyester oligomers, and compositions prepared thereby
US6376025B1 (en) * 2000-09-14 2002-04-23 Phillip Mark Method and system for applying minute bristles to a flow through applicator
US6420048B1 (en) * 2001-06-05 2002-07-16 Cyclics Corporation High molecular weight copolyesters from macrocyclic oligoesters and cyclic esters
US6436549B1 (en) * 2001-07-16 2002-08-20 Cyclics Corporation Block copolymers from macrocyclic oligoesters and dihydroxyl-functionalized polymers
US20040018883A1 (en) * 2002-07-17 2004-01-29 Robert Toth Bowling tournament method
CN100392006C (zh) * 2002-12-20 2008-06-04 陶氏环球技术公司 聚合的大环低聚物纳米复合材料组合物
JP2007521341A (ja) * 2002-12-23 2007-08-02 ダウ グローバル テクノロジーズ インコーポレイティド Ｓｍｃ成形方法

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US6639009B2 (en) 2003-10-28
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