DE4227299C1 - Verfahren zur Herstellung von monomeren Terephthalsäurediestern und Diolen aus Polyestern - Google Patents

Verfahren zur Herstellung von monomeren Terephthalsäurediestern und Diolen aus Polyestern

Info

Publication number
DE4227299C1
DE4227299C1 DE4227299A DE4227299A DE4227299C1 DE 4227299 C1 DE4227299 C1 DE 4227299C1 DE 4227299 A DE4227299 A DE 4227299A DE 4227299 A DE4227299 A DE 4227299A DE 4227299 C1 DE4227299 C1 DE 4227299C1
Authority
DE
Germany
Prior art keywords
transesterification
polyester
depolymerization
terephthalic acid
stage
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
DE4227299A
Other languages
German (de)
English (en)
Inventor
Ulrich Dr Hertenstein
Rudolf Neugebauer
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Hoechst AG
Original Assignee
Hoechst AG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Hoechst AG filed Critical Hoechst AG
Priority to DE4227299A priority Critical patent/DE4227299C1/de
Priority to TW082105966A priority patent/TW250484B/zh
Priority to ES93112942T priority patent/ES2098603T3/es
Priority to DE59305118T priority patent/DE59305118D1/de
Priority to AT93112942T priority patent/ATE147718T1/de
Priority to EP93112942A priority patent/EP0583743B1/de
Priority to DK93112942.3T priority patent/DK0583743T3/da
Priority to NZ248411A priority patent/NZ248411A/en
Priority to US08/107,236 priority patent/US5481024A/en
Priority to KR1019930015796A priority patent/KR940003915A/ko
Priority to MYPI93001533A priority patent/MY109890A/en
Priority to FI933610A priority patent/FI933610A7/fi
Priority to CZ931675A priority patent/CZ167593A3/cs
Priority to HU9302351A priority patent/HUT64937A/hu
Priority to TR00737/93A priority patent/TR28586A/xx
Priority to BR9303407A priority patent/BR9303407A/pt
Priority to RU93041382A priority patent/RU2103257C1/ru
Priority to MX9304997A priority patent/MX9304997A/es
Priority to CA002104253A priority patent/CA2104253A1/en
Priority to MA23261A priority patent/MA22954A1/fr
Priority to PL93300120A priority patent/PL300120A1/xx
Priority to NO932917A priority patent/NO180535C/no
Priority to IL106716A priority patent/IL106716A/xx
Priority to ZA935996A priority patent/ZA935996B/xx
Priority to CN93109298A priority patent/CN1086206A/zh
Priority to AU44663/93A priority patent/AU660371B2/en
Priority to JP5204199A priority patent/JPH06184053A/ja
Application granted granted Critical
Publication of DE4227299C1 publication Critical patent/DE4227299C1/de
Priority to GR970400655T priority patent/GR3022979T3/el
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
    • C08G63/02—Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds
    • C08G63/12—Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds derived from polycarboxylic acids and polyhydroxy compounds
    • C08G63/16—Dicarboxylic acids and dihydroxy compounds
    • C08G63/18—Dicarboxylic acids and dihydroxy compounds the acids or hydroxy compounds containing carbocyclic rings
    • C08G63/181—Acids containing aromatic rings
    • C08G63/183—Terephthalic acids
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/04—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing carboxylic acids or their salts
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00—Preparation of carboxylic acid esters
    • C07C67/03—Preparation of carboxylic acid esters by reacting an ester group with a hydroxy group
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/40—Substitution reactions at carbon centres, e.g. C-C or C-X, i.e. carbon-hetero atom, cross-coupling, C-H activation or ring-opening reactions
    • B01J2231/49—Esterification or transesterification

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Health & Medical Sciences (AREA)
  • Materials Engineering (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Separation, Recovery Or Treatment Of Waste Materials Containing Plastics (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Polyesters Or Polycarbonates (AREA)
  • Steroid Compounds (AREA)
  • Tires In General (AREA)
DE4227299A 1992-08-18 1992-08-18 Verfahren zur Herstellung von monomeren Terephthalsäurediestern und Diolen aus Polyestern Expired - Fee Related DE4227299C1 (de)

Priority Applications (28)

Application Number Priority Date Filing Date Title
DE4227299A DE4227299C1 (de) 1992-08-18 1992-08-18 Verfahren zur Herstellung von monomeren Terephthalsäurediestern und Diolen aus Polyestern
TW082105966A TW250484B (OSRAM) 1992-08-18 1993-07-27
DE59305118T DE59305118D1 (de) 1992-08-18 1993-08-12 Verfahren zur Herstellung von monomeren Terephthalsäurediestern und Diolen aus Polyestern
AT93112942T ATE147718T1 (de) 1992-08-18 1993-08-12 Verfahren zur herstellung von monomeren terephthalsäurediestern und diolen aus polyestern
EP93112942A EP0583743B1 (de) 1992-08-18 1993-08-12 Verfahren zur Herstellung von monomeren Terephthalsäurediestern und Diolen aus Polyestern
DK93112942.3T DK0583743T3 (da) 1992-08-18 1993-08-12 Fremgangsmåde til fremstilling af monomere terephthalsyrediestere og dioler ud fra polyestere
ES93112942T ES2098603T3 (es) 1992-08-18 1993-08-12 Procedimiento para la preparacion de diesteres de acido tereftalico y de dioles, monomeros, a partir de poliesteres.
US08/107,236 US5481024A (en) 1992-08-18 1993-08-16 Process for the preparation of monomeric terephthalic diesters and diols from polyesters
KR1019930015796A KR940003915A (ko) 1992-08-18 1993-08-16 폴리에스테르로부터 단량체 테레프탈산 디에스테르 및 디올의 제조방법
MYPI93001533A MY109890A (en) 1992-08-18 1993-08-16 Process for the preparation of monomeric terephthalic diesters and diols from polyesters
FI933610A FI933610A7 (fi) 1992-08-18 1993-08-16 Menetelmä monomeeristen tereftaalihappodiestereiden ja diolien valmistamiseksi polyestereistä
CZ931675A CZ167593A3 (en) 1992-08-18 1993-08-16 Process for preparing monomeric diesters of terephthalic acid and diols from polyesters
HU9302351A HUT64937A (en) 1992-08-18 1993-08-16 Method for producing monomeric terephthalic acid diesters and dioles from polyesters
TR00737/93A TR28586A (tr) 1992-08-18 1993-08-16 Poliester'lerden monomer tereftalik asit diesterlerinin ve diol'larin üretilmesine mahsus usul.
NZ248411A NZ248411A (en) 1992-08-18 1993-08-16 Preparation of terephthalic diesters and diols by depolymerisation of a polyester in the presence of a transesterification catalyst and a monohydric alcohol
MA23261A MA22954A1 (fr) 1992-08-18 1993-08-17 Procede de preparation de diesters de l'acide terephtalique, monomeres et de diols a partir de polyesters.
RU93041382A RU2103257C1 (ru) 1992-08-18 1993-08-17 Способ получения сложных диэфиров терефталевой кислоты и диолов сложных полиэфиров
MX9304997A MX9304997A (es) 1992-08-18 1993-08-17 Procedimiento para la preparacion de diesteres de acido tereftalico y de dioles, monomeros, a partir de poliesteres.
CA002104253A CA2104253A1 (en) 1992-08-18 1993-08-17 Process for the preparation of monomeric terephthalic diesters and diols from polyesters
BR9303407A BR9303407A (pt) 1992-08-18 1993-08-17 Processo para a preparacao de diesteres de acido tereftalico e diois
PL93300120A PL300120A1 (en) 1992-08-18 1993-08-17 Method of obtaining monomer terphtalic diesters and dioles from polyesters
NO932917A NO180535C (no) 1992-08-18 1993-08-17 Fremgangsmåte for fremstilling av monomere tereftalsyrediestere og dioler fra polyestere
IL106716A IL106716A (en) 1992-08-18 1993-08-17 Process for the preparation of monomeric terephthalic diesters and diols from polyesters
ZA935996A ZA935996B (en) 1992-08-18 1993-08-17 Process for the preparation of monomeric terephthalic diesters and diols from polyesters
CN93109298A CN1086206A (zh) 1992-08-18 1993-08-17 由聚酯制造对苯二甲酸二酯和二醇单体的方法
AU44663/93A AU660371B2 (en) 1992-08-18 1993-08-17 Process for the preparation of monomeric terephthalic diesters and diols from polyesters
JP5204199A JPH06184053A (ja) 1992-08-18 1993-08-18 ポリエステルからモノマーテレフタル酸ジエステル及びモノマーテレフタル酸ジオールを調製する方法
GR970400655T GR3022979T3 (en) 1992-08-18 1997-03-31 Process for the production of monomeric terephthalic acid diesters and diols from polyesters

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
DE4227299A DE4227299C1 (de) 1992-08-18 1992-08-18 Verfahren zur Herstellung von monomeren Terephthalsäurediestern und Diolen aus Polyestern

Publications (1)

Publication Number Publication Date
DE4227299C1 true DE4227299C1 (de) 1994-01-27

Family

ID=6465793

Family Applications (2)

Application Number Title Priority Date Filing Date
DE4227299A Expired - Fee Related DE4227299C1 (de) 1992-08-18 1992-08-18 Verfahren zur Herstellung von monomeren Terephthalsäurediestern und Diolen aus Polyestern
DE59305118T Expired - Fee Related DE59305118D1 (de) 1992-08-18 1993-08-12 Verfahren zur Herstellung von monomeren Terephthalsäurediestern und Diolen aus Polyestern

Family Applications After (1)

Application Number Title Priority Date Filing Date
DE59305118T Expired - Fee Related DE59305118D1 (de) 1992-08-18 1993-08-12 Verfahren zur Herstellung von monomeren Terephthalsäurediestern und Diolen aus Polyestern

Country Status (27)

Country Link
US (1) US5481024A (OSRAM)
EP (1) EP0583743B1 (OSRAM)
JP (1) JPH06184053A (OSRAM)
KR (1) KR940003915A (OSRAM)
CN (1) CN1086206A (OSRAM)
AT (1) ATE147718T1 (OSRAM)
AU (1) AU660371B2 (OSRAM)
BR (1) BR9303407A (OSRAM)
CA (1) CA2104253A1 (OSRAM)
CZ (1) CZ167593A3 (OSRAM)
DE (2) DE4227299C1 (OSRAM)
DK (1) DK0583743T3 (OSRAM)
ES (1) ES2098603T3 (OSRAM)
FI (1) FI933610A7 (OSRAM)
GR (1) GR3022979T3 (OSRAM)
HU (1) HUT64937A (OSRAM)
IL (1) IL106716A (OSRAM)
MA (1) MA22954A1 (OSRAM)
MX (1) MX9304997A (OSRAM)
MY (1) MY109890A (OSRAM)
NO (1) NO180535C (OSRAM)
NZ (1) NZ248411A (OSRAM)
PL (1) PL300120A1 (OSRAM)
RU (1) RU2103257C1 (OSRAM)
TR (1) TR28586A (OSRAM)
TW (1) TW250484B (OSRAM)
ZA (1) ZA935996B (OSRAM)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0717030B2 (en) † 1994-12-12 2003-11-05 Eastman Kodak Company Recovery of ester monomers from polyester resins

Families Citing this family (16)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5710315A (en) * 1994-05-27 1998-01-20 E. I. Du Pont De Nemours And Company Monomer recovery process for contaminated polymers
US5744503A (en) * 1996-02-01 1998-04-28 Hoechst Celanese Corporation Recycling polyester and recovering glycols
CN1203037C (zh) * 1999-10-22 2005-05-25 帝人株式会社 从聚酯废料中分离和回收对苯二甲酸二甲酯和乙二醇的方法
CZ288622B6 (cs) * 2000-03-17 2001-08-15 Milan Ing. Šírek Způsob chemické recyklace odpadního polyethylentereftalátu
TWI313188B (en) * 2002-09-12 2009-08-11 Shell Int Research Catalytic conversion of an organic carbonate
RU2458946C2 (ru) * 2005-12-29 2012-08-20 Бп Корпорейшн Норт Америка Инк. Способ этанолиза поли(этилентерефталата) (пэт) с образованием диэтилентерефталата
GB201009969D0 (en) 2010-06-15 2010-07-21 Ecosynth Bvba Transesterification process using mixed salt acetylacetonates catalysts
US9981902B2 (en) 2015-10-23 2018-05-29 Columbia Insurance Company Process for production of an ester and diol from reclaimed carpet material
WO2017087752A1 (en) 2015-11-20 2017-05-26 The University Of North Carolina At Chapel Hill Chemical recycling of polyethylene terephthalate by microwave irradiation
CN108004759B (zh) * 2017-12-21 2020-05-22 福建荔枝新材料有限公司 一种聚酯材料回收及利用激光进行表面处理方法
KR20220118503A (ko) * 2019-12-19 2022-08-25 이스트만 케미칼 컴파니 다이메틸 테레프탈레이트를 폴리에스터 가메탄올분해 해중합 시스템으로부터 제조하는 방법
CN115244120B (zh) * 2020-01-23 2025-01-14 普莱米尔塑料公司 用于解聚废塑料的方法和系统
US11639431B2 (en) * 2020-01-23 2023-05-02 Premirr Plastics Inc. Process and system for depolymerizing plastic
CN112076790B (zh) * 2020-08-27 2021-07-23 中国科学院青岛生物能源与过程研究所 一种应用聚酯材料可控解聚的锌催化剂及其催化方法
KR102505758B1 (ko) * 2021-03-30 2023-03-06 김수연 응축수 배관의 수격 방지 장치
CN119039136B (zh) * 2024-10-30 2025-02-21 浙江大学 一种芳香酯类溶剂降解升级聚酯类材料的方法

Family Cites Families (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2884443A (en) * 1955-03-19 1959-04-28 Glanzstoff Ag Process for the regeneration of terephthalic acid dimethyl ester from polyethylene terephthalate
US3037050A (en) * 1955-08-05 1962-05-29 Glanzstoff Ag Regeneration of terephthalic acid dimethyl ester from polyethylene terephthalate
DE1003714B (de) * 1956-01-25 1957-03-07 Glanzstoff Ag Verfahren zum Abbau von Polyaethylenterephthalat zu Terephthalsaeuredimethylester
BE635706A (OSRAM) * 1962-08-17
NL301426A (OSRAM) * 1962-12-06
CH550753A (it) * 1970-11-26 1974-06-28 Sir Soc Italiana Resine Spa Procedimento per la depolimerizzazione di polietilentereftalato.
US5051528A (en) * 1990-04-24 1991-09-24 Eastman Kodak Company Recovery process for ethylene glycol and dimethylterephthalate

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
Der Versuchsbericht eingegangen am 4.6.93 eingegangen ist zur Einsicht für jedermann bereitzuhalten *

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0717030B2 (en) † 1994-12-12 2003-11-05 Eastman Kodak Company Recovery of ester monomers from polyester resins

Also Published As

Publication number Publication date
NO180535C (no) 1997-05-07
EP0583743A2 (de) 1994-02-23
US5481024A (en) 1996-01-02
JPH06184053A (ja) 1994-07-05
TR28586A (tr) 1996-11-07
IL106716A (en) 1997-06-10
MX9304997A (es) 1994-05-31
MA22954A1 (fr) 1994-04-01
DK0583743T3 (da) 1997-06-09
NO932917L (no) 1994-02-21
TW250484B (OSRAM) 1995-07-01
EP0583743B1 (de) 1997-01-15
PL300120A1 (en) 1994-03-07
DE59305118D1 (de) 1997-02-27
CN1086206A (zh) 1994-05-04
FI933610L (fi) 1994-02-19
ZA935996B (en) 1994-03-14
FI933610A7 (fi) 1994-02-19
FI933610A0 (fi) 1993-08-16
CA2104253A1 (en) 1994-02-19
BR9303407A (pt) 1994-03-01
RU2103257C1 (ru) 1998-01-27
NO932917D0 (no) 1993-08-17
NZ248411A (en) 1995-02-24
NO180535B (no) 1997-01-27
ES2098603T3 (es) 1997-05-01
MY109890A (en) 1997-09-30
AU4466393A (en) 1994-02-24
EP0583743A3 (OSRAM) 1994-08-31
KR940003915A (ko) 1994-03-14
ATE147718T1 (de) 1997-02-15
HUT64937A (en) 1994-03-28
CZ167593A3 (en) 1994-03-16
HU9302351D0 (en) 1993-11-29
IL106716A0 (en) 1993-12-08
AU660371B2 (en) 1995-06-22
GR3022979T3 (en) 1997-06-30

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Legal Events

Date Code Title Description
8100 Publication of patent without earlier publication of application
D1 Grant (no unexamined application published) patent law 81
8364 No opposition during term of opposition
8339 Ceased/non-payment of the annual fee