MX9304997A - Procedimiento para la preparacion de diesteres de acido tereftalico y de dioles, monomeros, a partir de poliesteres. - Google Patents

Procedimiento para la preparacion de diesteres de acido tereftalico y de dioles, monomeros, a partir de poliesteres.

Info

Publication number
MX9304997A
MX9304997A MX9304997A MX9304997A MX9304997A MX 9304997 A MX9304997 A MX 9304997A MX 9304997 A MX9304997 A MX 9304997A MX 9304997 A MX9304997 A MX 9304997A MX 9304997 A MX9304997 A MX 9304997A
Authority
MX
Mexico
Prior art keywords
polyesters
preparation
diesters
tereftalico
dioles
Prior art date
Application number
MX9304997A
Other languages
English (en)
Inventor
Ulrich Hertenstein
Rudolf Neugebauer
Original Assignee
Hoechst Ag
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Hoechst Ag filed Critical Hoechst Ag
Publication of MX9304997A publication Critical patent/MX9304997A/es

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
    • C08G63/02—Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds
    • C08G63/12—Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds derived from polycarboxylic acids and polyhydroxy compounds
    • C08G63/16—Dicarboxylic acids and dihydroxy compounds
    • C08G63/18—Dicarboxylic acids and dihydroxy compounds the acids or hydroxy compounds containing carbocyclic rings
    • C08G63/181—Acids containing aromatic rings
    • C08G63/183—Terephthalic acids
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/04—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing carboxylic acids or their salts
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00—Preparation of carboxylic acid esters
    • C07C67/03—Preparation of carboxylic acid esters by reacting an ester group with a hydroxy group
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/40—Substitution reactions at carbon centres, e.g. C-C or C-X, i.e. carbon-hetero atom, cross-coupling, C-H activation or ring-opening reactions
    • B01J2231/49—Esterification or transesterification

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Separation, Recovery Or Treatment Of Waste Materials Containing Plastics (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Polyesters Or Polycarbonates (AREA)
  • Steroid Compounds (AREA)
  • Tires In General (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)

Abstract

Se describe un nuevo procedimiento para la preparación de diésteres de ácido tereftálico y dioles de poliésteres. El procedimiento está caracterizado por una despolimerización de poliéster en presencia de catalizadores de transesterificación para el mencionado poliéster y en presencia de un éster, y por una posterior transesterificación de la mezcla de reacción para formar diésteres de ácido tereftálico por reacción con un alcohol univalente. Mediante el nuevo procedimiento los componentes de partida de poliésteres se pueden recuperar con rapidez y bajo condiciones suaves de la reacción.
MX9304997A 1992-08-18 1993-08-17 Procedimiento para la preparacion de diesteres de acido tereftalico y de dioles, monomeros, a partir de poliesteres. MX9304997A (es)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
DE4227299A DE4227299C1 (de) 1992-08-18 1992-08-18 Verfahren zur Herstellung von monomeren Terephthalsäurediestern und Diolen aus Polyestern

Publications (1)

Publication Number Publication Date
MX9304997A true MX9304997A (es) 1994-05-31

Family

ID=6465793

Family Applications (1)

Application Number Title Priority Date Filing Date
MX9304997A MX9304997A (es) 1992-08-18 1993-08-17 Procedimiento para la preparacion de diesteres de acido tereftalico y de dioles, monomeros, a partir de poliesteres.

Country Status (27)

Country Link
US (1) US5481024A (es)
EP (1) EP0583743B1 (es)
JP (1) JPH06184053A (es)
KR (1) KR940003915A (es)
CN (1) CN1086206A (es)
AT (1) ATE147718T1 (es)
AU (1) AU660371B2 (es)
BR (1) BR9303407A (es)
CA (1) CA2104253A1 (es)
CZ (1) CZ167593A3 (es)
DE (2) DE4227299C1 (es)
DK (1) DK0583743T3 (es)
ES (1) ES2098603T3 (es)
FI (1) FI933610A (es)
GR (1) GR3022979T3 (es)
HU (1) HUT64937A (es)
IL (1) IL106716A (es)
MA (1) MA22954A1 (es)
MX (1) MX9304997A (es)
MY (1) MY109890A (es)
NO (1) NO180535C (es)
NZ (1) NZ248411A (es)
PL (1) PL300120A1 (es)
RU (1) RU2103257C1 (es)
TR (1) TR28586A (es)
TW (1) TW250484B (es)
ZA (1) ZA935996B (es)

Families Citing this family (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5710315A (en) * 1994-05-27 1998-01-20 E. I. Du Pont De Nemours And Company Monomer recovery process for contaminated polymers
US5432203A (en) † 1994-12-12 1995-07-11 Eastman Kodak Company Process of recovering components from polyester resins
US5744503A (en) * 1996-02-01 1998-04-28 Hoechst Celanese Corporation Recycling polyester and recovering glycols
CN1203037C (zh) * 1999-10-22 2005-05-25 帝人株式会社 从聚酯废料中分离和回收对苯二甲酸二甲酯和乙二醇的方法
RU2458946C2 (ru) * 2005-12-29 2012-08-20 Бп Корпорейшн Норт Америка Инк. Способ этанолиза поли(этилентерефталата) (пэт) с образованием диэтилентерефталата
GB201009969D0 (en) 2010-06-15 2010-07-21 Ecosynth Bvba Transesterification process using mixed salt acetylacetonates catalysts
US9981902B2 (en) 2015-10-23 2018-05-29 Columbia Insurance Company Process for production of an ester and diol from reclaimed carpet material
US10508186B2 (en) 2015-11-20 2019-12-17 The University Of North Carolina At Chapel Hill Chemical recycling of polyethylene terephthalate by microwave irradiation
CN108004759B (zh) * 2017-12-21 2020-05-22 福建荔枝新材料有限公司 一种聚酯材料回收及利用激光进行表面处理方法
EP4077267A1 (en) * 2019-12-19 2022-10-26 Eastman Chemical Company Method for producing dimethyl terephthalate from polyester methanolysis depolymerization systems
MX2022008680A (es) * 2020-01-23 2022-10-03 Premirr Plastics Inc Proceso y sistema para la despolimerización de residuos plásticos.
US11639431B2 (en) * 2020-01-23 2023-05-02 Premirr Plastics Inc. Process and system for depolymerizing plastic
CN112076790B (zh) * 2020-08-27 2021-07-23 中国科学院青岛生物能源与过程研究所 一种应用聚酯材料可控解聚的锌催化剂及其催化方法
KR102505758B1 (ko) * 2021-03-30 2023-03-06 김수연 응축수 배관의 수격 방지 장치

Family Cites Families (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2884443A (en) * 1955-03-19 1959-04-28 Glanzstoff Ag Process for the regeneration of terephthalic acid dimethyl ester from polyethylene terephthalate
US3037050A (en) * 1955-08-05 1962-05-29 Glanzstoff Ag Regeneration of terephthalic acid dimethyl ester from polyethylene terephthalate
DE1003714B (de) * 1956-01-25 1957-03-07 Glanzstoff Ag Verfahren zum Abbau von Polyaethylenterephthalat zu Terephthalsaeuredimethylester
NL136399C (es) * 1962-08-17 1900-01-01
NL301426A (es) * 1962-12-06
CH550753A (it) * 1970-11-26 1974-06-28 Sir Soc Italiana Resine Spa Procedimento per la depolimerizzazione di polietilentereftalato.
US5051528A (en) * 1990-04-24 1991-09-24 Eastman Kodak Company Recovery process for ethylene glycol and dimethylterephthalate

Also Published As

Publication number Publication date
EP0583743B1 (de) 1997-01-15
BR9303407A (pt) 1994-03-01
ATE147718T1 (de) 1997-02-15
KR940003915A (ko) 1994-03-14
IL106716A (en) 1997-06-10
ZA935996B (en) 1994-03-14
TW250484B (es) 1995-07-01
HUT64937A (en) 1994-03-28
MY109890A (en) 1997-09-30
TR28586A (tr) 1996-11-07
DE59305118D1 (de) 1997-02-27
IL106716A0 (en) 1993-12-08
DK0583743T3 (da) 1997-06-09
CZ167593A3 (en) 1994-03-16
EP0583743A2 (de) 1994-02-23
CA2104253A1 (en) 1994-02-19
AU660371B2 (en) 1995-06-22
MA22954A1 (fr) 1994-04-01
FI933610A0 (fi) 1993-08-16
GR3022979T3 (en) 1997-06-30
RU2103257C1 (ru) 1998-01-27
PL300120A1 (en) 1994-03-07
NO932917L (no) 1994-02-21
EP0583743A3 (es) 1994-08-31
NO932917D0 (no) 1993-08-17
AU4466393A (en) 1994-02-24
NO180535B (no) 1997-01-27
US5481024A (en) 1996-01-02
NZ248411A (en) 1995-02-24
FI933610A (fi) 1994-02-19
ES2098603T3 (es) 1997-05-01
DE4227299C1 (de) 1994-01-27
HU9302351D0 (en) 1993-11-29
CN1086206A (zh) 1994-05-04
JPH06184053A (ja) 1994-07-05
NO180535C (no) 1997-05-07

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Legal Events

Date Code Title Description
FG Grant or registration
MM Annulment or lapse due to non-payment of fees