DE3519430C2 - Kautschukmasse für Kraftfahrzeugreifen - Google Patents
Kautschukmasse für KraftfahrzeugreifenInfo
- Publication number
- DE3519430C2 DE3519430C2 DE3519430A DE3519430A DE3519430C2 DE 3519430 C2 DE3519430 C2 DE 3519430C2 DE 3519430 A DE3519430 A DE 3519430A DE 3519430 A DE3519430 A DE 3519430A DE 3519430 C2 DE3519430 C2 DE 3519430C2
- Authority
- DE
- Germany
- Prior art keywords
- copolymer
- tin
- rubber
- vinyl
- content
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 229920001971 elastomer Polymers 0.000 title claims abstract description 34
- 239000005060 rubber Substances 0.000 title claims abstract description 34
- 150000001875 compounds Chemical class 0.000 title claims description 12
- 239000003999 initiator Substances 0.000 claims abstract description 24
- 150000001993 dienes Chemical class 0.000 claims abstract description 16
- 150000004945 aromatic hydrocarbons Chemical class 0.000 claims abstract description 14
- 229920005604 random copolymer Polymers 0.000 claims abstract description 7
- 238000005859 coupling reaction Methods 0.000 claims abstract description 6
- 125000001979 organolithium group Chemical group 0.000 claims description 10
- 239000000178 monomer Substances 0.000 claims description 5
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 claims 1
- 229920001577 copolymer Polymers 0.000 abstract description 31
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 abstract description 23
- 239000000203 mixture Substances 0.000 abstract description 17
- 238000005096 rolling process Methods 0.000 abstract description 15
- 238000007334 copolymerization reaction Methods 0.000 abstract description 12
- 230000008878 coupling Effects 0.000 abstract description 5
- 238000010168 coupling process Methods 0.000 abstract description 5
- 239000007822 coupling agent Substances 0.000 abstract description 4
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 26
- 229910052718 tin Inorganic materials 0.000 description 23
- 229920000642 polymer Polymers 0.000 description 16
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 description 10
- 238000004458 analytical method Methods 0.000 description 9
- 229920002554 vinyl polymer Polymers 0.000 description 9
- 238000012986 modification Methods 0.000 description 7
- 230000004048 modification Effects 0.000 description 7
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 6
- MZRVEZGGRBJDDB-UHFFFAOYSA-N N-Butyllithium Chemical compound [Li]CCCC MZRVEZGGRBJDDB-UHFFFAOYSA-N 0.000 description 6
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 6
- 229920003048 styrene butadiene rubber Polymers 0.000 description 6
- 150000003606 tin compounds Chemical group 0.000 description 5
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 description 4
- 230000000052 comparative effect Effects 0.000 description 4
- RJGHQTVXGKYATR-UHFFFAOYSA-L dibutyl(dichloro)stannane Chemical compound CCCC[Sn](Cl)(Cl)CCCC RJGHQTVXGKYATR-UHFFFAOYSA-L 0.000 description 4
- 229920002857 polybutadiene Polymers 0.000 description 4
- YMWUJEATGCHHMB-UHFFFAOYSA-N Dichloromethane Chemical compound ClCCl YMWUJEATGCHHMB-UHFFFAOYSA-N 0.000 description 3
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
- IMNFDUFMRHMDMM-UHFFFAOYSA-N N-Heptane Chemical compound CCCCCCC IMNFDUFMRHMDMM-UHFFFAOYSA-N 0.000 description 3
- 239000005062 Polybutadiene Substances 0.000 description 3
- -1 ar-methylstyrene Chemical compound 0.000 description 3
- 125000003118 aryl group Chemical class 0.000 description 3
- 238000009826 distribution Methods 0.000 description 3
- 239000002184 metal Substances 0.000 description 3
- 229910052751 metal Inorganic materials 0.000 description 3
- 239000003921 oil Substances 0.000 description 3
- 239000002904 solvent Substances 0.000 description 3
- MYRTYDVEIRVNKP-UHFFFAOYSA-N 1,2-Divinylbenzene Chemical compound C=CC1=CC=CC=C1C=C MYRTYDVEIRVNKP-UHFFFAOYSA-N 0.000 description 2
- HIACAHMKXQESOV-UHFFFAOYSA-N 1,2-bis(prop-1-en-2-yl)benzene Chemical compound CC(=C)C1=CC=CC=C1C(C)=C HIACAHMKXQESOV-UHFFFAOYSA-N 0.000 description 2
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- NLZUEZXRPGMBCV-UHFFFAOYSA-N Butylhydroxytoluene Chemical compound CC1=CC(C(C)(C)C)=C(O)C(C(C)(C)C)=C1 NLZUEZXRPGMBCV-UHFFFAOYSA-N 0.000 description 2
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 2
- ZRALSGWEFCBTJO-UHFFFAOYSA-N Guanidine Chemical compound NC(N)=N ZRALSGWEFCBTJO-UHFFFAOYSA-N 0.000 description 2
- RRHGJUQNOFWUDK-UHFFFAOYSA-N Isoprene Chemical compound CC(=C)C=C RRHGJUQNOFWUDK-UHFFFAOYSA-N 0.000 description 2
- 239000004793 Polystyrene Substances 0.000 description 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
- 239000002174 Styrene-butadiene Substances 0.000 description 2
- 229910021626 Tin(II) chloride Inorganic materials 0.000 description 2
- 229910021627 Tin(IV) chloride Inorganic materials 0.000 description 2
- GCTFWCDSFPMHHS-UHFFFAOYSA-M Tributyltin chloride Chemical compound CCCC[Sn](Cl)(CCCC)CCCC GCTFWCDSFPMHHS-UHFFFAOYSA-M 0.000 description 2
- 239000000654 additive Substances 0.000 description 2
- 125000000217 alkyl group Chemical group 0.000 description 2
- 239000010692 aromatic oil Substances 0.000 description 2
- YMLFYGFCXGNERH-UHFFFAOYSA-K butyltin trichloride Chemical compound CCCC[Sn](Cl)(Cl)Cl YMLFYGFCXGNERH-UHFFFAOYSA-K 0.000 description 2
- VTYYLEPIZMXCLO-UHFFFAOYSA-L calcium carbonate Substances [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 2
- PKKGKUDPKRTKLJ-UHFFFAOYSA-L dichloro(dimethyl)stannane Chemical compound C[Sn](C)(Cl)Cl PKKGKUDPKRTKLJ-UHFFFAOYSA-L 0.000 description 2
- 125000005843 halogen group Chemical group 0.000 description 2
- WGOPGODQLGJZGL-UHFFFAOYSA-N lithium;butane Chemical compound [Li+].CC[CH-]C WGOPGODQLGJZGL-UHFFFAOYSA-N 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- 150000002900 organolithium compounds Chemical class 0.000 description 2
- 239000003505 polymerization initiator Substances 0.000 description 2
- 238000006116 polymerization reaction Methods 0.000 description 2
- 235000012239 silicon dioxide Nutrition 0.000 description 2
- 235000011150 stannous chloride Nutrition 0.000 description 2
- 229920003051 synthetic elastomer Polymers 0.000 description 2
- YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 description 2
- AXZWODMDQAVCJE-UHFFFAOYSA-L tin(II) chloride (anhydrous) Chemical compound [Cl-].[Cl-].[Sn+2] AXZWODMDQAVCJE-UHFFFAOYSA-L 0.000 description 2
- HPGGPRDJHPYFRM-UHFFFAOYSA-J tin(iv) chloride Chemical compound Cl[Sn](Cl)(Cl)Cl HPGGPRDJHPYFRM-UHFFFAOYSA-J 0.000 description 2
- YFRLQYJXUZRYDN-UHFFFAOYSA-K trichloro(methyl)stannane Chemical compound C[Sn](Cl)(Cl)Cl YFRLQYJXUZRYDN-UHFFFAOYSA-K 0.000 description 2
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 2
- 238000004073 vulcanization Methods 0.000 description 2
- YXIWHUQXZSMYRE-UHFFFAOYSA-N 1,3-benzothiazole-2-thiol Chemical compound C1=CC=C2SC(S)=NC2=C1 YXIWHUQXZSMYRE-UHFFFAOYSA-N 0.000 description 1
- OWRCNXZUPFZXOS-UHFFFAOYSA-N 1,3-diphenylguanidine Chemical compound C=1C=CC=CC=1NC(=N)NC1=CC=CC=C1 OWRCNXZUPFZXOS-UHFFFAOYSA-N 0.000 description 1
- JLBJTVDPSNHSKJ-UHFFFAOYSA-N 4-Methylstyrene Chemical compound CC1=CC=C(C=C)C=C1 JLBJTVDPSNHSKJ-UHFFFAOYSA-N 0.000 description 1
- VXEGSRKPIUDPQT-UHFFFAOYSA-N 4-[4-(4-methoxyphenyl)piperazin-1-yl]aniline Chemical compound C1=CC(OC)=CC=C1N1CCN(C=2C=CC(N)=CC=2)CC1 VXEGSRKPIUDPQT-UHFFFAOYSA-N 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- XDTMQSROBMDMFD-UHFFFAOYSA-N Cyclohexane Chemical compound C1CCCCC1 XDTMQSROBMDMFD-UHFFFAOYSA-N 0.000 description 1
- 229920002943 EPDM rubber Polymers 0.000 description 1
- 244000043261 Hevea brasiliensis Species 0.000 description 1
- 238000004566 IR spectroscopy Methods 0.000 description 1
- 229930195132 Millinol Natural products 0.000 description 1
- CHJJGSNFBQVOTG-UHFFFAOYSA-N N-methyl-guanidine Natural products CNC(N)=N CHJJGSNFBQVOTG-UHFFFAOYSA-N 0.000 description 1
- 235000021355 Stearic acid Nutrition 0.000 description 1
- 229920006328 Styrofoam Polymers 0.000 description 1
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 1
- VOTZHAZMXFYESM-UHFFFAOYSA-N [Li]C1=CC=CC([Li])=C1 Chemical compound [Li]C1=CC=CC([Li])=C1 VOTZHAZMXFYESM-UHFFFAOYSA-N 0.000 description 1
- CEAYJLIWHKSKBI-UHFFFAOYSA-N [Li]C1CCC([Li])CC1 Chemical compound [Li]C1CCC([Li])CC1 CEAYJLIWHKSKBI-UHFFFAOYSA-N 0.000 description 1
- 238000005299 abrasion Methods 0.000 description 1
- 235000011037 adipic acid Nutrition 0.000 description 1
- 239000001361 adipic acid Substances 0.000 description 1
- 125000003710 aryl alkyl group Chemical group 0.000 description 1
- 238000001479 atomic absorption spectroscopy Methods 0.000 description 1
- 230000027455 binding Effects 0.000 description 1
- 238000009739 binding Methods 0.000 description 1
- MTAZNLWOLGHBHU-UHFFFAOYSA-N butadiene-styrene rubber Chemical compound C=CC=C.C=CC1=CC=CC=C1 MTAZNLWOLGHBHU-UHFFFAOYSA-N 0.000 description 1
- 235000010216 calcium carbonate Nutrition 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 239000006229 carbon black Substances 0.000 description 1
- 235000019241 carbon black Nutrition 0.000 description 1
- 125000000753 cycloalkyl group Chemical group 0.000 description 1
- SWSQBOPZIKWTGO-UHFFFAOYSA-N dimethylaminoamidine Natural products CN(C)C(N)=N SWSQBOPZIKWTGO-UHFFFAOYSA-N 0.000 description 1
- 238000007720 emulsion polymerization reaction Methods 0.000 description 1
- 238000011156 evaluation Methods 0.000 description 1
- 238000010528 free radical solution polymerization reaction Methods 0.000 description 1
- 239000000446 fuel Substances 0.000 description 1
- 238000005227 gel permeation chromatography Methods 0.000 description 1
- 229910052732 germanium Inorganic materials 0.000 description 1
- VLKZOEOYAKHREP-UHFFFAOYSA-N hexane Substances CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 1
- WNLRTRBMVRJNCN-UHFFFAOYSA-N hexanedioic acid Natural products OC(=O)CCCCC(O)=O WNLRTRBMVRJNCN-UHFFFAOYSA-N 0.000 description 1
- 238000009776 industrial production Methods 0.000 description 1
- 238000004898 kneading Methods 0.000 description 1
- 229910052745 lead Inorganic materials 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 229920003052 natural elastomer Polymers 0.000 description 1
- 229920001194 natural rubber Polymers 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 1
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 description 1
- 229920001195 polyisoprene Polymers 0.000 description 1
- 239000002244 precipitate Substances 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- RMAQACBXLXPBSY-UHFFFAOYSA-N silicic acid Chemical compound O[Si](O)(O)O RMAQACBXLXPBSY-UHFFFAOYSA-N 0.000 description 1
- 229910052710 silicon Inorganic materials 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 239000005049 silicon tetrachloride Substances 0.000 description 1
- 239000008117 stearic acid Substances 0.000 description 1
- 239000011115 styrene butadiene Substances 0.000 description 1
- 239000008261 styrofoam Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 239000005061 synthetic rubber Substances 0.000 description 1
- 229920001897 terpolymer Polymers 0.000 description 1
- 150000003512 tertiary amines Chemical class 0.000 description 1
- 125000000383 tetramethylene group Chemical group [H]C([H])([*:1])C([H])([H])C([H])([H])C([H])([H])[*:2] 0.000 description 1
- 235000014692 zinc oxide Nutrition 0.000 description 1
- 239000011787 zinc oxide Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08C—TREATMENT OR CHEMICAL MODIFICATION OF RUBBERS
- C08C19/00—Chemical modification of rubber
- C08C19/30—Addition of a reagent which reacts with a hetero atom or a group containing hetero atoms of the macromolecule
- C08C19/42—Addition of a reagent which reacts with a hetero atom or a group containing hetero atoms of the macromolecule reacting with metals or metal-containing groups
- C08C19/44—Addition of a reagent which reacts with a hetero atom or a group containing hetero atoms of the macromolecule reacting with metals or metal-containing groups of polymers containing metal atoms exclusively at one or both ends of the skeleton
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L9/00—Compositions of homopolymers or copolymers of conjugated diene hydrocarbons
- C08L9/06—Copolymers with styrene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/56—Organo-metallic compounds, i.e. organic compounds containing a metal-to-carbon bond
- C08K5/57—Organo-tin compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L7/00—Compositions of natural rubber
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L9/00—Compositions of homopolymers or copolymers of conjugated diene hydrocarbons
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Polymerization Catalysts (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP59110870A JPS60255838A (ja) | 1984-06-01 | 1984-06-01 | タイヤ用ゴム組成物 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| DE3519430A1 DE3519430A1 (de) | 1985-12-05 |
| DE3519430C2 true DE3519430C2 (de) | 1986-04-10 |
Family
ID=14546782
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE3519430A Expired DE3519430C2 (de) | 1984-06-01 | 1985-05-30 | Kautschukmasse für Kraftfahrzeugreifen |
Country Status (5)
| Country | Link |
|---|---|
| US (1) | US4742124A (enExample) |
| JP (1) | JPS60255838A (enExample) |
| DE (1) | DE3519430C2 (enExample) |
| FR (1) | FR2565236B1 (enExample) |
| GB (1) | GB2160207B (enExample) |
Families Citing this family (61)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS63297438A (ja) * | 1987-05-28 | 1988-12-05 | Toyo Tire & Rubber Co Ltd | タイヤトレッド用ゴム組成物 |
| DE69212669T2 (de) * | 1991-03-05 | 1997-01-30 | Bridgestone Corp | Luftreifen |
| US5173550A (en) * | 1991-04-05 | 1992-12-22 | The Goodyear Tire & Rubber Company | Synthesis of random styrene-isoprene rubbers |
| JP2611717B2 (ja) * | 1992-06-10 | 1997-05-21 | 住友化学工業株式会社 | ブタジエン系共重合体 |
| CA2111143A1 (en) * | 1992-12-11 | 1994-06-12 | Yuichi Saito | Rubber composition for tire treads |
| US5430086A (en) * | 1992-12-11 | 1995-07-04 | Sumitomo Rubber Industries | Rubber composition for tire treads |
| DE69501999T2 (de) * | 1994-10-28 | 1998-09-10 | Bridgestone Corp | Kautschukmischung für Laufflächen |
| CN1045779C (zh) * | 1995-10-17 | 1999-10-20 | 中国石油化工总公司 | 星形溶聚丁苯橡胶的合成方法 |
| CN1048989C (zh) * | 1995-10-17 | 2000-02-02 | 中国石油化工总公司 | 多官能团有机碱金属引发剂及其合成方法 |
| US6127472A (en) * | 1997-11-11 | 2000-10-03 | Jsr Corporation | Rubber composition |
| US20020107317A1 (en) * | 1998-02-06 | 2002-08-08 | Luciano Garro | Vulcanizable rubber composition, in particular for low rolling resistance treads of vehicle tires |
| US6211271B1 (en) | 1998-07-15 | 2001-04-03 | Pirelli Pneumatici S.P.A. | Process for producing a vulcanizable rubber composition including carbon black-based and silica-based reinforcing fillers |
| ES2254259T3 (es) * | 1999-12-30 | 2006-06-16 | Pirelli Pneumatici Societa Per Azioni | Neumatico que comprende un polimero hidrofilico y una composicion elastomerica asociada. |
| US20030119965A1 (en) * | 1999-12-30 | 2003-06-26 | Maurizio Galimberti | Method for improving processability and storage stability of a silica filled elastomeric composition |
| US6921793B2 (en) * | 2000-08-18 | 2005-07-26 | Bridgestone Corporation | Rubber compositions and vulcanizates including comb-branched polymers |
| DE60201595T2 (de) * | 2001-04-13 | 2006-02-09 | Pirelli Pneumatici S.P.A. | Reifen mit hoher strassenhaftung, lauffläche und darin benutzte elastomermischung |
| BR0208762B1 (pt) * | 2001-04-13 | 2012-10-30 | pneu para rodas de veìculo, banda de rodagem de pneu para rodas de veìculo, composição elastomérica, e, produto manufaturado elastomérico reticulado. | |
| US20040192816A1 (en) * | 2001-04-13 | 2004-09-30 | Maurizio Galimberti | Product in subdivided form for preparing crosslinkable elastomeric compositions |
| WO2003009989A1 (en) * | 2001-07-25 | 2003-02-06 | Pirelli Pneumatici S.P.A. | Process and apparatus for continuously producing an elastomeric composition |
| WO2003011917A1 (en) * | 2001-07-31 | 2003-02-13 | Exxonmobil Chemical Patents Inc. | Method of curing elastomers |
| JP2005507440A (ja) * | 2001-10-30 | 2005-03-17 | ピレリ・プネウマティチ・ソチエタ・ペル・アツィオーニ | 転動抵抗が低いタイヤ、トレッドバンド、およびこれらに使用されるエラストマー組成物 |
| US7964128B2 (en) | 2001-12-19 | 2011-06-21 | Pirelli Pneumatici S.P.A. | Process and apparatus for continuously producing an elastomeric composition |
| EP1456293A1 (en) * | 2001-12-21 | 2004-09-15 | Pirelli Pneumatici S.p.A. | Tyre for vehicle wheels, tread band and elastomeric composition used therein |
| US20050080190A1 (en) * | 2001-12-21 | 2005-04-14 | Maurizio Galimberti | Tyre comprising a cycloolefin polymer tread band and elastomeric composition used therein |
| US20050234165A1 (en) * | 2002-04-23 | 2005-10-20 | Stephane Schaal | Tyre having a high wear resistance, tread band and elastomeric composition used therein |
| EP1500112A1 (en) * | 2002-04-29 | 2005-01-26 | Pirelli & C. S.p.A. | Fire resistant cable |
| DE60236024D1 (de) * | 2002-07-11 | 2010-05-27 | Pirelli | Verfahren und vorrichtung zur kontinuierlichen herstellung einer elastomermischung |
| JP2005534779A (ja) * | 2002-07-31 | 2005-11-17 | ピレリ・プネウマティチ・ソチエタ・ペル・アツィオーニ | 車両用タイヤおよびそれに使用されるエラストマー組成物 |
| WO2004039872A1 (en) * | 2002-10-31 | 2004-05-13 | Pirelli Pneumatici S.P.A. | Method for preparing a crosslinkable elastomeric composition |
| AU2002356650A1 (en) * | 2002-12-12 | 2004-06-30 | Pirelli Pneumatici S.P.A. | Tyre for vehicle wheels and elastomeric composition |
| WO2004056586A1 (en) * | 2002-12-23 | 2004-07-08 | Pirelli Pneumatici S.P.A. | Tyre for two-wheeled vehicles |
| US20070006953A1 (en) * | 2003-06-24 | 2007-01-11 | Pirelli Pneumatici S.P.A. | Tyre for vehicle wheels with tread band of cap and base construction |
| AU2003282064A1 (en) * | 2003-10-31 | 2005-06-08 | Pirelli Pneumatici S.P.A. | High-performance tyre for vehicle wheels |
| JP2005272643A (ja) * | 2004-03-24 | 2005-10-06 | Jsr Corp | スズ含有重合体及びその製造方法並びに加工助剤としての使用 |
| JP4966652B2 (ja) * | 2004-04-05 | 2012-07-04 | 株式会社ブリヂストン | 末端変性共役ジエン系重合体、重合開始剤及びそれらの製造方法、並びにゴム組成物 |
| EP1765606B1 (en) * | 2004-07-01 | 2008-03-12 | PIRELLI TYRE S.p.A. | Studded tire |
| DE602005014360D1 (de) * | 2004-07-28 | 2009-06-18 | Pirelli | Reifen mit einem epoxidierten elastomeren polymer und vernetzbare elastomere zusammensetzung |
| US7441572B2 (en) * | 2004-09-17 | 2008-10-28 | The Goodyear Tire & Rubber Company | Pneumatic tire having a tread containing immiscible rubber blend and silica |
| EP1827875B1 (en) * | 2004-12-21 | 2009-06-03 | Pirelli Tyre S.p.A. | Heavy load vehicle tire |
| JP4944376B2 (ja) | 2004-12-22 | 2012-05-30 | 株式会社ブリヂストン | ゴム組成物、その製造方法及びタイヤ |
| ATE419297T1 (de) * | 2005-04-28 | 2009-01-15 | Pirelli | Reifen und vernetzbare elastomere zusammensetzung |
| US20090178748A1 (en) * | 2005-07-01 | 2009-07-16 | Francesca Baione | Process for Manufacturing Tires |
| BRPI0614658A2 (pt) * | 2005-07-29 | 2016-08-23 | Pirelli | pneu, banda de rodagem composição elastomérica reticulável, e, artigo fabricado reticulado |
| JP5350577B2 (ja) | 2005-09-15 | 2013-11-27 | 株式会社ブリヂストン | ゴム組成物およびそれを用いたタイヤ |
| DE602005018120D1 (de) * | 2005-10-26 | 2010-01-14 | Pirelli | Verfahren zur herstellung einer vernetzbaren elastomerzusammensetzung |
| WO2007062671A1 (en) * | 2005-11-29 | 2007-06-07 | Pirelli Tyre S.P.A. | Tire and crosslinkable elastomeric composition |
| CN101460559B (zh) * | 2006-06-14 | 2012-01-25 | 倍耐力轮胎股份公司 | 轮胎和可交联的弹性体组合物 |
| US8580885B2 (en) | 2006-09-04 | 2013-11-12 | Bridgestone Corporation | Rubber composition and pneumatic tire using the same |
| DE112006004023B4 (de) | 2006-09-15 | 2020-08-27 | Sumitomo Chemical Company, Ltd. | Konjugiertes-Dien-Polymer, Verfahren zur Herstellung eines Konjugiertes-Dien-Polymers, Konjugiertes-Dien-Polymerzusammensetzung und Verfahren zur Herstellung einer Konjugiertes-Dien-Polymerzusammmensetzung |
| US20100059158A1 (en) * | 2006-10-30 | 2010-03-11 | Pirelli Tyre S.P.A | Tire for vehicle wheels comprising an improved elastomeric component |
| WO2008052571A1 (en) * | 2006-10-30 | 2008-05-08 | Pirelli Tyre S.P.A. | Tire for vehicle wheels comprising crosslinked elastomeric composition |
| US20110112212A1 (en) | 2007-12-07 | 2011-05-12 | Bridgestone Corporation | Tire |
| CN102574420B (zh) | 2009-04-29 | 2014-10-22 | 倍耐力轮胎股份公司 | 具有可控的抗表面缺陷形成的轮胎 |
| WO2014097108A1 (en) | 2012-12-18 | 2014-06-26 | Pirelli Tyre S.P.A. | Tyre for vehicle wheels |
| ITUA20161388A1 (it) | 2016-03-04 | 2017-09-04 | Pirelli | Sali ad attività antidegradante, composizioni elastomeriche per pneumatici e pneumatici che li comprendono |
| MX2019009941A (es) | 2017-03-06 | 2019-11-05 | Pirelli | Neumatico para ruedas de vehiculo. |
| CN111051352A (zh) | 2017-09-01 | 2020-04-21 | 株式会社普利司通 | 改性共轭二烯系聚合物、橡胶组合物、轮胎和制造改性共轭二烯系聚合物的方法 |
| JP2019099695A (ja) | 2017-12-04 | 2019-06-24 | 株式会社ブリヂストン | タイヤ用ゴム組成物及びタイヤ |
| CN112135739B (zh) * | 2018-04-11 | 2022-07-15 | 埃克森美孚化学专利公司 | 用于改进的轮胎胎面性能的基于丙烯的聚合物添加剂 |
| MX2021001597A (es) | 2018-08-30 | 2021-08-16 | Pirelli | Neumatico para ruedas de vehiculo. |
| WO2020059367A1 (ja) | 2018-09-20 | 2020-03-26 | 株式会社ブリヂストン | ゴム組成物およびタイヤ |
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| US3414528A (en) * | 1965-04-09 | 1968-12-03 | Phillips Petroleum Co | Blown sponge rubber |
| NL86588C (enExample) * | 1980-09-20 | |||
| JPS5893709A (ja) * | 1981-11-30 | 1983-06-03 | Japan Synthetic Rubber Co Ltd | ウェットスキッド特性及び摩耗特性が改良されたゴム組成物 |
| US4526934A (en) * | 1982-03-19 | 1985-07-02 | Bridgestone Tire Company Limited | Branched styrene-butadiene copolymers and pneumatic tires using the same |
| JPS58168611A (ja) * | 1982-03-30 | 1983-10-05 | Sumitomo Chem Co Ltd | 分岐重合体及びその製造方法 |
| JPS5924733A (ja) * | 1982-07-31 | 1984-02-08 | Bridgestone Corp | タイヤトレツドゴム組成物 |
| JPS5936144A (ja) * | 1982-08-23 | 1984-02-28 | Sumitomo Rubber Ind Ltd | ジエン系ゴム組成物及び該組成物をトレツドに用いたタイヤ |
| JPS5945338A (ja) * | 1982-09-07 | 1984-03-14 | Japan Synthetic Rubber Co Ltd | ブタジエン系重合体ゴム組成物 |
| JPS59140240A (ja) * | 1983-01-31 | 1984-08-11 | Japan Synthetic Rubber Co Ltd | ゴム組成物 |
| JPS6026045A (ja) * | 1983-07-22 | 1985-02-08 | Toyo Tire & Rubber Co Ltd | タイヤ用ゴム組成物 |
-
1984
- 1984-06-01 JP JP59110870A patent/JPS60255838A/ja active Granted
-
1985
- 1985-05-28 GB GB08513289A patent/GB2160207B/en not_active Expired
- 1985-05-30 DE DE3519430A patent/DE3519430C2/de not_active Expired
- 1985-05-31 FR FR858508257A patent/FR2565236B1/fr not_active Expired
-
1987
- 1987-07-06 US US07/070,117 patent/US4742124A/en not_active Expired - Lifetime
Non-Patent Citations (1)
| Title |
|---|
| NICHTS-ERMITTELT |
Also Published As
| Publication number | Publication date |
|---|---|
| JPS60255838A (ja) | 1985-12-17 |
| FR2565236B1 (fr) | 1989-05-26 |
| US4742124A (en) | 1988-05-03 |
| FR2565236A1 (fr) | 1985-12-06 |
| JPH0587530B2 (enExample) | 1993-12-17 |
| DE3519430A1 (de) | 1985-12-05 |
| GB2160207A (en) | 1985-12-18 |
| GB8513289D0 (en) | 1985-07-03 |
| GB2160207B (en) | 1988-02-03 |
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Owner name: JSR CORP., TOKIO/TOKYO, JP BRIDGESTONE CORP., TOKI |