DE3439714C2 - - Google Patents
Info
- Publication number
- DE3439714C2 DE3439714C2 DE3439714A DE3439714A DE3439714C2 DE 3439714 C2 DE3439714 C2 DE 3439714C2 DE 3439714 A DE3439714 A DE 3439714A DE 3439714 A DE3439714 A DE 3439714A DE 3439714 C2 DE3439714 C2 DE 3439714C2
- Authority
- DE
- Germany
- Prior art keywords
- cellulose
- carbamate
- solution
- radiation
- urea
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 229920002678 cellulose Polymers 0.000 claims description 63
- 239000001913 cellulose Substances 0.000 claims description 61
- KXDHJXZQYSOELW-UHFFFAOYSA-M Carbamate Chemical compound NC([O-])=O KXDHJXZQYSOELW-UHFFFAOYSA-M 0.000 claims description 58
- 239000000243 solution Substances 0.000 claims description 34
- 230000005855 radiation Effects 0.000 claims description 29
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 claims description 19
- 239000004202 carbamide Substances 0.000 claims description 19
- 238000004519 manufacturing process Methods 0.000 claims description 17
- 238000000034 method Methods 0.000 claims description 17
- 239000000835 fiber Substances 0.000 claims description 16
- 239000003513 alkali Substances 0.000 claims description 14
- 238000001556 precipitation Methods 0.000 claims description 6
- 238000009987 spinning Methods 0.000 claims description 4
- 239000012670 alkaline solution Substances 0.000 claims description 2
- 239000003929 acidic solution Substances 0.000 claims 1
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 21
- 238000006116 polymerization reaction Methods 0.000 description 18
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 14
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 10
- 238000006243 chemical reaction Methods 0.000 description 9
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 6
- 229910021529 ammonia Inorganic materials 0.000 description 6
- 239000011888 foil Substances 0.000 description 6
- 229910052757 nitrogen Inorganic materials 0.000 description 5
- 238000004090 dissolution Methods 0.000 description 4
- 238000010438 heat treatment Methods 0.000 description 4
- 239000007858 starting material Substances 0.000 description 4
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 3
- LSNNMFCWUKXFEE-UHFFFAOYSA-N Sulfurous acid Chemical compound OS(O)=O LSNNMFCWUKXFEE-UHFFFAOYSA-N 0.000 description 3
- 238000005266 casting Methods 0.000 description 3
- 239000007795 chemical reaction product Substances 0.000 description 3
- 150000001875 compounds Chemical class 0.000 description 3
- 230000005865 ionizing radiation Effects 0.000 description 3
- 239000000463 material Substances 0.000 description 3
- 206010010774 Constipation Diseases 0.000 description 2
- OWIKHYCFFJSOEH-UHFFFAOYSA-N Isocyanic acid Chemical compound N=C=O OWIKHYCFFJSOEH-UHFFFAOYSA-N 0.000 description 2
- LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical compound CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 description 2
- 229920000297 Rayon Polymers 0.000 description 2
- 230000002378 acidificating effect Effects 0.000 description 2
- XLJMAIOERFSOGZ-UHFFFAOYSA-N anhydrous cyanic acid Natural products OC#N XLJMAIOERFSOGZ-UHFFFAOYSA-N 0.000 description 2
- 239000007864 aqueous solution Substances 0.000 description 2
- 230000008021 deposition Effects 0.000 description 2
- 239000012467 final product Substances 0.000 description 2
- 239000000178 monomer Substances 0.000 description 2
- 239000000047 product Substances 0.000 description 2
- 239000002994 raw material Substances 0.000 description 2
- 230000035484 reaction time Effects 0.000 description 2
- 239000002904 solvent Substances 0.000 description 2
- 230000008961 swelling Effects 0.000 description 2
- 238000005406 washing Methods 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- NLXLAEXVIDQMFP-UHFFFAOYSA-N Ammonium chloride Substances [NH4+].[Cl-] NLXLAEXVIDQMFP-UHFFFAOYSA-N 0.000 description 1
- VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 description 1
- 229920003043 Cellulose fiber Polymers 0.000 description 1
- GUTLYIVDDKVIGB-OUBTZVSYSA-N Cobalt-60 Chemical compound [60Co] GUTLYIVDDKVIGB-OUBTZVSYSA-N 0.000 description 1
- 229920000742 Cotton Polymers 0.000 description 1
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 235000011114 ammonium hydroxide Nutrition 0.000 description 1
- PPBAJDRXASKAGH-UHFFFAOYSA-N azane;urea Chemical compound N.NC(N)=O PPBAJDRXASKAGH-UHFFFAOYSA-N 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 230000005684 electric field Effects 0.000 description 1
- ZOOODBUHSVUZEM-UHFFFAOYSA-N ethoxymethanedithioic acid Chemical compound CCOC(S)=S ZOOODBUHSVUZEM-UHFFFAOYSA-N 0.000 description 1
- 238000001704 evaporation Methods 0.000 description 1
- 230000008020 evaporation Effects 0.000 description 1
- 238000001125 extrusion Methods 0.000 description 1
- 238000007380 fibre production Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 150000004666 short chain fatty acids Chemical class 0.000 description 1
- 239000011780 sodium chloride Substances 0.000 description 1
- 239000004753 textile Substances 0.000 description 1
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 description 1
- 229910052721 tungsten Inorganic materials 0.000 description 1
- 239000010937 tungsten Substances 0.000 description 1
- WTHDKMILWLGDKL-UHFFFAOYSA-N urea;hydrate Chemical compound O.NC(N)=O WTHDKMILWLGDKL-UHFFFAOYSA-N 0.000 description 1
- 238000009489 vacuum treatment Methods 0.000 description 1
- 239000012991 xanthate Substances 0.000 description 1
Classifications
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F2/00—Monocomponent artificial filaments or the like of cellulose or cellulose derivatives; Manufacture thereof
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08B—POLYSACCHARIDES; DERIVATIVES THEREOF
- C08B15/00—Preparation of other cellulose derivatives or modified cellulose, e.g. complexes
- C08B15/05—Derivatives containing elements other than carbon, hydrogen, oxygen, halogens or sulfur
- C08B15/06—Derivatives containing elements other than carbon, hydrogen, oxygen, halogens or sulfur containing nitrogen, e.g. carbamates
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Polymers & Plastics (AREA)
- General Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Biochemistry (AREA)
- Medicinal Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Organic Chemistry (AREA)
- Materials Engineering (AREA)
- Textile Engineering (AREA)
- Chemical Or Physical Treatment Of Fibers (AREA)
- Artificial Filaments (AREA)
- Polysaccharides And Polysaccharide Derivatives (AREA)
- Processes Of Treating Macromolecular Substances (AREA)
- Manufacture Of Macromolecular Shaped Articles (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FI834029A FI66624C (fi) | 1983-11-02 | 1983-11-02 | Foerfarande foer framstaellning av cellulosakarbamatfibrer eller -filmer |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| DE3439714A1 DE3439714A1 (de) | 1985-05-09 |
| DE3439714C2 true DE3439714C2 (h) | 1987-06-11 |
Family
ID=8518036
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE19843439714 Granted DE3439714A1 (de) | 1983-11-02 | 1984-10-30 | Verfahren zur herstellung von zellulosecarbamat-fasern oder -folien |
Country Status (16)
| Country | Link |
|---|---|
| US (1) | US4530999A (h) |
| JP (1) | JPS60123502A (h) |
| AT (1) | AT388753B (h) |
| BR (1) | BR8405591A (h) |
| CA (1) | CA1245180A (h) |
| CS (1) | CS828584A2 (h) |
| DE (1) | DE3439714A1 (h) |
| FI (1) | FI66624C (h) |
| FR (1) | FR2554134B1 (h) |
| GB (1) | GB2148789B (h) |
| IN (1) | IN161836B (h) |
| IT (1) | IT1196317B (h) |
| NO (1) | NO160453C (h) |
| RO (1) | RO90386A (h) |
| SE (1) | SE459255B (h) |
| ZA (1) | ZA848118B (h) |
Families Citing this family (25)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FI67562C (fi) * | 1984-03-12 | 1985-04-10 | Neste Oy | Foerfarande foer framstaellning av cellulosakarbamat |
| FI69851C (fi) * | 1984-09-27 | 1986-05-26 | Neste Oy | Foerfarande foer utfaellning av cellulosakarbamat |
| FI69853C (fi) * | 1984-09-27 | 1986-05-26 | Neste Oy | Cykliskt foerfarande foer framstaellning av en alkaliloesning av cellulosakarbamat foer utfaellning av karbamatet och foeraotervinning av kemikalierna |
| FI69852C (fi) * | 1984-09-27 | 1986-05-26 | Neste Oy | Cykliskt foerfarande foer framstaellning av en alkaliloesning av cellulosakarbamat foer utfaellning av karbamatet och foeraotervinning av kemikalierna |
| US4756755A (en) * | 1985-06-14 | 1988-07-12 | Harding Jr Norman T | Rodent repellent liquids |
| FI73960C (fi) * | 1986-05-14 | 1987-12-10 | Neste Oy | Foerfarande foer koncentrering av vattenloesningar av alkoholer medelst pervaporation. |
| US4762564A (en) * | 1987-03-13 | 1988-08-09 | Teepak, Inc. | Reinforced cellulose aminomethanate |
| US4789006A (en) * | 1987-03-13 | 1988-12-06 | Teepak, Inc. | Cellulose aminomethanate sausage casings |
| US5215125A (en) * | 1987-03-13 | 1993-06-01 | Teepak, Inc. | Cellulose aminomethanate sausage casings |
| US4777249A (en) * | 1987-03-13 | 1988-10-11 | Teepak, Inc. | Crosslinked cellulose aminomethanate |
| US4999425A (en) * | 1989-06-12 | 1991-03-12 | Teepak, Inc. | Cellulose aminomethanate by ion-exchange extraction |
| US4997934A (en) * | 1989-06-12 | 1991-03-05 | Teepak, Inc. | Cellulose aminomethanate by weight loss monitoring |
| US5229506A (en) * | 1989-06-12 | 1993-07-20 | Teepak, Inc. | Preparation of cellulose aminomethanate |
| US4997933A (en) * | 1989-06-12 | 1991-03-05 | Teepak, Inc. | Cellulose aminomethanate by acid neutralization |
| AT402739B (de) * | 1995-09-19 | 1997-08-25 | Chemiefaser Lenzing Ag | Verfahren zur herstellung eines cellulosischen formkörpers |
| DE19757958A1 (de) | 1997-12-24 | 1999-07-01 | Lurgi Zimmer Ag | Verfahren zur Herstellung einer Cellulosecarbamatlösung |
| DE19835688A1 (de) * | 1998-08-07 | 2000-02-10 | Piesteritz Stickstoff | Verfahren zur Herstellung von Cellulosecarbamat |
| CN1112396C (zh) * | 2000-04-17 | 2003-06-25 | 武汉大学 | 纤维素膜制备方法 |
| JP4443931B2 (ja) * | 2002-01-29 | 2010-03-31 | バルション テクニリネン ツツキムスケスクス | セルロースカルバメートの製造方法 |
| FI118689B (fi) | 2005-11-23 | 2008-02-15 | Valtion Teknillinen | Menetelmä selluloosakarbamaattiliuoksen valmistamiseksi |
| CN103276466B (zh) * | 2013-05-29 | 2016-03-16 | 西安工程大学 | 一种聚四氟乙烯纤维的制备方法 |
| JP7340195B2 (ja) * | 2017-06-14 | 2023-09-07 | 国立大学法人京都大学 | 微細セルロース繊維、その製造方法、スラリー及び複合体 |
| JP2019001876A (ja) * | 2017-06-14 | 2019-01-10 | 国立大学法人京都大学 | 微細セルロース繊維、その製造方法、スラリー及び複合体 |
| FI129441B (en) * | 2019-11-20 | 2022-02-28 | Andritz Oy | Method for producing cellulose carbamate |
| JP7429212B2 (ja) * | 2021-09-27 | 2024-02-07 | 大王製紙株式会社 | カルバメート化セルロース繊維の製造方法 |
Family Cites Families (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3352773A (en) * | 1964-09-16 | 1967-11-14 | Gillette Res Inst Inc | Method of degrading polysaccharides using light radiation and a watersoluble metal or nitrogen base salt of nitrous or hyponitric acid |
| US3738924A (en) * | 1971-07-06 | 1973-06-12 | Eastman Kodak Co | Process for the solvent casting of cellulose films using radiation,and products thereof |
| DE2362551A1 (de) * | 1973-12-17 | 1975-06-26 | Hoechst Ag | Verfahren zur herstellung eines weichgemachten formkoerpers auf basis von cellulosederivaten |
| FI62318C (fi) * | 1981-01-27 | 1982-12-10 | Neste Oy | Foerfarande foer framstaellning av ett alkaliloesligt cellulosaderivat |
| FI64603C (fi) * | 1981-12-30 | 1983-12-12 | Neste Oy | Foerfarande foer utfaellning av cellulosaderivat |
| FI64602C (fi) * | 1981-12-30 | 1983-12-12 | Neste Oy | Foerfarande foer framstaellning av loesliga cellulosaderivater |
-
1983
- 1983-11-02 FI FI834029A patent/FI66624C/fi not_active IP Right Cessation
-
1984
- 1984-10-17 ZA ZA848118A patent/ZA848118B/xx unknown
- 1984-10-19 GB GB08426427A patent/GB2148789B/en not_active Expired
- 1984-10-23 IN IN742/CAL/84A patent/IN161836B/en unknown
- 1984-10-25 NO NO844259A patent/NO160453C/no unknown
- 1984-10-30 AT AT0345184A patent/AT388753B/de not_active IP Right Cessation
- 1984-10-30 IT IT23388/84A patent/IT1196317B/it active
- 1984-10-30 DE DE19843439714 patent/DE3439714A1/de active Granted
- 1984-10-31 CS CS848285A patent/CS828584A2/cs unknown
- 1984-10-31 RO RO84116136A patent/RO90386A/ro unknown
- 1984-10-31 JP JP59230039A patent/JPS60123502A/ja active Granted
- 1984-11-01 SE SE8405478A patent/SE459255B/sv not_active IP Right Cessation
- 1984-11-01 CA CA000466872A patent/CA1245180A/en not_active Expired
- 1984-11-01 US US06/667,430 patent/US4530999A/en not_active Expired - Fee Related
- 1984-11-01 BR BR8405591A patent/BR8405591A/pt not_active IP Right Cessation
- 1984-11-02 FR FR8416766A patent/FR2554134B1/fr not_active Expired
Also Published As
| Publication number | Publication date |
|---|---|
| IT8423388A0 (it) | 1984-10-30 |
| FI834029A0 (fi) | 1983-11-02 |
| SE8405478L (sv) | 1985-05-03 |
| NO160453C (no) | 1989-04-19 |
| IN161836B (h) | 1988-02-13 |
| SE8405478D0 (sv) | 1984-11-01 |
| FR2554134A1 (fr) | 1985-05-03 |
| FR2554134B1 (fr) | 1988-04-01 |
| ZA848118B (en) | 1985-06-26 |
| IT8423388A1 (it) | 1986-04-30 |
| ATA345184A (de) | 1989-01-15 |
| AT388753B (de) | 1989-08-25 |
| GB8426427D0 (en) | 1984-11-28 |
| DE3439714A1 (de) | 1985-05-09 |
| RO90386A (ro) | 1986-10-30 |
| BR8405591A (pt) | 1985-09-10 |
| NO844259L (no) | 1985-05-03 |
| IT1196317B (it) | 1988-11-16 |
| JPS60123502A (ja) | 1985-07-02 |
| CA1245180A (en) | 1988-11-22 |
| CS828584A2 (en) | 1991-04-11 |
| JPS6259121B2 (h) | 1987-12-09 |
| US4530999A (en) | 1985-07-23 |
| FI66624B (fi) | 1984-07-31 |
| GB2148789B (en) | 1986-10-22 |
| FI66624C (fi) | 1984-11-12 |
| NO160453B (no) | 1989-01-09 |
| SE459255B (sv) | 1989-06-19 |
| GB2148789A (en) | 1985-06-05 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| OM8 | Search report available as to paragraph 43 lit. 1 sentence 1 patent law | ||
| 8110 | Request for examination paragraph 44 | ||
| D2 | Grant after examination | ||
| 8364 | No opposition during term of opposition | ||
| 8339 | Ceased/non-payment of the annual fee |