DE2748212A1 - Enzymatisches fluessigwaschmittel - Google Patents
Enzymatisches fluessigwaschmittelInfo
- Publication number
- DE2748212A1 DE2748212A1 DE19772748212 DE2748212A DE2748212A1 DE 2748212 A1 DE2748212 A1 DE 2748212A1 DE 19772748212 DE19772748212 DE 19772748212 DE 2748212 A DE2748212 A DE 2748212A DE 2748212 A1 DE2748212 A1 DE 2748212A1
- Authority
- DE
- Germany
- Prior art keywords
- weight
- percent
- detergents
- triethanolamine
- borax
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000003599 detergent Substances 0.000 title claims description 38
- 239000007788 liquid Substances 0.000 title claims description 24
- 230000002255 enzymatic effect Effects 0.000 title claims description 13
- -1 amino compound Chemical class 0.000 claims description 25
- 229910021538 borax Inorganic materials 0.000 claims description 19
- 239000004328 sodium tetraborate Substances 0.000 claims description 19
- 235000010339 sodium tetraborate Nutrition 0.000 claims description 19
- 239000000203 mixture Substances 0.000 claims description 16
- 239000003795 chemical substances by application Substances 0.000 claims description 15
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 claims description 14
- KGBXLFKZBHKPEV-UHFFFAOYSA-N boric acid Chemical compound OB(O)O KGBXLFKZBHKPEV-UHFFFAOYSA-N 0.000 claims description 14
- 239000004327 boric acid Substances 0.000 claims description 14
- 108091005804 Peptidases Proteins 0.000 claims description 10
- 239000004365 Protease Substances 0.000 claims description 10
- 239000003381 stabilizer Substances 0.000 claims description 10
- 238000003860 storage Methods 0.000 claims description 9
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 claims description 8
- 229910052796 boron Inorganic materials 0.000 claims description 8
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims description 5
- CZMRCDWAGMRECN-UGDNZRGBSA-N Sucrose Chemical compound O[C@H]1[C@H](O)[C@@H](CO)O[C@@]1(CO)O[C@@H]1[C@H](O)[C@@H](O)[C@H](O)[C@@H](CO)O1 CZMRCDWAGMRECN-UGDNZRGBSA-N 0.000 claims description 5
- 229930006000 Sucrose Natural products 0.000 claims description 5
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 claims description 5
- 229910052708 sodium Inorganic materials 0.000 claims description 5
- 239000011734 sodium Substances 0.000 claims description 5
- 239000005720 sucrose Substances 0.000 claims description 5
- LENZDBCJOHFCAS-UHFFFAOYSA-N tris Chemical compound OCC(N)(CO)CO LENZDBCJOHFCAS-UHFFFAOYSA-N 0.000 claims description 5
- 102000013142 Amylases Human genes 0.000 claims description 4
- 108010065511 Amylases Proteins 0.000 claims description 4
- 102000035195 Peptidases Human genes 0.000 claims description 4
- 235000019418 amylase Nutrition 0.000 claims description 4
- 229940025131 amylases Drugs 0.000 claims description 4
- ZBCBWPMODOFKDW-UHFFFAOYSA-N diethanolamine Chemical group OCCNCCO ZBCBWPMODOFKDW-UHFFFAOYSA-N 0.000 claims description 4
- 102000005575 Cellulases Human genes 0.000 claims description 3
- 108010084185 Cellulases Proteins 0.000 claims description 3
- SLINHMUFWFWBMU-UHFFFAOYSA-N Triisopropanolamine Chemical compound CC(O)CN(CC(C)O)CC(C)O SLINHMUFWFWBMU-UHFFFAOYSA-N 0.000 claims description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 3
- 239000011149 active material Substances 0.000 claims description 2
- 125000003277 amino group Chemical group 0.000 claims description 2
- 229910052810 boron oxide Inorganic materials 0.000 claims description 2
- JKWMSGQKBLHBQQ-UHFFFAOYSA-N diboron trioxide Chemical compound O=BOB=O JKWMSGQKBLHBQQ-UHFFFAOYSA-N 0.000 claims description 2
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims description 2
- 229940125782 compound 2 Drugs 0.000 claims 1
- 102000004190 Enzymes Human genes 0.000 description 26
- 108090000790 Enzymes Proteins 0.000 description 26
- 229940088598 enzyme Drugs 0.000 description 26
- 230000000694 effects Effects 0.000 description 17
- 229960004418 trolamine Drugs 0.000 description 15
- HJVAFZMYQQSPHF-UHFFFAOYSA-N 2-[bis(2-hydroxyethyl)amino]ethanol;boric acid Chemical compound OB(O)O.OCCN(CCO)CCO HJVAFZMYQQSPHF-UHFFFAOYSA-N 0.000 description 9
- 230000001580 bacterial effect Effects 0.000 description 9
- 108010056079 Subtilisins Proteins 0.000 description 7
- 102000005158 Subtilisins Human genes 0.000 description 7
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 6
- 102100037486 Reverse transcriptase/ribonuclease H Human genes 0.000 description 6
- 125000000129 anionic group Chemical group 0.000 description 5
- 239000000047 product Substances 0.000 description 5
- RTZKZFJDLAIYFH-UHFFFAOYSA-N ether Substances CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 4
- 239000000463 material Substances 0.000 description 4
- 108010003855 mesentericopeptidase Proteins 0.000 description 4
- 241000233866 Fungi Species 0.000 description 3
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 3
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- CDZHZLQKNAKKEC-UHFFFAOYSA-N [bis(hydroxymethylamino)methylamino]methanol Chemical compound OCNC(NCO)NCO CDZHZLQKNAKKEC-UHFFFAOYSA-N 0.000 description 3
- 239000002253 acid Substances 0.000 description 3
- 239000000654 additive Substances 0.000 description 3
- 150000003863 ammonium salts Chemical class 0.000 description 3
- 125000002091 cationic group Chemical group 0.000 description 3
- 238000010348 incorporation Methods 0.000 description 3
- 229910052700 potassium Inorganic materials 0.000 description 3
- 239000011591 potassium Substances 0.000 description 3
- 230000002797 proteolythic effect Effects 0.000 description 3
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 2
- 241000194108 Bacillus licheniformis Species 0.000 description 2
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 2
- DHMQDGOQFOQNFH-UHFFFAOYSA-N Glycine Chemical compound NCC(O)=O DHMQDGOQFOQNFH-UHFFFAOYSA-N 0.000 description 2
- GOOHAUXETOMSMM-UHFFFAOYSA-N Propylene oxide Chemical compound CC1CO1 GOOHAUXETOMSMM-UHFFFAOYSA-N 0.000 description 2
- 108090000787 Subtilisin Proteins 0.000 description 2
- 150000007513 acids Chemical class 0.000 description 2
- 230000000996 additive effect Effects 0.000 description 2
- 239000007859 condensation product Substances 0.000 description 2
- 235000014113 dietary fatty acids Nutrition 0.000 description 2
- 229930195729 fatty acid Natural products 0.000 description 2
- 239000000194 fatty acid Substances 0.000 description 2
- 150000004665 fatty acids Chemical class 0.000 description 2
- 239000006260 foam Substances 0.000 description 2
- IZXGZAJMDLJLMF-UHFFFAOYSA-N methylaminomethanol Chemical compound CNCO IZXGZAJMDLJLMF-UHFFFAOYSA-N 0.000 description 2
- 150000003856 quaternary ammonium compounds Chemical class 0.000 description 2
- 239000000344 soap Substances 0.000 description 2
- 235000019832 sodium triphosphate Nutrition 0.000 description 2
- 239000000271 synthetic detergent Substances 0.000 description 2
- WRIDQFICGBMAFQ-UHFFFAOYSA-N (E)-8-Octadecenoic acid Natural products CCCCCCCCCC=CCCCCCCC(O)=O WRIDQFICGBMAFQ-UHFFFAOYSA-N 0.000 description 1
- LQJBNNIYVWPHFW-UHFFFAOYSA-N 20:1omega9c fatty acid Natural products CCCCCCCCCCC=CCCCCCCCC(O)=O LQJBNNIYVWPHFW-UHFFFAOYSA-N 0.000 description 1
- GDTSJMKGXGJFGQ-UHFFFAOYSA-N 3,7-dioxido-2,4,6,8,9-pentaoxa-1,3,5,7-tetraborabicyclo[3.3.1]nonane Chemical compound O1B([O-])OB2OB([O-])OB1O2 GDTSJMKGXGJFGQ-UHFFFAOYSA-N 0.000 description 1
- QSBYPNXLFMSGKH-UHFFFAOYSA-N 9-Heptadecensaeure Natural products CCCCCCCC=CCCCCCCCC(O)=O QSBYPNXLFMSGKH-UHFFFAOYSA-N 0.000 description 1
- 239000004382 Amylase Substances 0.000 description 1
- 241000193830 Bacillus <bacterium> Species 0.000 description 1
- 235000014469 Bacillus subtilis Nutrition 0.000 description 1
- FBPFZTCFMRRESA-FSIIMWSLSA-N D-Glucitol Natural products OC[C@H](O)[C@H](O)[C@@H](O)[C@H](O)CO FBPFZTCFMRRESA-FSIIMWSLSA-N 0.000 description 1
- FBPFZTCFMRRESA-JGWLITMVSA-N D-glucitol Chemical compound OC[C@H](O)[C@@H](O)[C@H](O)[C@H](O)CO FBPFZTCFMRRESA-JGWLITMVSA-N 0.000 description 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- 239000004471 Glycine Substances 0.000 description 1
- FFDGPVCHZBVARC-UHFFFAOYSA-N N,N-dimethylglycine Chemical compound CN(C)CC(O)=O FFDGPVCHZBVARC-UHFFFAOYSA-N 0.000 description 1
- 239000005642 Oleic acid Substances 0.000 description 1
- ZQPPMHVWECSIRJ-UHFFFAOYSA-N Oleic acid Natural products CCCCCCCCC=CCCCCCCCC(O)=O ZQPPMHVWECSIRJ-UHFFFAOYSA-N 0.000 description 1
- 229910019142 PO4 Inorganic materials 0.000 description 1
- 240000004808 Saccharomyces cerevisiae Species 0.000 description 1
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 description 1
- 230000002378 acidificating effect Effects 0.000 description 1
- 238000007792 addition Methods 0.000 description 1
- 229910052783 alkali metal Inorganic materials 0.000 description 1
- 229910052784 alkaline earth metal Inorganic materials 0.000 description 1
- 150000004996 alkyl benzenes Chemical class 0.000 description 1
- 150000001408 amides Chemical class 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
- 230000003625 amylolytic effect Effects 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 239000007844 bleaching agent Substances 0.000 description 1
- 150000001639 boron compounds Chemical class 0.000 description 1
- 239000000872 buffer Substances 0.000 description 1
- 159000000007 calcium salts Chemical class 0.000 description 1
- 150000004649 carbonic acid derivatives Chemical class 0.000 description 1
- 239000005018 casein Substances 0.000 description 1
- BECPQYXYKAMYBN-UHFFFAOYSA-N casein, tech. Chemical compound NCCCCC(C(O)=O)N=C(O)C(CC(O)=O)N=C(O)C(CCC(O)=N)N=C(O)C(CC(C)C)N=C(O)C(CCC(O)=O)N=C(O)C(CC(O)=O)N=C(O)C(CCC(O)=O)N=C(O)C(C(C)O)N=C(O)C(CCC(O)=N)N=C(O)C(CCC(O)=N)N=C(O)C(CCC(O)=N)N=C(O)C(CCC(O)=O)N=C(O)C(CCC(O)=O)N=C(O)C(COP(O)(O)=O)N=C(O)C(CCC(O)=N)N=C(O)C(N)CC1=CC=CC=C1 BECPQYXYKAMYBN-UHFFFAOYSA-N 0.000 description 1
- 235000021240 caseins Nutrition 0.000 description 1
- 239000007795 chemical reaction product Substances 0.000 description 1
- 150000001860 citric acid derivatives Chemical class 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 229920001577 copolymer Polymers 0.000 description 1
- 230000001461 cytolytic effect Effects 0.000 description 1
- 230000001419 dependent effect Effects 0.000 description 1
- 229940043237 diethanolamine Drugs 0.000 description 1
- LVTYICIALWPMFW-UHFFFAOYSA-N diisopropanolamine Chemical compound CC(O)CNCC(C)O LVTYICIALWPMFW-UHFFFAOYSA-N 0.000 description 1
- 229940043276 diisopropanolamine Drugs 0.000 description 1
- 108700003601 dimethylglycine Proteins 0.000 description 1
- 235000011180 diphosphates Nutrition 0.000 description 1
- LQZZUXJYWNFBMV-UHFFFAOYSA-N dodecan-1-ol Chemical compound CCCCCCCCCCCCO LQZZUXJYWNFBMV-UHFFFAOYSA-N 0.000 description 1
- 239000000975 dye Substances 0.000 description 1
- LYCAIKOWRPUZTN-UHFFFAOYSA-N ethylene glycol Natural products OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 1
- 239000002979 fabric softener Substances 0.000 description 1
- 238000005187 foaming Methods 0.000 description 1
- 239000003205 fragrance Substances 0.000 description 1
- 230000002070 germicidal effect Effects 0.000 description 1
- 235000011187 glycerol Nutrition 0.000 description 1
- 150000004820 halides Chemical class 0.000 description 1
- 239000003752 hydrotrope Substances 0.000 description 1
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 1
- 238000011065 in-situ storage Methods 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 230000000977 initiatory effect Effects 0.000 description 1
- QXJSBBXBKPUZAA-UHFFFAOYSA-N isooleic acid Natural products CCCCCCCC=CCCCCCCCCC(O)=O QXJSBBXBKPUZAA-UHFFFAOYSA-N 0.000 description 1
- MGFYIUFZLHCRTH-UHFFFAOYSA-N nitrilotriacetic acid Chemical class OC(=O)CN(CC(O)=O)CC(O)=O MGFYIUFZLHCRTH-UHFFFAOYSA-N 0.000 description 1
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 1
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(O)=O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 description 1
- 239000003605 opacifier Substances 0.000 description 1
- 230000003287 optical effect Effects 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 1
- 239000010452 phosphate Substances 0.000 description 1
- 229920002432 poly(vinyl methyl ether) polymer Polymers 0.000 description 1
- 229920005646 polycarboxylate Polymers 0.000 description 1
- 229920000867 polyelectrolyte Polymers 0.000 description 1
- 229920000151 polyglycol Polymers 0.000 description 1
- 239000010695 polyglycol Substances 0.000 description 1
- 229920005862 polyol Polymers 0.000 description 1
- 150000003077 polyols Chemical class 0.000 description 1
- 239000002243 precursor Substances 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 239000003531 protein hydrolysate Substances 0.000 description 1
- WQGWDDDVZFFDIG-UHFFFAOYSA-N pyrogallol Chemical compound OC1=CC=CC(O)=C1O WQGWDDDVZFFDIG-UHFFFAOYSA-N 0.000 description 1
- 238000000197 pyrolysis Methods 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 150000004760 silicates Chemical class 0.000 description 1
- 239000002002 slurry Substances 0.000 description 1
- 229960001922 sodium perborate Drugs 0.000 description 1
- 229940045872 sodium percarbonate Drugs 0.000 description 1
- 229940048842 sodium xylenesulfonate Drugs 0.000 description 1
- QUCDWLYKDRVKMI-UHFFFAOYSA-M sodium;3,4-dimethylbenzenesulfonate Chemical compound [Na+].CC1=CC=C(S([O-])(=O)=O)C=C1C QUCDWLYKDRVKMI-UHFFFAOYSA-M 0.000 description 1
- MWNQXXOSWHCCOZ-UHFFFAOYSA-L sodium;oxido carbonate Chemical compound [Na+].[O-]OC([O-])=O MWNQXXOSWHCCOZ-UHFFFAOYSA-L 0.000 description 1
- YKLJGMBLPUQQOI-UHFFFAOYSA-M sodium;oxidooxy(oxo)borane Chemical compound [Na+].[O-]OB=O YKLJGMBLPUQQOI-UHFFFAOYSA-M 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 239000000600 sorbitol Substances 0.000 description 1
- 230000000087 stabilizing effect Effects 0.000 description 1
- 239000000758 substrate Substances 0.000 description 1
- 150000005846 sugar alcohols Polymers 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- 239000000375 suspending agent Substances 0.000 description 1
- 238000005494 tarnishing Methods 0.000 description 1
- 150000003512 tertiary amines Chemical class 0.000 description 1
- UNXRWKVEANCORM-UHFFFAOYSA-I triphosphate(5-) Chemical compound [O-]P([O-])(=O)OP([O-])(=O)OP([O-])([O-])=O UNXRWKVEANCORM-UHFFFAOYSA-I 0.000 description 1
- 235000013311 vegetables Nutrition 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/38—Products with no well-defined composition, e.g. natural products
- C11D3/386—Preparations containing enzymes, e.g. protease or amylase
- C11D3/38663—Stabilised liquid enzyme compositions
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/26—Organic compounds containing nitrogen
- C11D3/30—Amines; Substituted amines ; Quaternized amines
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Detergent Compositions (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB45345/76A GB1590445A (en) | 1976-11-01 | 1976-11-01 | Enzymatic liquid composition |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| DE2748212A1 true DE2748212A1 (de) | 1978-05-11 |
Family
ID=10436873
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE19772748212 Granted DE2748212A1 (de) | 1976-11-01 | 1977-10-27 | Enzymatisches fluessigwaschmittel |
Country Status (21)
| Country | Link |
|---|---|
| JP (1) | JPS6018718B2 (enExample) |
| AT (1) | AT362854B (enExample) |
| AU (1) | AU513867B2 (enExample) |
| BE (1) | BE860375A (enExample) |
| BR (1) | BR7707291A (enExample) |
| CA (1) | CA1092037A (enExample) |
| CH (1) | CH630407A5 (enExample) |
| DE (1) | DE2748212A1 (enExample) |
| DK (1) | DK147557C (enExample) |
| ES (1) | ES463754A1 (enExample) |
| FI (1) | FI61716C (enExample) |
| FR (1) | FR2369339A1 (enExample) |
| GB (1) | GB1590445A (enExample) |
| GR (1) | GR66147B (enExample) |
| IT (1) | IT1093028B (enExample) |
| LU (1) | LU78423A1 (enExample) |
| NL (1) | NL188760C (enExample) |
| NO (1) | NO148855C (enExample) |
| PT (1) | PT67226B (enExample) |
| SE (1) | SE425669B (enExample) |
| ZA (1) | ZA776457B (enExample) |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE3207825A1 (de) * | 1981-03-05 | 1982-09-16 | Kao Soap Co., Ltd., Tokyo | Reinigungsmittelzusammensetzung |
| EP0080223A3 (en) * | 1981-11-19 | 1984-10-03 | Unilever Nv | Enzymatic liquid detergent composition |
| EP0120528A1 (en) * | 1983-03-10 | 1984-10-03 | Unilever N.V. | Detergent compositions |
| WO1997009332A1 (en) * | 1995-09-04 | 1997-03-13 | Franc Cadez | Triethanolaminetriborate, a compound of boric (iii) acid and triethanolamine with high content of borate component, highly soluble in water and in some organic solvents |
| EP1141221B2 (en) † | 1998-12-16 | 2011-11-30 | Unilever N.V. | Structured liquid detergent composition |
Families Citing this family (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| IT1129814B (it) * | 1980-07-02 | 1986-06-11 | Unilever Nv | Composizione detergente enzimatica liquida |
| EP0080748B1 (en) | 1981-11-13 | 1985-07-10 | Unilever N.V. | Enzymatic liquid cleaning composition |
| US4529525A (en) * | 1982-08-30 | 1985-07-16 | Colgate-Palmolive Co. | Stabilized enzyme-containing detergent compositions |
| GB8421801D0 (en) * | 1984-08-29 | 1984-10-03 | Unilever Plc | Detergent composition |
| JPS61160814U (enExample) * | 1985-03-28 | 1986-10-04 | ||
| US4797362A (en) | 1985-06-06 | 1989-01-10 | Lion Corporation | Alkaline proteases and microorganisms producing same |
| AU3667189A (en) * | 1988-06-23 | 1990-01-04 | Unilever Plc | Enzyme-containing liquid detergents |
| US20060293212A1 (en) * | 2005-05-05 | 2006-12-28 | Ecolab Inc. | Stable solid compositions of spores, bacteria, fungi and/or enzyme |
| AR061906A1 (es) | 2006-07-18 | 2008-10-01 | Novapharm Res Australia | Limpiador de baja espuma |
| JP6961114B1 (ja) * | 2021-03-10 | 2021-11-05 | 株式会社アルボース | 洗浄剤組成物及び洗浄方法 |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3893954A (en) * | 1970-09-30 | 1975-07-08 | Procter & Gamble | Detergent compositions containing enzyme and chlorine scavenger |
Family Cites Families (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3723327A (en) * | 1972-06-05 | 1973-03-27 | Lever Brothers Ltd | Granular proteolytic enzyme composition |
| GB1442419A (en) * | 1972-12-14 | 1976-07-14 | Procter & Gamble | Laundry process |
-
1976
- 1976-11-01 GB GB45345/76A patent/GB1590445A/en not_active Expired
-
1977
- 1977-10-25 FI FI773178A patent/FI61716C/fi not_active IP Right Cessation
- 1977-10-26 AU AU30052/77A patent/AU513867B2/en not_active Expired
- 1977-10-27 FR FR7732531A patent/FR2369339A1/fr active Granted
- 1977-10-27 DE DE19772748212 patent/DE2748212A1/de active Granted
- 1977-10-28 NO NO773697A patent/NO148855C/no unknown
- 1977-10-29 GR GR54668A patent/GR66147B/el unknown
- 1977-10-31 ZA ZA00776457A patent/ZA776457B/xx unknown
- 1977-10-31 BR BR7707291A patent/BR7707291A/pt unknown
- 1977-10-31 CA CA289,924A patent/CA1092037A/en not_active Expired
- 1977-10-31 CH CH1322877A patent/CH630407A5/de not_active IP Right Cessation
- 1977-10-31 PT PT67226A patent/PT67226B/pt unknown
- 1977-10-31 ES ES463754A patent/ES463754A1/es not_active Expired
- 1977-10-31 IT IT69439/77A patent/IT1093028B/it active
- 1977-10-31 BE BE182265A patent/BE860375A/xx not_active IP Right Cessation
- 1977-10-31 SE SE7712283A patent/SE425669B/xx unknown
- 1977-10-31 DK DK482477A patent/DK147557C/da not_active IP Right Cessation
- 1977-10-31 NL NLAANVRAGE7711924,A patent/NL188760C/xx not_active IP Right Cessation
- 1977-10-31 LU LU78423A patent/LU78423A1/xx unknown
- 1977-10-31 AT AT0776377A patent/AT362854B/de not_active IP Right Cessation
- 1977-11-01 JP JP52130385A patent/JPS6018718B2/ja not_active Expired
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3893954A (en) * | 1970-09-30 | 1975-07-08 | Procter & Gamble | Detergent compositions containing enzyme and chlorine scavenger |
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE3207825A1 (de) * | 1981-03-05 | 1982-09-16 | Kao Soap Co., Ltd., Tokyo | Reinigungsmittelzusammensetzung |
| EP0080223A3 (en) * | 1981-11-19 | 1984-10-03 | Unilever Nv | Enzymatic liquid detergent composition |
| EP0120528A1 (en) * | 1983-03-10 | 1984-10-03 | Unilever N.V. | Detergent compositions |
| WO1997009332A1 (en) * | 1995-09-04 | 1997-03-13 | Franc Cadez | Triethanolaminetriborate, a compound of boric (iii) acid and triethanolamine with high content of borate component, highly soluble in water and in some organic solvents |
| AT406679B (de) * | 1995-09-04 | 2000-07-25 | Cadez Franc | Triäthanolamintriborat, eine verbindung von bor(iii)säure und triäthanolamin mit hohem gehalt der boratkomponente und mit hoher löslichkeit in wasser und einigen organischen lösungsmitteln |
| EP1141221B2 (en) † | 1998-12-16 | 2011-11-30 | Unilever N.V. | Structured liquid detergent composition |
Also Published As
| Publication number | Publication date |
|---|---|
| NO148855B (no) | 1983-09-19 |
| AT362854B (de) | 1981-06-25 |
| JPS5356204A (en) | 1978-05-22 |
| NO773697L (no) | 1978-05-03 |
| NL188760C (nl) | 1992-09-16 |
| LU78423A1 (enExample) | 1978-07-12 |
| GB1590445A (en) | 1981-06-03 |
| NO148855C (no) | 1983-12-28 |
| DK147557C (da) | 1985-03-04 |
| CH630407A5 (en) | 1982-06-15 |
| ES463754A1 (es) | 1979-07-16 |
| DK482477A (da) | 1978-05-02 |
| ZA776457B (en) | 1979-06-27 |
| FR2369339A1 (fr) | 1978-05-26 |
| GR66147B (enExample) | 1981-01-19 |
| NL188760B (nl) | 1992-04-16 |
| NL7711924A (nl) | 1978-05-03 |
| CA1092037A (en) | 1980-12-23 |
| PT67226B (en) | 1980-02-20 |
| ATA776377A (de) | 1980-11-15 |
| AU513867B2 (en) | 1981-01-08 |
| PT67226A (en) | 1977-11-01 |
| FI61716C (fi) | 1982-09-10 |
| IT1093028B (it) | 1985-07-19 |
| SE7712283L (sv) | 1978-05-02 |
| FI773178A7 (fi) | 1978-05-02 |
| AU3005277A (en) | 1979-05-03 |
| SE425669B (sv) | 1982-10-25 |
| BR7707291A (pt) | 1978-07-25 |
| JPS6018718B2 (ja) | 1985-05-11 |
| FI61716B (fi) | 1982-05-31 |
| DK147557B (da) | 1984-10-01 |
| FR2369339B1 (enExample) | 1982-02-05 |
| BE860375A (fr) | 1978-05-02 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| DE2748211A1 (de) | Enzymatisches fluessigwaschmittel | |
| DE2748212A1 (de) | Enzymatisches fluessigwaschmittel | |
| DE69209500T2 (de) | Gerüstsubstanzhaltige flüssigwaschmittel mit borsäure-polyolkomplex zur ptoteolytischen enzyminhibierung | |
| EP3024917B1 (de) | Waschmittel enthaltend aminoxid | |
| DE3689385T2 (de) | Stabile flüssige Reinigungsmittel. | |
| DE69204472T2 (de) | Fluessige waschmittel mit zitronensaeure, cellulase und bor-diol-komplex um proteolytisches enzym zu inhibieren. | |
| DE69229830T2 (de) | Flüssiges waschmittel mit stabilisiertem enzym | |
| AT394385B (de) | Stabilisiertes, klares, einphasiges, builder und enzym enthaltendes fluessigwaschmittel | |
| BR8401364A (pt) | Composicao detergente liquida | |
| DE3125533A1 (de) | Fluessiges, enzymhaltiges wasch- bzw. reinigungsmittel | |
| EP0757094A2 (de) | Wasch- und Reinigungsmittel mit Iminodisuccinaten | |
| EP3250669B1 (de) | Saures flüssigkompaktwaschmittel enthaltend hydroxycarbonsäure, niotensid und enzym | |
| DE68917777T2 (de) | Enzymatische Waschmittelzusammensetzung. | |
| DE3751304T2 (de) | Cellulase enthaltende, weichmachende Reinigungsmittel. | |
| DE4344357A1 (de) | Flüssiges Wasch- und Reinigungsmittel | |
| CH659478A5 (de) | Stabilisiertes, klares, einphasiges, builder und enzym enthaltendes waessriges fluessigwaschmittel. | |
| DE69121059T2 (de) | Lipase- und proteasehaltige flüssige Waschmittelzusammensetzung | |
| EP3083915A1 (de) | Konservierungsmittelsystem für waschmittel | |
| DE102013202772A1 (de) | Wasch- oder Reinigungsmittel mit verbesserter Reinigungsleistung | |
| EP3864119B1 (de) | Flüssige zusammensetzung mit dihydroxyterephthalsäurediamid-verbindung und hoher tensidmenge | |
| EP1308499A1 (de) | Tensidmischung mit Hydroxymischethern und Polymeren | |
| DE69007121T2 (de) | Enzymhaltige flüssige waschmittelzusammensetzungen und deren verwendung. | |
| DE69200612T2 (de) | Polyphosphonatkomplexbildner enthaltende flüssige, konzentrierte Waschmittelzusammensetzung. | |
| DE69413987T2 (de) | Amidoferoxocarbonsäuren als bleichmittel | |
| EP0729502B1 (de) | Enzymkombinationshaltige flüssige wasch- und reinigungsmittel |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| 8110 | Request for examination paragraph 44 | ||
| 8128 | New person/name/address of the agent |
Representative=s name: LEDERER, F., DIPL.-CHEM. DR. MEYER-ROXLAU, R., DIP |
|
| 8128 | New person/name/address of the agent |
Representative=s name: LEDERER, F., DIPL.-CHEM. DR., PAT.-ANW., 8000 MUEN |
|
| D2 | Grant after examination | ||
| 8363 | Opposition against the patent | ||
| 8365 | Fully valid after opposition proceedings |