DE2544041C3 - Gegenstand aus einem metallischen Substrat und einem darauf galvanisch abgeschiedenen, mehrschichtigen metallischen Überzug - Google Patents
Gegenstand aus einem metallischen Substrat und einem darauf galvanisch abgeschiedenen, mehrschichtigen metallischen ÜberzugInfo
- Publication number
- DE2544041C3 DE2544041C3 DE2544041A DE2544041A DE2544041C3 DE 2544041 C3 DE2544041 C3 DE 2544041C3 DE 2544041 A DE2544041 A DE 2544041A DE 2544041 A DE2544041 A DE 2544041A DE 2544041 C3 DE2544041 C3 DE 2544041C3
- Authority
- DE
- Germany
- Prior art keywords
- layer
- nickel
- iron
- micro
- article according
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 238000000576 coating method Methods 0.000 title claims description 18
- 239000011248 coating agent Substances 0.000 title claims description 12
- 239000000758 substrate Substances 0.000 title claims description 9
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims description 74
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 72
- 229910052742 iron Inorganic materials 0.000 claims description 37
- 229910052759 nickel Inorganic materials 0.000 claims description 37
- UGKDIUIOSMUOAW-UHFFFAOYSA-N iron nickel Chemical compound [Fe].[Ni] UGKDIUIOSMUOAW-UHFFFAOYSA-N 0.000 claims description 35
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 claims description 27
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims description 6
- 229910052802 copper Inorganic materials 0.000 claims description 6
- 239000010949 copper Substances 0.000 claims description 6
- 239000010954 inorganic particle Substances 0.000 claims description 3
- 230000008021 deposition Effects 0.000 claims description 2
- 239000010410 layer Substances 0.000 description 89
- 229910052804 chromium Inorganic materials 0.000 description 9
- 239000011651 chromium Substances 0.000 description 9
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 7
- 239000008139 complexing agent Substances 0.000 description 7
- 229910000831 Steel Inorganic materials 0.000 description 5
- 239000000654 additive Substances 0.000 description 5
- 238000005260 corrosion Methods 0.000 description 5
- 239000010959 steel Substances 0.000 description 5
- 229910045601 alloy Inorganic materials 0.000 description 4
- 239000000956 alloy Substances 0.000 description 4
- 230000007797 corrosion Effects 0.000 description 4
- 229910000640 Fe alloy Inorganic materials 0.000 description 3
- 150000001875 compounds Chemical class 0.000 description 3
- -1 iron (II) fluoroborates Chemical class 0.000 description 3
- 159000000014 iron salts Chemical class 0.000 description 3
- 238000000034 method Methods 0.000 description 3
- RGHNJXZEOKUKBD-SQOUGZDYSA-N D-gluconic acid Chemical compound OC[C@@H](O)[C@@H](O)[C@H](O)[C@@H](O)C(O)=O RGHNJXZEOKUKBD-SQOUGZDYSA-N 0.000 description 2
- AEMRFAOFKBGASW-UHFFFAOYSA-N Glycolic acid Chemical compound OCC(O)=O AEMRFAOFKBGASW-UHFFFAOYSA-N 0.000 description 2
- 229910001030 Iron–nickel alloy Inorganic materials 0.000 description 2
- 238000013019 agitation Methods 0.000 description 2
- 239000010941 cobalt Substances 0.000 description 2
- 229910017052 cobalt Inorganic materials 0.000 description 2
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 2
- 230000000536 complexating effect Effects 0.000 description 2
- 230000006866 deterioration Effects 0.000 description 2
- 239000011229 interlayer Substances 0.000 description 2
- TXXHDPDFNKHHGW-UHFFFAOYSA-N muconic acid Chemical compound OC(=O)C=CC=CC(O)=O TXXHDPDFNKHHGW-UHFFFAOYSA-N 0.000 description 2
- 150000002815 nickel Chemical class 0.000 description 2
- BJEPYKJPYRNKOW-REOHCLBHSA-N (S)-malic acid Chemical compound OC(=O)[C@@H](O)CC(O)=O BJEPYKJPYRNKOW-REOHCLBHSA-N 0.000 description 1
- RTBFRGCFXZNCOE-UHFFFAOYSA-N 1-methylsulfonylpiperidin-4-one Chemical compound CS(=O)(=O)N1CCC(=O)CC1 RTBFRGCFXZNCOE-UHFFFAOYSA-N 0.000 description 1
- HOSGXJWQVBHGLT-UHFFFAOYSA-N 6-hydroxy-3,4-dihydro-1h-quinolin-2-one Chemical group N1C(=O)CCC2=CC(O)=CC=C21 HOSGXJWQVBHGLT-UHFFFAOYSA-N 0.000 description 1
- 229910001369 Brass Inorganic materials 0.000 description 1
- RGHNJXZEOKUKBD-UHFFFAOYSA-N D-gluconic acid Natural products OCC(O)C(O)C(O)C(O)C(O)=O RGHNJXZEOKUKBD-UHFFFAOYSA-N 0.000 description 1
- CWYNVVGOOAEACU-UHFFFAOYSA-N Fe2+ Chemical class [Fe+2] CWYNVVGOOAEACU-UHFFFAOYSA-N 0.000 description 1
- WHUUTDBJXJRKMK-UHFFFAOYSA-N Glutamic acid Natural products OC(=O)C(N)CCC(O)=O WHUUTDBJXJRKMK-UHFFFAOYSA-N 0.000 description 1
- 229910021577 Iron(II) chloride Inorganic materials 0.000 description 1
- CKLJMWTZIZZHCS-REOHCLBHSA-N L-aspartic acid Chemical compound OC(=O)[C@@H](N)CC(O)=O CKLJMWTZIZZHCS-REOHCLBHSA-N 0.000 description 1
- WHUUTDBJXJRKMK-VKHMYHEASA-N L-glutamic acid Chemical compound OC(=O)[C@@H](N)CCC(O)=O WHUUTDBJXJRKMK-VKHMYHEASA-N 0.000 description 1
- TXXHDPDFNKHHGW-CCAGOZQPSA-N Muconic acid Natural products OC(=O)\C=C/C=C\C(O)=O TXXHDPDFNKHHGW-CCAGOZQPSA-N 0.000 description 1
- VEQPNABPJHWNSG-UHFFFAOYSA-N Nickel(2+) Chemical compound [Ni+2] VEQPNABPJHWNSG-UHFFFAOYSA-N 0.000 description 1
- 229910021586 Nickel(II) chloride Inorganic materials 0.000 description 1
- QXZUUHYBWMWJHK-UHFFFAOYSA-N [Co].[Ni] Chemical compound [Co].[Ni] QXZUUHYBWMWJHK-UHFFFAOYSA-N 0.000 description 1
- RYDPIAIFQLDAQQ-UHFFFAOYSA-N [Ni].C#C Chemical compound [Ni].C#C RYDPIAIFQLDAQQ-UHFFFAOYSA-N 0.000 description 1
- XOCUXOWLYLLJLV-UHFFFAOYSA-N [O].[S] Chemical class [O].[S] XOCUXOWLYLLJLV-UHFFFAOYSA-N 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 239000013543 active substance Substances 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 150000007933 aliphatic carboxylic acids Chemical class 0.000 description 1
- BJEPYKJPYRNKOW-UHFFFAOYSA-N alpha-hydroxysuccinic acid Natural products OC(=O)C(O)CC(O)=O BJEPYKJPYRNKOW-UHFFFAOYSA-N 0.000 description 1
- JFCQEDHGNNZCLN-UHFFFAOYSA-N anhydrous glutaric acid Natural products OC(=O)CCCC(O)=O JFCQEDHGNNZCLN-UHFFFAOYSA-N 0.000 description 1
- 150000001450 anions Chemical class 0.000 description 1
- 235000003704 aspartic acid Nutrition 0.000 description 1
- OQFSQFPPLPISGP-UHFFFAOYSA-N beta-carboxyaspartic acid Natural products OC(=O)C(N)C(C(O)=O)C(O)=O OQFSQFPPLPISGP-UHFFFAOYSA-N 0.000 description 1
- 239000010951 brass Substances 0.000 description 1
- 238000005282 brightening Methods 0.000 description 1
- FATUQANACHZLRT-KMRXSBRUSA-L calcium glucoheptonate Chemical compound [Ca+2].OC[C@@H](O)[C@@H](O)[C@H](O)[C@@H](O)C(O)C([O-])=O.OC[C@@H](O)[C@@H](O)[C@H](O)[C@@H](O)C(O)C([O-])=O FATUQANACHZLRT-KMRXSBRUSA-L 0.000 description 1
- 125000004432 carbon atom Chemical group C* 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000011156 evaluation Methods 0.000 description 1
- 239000004744 fabric Substances 0.000 description 1
- 235000012208 gluconic acid Nutrition 0.000 description 1
- 239000000174 gluconic acid Substances 0.000 description 1
- 235000013922 glutamic acid Nutrition 0.000 description 1
- 239000004220 glutamic acid Substances 0.000 description 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
- NMCUIPGRVMDVDB-UHFFFAOYSA-L iron dichloride Chemical compound Cl[Fe]Cl NMCUIPGRVMDVDB-UHFFFAOYSA-L 0.000 description 1
- BAUYGSIQEAFULO-UHFFFAOYSA-L iron(2+) sulfate (anhydrous) Chemical compound [Fe+2].[O-]S([O-])(=O)=O BAUYGSIQEAFULO-UHFFFAOYSA-L 0.000 description 1
- 229910000359 iron(II) sulfate Inorganic materials 0.000 description 1
- 239000002932 luster Substances 0.000 description 1
- 235000011090 malic acid Nutrition 0.000 description 1
- 239000001630 malic acid Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- QMMRZOWCJAIUJA-UHFFFAOYSA-L nickel dichloride Chemical compound Cl[Ni]Cl QMMRZOWCJAIUJA-UHFFFAOYSA-L 0.000 description 1
- 229910001453 nickel ion Inorganic materials 0.000 description 1
- LGQLOGILCSXPEA-UHFFFAOYSA-L nickel sulfate Chemical compound [Ni+2].[O-]S([O-])(=O)=O LGQLOGILCSXPEA-UHFFFAOYSA-L 0.000 description 1
- KERTUBUCQCSNJU-UHFFFAOYSA-L nickel(2+);disulfamate Chemical compound [Ni+2].NS([O-])(=O)=O.NS([O-])(=O)=O KERTUBUCQCSNJU-UHFFFAOYSA-L 0.000 description 1
- 229910000363 nickel(II) sulfate Inorganic materials 0.000 description 1
- 239000011148 porous material Substances 0.000 description 1
- 239000002244 precipitate Substances 0.000 description 1
- 230000000750 progressive effect Effects 0.000 description 1
- 230000002035 prolonged effect Effects 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 230000037390 scarring Effects 0.000 description 1
- 238000010186 staining Methods 0.000 description 1
- IIACRCGMVDHOTQ-UHFFFAOYSA-N sulfamic acid Chemical class NS(O)(=O)=O IIACRCGMVDHOTQ-UHFFFAOYSA-N 0.000 description 1
- 150000003568 thioethers Chemical class 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25D—PROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
- C25D5/00—Electroplating characterised by the process; Pretreatment or after-treatment of workpieces
- C25D5/10—Electroplating with more than one layer of the same or of different metals
- C25D5/12—Electroplating with more than one layer of the same or of different metals at least one layer being of nickel or chromium
- C25D5/14—Electroplating with more than one layer of the same or of different metals at least one layer being of nickel or chromium two or more layers being of nickel or chromium, e.g. duplex or triplex layers
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25D—PROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
- C25D5/00—Electroplating characterised by the process; Pretreatment or after-treatment of workpieces
- C25D5/60—Electroplating characterised by the structure or texture of the layers
- C25D5/623—Porosity of the layers
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25D—PROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
- C25D5/00—Electroplating characterised by the process; Pretreatment or after-treatment of workpieces
- C25D5/60—Electroplating characterised by the structure or texture of the layers
- C25D5/625—Discontinuous layers, e.g. microcracked layers
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25D—PROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
- C25D5/00—Electroplating characterised by the process; Pretreatment or after-treatment of workpieces
- C25D5/627—Electroplating characterised by the visual appearance of the layers, e.g. colour, brightness or mat appearance
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S428/00—Stock material or miscellaneous articles
- Y10S428/922—Static electricity metal bleed-off metallic stock
- Y10S428/923—Physical dimension
- Y10S428/924—Composite
- Y10S428/926—Thickness of individual layer specified
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S428/00—Stock material or miscellaneous articles
- Y10S428/922—Static electricity metal bleed-off metallic stock
- Y10S428/9335—Product by special process
- Y10S428/934—Electrical process
- Y10S428/935—Electroplating
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/12—All metal or with adjacent metals
- Y10T428/12479—Porous [e.g., foamed, spongy, cracked, etc.]
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/12—All metal or with adjacent metals
- Y10T428/12493—Composite; i.e., plural, adjacent, spatially distinct metal components [e.g., layers, joint, etc.]
- Y10T428/12535—Composite; i.e., plural, adjacent, spatially distinct metal components [e.g., layers, joint, etc.] with additional, spatially distinct nonmetal component
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/12—All metal or with adjacent metals
- Y10T428/12493—Composite; i.e., plural, adjacent, spatially distinct metal components [e.g., layers, joint, etc.]
- Y10T428/12771—Transition metal-base component
- Y10T428/12806—Refractory [Group IVB, VB, or VIB] metal-base component
- Y10T428/12826—Group VIB metal-base component
- Y10T428/12847—Cr-base component
- Y10T428/12854—Next to Co-, Fe-, or Ni-base component
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/12—All metal or with adjacent metals
- Y10T428/12493—Composite; i.e., plural, adjacent, spatially distinct metal components [e.g., layers, joint, etc.]
- Y10T428/12771—Transition metal-base component
- Y10T428/12861—Group VIII or IB metal-base component
- Y10T428/12903—Cu-base component
- Y10T428/1291—Next to Co-, Cu-, or Ni-base component
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/12—All metal or with adjacent metals
- Y10T428/12993—Surface feature [e.g., rough, mirror]
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- Materials Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Laminated Bodies (AREA)
- Electroplating Methods And Accessories (AREA)
- Electroplating And Plating Baths Therefor (AREA)
- Other Surface Treatments For Metallic Materials (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US05/554,843 US3994694A (en) | 1975-03-03 | 1975-03-03 | Composite nickel-iron electroplated article |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| DE2544041A1 DE2544041A1 (de) | 1976-09-16 |
| DE2544041B2 DE2544041B2 (de) | 1978-08-03 |
| DE2544041C3 true DE2544041C3 (de) | 1979-05-03 |
Family
ID=24214917
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE2544041A Expired DE2544041C3 (de) | 1975-03-03 | 1975-10-02 | Gegenstand aus einem metallischen Substrat und einem darauf galvanisch abgeschiedenen, mehrschichtigen metallischen Überzug |
Country Status (12)
| Country | Link |
|---|---|
| US (1) | US3994694A (enExample) |
| JP (1) | JPS5635755B2 (enExample) |
| AR (1) | AR206638A1 (enExample) |
| BR (1) | BR7504246A (enExample) |
| CA (1) | CA1024465A (enExample) |
| DE (1) | DE2544041C3 (enExample) |
| ES (1) | ES438351A1 (enExample) |
| FR (1) | FR2303095A1 (enExample) |
| GB (1) | GB1514816A (enExample) |
| IT (1) | IT1035925B (enExample) |
| NL (1) | NL7507009A (enExample) |
| SU (1) | SU882417A3 (enExample) |
Families Citing this family (24)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4179343A (en) * | 1979-02-12 | 1979-12-18 | Oxy Metal Industries Corporation | Electroplating bath and process for producing bright, high-leveling nickel iron electrodeposits |
| JPS581076A (ja) * | 1981-06-26 | 1983-01-06 | Nisshin Steel Co Ltd | Ｌｎｇ又はｌｐｇタンク用高ニッケル―鉄合金鋼板の表面処理方法 |
| US4411961A (en) * | 1981-09-28 | 1983-10-25 | Occidental Chemical Corporation | Composite electroplated article and process |
| US5015803A (en) * | 1989-05-31 | 1991-05-14 | Olin Corporation | Thermal performance package for integrated circuit chip |
| US7569131B2 (en) * | 2002-08-12 | 2009-08-04 | International Business Machines Corporation | Method for producing multiple magnetic layers of materials with known thickness and composition using a one-step electrodeposition process |
| JP5301993B2 (ja) | 2005-08-12 | 2013-09-25 | モジュメタル エルエルシー | 組成変調複合材料及びその形成方法 |
| EP2396455B1 (en) | 2009-02-13 | 2018-10-24 | Nissan Motor Co., Ltd. | Chrome-plated part and manufacturing method of the same |
| EP2440691B1 (en) | 2009-06-08 | 2019-10-23 | Modumetal, Inc. | Electrodeposited, nanolaminate coatings and claddings for corrosion protection |
| US8637165B2 (en) | 2011-09-30 | 2014-01-28 | Apple Inc. | Connector with multi-layer Ni underplated contacts |
| US9004960B2 (en) | 2012-08-10 | 2015-04-14 | Apple Inc. | Connector with gold-palladium plated contacts |
| EA201500947A1 (ru) | 2013-03-15 | 2016-03-31 | Модьюметл, Инк. | Устройство и способ электроосаждения нанослоистого покрытия |
| BR112015022192A8 (pt) | 2013-03-15 | 2019-11-26 | Modumetal Inc | artigo e seu método de preparação |
| CN108486622B (zh) | 2013-03-15 | 2020-10-30 | 莫杜美拓有限公司 | 具有高硬度的镍铬纳米层压涂层 |
| CN105283587B (zh) | 2013-03-15 | 2019-05-10 | 莫杜美拓有限公司 | 纳米叠层涂层 |
| CN106794673B (zh) | 2014-09-18 | 2021-01-22 | 莫杜美拓有限公司 | 通过电沉积和添加制造工艺制备制品的方法 |
| EP3194642A4 (en) | 2014-09-18 | 2018-07-04 | Modumetal, Inc. | A method and apparatus for continuously applying nanolaminate metal coatings |
| CA3036191A1 (en) | 2016-09-08 | 2018-03-15 | Modumetal, Inc. | Processes for providing laminated coatings on workpieces, and articles made therefrom |
| TW201821649A (zh) | 2016-09-09 | 2018-06-16 | 美商馬杜合金股份有限公司 | 層合物與奈米層合物材料於工具及模製方法之應用 |
| KR102412452B1 (ko) | 2016-09-14 | 2022-06-23 | 모두메탈, 인크. | 신뢰가능한 고처리량 복합 전기장 발생을 위한 시스템, 및 그로부터 코팅을 제조하는 방법 |
| US12076965B2 (en) | 2016-11-02 | 2024-09-03 | Modumetal, Inc. | Topology optimized high interface packing structures |
| WO2018175975A1 (en) | 2017-03-24 | 2018-09-27 | Modumetal, Inc. | Lift plungers with electrodeposited coatings, and systems and methods for producing the same |
| CN110770372B (zh) | 2017-04-21 | 2022-10-11 | 莫杜美拓有限公司 | 具有电沉积涂层的管状制品及其生产系统和方法 |
| WO2019210264A1 (en) | 2018-04-27 | 2019-10-31 | Modumetal, Inc. | Apparatuses, systems, and methods for producing a plurality of articles with nanolaminated coatings using rotation |
| CN110846696A (zh) * | 2019-11-28 | 2020-02-28 | 汕头市铠嘉模具有限公司 | 提高凹版使用寿命的电镀新工艺 |
Family Cites Families (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR1438565A (fr) * | 1965-04-02 | 1966-05-13 | Bull General Electric | Procédé pour préparer des lames minces ferromagnétiques à anisotropie prédéterminée et lames minces obtenues par ce procédé |
| US3451793A (en) * | 1966-02-12 | 1969-06-24 | Toko Inc | Magnetic thin film wire with multiple laminated film coating |
| US3480522A (en) * | 1966-08-18 | 1969-11-25 | Ibm | Method of making magnetic thin film device |
| US3488167A (en) * | 1967-07-06 | 1970-01-06 | Ibm | Magnetic memory element with variable exchange coupling |
| DE1771286A1 (de) * | 1968-04-30 | 1971-11-25 | Telefunken Patent | Verfahren zur Herstellung duenner ferromagnetischer Schichtspeicherelemente |
| US3525677A (en) * | 1969-03-24 | 1970-08-25 | Ncr Co | Electrodeposition of constant-composition thin films |
| US3645857A (en) * | 1969-05-28 | 1972-02-29 | Ferroxcube Corp | Method of making plated wire memory element |
| US3716464A (en) * | 1969-12-30 | 1973-02-13 | Ibm | Method for electrodepositing of alloy film of a given composition from a given solution |
| US3812566A (en) * | 1972-07-03 | 1974-05-28 | Oxy Metal Finishing Corp | Composite nickel iron electroplate and method of making said electroplate |
| CA1009603A (en) * | 1972-07-03 | 1977-05-03 | Richard J. Clauss | Composite nickel iron electroplate |
| US3878067A (en) * | 1972-07-03 | 1975-04-15 | Oxy Metal Finishing Corp | Electrolyte and method for electrodepositing of bright nickel-iron alloy deposits |
-
1975
- 1975-01-01 AR AR259586A patent/AR206638A1/es active
- 1975-03-03 US US05/554,843 patent/US3994694A/en not_active Expired - Lifetime
- 1975-05-21 CA CA227,424A patent/CA1024465A/en not_active Expired
- 1975-05-23 GB GB22803/75A patent/GB1514816A/en not_active Expired
- 1975-06-03 IT IT7549874A patent/IT1035925B/it active
- 1975-06-09 ES ES438351A patent/ES438351A1/es not_active Expired
- 1975-06-12 NL NL7507009A patent/NL7507009A/xx not_active Application Discontinuation
- 1975-06-16 FR FR7518794A patent/FR2303095A1/fr active Granted
- 1975-06-30 SU SU752150652A patent/SU882417A3/ru active
- 1975-07-04 BR BR5436/75D patent/BR7504246A/pt unknown
- 1975-10-02 DE DE2544041A patent/DE2544041C3/de not_active Expired
- 1975-11-05 JP JP13284375A patent/JPS5635755B2/ja not_active Expired
Also Published As
| Publication number | Publication date |
|---|---|
| BR7504246A (pt) | 1976-09-14 |
| GB1514816A (en) | 1978-06-21 |
| JPS5635755B2 (enExample) | 1981-08-19 |
| AU8172175A (en) | 1976-12-02 |
| US3994694A (en) | 1976-11-30 |
| AR206638A1 (es) | 1976-08-06 |
| SU882417A3 (ru) | 1981-11-15 |
| ES438351A1 (es) | 1977-06-16 |
| DE2544041A1 (de) | 1976-09-16 |
| FR2303095B1 (enExample) | 1978-10-20 |
| NL7507009A (nl) | 1976-09-07 |
| JPS51100940A (enExample) | 1976-09-06 |
| DE2544041B2 (de) | 1978-08-03 |
| FR2303095A1 (fr) | 1976-10-01 |
| CA1024465A (en) | 1978-01-17 |
| IT1035925B (it) | 1979-10-20 |
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| C3 | Grant after two publication steps (3rd publication) | ||
| 8327 | Change in the person/name/address of the patent owner |
Owner name: OMI INTERNATIONAL CORP. (EINE GESELLSCHAFT N.D.GES |
|
| 8328 | Change in the person/name/address of the agent |
Free format text: HAUCK, H., DIPL.-ING. DIPL.-WIRTSCH.-ING., 8000 MUENCHEN SCHMITZ, W., DIPL.-PHYS. GRAALFS, E., DIPL.-ING., 2000 HAMBURG WEHNERT, W., DIPL.-ING., 8000 MUENCHEN DOERING, W., DIPL.-WIRTSCH.-ING. DR.-ING., PAT.-ANW., 4000 DUESSELDORF |
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| 8339 | Ceased/non-payment of the annual fee |