DE2519288C2 - Verfahren zur Herstellung von Percarbonsäurelösungen - Google Patents
Verfahren zur Herstellung von PercarbonsäurelösungenInfo
- Publication number
- DE2519288C2 DE2519288C2 DE19752519288 DE2519288A DE2519288C2 DE 2519288 C2 DE2519288 C2 DE 2519288C2 DE 19752519288 DE19752519288 DE 19752519288 DE 2519288 A DE2519288 A DE 2519288A DE 2519288 C2 DE2519288 C2 DE 2519288C2
- Authority
- DE
- Germany
- Prior art keywords
- raffinate
- hydrogen peroxide
- acid
- extract
- percarboxylic
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 238000000034 method Methods 0.000 title claims description 17
- SCKXCAADGDQQCS-UHFFFAOYSA-N Performic acid Chemical compound OOC=O SCKXCAADGDQQCS-UHFFFAOYSA-N 0.000 title claims description 10
- 238000002360 preparation method Methods 0.000 title description 3
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 claims description 58
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 17
- 238000006243 chemical reaction Methods 0.000 claims description 16
- 238000000605 extraction Methods 0.000 claims description 14
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 claims description 12
- 239000002253 acid Substances 0.000 claims description 12
- 150000007513 acids Chemical class 0.000 claims description 11
- 239000003960 organic solvent Substances 0.000 claims description 10
- 230000002378 acidificating effect Effects 0.000 claims description 9
- 150000001735 carboxylic acids Chemical class 0.000 claims description 9
- 239000003054 catalyst Substances 0.000 claims description 9
- 239000000284 extract Substances 0.000 claims description 8
- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 claims description 6
- 229910052726 zirconium Inorganic materials 0.000 claims description 6
- 125000004432 carbon atom Chemical group C* 0.000 claims description 5
- 229910052715 tantalum Inorganic materials 0.000 claims description 4
- GUVRBAGPIYLISA-UHFFFAOYSA-N tantalum atom Chemical compound [Ta] GUVRBAGPIYLISA-UHFFFAOYSA-N 0.000 claims description 4
- 238000010626 work up procedure Methods 0.000 claims description 4
- 238000010533 azeotropic distillation Methods 0.000 claims description 2
- 238000010924 continuous production Methods 0.000 claims description 2
- 238000004064 recycling Methods 0.000 claims description 2
- 239000002904 solvent Substances 0.000 claims description 2
- 150000001732 carboxylic acid derivatives Chemical class 0.000 claims 2
- 229910001128 Sn alloy Inorganic materials 0.000 claims 1
- 230000009469 supplementation Effects 0.000 claims 1
- XBDQKXXYIPTUBI-UHFFFAOYSA-N dimethylselenoniopropionate Natural products CCC(O)=O XBDQKXXYIPTUBI-UHFFFAOYSA-N 0.000 description 20
- 239000000243 solution Substances 0.000 description 14
- 235000019260 propionic acid Nutrition 0.000 description 10
- IUVKMZGDUIUOCP-BTNSXGMBSA-N quinbolone Chemical compound O([C@H]1CC[C@H]2[C@H]3[C@@H]([C@]4(C=CC(=O)C=C4CC3)C)CC[C@@]21C)C1=CCCC1 IUVKMZGDUIUOCP-BTNSXGMBSA-N 0.000 description 10
- 239000000203 mixture Substances 0.000 description 9
- 229910052760 oxygen Inorganic materials 0.000 description 7
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 6
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 6
- 239000001301 oxygen Substances 0.000 description 6
- CZPZWMPYEINMCF-UHFFFAOYSA-N propaneperoxoic acid Chemical compound CCC(=O)OO CZPZWMPYEINMCF-UHFFFAOYSA-N 0.000 description 6
- FHHJDRFHHWUPDG-UHFFFAOYSA-N peroxysulfuric acid Chemical compound OOS(O)(=O)=O FHHJDRFHHWUPDG-UHFFFAOYSA-N 0.000 description 5
- 239000011541 reaction mixture Substances 0.000 description 5
- 238000004821 distillation Methods 0.000 description 4
- 229910052845 zircon Inorganic materials 0.000 description 4
- GFQYVLUOOAAOGM-UHFFFAOYSA-N zirconium(iv) silicate Chemical compound [Zr+4].[O-][Si]([O-])([O-])[O-] GFQYVLUOOAAOGM-UHFFFAOYSA-N 0.000 description 4
- 238000004519 manufacturing process Methods 0.000 description 3
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- 229910001093 Zr alloy Inorganic materials 0.000 description 2
- 150000001299 aldehydes Chemical class 0.000 description 2
- 150000001336 alkenes Chemical class 0.000 description 2
- 239000007864 aqueous solution Substances 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 150000001451 organic peroxides Chemical class 0.000 description 2
- 239000000047 product Substances 0.000 description 2
- 238000010992 reflux Methods 0.000 description 2
- -1 B. with an olefin Chemical compound 0.000 description 1
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 1
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 description 1
- 229910045601 alloy Inorganic materials 0.000 description 1
- 239000000956 alloy Substances 0.000 description 1
- 150000004945 aromatic hydrocarbons Chemical class 0.000 description 1
- 238000006701 autoxidation reaction Methods 0.000 description 1
- SESFRYSPDFLNCH-UHFFFAOYSA-N benzyl benzoate Chemical compound C=1C=CC=CC=1C(=O)OCC1=CC=CC=C1 SESFRYSPDFLNCH-UHFFFAOYSA-N 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 239000006227 byproduct Substances 0.000 description 1
- 239000003990 capacitor Substances 0.000 description 1
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 1
- 150000001733 carboxylic acid esters Chemical class 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 229910052804 chromium Inorganic materials 0.000 description 1
- 239000011651 chromium Substances 0.000 description 1
- VNNRSPGTAMTISX-UHFFFAOYSA-N chromium nickel Chemical compound [Cr].[Ni] VNNRSPGTAMTISX-UHFFFAOYSA-N 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 239000012141 concentrate Substances 0.000 description 1
- 150000003997 cyclic ketones Chemical class 0.000 description 1
- 238000004200 deflagration Methods 0.000 description 1
- 230000018044 dehydration Effects 0.000 description 1
- 238000006297 dehydration reaction Methods 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 239000002360 explosive Substances 0.000 description 1
- 239000011552 falling film Substances 0.000 description 1
- 229910052735 hafnium Inorganic materials 0.000 description 1
- VBJZVLUMGGDVMO-UHFFFAOYSA-N hafnium atom Chemical compound [Hf] VBJZVLUMGGDVMO-UHFFFAOYSA-N 0.000 description 1
- BGMBLIGYOGMCHI-UHFFFAOYSA-N hafnium iron Chemical compound [Fe].[Hf].[Hf] BGMBLIGYOGMCHI-UHFFFAOYSA-N 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 238000011835 investigation Methods 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 150000002596 lactones Chemical class 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 229910052758 niobium Inorganic materials 0.000 description 1
- 239000010955 niobium Substances 0.000 description 1
- GUCVJGMIXFAOAE-UHFFFAOYSA-N niobium atom Chemical compound [Nb] GUCVJGMIXFAOAE-UHFFFAOYSA-N 0.000 description 1
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 1
- 235000013348 organic food Nutrition 0.000 description 1
- 150000004965 peroxy acids Chemical class 0.000 description 1
- 150000003014 phosphoric acid esters Chemical class 0.000 description 1
- 238000003385 ring cleavage reaction Methods 0.000 description 1
- 239000010935 stainless steel Substances 0.000 description 1
- 229910001220 stainless steel Inorganic materials 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- 229910052718 tin Inorganic materials 0.000 description 1
- 239000011135 tin Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C409/00—Peroxy compounds
- C07C409/24—Peroxy compounds the —O—O— group being bound between a >C=O group and hydrogen, i.e. peroxy acids
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C407/00—Preparation of peroxy compounds
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C407/00—Preparation of peroxy compounds
- C07C407/003—Separation; Purification; Stabilisation; Use of additives
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Priority Applications (8)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE19752519288 DE2519288C2 (de) | 1975-04-30 | 1975-04-30 | Verfahren zur Herstellung von Percarbonsäurelösungen |
| GB1718176A GB1550164A (en) | 1975-04-30 | 1976-04-28 | Process for the preparation of percarboxylic acid solutions |
| NL7604540A NL7604540A (nl) | 1975-04-30 | 1976-04-28 | Werkwijze ter bereiding van percarbonzuuroplos- singen. |
| JP51047903A JPS5917110B2 (ja) | 1975-04-30 | 1976-04-28 | 過カルボン酸溶液の製造方法 |
| BE2054981A BE841198A (fr) | 1975-04-30 | 1976-04-28 | Procede de preparation de solutions d'acides percarboxyliques |
| SU762353640A SU652891A3 (ru) | 1975-04-30 | 1976-04-28 | Способ получени бензольного раствора надпропионовой кислоты |
| FR7612603A FR2309526A1 (fr) | 1975-04-30 | 1976-04-28 | Procede de preparation de solutions d'acides percarboxyliques |
| IE89376A IE42801B1 (en) | 1975-04-30 | 1976-04-28 | Process for the preparation of percarboxylic acid solutions |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE19752519288 DE2519288C2 (de) | 1975-04-30 | 1975-04-30 | Verfahren zur Herstellung von Percarbonsäurelösungen |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| DE2519288A1 DE2519288A1 (de) | 1976-11-11 |
| DE2519288C2 true DE2519288C2 (de) | 1982-09-16 |
Family
ID=5945440
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE19752519288 Expired DE2519288C2 (de) | 1975-04-30 | 1975-04-30 | Verfahren zur Herstellung von Percarbonsäurelösungen |
Country Status (8)
| Country | Link |
|---|---|
| JP (1) | JPS5917110B2 (en:Method) |
| BE (1) | BE841198A (en:Method) |
| DE (1) | DE2519288C2 (en:Method) |
| FR (1) | FR2309526A1 (en:Method) |
| GB (1) | GB1550164A (en:Method) |
| IE (1) | IE42801B1 (en:Method) |
| NL (1) | NL7604540A (en:Method) |
| SU (1) | SU652891A3 (en:Method) |
Family Cites Families (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| BE808108A (fr) * | 1972-12-22 | 1974-05-30 | Degussa | Procede pour la preparation de solutions d'acide percarboxylique dans des solvants organiques |
| DE2519287C3 (de) * | 1975-04-30 | 1979-04-19 | Bayer Ag, 5090 Leverkusen | Verfahren zur kontinuierlichen Herstellung von wasserfreien oder weitgehend wasserfreien Percarbonsäurelösungen |
| DE2519301C2 (de) * | 1975-04-30 | 1984-12-13 | Bayer Ag, 5090 Leverkusen | Verfahren zur Herstellung von Lösungen von Percarbonsäuren in organischen Lösungsmitteln |
-
1975
- 1975-04-30 DE DE19752519288 patent/DE2519288C2/de not_active Expired
-
1976
- 1976-04-28 FR FR7612603A patent/FR2309526A1/fr active Granted
- 1976-04-28 GB GB1718176A patent/GB1550164A/en not_active Expired
- 1976-04-28 SU SU762353640A patent/SU652891A3/ru active
- 1976-04-28 BE BE2054981A patent/BE841198A/xx unknown
- 1976-04-28 IE IE89376A patent/IE42801B1/en unknown
- 1976-04-28 NL NL7604540A patent/NL7604540A/xx active Search and Examination
- 1976-04-28 JP JP51047903A patent/JPS5917110B2/ja not_active Expired
Also Published As
| Publication number | Publication date |
|---|---|
| BE841198A (fr) | 1976-10-28 |
| NL7604540A (nl) | 1976-11-02 |
| FR2309526A1 (fr) | 1976-11-26 |
| DE2519288A1 (de) | 1976-11-11 |
| SU652891A3 (ru) | 1979-03-15 |
| JPS51133223A (en) | 1976-11-18 |
| IE42801B1 (en) | 1980-10-22 |
| GB1550164A (en) | 1979-08-08 |
| FR2309526B1 (en:Method) | 1980-08-22 |
| JPS5917110B2 (ja) | 1984-04-19 |
| IE42801L (en) | 1976-10-30 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| OGA | New person/name/address of the applicant | ||
| D2 | Grant after examination | ||
| 8363 | Opposition against the patent | ||
| 8330 | Complete disclaimer |