DE2447727A1 - Schwerentflammbare polyamidformmassen - Google Patents
Schwerentflammbare polyamidformmassenInfo
- Publication number
- DE2447727A1 DE2447727A1 DE19742447727 DE2447727A DE2447727A1 DE 2447727 A1 DE2447727 A1 DE 2447727A1 DE 19742447727 DE19742447727 DE 19742447727 DE 2447727 A DE2447727 A DE 2447727A DE 2447727 A1 DE2447727 A1 DE 2447727A1
- Authority
- DE
- Germany
- Prior art keywords
- polyamide
- acid
- carbon atoms
- polyamide molding
- bis
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
- 239000004952 Polyamide Substances 0.000 title claims description 42
- 229920002647 polyamide Polymers 0.000 title claims description 42
- 238000000465 moulding Methods 0.000 title claims description 17
- 150000001875 compounds Chemical class 0.000 title claims description 10
- 125000004432 carbon atom Chemical group C* 0.000 claims description 24
- 239000002253 acid Substances 0.000 claims description 12
- -1 cyclic alkyl radicals Chemical class 0.000 claims description 9
- ACVYVLVWPXVTIT-UHFFFAOYSA-N phosphinic acid Chemical compound O[PH2]=O ACVYVLVWPXVTIT-UHFFFAOYSA-N 0.000 claims description 9
- 150000003839 salts Chemical class 0.000 claims description 9
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 claims description 8
- 239000003063 flame retardant Substances 0.000 claims description 7
- 229910052751 metal Inorganic materials 0.000 claims description 7
- 239000002184 metal Substances 0.000 claims description 7
- 229920006395 saturated elastomer Polymers 0.000 claims description 7
- 125000004202 aminomethyl group Chemical group [H]N([H])C([H])([H])* 0.000 claims description 6
- 229910052783 alkali metal Inorganic materials 0.000 claims description 3
- 150000001340 alkali metals Chemical class 0.000 claims description 3
- 125000000732 arylene group Chemical group 0.000 claims description 3
- 150000004985 diamines Chemical class 0.000 claims description 3
- 230000000737 periodic effect Effects 0.000 claims description 3
- BDBZTOMUANOKRT-UHFFFAOYSA-N 4-[2-(4-aminocyclohexyl)propan-2-yl]cyclohexan-1-amine Chemical compound C1CC(N)CCC1C(C)(C)C1CCC(N)CC1 BDBZTOMUANOKRT-UHFFFAOYSA-N 0.000 claims description 2
- GKXVJHDEWHKBFH-UHFFFAOYSA-N [2-(aminomethyl)phenyl]methanamine Chemical compound NCC1=CC=CC=C1CN GKXVJHDEWHKBFH-UHFFFAOYSA-N 0.000 claims description 2
- OXIKYYJDTWKERT-UHFFFAOYSA-N [4-(aminomethyl)cyclohexyl]methanamine Chemical compound NCC1CCC(CN)CC1 OXIKYYJDTWKERT-UHFFFAOYSA-N 0.000 claims description 2
- 229920006020 amorphous polyamide Polymers 0.000 claims description 2
- 150000005840 aryl radicals Chemical class 0.000 claims description 2
- 239000000945 filler Substances 0.000 claims description 2
- 229920000642 polymer Polymers 0.000 claims description 2
- 150000003254 radicals Chemical class 0.000 claims description 2
- 239000012757 flame retardant agent Substances 0.000 claims 1
- 239000000203 mixture Substances 0.000 description 15
- KKEYFWRCBNTPAC-UHFFFAOYSA-N Terephthalic acid Chemical compound OC(=O)C1=CC=C(C(O)=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-N 0.000 description 14
- 238000012360 testing method Methods 0.000 description 12
- QLBRROYTTDFLDX-UHFFFAOYSA-N [3-(aminomethyl)cyclohexyl]methanamine Chemical compound NCC1CCCC(CN)C1 QLBRROYTTDFLDX-UHFFFAOYSA-N 0.000 description 9
- 150000003751 zinc Chemical class 0.000 description 9
- QXNVGIXVLWOKEQ-UHFFFAOYSA-N Disodium Chemical class [Na][Na] QXNVGIXVLWOKEQ-UHFFFAOYSA-N 0.000 description 8
- QQVIHTHCMHWDBS-UHFFFAOYSA-N isophthalic acid Chemical compound OC(=O)C1=CC=CC(C(O)=O)=C1 QQVIHTHCMHWDBS-UHFFFAOYSA-N 0.000 description 8
- GOJNABIZVJCYFL-UHFFFAOYSA-N dimethylphosphinic acid Chemical class CP(C)(O)=O GOJNABIZVJCYFL-UHFFFAOYSA-N 0.000 description 7
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 6
- 150000007513 acids Chemical class 0.000 description 6
- 238000009833 condensation Methods 0.000 description 6
- 230000005494 condensation Effects 0.000 description 6
- 238000004519 manufacturing process Methods 0.000 description 6
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 6
- KXDHJXZQYSOELW-UHFFFAOYSA-N Carbamic acid Chemical compound NC(O)=O KXDHJXZQYSOELW-UHFFFAOYSA-N 0.000 description 5
- JBKVHLHDHHXQEQ-UHFFFAOYSA-N epsilon-caprolactam Chemical compound O=C1CCCCCN1 JBKVHLHDHHXQEQ-UHFFFAOYSA-N 0.000 description 5
- 239000000047 product Substances 0.000 description 5
- 238000003756 stirring Methods 0.000 description 5
- QPFMBZIOSGYJDE-UHFFFAOYSA-N 1,1,2,2-tetrachloroethane Chemical compound ClC(Cl)C(Cl)Cl QPFMBZIOSGYJDE-UHFFFAOYSA-N 0.000 description 4
- AZUYLZMQTIKGSC-UHFFFAOYSA-N 1-[6-[4-(5-chloro-6-methyl-1H-indazol-4-yl)-5-methyl-3-(1-methylindazol-5-yl)pyrazol-1-yl]-2-azaspiro[3.3]heptan-2-yl]prop-2-en-1-one Chemical compound ClC=1C(=C2C=NNC2=CC=1C)C=1C(=NN(C=1C)C1CC2(CN(C2)C(C=C)=O)C1)C=1C=C2C=NN(C2=CC=1)C AZUYLZMQTIKGSC-UHFFFAOYSA-N 0.000 description 3
- UFFRSDWQMJYQNE-UHFFFAOYSA-N 6-azaniumylhexylazanium;hexanedioate Chemical class [NH3+]CCCCCC[NH3+].[O-]C(=O)CCCCC([O-])=O UFFRSDWQMJYQNE-UHFFFAOYSA-N 0.000 description 3
- OFOBLEOULBTSOW-UHFFFAOYSA-N Malonic acid Chemical compound OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 3
- 125000001931 aliphatic group Chemical group 0.000 description 3
- 238000000034 method Methods 0.000 description 3
- 229910052757 nitrogen Inorganic materials 0.000 description 3
- 239000007787 solid Substances 0.000 description 3
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 2
- OTMSDBZUPAUEDD-UHFFFAOYSA-N Ethane Chemical compound CC OTMSDBZUPAUEDD-UHFFFAOYSA-N 0.000 description 2
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 2
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 2
- RPYFJVIASOJLJS-UHFFFAOYSA-N [3-(aminomethyl)-2-bicyclo[2.2.1]heptanyl]methanamine Chemical compound C1CC2C(CN)C(CN)C1C2 RPYFJVIASOJLJS-UHFFFAOYSA-N 0.000 description 2
- FDLQZKYLHJJBHD-UHFFFAOYSA-N [3-(aminomethyl)phenyl]methanamine Chemical compound NCC1=CC=CC(CN)=C1 FDLQZKYLHJJBHD-UHFFFAOYSA-N 0.000 description 2
- 125000003118 aryl group Chemical group 0.000 description 2
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 2
- 230000000052 comparative effect Effects 0.000 description 2
- 239000000835 fiber Substances 0.000 description 2
- 239000003365 glass fiber Substances 0.000 description 2
- NAQMVNRVTILPCV-UHFFFAOYSA-N hexane-1,6-diamine Chemical compound NCCCCCCN NAQMVNRVTILPCV-UHFFFAOYSA-N 0.000 description 2
- 150000003951 lactams Chemical class 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- BCDIWLCKOCHCIH-UHFFFAOYSA-N methylphosphinic acid Chemical compound CP(O)=O BCDIWLCKOCHCIH-UHFFFAOYSA-N 0.000 description 2
- 239000012299 nitrogen atmosphere Substances 0.000 description 2
- 150000003018 phosphorus compounds Chemical class 0.000 description 2
- 239000011541 reaction mixture Substances 0.000 description 2
- 239000000243 solution Substances 0.000 description 2
- TYFJTEPDESMEHE-UHFFFAOYSA-N 6,8-dihydroxy-3-[2-(4-methoxyphenyl)ethyl]-3,4-dihydroisochromen-1-one Chemical compound C1=CC(OC)=CC=C1CCC1OC(=O)C2=C(O)C=C(O)C=C2C1 TYFJTEPDESMEHE-UHFFFAOYSA-N 0.000 description 1
- 244000118350 Andrographis paniculata Species 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 1
- 229910000831 Steel Inorganic materials 0.000 description 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 1
- ISKQADXMHQSTHK-UHFFFAOYSA-N [4-(aminomethyl)phenyl]methanamine Chemical compound NCC1=CC=C(CN)C=C1 ISKQADXMHQSTHK-UHFFFAOYSA-N 0.000 description 1
- ZVQOOHYFBIDMTQ-UHFFFAOYSA-N [methyl(oxido){1-[6-(trifluoromethyl)pyridin-3-yl]ethyl}-lambda(6)-sulfanylidene]cyanamide Chemical compound N#CN=S(C)(=O)C(C)C1=CC=C(C(F)(F)F)N=C1 ZVQOOHYFBIDMTQ-UHFFFAOYSA-N 0.000 description 1
- 150000001335 aliphatic alkanes Chemical class 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- AZDRQVAHHNSJOQ-UHFFFAOYSA-N alumane Chemical class [AlH3] AZDRQVAHHNSJOQ-UHFFFAOYSA-N 0.000 description 1
- 125000003277 amino group Chemical group 0.000 description 1
- 229910021529 ammonia Inorganic materials 0.000 description 1
- IMNFDUFMRHMDMM-UHFFFAOYSA-N anhydrous n-heptane Natural products CCCCCCC IMNFDUFMRHMDMM-UHFFFAOYSA-N 0.000 description 1
- 239000002216 antistatic agent Substances 0.000 description 1
- 150000004945 aromatic hydrocarbons Chemical class 0.000 description 1
- 239000010425 asbestos Substances 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 150000001722 carbon compounds Chemical class 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 239000007795 chemical reaction product Substances 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 125000000118 dimethyl group Chemical group [H]C([H])([H])* 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 239000000975 dye Substances 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 235000013601 eggs Nutrition 0.000 description 1
- 230000008030 elimination Effects 0.000 description 1
- 238000003379 elimination reaction Methods 0.000 description 1
- NXHKQBCTZHECQF-UHFFFAOYSA-N ethyl(methyl)phosphinic acid Chemical class CCP(C)(O)=O NXHKQBCTZHECQF-UHFFFAOYSA-N 0.000 description 1
- WPYVFMKRHQSQSU-UHFFFAOYSA-N ethyl(phenyl)phosphinic acid Chemical compound CCP(O)(=O)C1=CC=CC=C1 WPYVFMKRHQSQSU-UHFFFAOYSA-N 0.000 description 1
- 239000008187 granular material Substances 0.000 description 1
- DZAMTRBPWASOKC-UHFFFAOYSA-N hexyl(methyl)phosphinic acid Chemical compound CCCCCCP(C)(O)=O DZAMTRBPWASOKC-UHFFFAOYSA-N 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 238000007654 immersion Methods 0.000 description 1
- 238000001746 injection moulding Methods 0.000 description 1
- 239000012784 inorganic fiber Substances 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 239000000314 lubricant Substances 0.000 description 1
- 229910052749 magnesium Inorganic materials 0.000 description 1
- 239000011777 magnesium Substances 0.000 description 1
- 230000009347 mechanical transmission Effects 0.000 description 1
- 239000000155 melt Substances 0.000 description 1
- 150000002903 organophosphorus compounds Chemical class 0.000 description 1
- BTLSLHNLDQCWKS-UHFFFAOYSA-N oxocan-2-one Chemical compound O=C1CCCCCCO1 BTLSLHNLDQCWKS-UHFFFAOYSA-N 0.000 description 1
- 229910052698 phosphorus Inorganic materials 0.000 description 1
- 239000011574 phosphorus Substances 0.000 description 1
- 239000010453 quartz Substances 0.000 description 1
- 229910052895 riebeckite Inorganic materials 0.000 description 1
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N silicon dioxide Inorganic materials O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- 229910001220 stainless steel Inorganic materials 0.000 description 1
- 239000010935 stainless steel Substances 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- 210000001550 testis Anatomy 0.000 description 1
- 230000008646 thermal stress Effects 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/49—Phosphorus-containing compounds
- C08K5/51—Phosphorus bound to oxygen
- C08K5/53—Phosphorus bound to oxygen bound to oxygen and to carbon only
- C08K5/5313—Phosphinic compounds, e.g. R2=P(:O)OR'
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/49—Phosphorus-containing compounds
- C08K5/51—Phosphorus bound to oxygen
- C08K5/53—Phosphorus bound to oxygen bound to oxygen and to carbon only
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Polyamides (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
- Organic Insulating Materials (AREA)
Priority Applications (13)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE19742447727 DE2447727A1 (de) | 1974-10-07 | 1974-10-07 | Schwerentflammbare polyamidformmassen |
| NL7511603A NL7511603A (nl) | 1974-10-07 | 1975-10-02 | Moeilijk ontvlambare polyamidevormmassa's. |
| IT27967/75A IT1043125B (it) | 1974-10-07 | 1975-10-03 | Masse per formatura poliamidiche dificilmente inflamabili |
| GB40560/75A GB1509739A (en) | 1974-10-07 | 1975-10-03 | Flame retarding polyamide compositions |
| LU73523A LU73523A1 (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) | 1974-10-07 | 1975-10-06 | |
| US05/620,141 US4036811A (en) | 1974-10-07 | 1975-10-06 | Flame retarding polyamide molding compositions |
| JP50119868A JPS5163859A (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) | 1974-10-07 | 1975-10-06 | |
| ZA00756304A ZA756304B (en) | 1974-10-07 | 1975-10-06 | Flame retarding polyamide molding compositions |
| AT761575A ATA761575A (de) | 1974-10-07 | 1975-10-06 | Ein flammwidrig machendes mittel enthaltende polyamidformmasse |
| DK449375A DK449375A (da) | 1974-10-07 | 1975-10-06 | Vanskeligt antendelige polyamidformmasser |
| CA237,304A CA1052036A (en) | 1974-10-07 | 1975-10-06 | Flame retarding polyamide molding compositions |
| FR7530623A FR2287482A1 (fr) | 1974-10-07 | 1975-10-07 | Matieres a mouler en polyamides ignifugees |
| BE160757A BE834277A (fr) | 1974-10-07 | 1975-10-07 | Matieres a mouler en polyamides ignifugees |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE19742447727 DE2447727A1 (de) | 1974-10-07 | 1974-10-07 | Schwerentflammbare polyamidformmassen |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| DE2447727A1 true DE2447727A1 (de) | 1976-04-08 |
Family
ID=5927720
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE19742447727 Withdrawn DE2447727A1 (de) | 1974-10-07 | 1974-10-07 | Schwerentflammbare polyamidformmassen |
Country Status (13)
Cited By (109)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0699708A2 (de) | 1994-08-31 | 1996-03-06 | Hoechst Aktiengesellschaft | Flammengeschützte Polyesterformmassen |
| EP0794191A1 (de) | 1996-03-04 | 1997-09-10 | Hoechst Aktiengesellschaft | Salze von 1-Hydroxy-dihydrophospholoxiden und 1-Hydroxy-phospholanoxiden und ihre Verwendung als Flammschutzmittel |
| EP0792912A3 (de) * | 1996-02-29 | 1997-10-01 | Hoechst Aktiengesellschaft | Schwerentflammbare Polyamidformmassen |
| WO1998039381A1 (de) * | 1997-03-04 | 1998-09-11 | Ticona Gmbh | Flammgeschützte polymerformmassen |
| DE19851768C2 (de) * | 1997-11-28 | 2000-03-23 | Clariant Gmbh | Verfahren zur Herstellung von Dialkylphosphinsäuresalzen |
| DE19851724C2 (de) * | 1997-11-28 | 2000-06-21 | Clariant Gmbh | Verfahren zur Herstellung von Aryl-alkylphosphinsäuren |
| US6229044B1 (en) | 1997-03-04 | 2001-05-08 | Ticona Gmbh Deutschland Kg | Alkyl-1-alkoxyethylphosphinous acid aluminum salts |
| US6252108B1 (en) | 1997-08-07 | 2001-06-26 | Ticona Gmbh | Method for producing aluminium salts of cyclic phosphinic acid |
| US6303674B1 (en) | 1997-03-04 | 2001-10-16 | Ticona Gmbh | Aluminium salts of alkylhydroxymethylphosphinic acids |
| US6307097B1 (en) | 1997-05-20 | 2001-10-23 | Ticona Gmbh | Method for producing aluminum salts of cyclic phosphinic acids |
| US6344158B1 (en) | 1999-01-30 | 2002-02-05 | Clariant Gmbh | Flame retardant combinations for thermoplastic polymers II |
| US6359171B1 (en) | 1999-05-25 | 2002-03-19 | Clariant Gmbh | Process for preparing dialkylphosphinic acids and their salts |
| US6365071B1 (en) | 1996-04-12 | 2002-04-02 | Clariant Gmbh | Synergistic flame protection agent combination for thermoplastic polymers |
| US6420459B1 (en) | 1999-01-30 | 2002-07-16 | Clariant Gmbh | Flame-retarding thermosetting compositions |
| EP1454912A1 (de) * | 2003-03-04 | 2004-09-08 | Clariant GmbH | Schmelzbare Zinkphosphinate |
| EP1454949A2 (de) | 2003-03-05 | 2004-09-08 | Clariant GmbH | Flammschutzmittel-Dispersion |
| WO2004090036A1 (de) * | 2003-04-11 | 2004-10-21 | Ems-Chemie Ag | Flammgeschützte polyamidformmassen |
| EP1479718A2 (de) | 2003-05-22 | 2004-11-24 | Clariant GmbH | Titanhaltige Phosphinat-Flammschutzmittel |
| DE10331889A1 (de) * | 2003-07-14 | 2005-02-17 | Clariant Gmbh | Flammwidrige Polyamide |
| US7005089B2 (en) | 2002-04-12 | 2006-02-28 | Nicca Chemical Co., Ltd. | Flame retardant treating agents, flame retardant treating process and flame retardant treated articles |
| WO2006029711A1 (de) | 2004-09-13 | 2006-03-23 | Lanxess Deutschland Gmbh | Halogenfreie flammgeschützte thermoplastische formmassen auf basis von polyamid mit erhöhter glühdrahtbeständigkeit |
| EP1657972A1 (de) | 2004-10-12 | 2006-05-17 | Schill + Seilacher "Struktol" Aktiengesellschaft | Phosphinat-Komplexverbindungen der 2., 3., 12. und 13. Gruppen und deren Verwendung als Flammenschutzmittel |
| US7087666B2 (en) | 2002-09-06 | 2006-08-08 | Clariant Gmbh | Surface-modified salts of phosphinic acid |
| US7255814B2 (en) | 2003-03-03 | 2007-08-14 | Clariant Produkte (Deutschland) Gmbh | Flame retardant and stabilizer combined for thermoplastics polymers |
| US7332534B2 (en) | 2003-07-14 | 2008-02-19 | Clariant Produkte (Deutschland) Gmbh | Flame retardant formulation |
| EP1958950A1 (de) | 2003-12-19 | 2008-08-20 | Clariant Produkte (Deutschland) GmbH | Verwendung von Dialkylphosphinsäuresalzen |
| US7420007B2 (en) | 2003-12-19 | 2008-09-02 | Clariant Produkte (Deutschland) Gmbh | Dialkylphosphinic salts |
| US7449508B2 (en) | 2004-02-27 | 2008-11-11 | Clariant Produkte (Deutschland) Gmbh | Flame retardant combination for thermoplastic polymers |
| DE102007037019A1 (de) | 2007-08-06 | 2009-02-12 | Clariant International Limited | Flammschutzmittelmischung für thermoplastische Polymere sowie flammwidrige Polymere |
| EP2031019A2 (de) | 2007-09-01 | 2009-03-04 | Clariant International Ltd. | Flammwidrige Polyestercompounds |
| WO2009110480A1 (ja) | 2008-03-03 | 2009-09-11 | 旭化成ケミカルズ株式会社 | 難燃性樹脂組成物 |
| WO2010112375A1 (en) | 2009-03-31 | 2010-10-07 | Dsm Ip Assets B.V. | Polymer composition containing polybutylene terephthalate and flame retardant additives |
| WO2011116906A1 (en) | 2010-03-23 | 2011-09-29 | Clariant International Ltd | Flame retardant combinations for polyester elastomers and flame retarded extrusion or molding compositions therefrom |
| WO2011134623A1 (de) | 2010-04-29 | 2011-11-03 | Clariant International Ltd | Flammschutzmittel-stabilisator-kombination für thermoplastische und duroplastische polymere |
| DE102010018681A1 (de) | 2010-04-29 | 2011-11-03 | Clariant International Ltd. | Flammschutzmittel-Stabilisator-Kombination für thermoplastische und duroplastische Polymere |
| DE102010018684A1 (de) | 2010-04-29 | 2011-11-03 | Clariant International Ltd. | Verfahren zur Herstellung von Mischungen aus Alkylphosphonigsäuresalzen und Dialkylphosphinsäuresalzen |
| WO2012007124A1 (de) | 2010-07-13 | 2012-01-19 | Clariant International Ltd | Flammschutzmittel-stabilisator-kombination für thermoplastische polymere |
| WO2012024280A1 (en) | 2010-08-17 | 2012-02-23 | E. I. Du Pont De Nemours And Company | Heat stable halogen-free flame retardant copolyester thermoplastic elastomer compositions |
| WO2012045414A1 (de) | 2010-10-09 | 2012-04-12 | Clariant International Ltd | Flammschutzmittel- stabilisator-kombination für thermoplastische polymere |
| DE102010049968A1 (de) | 2010-10-28 | 2012-05-03 | Clariant International Ltd. | Flammwidrige Polyestercompounds |
| EP2450401A1 (de) | 2008-09-05 | 2012-05-09 | THOR GmbH | Flammschutzzusammensetzung enthaltend ein Phosphonsäurederivat |
| WO2012072739A1 (en) | 2010-12-02 | 2012-06-07 | Basf Se | Anti-corrosive phosphinate flame retardant compositions |
| DE102011011928A1 (de) | 2011-02-22 | 2012-08-23 | Clariant International Ltd. | Flammschutzmittel-Stabilisator-Kombination für thermoplastische Polymere |
| WO2012119057A1 (en) | 2011-03-02 | 2012-09-07 | E. I. Dupont De Nemours And Company | Low smoke halogen free flame retardant thermoplastic elastomer compositions containing zeolites |
| WO2012119067A1 (en) | 2011-03-02 | 2012-09-07 | E. I. Du Pont De Nemours And Company | Low smoke halogen free flame retardant thermoplastic vulcanizate compositions containing zeolites |
| US8268956B2 (en) | 2006-12-08 | 2012-09-18 | Ems-Chemie Ag | Transparent mold made of a polyamide molding material |
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Also Published As
| Publication number | Publication date |
|---|---|
| IT1043125B (it) | 1980-02-20 |
| GB1509739A (en) | 1978-05-04 |
| BE834277A (fr) | 1976-04-07 |
| JPS5163859A (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) | 1976-06-02 |
| ZA756304B (en) | 1976-10-27 |
| US4036811A (en) | 1977-07-19 |
| ATA761575A (de) | 1977-03-15 |
| CA1052036A (en) | 1979-04-03 |
| NL7511603A (nl) | 1976-04-09 |
| DK449375A (da) | 1976-04-08 |
| FR2287482A1 (fr) | 1976-05-07 |
| LU73523A1 (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) | 1976-08-19 |
| FR2287482B1 (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) | 1979-04-06 |
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