DE2333938C2 - Verfahren zur Herstellung von gummiähnlichen Gegenständen und Mittel zur Durchführung des Verfahrens - Google Patents
Verfahren zur Herstellung von gummiähnlichen Gegenständen und Mittel zur Durchführung des VerfahrensInfo
- Publication number
- DE2333938C2 DE2333938C2 DE19732333938 DE2333938A DE2333938C2 DE 2333938 C2 DE2333938 C2 DE 2333938C2 DE 19732333938 DE19732333938 DE 19732333938 DE 2333938 A DE2333938 A DE 2333938A DE 2333938 C2 DE2333938 C2 DE 2333938C2
- Authority
- DE
- Germany
- Prior art keywords
- weight
- rubber
- elastomer
- solution
- solutions
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 238000000034 method Methods 0.000 title claims description 9
- 238000004519 manufacturing process Methods 0.000 title claims description 8
- 230000008569 process Effects 0.000 title claims description 6
- 239000000243 solution Substances 0.000 claims description 33
- 229920001971 elastomer Polymers 0.000 claims description 19
- 239000004606 Fillers/Extenders Substances 0.000 claims description 15
- 239000003921 oil Substances 0.000 claims description 15
- 239000002904 solvent Substances 0.000 claims description 13
- 229920003051 synthetic elastomer Polymers 0.000 claims description 12
- 239000005061 synthetic rubber Substances 0.000 claims description 12
- 150000001338 aliphatic hydrocarbons Chemical class 0.000 claims description 9
- 239000000806 elastomer Substances 0.000 claims description 9
- 239000003963 antioxidant agent Substances 0.000 claims description 7
- 239000012990 dithiocarbamate Substances 0.000 claims description 7
- DKVNPHBNOWQYFE-UHFFFAOYSA-N carbamodithioic acid Chemical compound NC(S)=S DKVNPHBNOWQYFE-UHFFFAOYSA-N 0.000 claims description 6
- 229920000642 polymer Polymers 0.000 claims description 6
- 238000007598 dipping method Methods 0.000 claims description 5
- 238000007654 immersion Methods 0.000 claims description 5
- 125000003118 aryl group Chemical group 0.000 claims description 4
- 239000003795 chemical substances by application Substances 0.000 claims description 4
- 230000003078 antioxidant effect Effects 0.000 claims description 3
- 238000009835 boiling Methods 0.000 claims description 3
- 239000000203 mixture Substances 0.000 claims description 3
- 229920003048 styrene butadiene rubber Polymers 0.000 claims description 3
- 239000002174 Styrene-butadiene Substances 0.000 claims description 2
- MTAZNLWOLGHBHU-UHFFFAOYSA-N butadiene-styrene rubber Chemical compound C=CC=C.C=CC1=CC=CC=C1 MTAZNLWOLGHBHU-UHFFFAOYSA-N 0.000 claims description 2
- 239000003209 petroleum derivative Substances 0.000 claims description 2
- 239000003381 stabilizer Substances 0.000 claims description 2
- 239000011115 styrene butadiene Substances 0.000 claims description 2
- VSAWBBYYMBQKIK-UHFFFAOYSA-N 4-[[3,5-bis[(3,5-ditert-butyl-4-hydroxyphenyl)methyl]-2,4,6-trimethylphenyl]methyl]-2,6-ditert-butylphenol Chemical compound CC1=C(CC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)C(C)=C(CC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)C(C)=C1CC1=CC(C(C)(C)C)=C(O)C(C(C)(C)C)=C1 VSAWBBYYMBQKIK-UHFFFAOYSA-N 0.000 claims 1
- NPPQSCRMBWNHMW-UHFFFAOYSA-N Meprobamate Chemical compound NC(=O)OCC(C)(CCC)COC(N)=O NPPQSCRMBWNHMW-UHFFFAOYSA-N 0.000 claims 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 claims 1
- 239000011701 zinc Substances 0.000 claims 1
- 229910052725 zinc Inorganic materials 0.000 claims 1
- 239000005060 rubber Substances 0.000 description 10
- 238000004073 vulcanization Methods 0.000 description 10
- 229920003052 natural elastomer Polymers 0.000 description 8
- 229920001194 natural rubber Polymers 0.000 description 8
- 244000043261 Hevea brasiliensis Species 0.000 description 7
- 229920001400 block copolymer Polymers 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 230000000087 stabilizing effect Effects 0.000 description 3
- 229920001169 thermoplastic Polymers 0.000 description 3
- 229920002725 thermoplastic elastomer Polymers 0.000 description 3
- 239000004416 thermosoftening plastic Substances 0.000 description 3
- BOXSVZNGTQTENJ-UHFFFAOYSA-L zinc dibutyldithiocarbamate Chemical compound [Zn+2].CCCCN(C([S-])=S)CCCC.CCCCN(C([S-])=S)CCCC BOXSVZNGTQTENJ-UHFFFAOYSA-L 0.000 description 3
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 2
- 239000004840 adhesive resin Substances 0.000 description 2
- 229920006223 adhesive resin Polymers 0.000 description 2
- 125000001931 aliphatic group Chemical group 0.000 description 2
- 229920001577 copolymer Polymers 0.000 description 2
- 238000004090 dissolution Methods 0.000 description 2
- 239000000839 emulsion Substances 0.000 description 2
- 230000035945 sensitivity Effects 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- ROGIWVXWXZRRMZ-UHFFFAOYSA-N 2-methylbuta-1,3-diene;styrene Chemical compound CC(=C)C=C.C=CC1=CC=CC=C1 ROGIWVXWXZRRMZ-UHFFFAOYSA-N 0.000 description 1
- PDHRHCVPAXDFSC-UHFFFAOYSA-N 4-[[3,5-bis[(3,4-ditert-butyl-4-hydroxycyclohexa-1,5-dien-1-yl)methyl]-2,4,6-trimethylphenyl]methyl]-1,6-ditert-butylcyclohexa-2,4-dien-1-ol Chemical compound CC1=C(CC=2C=CC(O)(C(C(C)(C)C)C=2)C(C)(C)C)C(C)=C(CC=2C=CC(O)(C(C(C)(C)C)C=2)C(C)(C)C)C(C)=C1CC1=CC(C(C)(C)C)C(O)(C(C)(C)C)C=C1 PDHRHCVPAXDFSC-UHFFFAOYSA-N 0.000 description 1
- RRHGJUQNOFWUDK-UHFFFAOYSA-N Isoprene Chemical compound CC(=C)C=C RRHGJUQNOFWUDK-UHFFFAOYSA-N 0.000 description 1
- CBENFWSGALASAD-UHFFFAOYSA-N Ozone Chemical compound [O-][O+]=O CBENFWSGALASAD-UHFFFAOYSA-N 0.000 description 1
- 239000007983 Tris buffer Substances 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 239000000853 adhesive Substances 0.000 description 1
- 230000001070 adhesive effect Effects 0.000 description 1
- 230000032683 aging Effects 0.000 description 1
- 150000004945 aromatic hydrocarbons Chemical class 0.000 description 1
- 230000008901 benefit Effects 0.000 description 1
- UHOVQNZJYSORNB-UHFFFAOYSA-N benzene Substances C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 239000007859 condensation product Substances 0.000 description 1
- 238000004132 cross linking Methods 0.000 description 1
- 150000001993 dienes Chemical class 0.000 description 1
- 150000004659 dithiocarbamates Chemical class 0.000 description 1
- 238000000605 extraction Methods 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- -1 gasoline Chemical class 0.000 description 1
- 230000009477 glass transition Effects 0.000 description 1
- 231100000053 low toxicity Toxicity 0.000 description 1
- 210000002445 nipple Anatomy 0.000 description 1
- 239000003208 petroleum Substances 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 239000010734 process oil Substances 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- 238000011084 recovery Methods 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 238000007711 solidification Methods 0.000 description 1
- 230000008023 solidification Effects 0.000 description 1
- 230000006641 stabilisation Effects 0.000 description 1
- 238000011105 stabilization Methods 0.000 description 1
- 230000035882 stress Effects 0.000 description 1
- 150000003463 sulfur Chemical class 0.000 description 1
- 239000001993 wax Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J3/00—Processes of treating or compounding macromolecular substances
- C08J3/02—Making solutions, dispersions, lattices or gels by other methods than by solution, emulsion or suspension polymerisation techniques
- C08J3/09—Making solutions, dispersions, lattices or gels by other methods than by solution, emulsion or suspension polymerisation techniques in organic liquids
- C08J3/091—Making solutions, dispersions, lattices or gels by other methods than by solution, emulsion or suspension polymerisation techniques in organic liquids characterised by the chemical constitution of the organic liquid
- C08J3/092—Hydrocarbons
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
- C08J5/02—Direct processing of dispersions, e.g. latex, to articles
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2353/00—Characterised by the use of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Derivatives of such polymers
- C08J2353/02—Characterised by the use of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Derivatives of such polymers of vinyl aromatic monomers and conjugated dienes
Landscapes
- Chemical & Material Sciences (AREA)
- Polymers & Plastics (AREA)
- Dispersion Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Organic Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Manufacturing & Machinery (AREA)
- Materials Engineering (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Processes Of Treating Macromolecular Substances (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB3149872A GB1428128A (en) | 1972-07-05 | 1972-07-05 | Solutions of thermoplastic blockcopolymers |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| DE2333938A1 DE2333938A1 (de) | 1974-01-24 |
| DE2333938C2 true DE2333938C2 (de) | 1983-04-28 |
Family
ID=10323983
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE19732333938 Expired DE2333938C2 (de) | 1972-07-05 | 1973-07-04 | Verfahren zur Herstellung von gummiähnlichen Gegenständen und Mittel zur Durchführung des Verfahrens |
Country Status (12)
| Country | Link |
|---|---|
| JP (1) | JPS4952846A (cs) |
| AT (1) | AT326909B (cs) |
| AU (1) | AU5716373A (cs) |
| BE (1) | BE801914A (cs) |
| CA (1) | CA1038990A (cs) |
| DE (1) | DE2333938C2 (cs) |
| DK (1) | DK137243B (cs) |
| FR (1) | FR2236876B3 (cs) |
| GB (1) | GB1428128A (cs) |
| IT (1) | IT998196B (cs) |
| NL (1) | NL169333C (cs) |
| SE (1) | SE408558B (cs) |
Family Cites Families (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3239478A (en) * | 1963-06-26 | 1966-03-08 | Shell Oil Co | Block copolymer adhesive compositions and articles prepared therefrom |
-
1972
- 1972-07-05 GB GB3149872A patent/GB1428128A/en not_active Expired
-
1973
- 1973-06-21 AU AU57163/73A patent/AU5716373A/en not_active Expired
- 1973-07-02 FR FR7324186A patent/FR2236876B3/fr not_active Expired
- 1973-07-03 JP JP48074503A patent/JPS4952846A/ja active Pending
- 1973-07-04 IT IT2616573A patent/IT998196B/it active
- 1973-07-04 CA CA175,629A patent/CA1038990A/en not_active Expired
- 1973-07-04 DK DK369573A patent/DK137243B/da not_active IP Right Cessation
- 1973-07-04 DE DE19732333938 patent/DE2333938C2/de not_active Expired
- 1973-07-04 SE SE7309410A patent/SE408558B/xx unknown
- 1973-07-04 BE BE133118A patent/BE801914A/xx not_active IP Right Cessation
- 1973-07-04 AT AT591073A patent/AT326909B/de not_active IP Right Cessation
- 1973-07-04 NL NL7309375A patent/NL169333C/xx not_active IP Right Cessation
Also Published As
| Publication number | Publication date |
|---|---|
| BE801914A (fr) | 1973-11-05 |
| ATA591073A (de) | 1975-03-15 |
| NL7309375A (cs) | 1974-01-08 |
| DK137243B (da) | 1978-02-06 |
| NL169333B (nl) | 1982-02-01 |
| SE408558B (sv) | 1979-06-18 |
| JPS4952846A (cs) | 1974-05-22 |
| FR2236876A1 (cs) | 1975-02-07 |
| DK137243C (cs) | 1978-07-10 |
| AT326909B (de) | 1976-01-12 |
| GB1428128A (en) | 1976-03-17 |
| CA1038990A (en) | 1978-09-19 |
| DE2333938A1 (de) | 1974-01-24 |
| AU5716373A (en) | 1975-01-09 |
| NL169333C (nl) | 1982-07-01 |
| FR2236876B3 (cs) | 1976-07-16 |
| IT998196B (it) | 1976-01-20 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| OD | Request for examination | ||
| 8181 | Inventor (new situation) |
Free format text: ERFINDER IST ANMELDER |
|
| D2 | Grant after examination | ||
| 8364 | No opposition during term of opposition |