DE2326236A1 - Verfahren zum entschwefeln von erdoelen - Google Patents

Verfahren zum entschwefeln von erdoelen

Info

Publication number
DE2326236A1
DE2326236A1 DE2326236A DE2326236A DE2326236A1 DE 2326236 A1 DE2326236 A1 DE 2326236A1 DE 2326236 A DE2326236 A DE 2326236A DE 2326236 A DE2326236 A DE 2326236A DE 2326236 A1 DE2326236 A1 DE 2326236A1
Authority
DE
Germany
Prior art keywords
sodium
sulfur
alkali
treated
mixture
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
DE2326236A
Other languages
German (de)
English (en)
Inventor
Jun Roby Bearden
William E Lewis
Robert B Macmullin
Jun Albert B Welty
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
ExxonMobil Technology and Engineering Co
Original Assignee
Exxon Research and Engineering Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Exxon Research and Engineering Co filed Critical Exxon Research and Engineering Co
Publication of DE2326236A1 publication Critical patent/DE2326236A1/de
Pending legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G29/00—Refining of hydrocarbon oils, in the absence of hydrogen, with other chemicals
    • C10G29/02—Non-metals
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B17/00—Sulfur; Compounds thereof
    • C01B17/22—Alkali metal sulfides or polysulfides
    • C01B17/34—Polysulfides of sodium or potassium
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G29/00—Refining of hydrocarbon oils, in the absence of hydrogen, with other chemicals
    • C10G29/04—Metals, or metals deposited on a carrier
    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25C—PROCESSES FOR THE ELECTROLYTIC PRODUCTION, RECOVERY OR REFINING OF METALS; APPARATUS THEREFOR
    • C25C3/00—Electrolytic production, recovery or refining of metals by electrolysis of melts
    • C25C3/02—Electrolytic production, recovery or refining of metals by electrolysis of melts of alkali or alkaline earth metals
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2006/00—Physical properties of inorganic compounds
    • C01P2006/32—Thermal properties
    • C01P2006/33—Phase transition temperatures
    • C01P2006/34—Melting temperatures
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2006/00—Physical properties of inorganic compounds
    • C01P2006/80—Compositional purity

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Electrochemistry (AREA)
  • Materials Engineering (AREA)
  • Metallurgy (AREA)
  • Inorganic Chemistry (AREA)
  • Electrolytic Production Of Metals (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
DE2326236A 1972-05-24 1973-05-23 Verfahren zum entschwefeln von erdoelen Pending DE2326236A1 (de)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US25654772A 1972-05-24 1972-05-24

Publications (1)

Publication Number Publication Date
DE2326236A1 true DE2326236A1 (de) 1973-12-06

Family

ID=22972646

Family Applications (1)

Application Number Title Priority Date Filing Date
DE2326236A Pending DE2326236A1 (de) 1972-05-24 1973-05-23 Verfahren zum entschwefeln von erdoelen

Country Status (8)

Country Link
US (1) US3788978A (cg-RX-API-DMAC7.html)
JP (1) JPS5621782B2 (cg-RX-API-DMAC7.html)
CA (1) CA1001978A (cg-RX-API-DMAC7.html)
DE (1) DE2326236A1 (cg-RX-API-DMAC7.html)
FR (1) FR2185671B1 (cg-RX-API-DMAC7.html)
GB (1) GB1431491A (cg-RX-API-DMAC7.html)
IT (1) IT987858B (cg-RX-API-DMAC7.html)
NL (1) NL7307131A (cg-RX-API-DMAC7.html)

Families Citing this family (59)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4017381A (en) * 1975-04-28 1977-04-12 Exxon Research And Engineering Company Process for desulfurization of residua with sodamide-hydrogen and regeneration of sodamide
US4076613A (en) * 1975-04-28 1978-02-28 Exxon Research & Engineering Co. Combined disulfurization and conversion with alkali metals
US4003824A (en) * 1975-04-28 1977-01-18 Exxon Research And Engineering Company Desulfurization and hydroconversion of residua with sodium hydride and hydrogen
US3976559A (en) * 1975-04-28 1976-08-24 Exxon Research And Engineering Company Combined catalytic and alkali metal hydrodesulfurization and conversion process
US4007111A (en) * 1975-04-28 1977-02-08 Exxon Research And Engineering Company Residua desulfurization and hydroconversion with sodamide and hydrogen
US4119528A (en) * 1977-08-01 1978-10-10 Exxon Research & Engineering Co. Hydroconversion of residua with potassium sulfide
US4127470A (en) * 1977-08-01 1978-11-28 Exxon Research & Engineering Company Hydroconversion with group IA, IIA metal compounds
US4366045A (en) * 1980-01-22 1982-12-28 Rollan Swanson Process for conversion of coal to gaseous hydrocarbons
DE3114766A1 (de) * 1980-04-15 1982-06-16 Rollan Dr. 89316 Eureka Nev. Swanson Verfahren zum umwandeln von kohle oder torf in gasfoermige kohlenwasserstoffe oder fluechtige destillate oder gemische hiervon
US4606812A (en) * 1980-04-15 1986-08-19 Chemroll Enterprises, Inc. Hydrotreating of carbonaceous materials
WO1982003404A1 (en) * 1981-03-31 1982-10-14 Meyers Robert A Extraction and upgrading of fossil fuels using fused caustic and acid solutions
US5059307A (en) * 1981-03-31 1991-10-22 Trw Inc. Process for upgrading coal
US5085764A (en) * 1981-03-31 1992-02-04 Trw Inc. Process for upgrading coal
US4468316A (en) * 1983-03-03 1984-08-28 Chemroll Enterprises, Inc. Hydrogenation of asphaltenes and the like
DE4034137C1 (cg-RX-API-DMAC7.html) * 1990-10-26 1991-10-10 Kernforschungszentrum Karlsruhe Gmbh, 7500 Karlsruhe, De
US5250181A (en) * 1991-06-17 1993-10-05 Exxon Research And Engineering Company Process for removing elemental sulfur from fluids
US5935421A (en) * 1995-05-02 1999-08-10 Exxon Research And Engineering Company Continuous in-situ combination process for upgrading heavy oil
US5695632A (en) * 1995-05-02 1997-12-09 Exxon Research And Engineering Company Continuous in-situ combination process for upgrading heavy oil
US6210564B1 (en) 1996-06-04 2001-04-03 Exxon Research And Engineering Company Process for desulfurization of petroleum feeds utilizing sodium metal
US5840450A (en) * 1996-12-24 1998-11-24 Samsung Display Devices Co., Ltd. Method for forming a black matrix on a faceplate panel for a color CRT
US7192516B2 (en) * 2003-04-17 2007-03-20 Trans Ionics Corporation Desulfurization of petroleum streams using metallic sodium
US7897028B2 (en) * 2004-01-26 2011-03-01 Ceramatec, Inc. Process for the recovery of materials from a desulfurization reaction
US7507327B2 (en) * 2004-09-30 2009-03-24 Exxonmobil Research And Engineering Company Desulfurizing organosulfur heterocycles in feeds with supported sodium
CA2531262A1 (en) * 2005-12-21 2007-06-21 Imperial Oil Resources Limited Very low sulfur heavy crude oil and process for the production thereof
EP1989657A4 (en) * 2006-02-10 2010-10-20 Parallel Synthesis Technologie METHODS AND DEVICES FOR ESTABLISHING AUTHENTICATION AND FOR REJECTING A COUNTERFEIT
US8012633B2 (en) * 2006-10-13 2011-09-06 Ceramatec, Inc. Advanced metal-air battery having a ceramic membrane electrolyte
WO2009032313A1 (en) * 2007-09-05 2009-03-12 Ceramatec, Inc. Lithium-sulfur battery with a substantially non- porous membrane and enhanced cathode utilization
US9209445B2 (en) 2007-11-26 2015-12-08 Ceramatec, Inc. Nickel-metal hydride/hydrogen hybrid battery using alkali ion conducting separator
US8012621B2 (en) 2007-11-26 2011-09-06 Ceramatec, Inc. Nickel-metal hydride battery using alkali ion conducting separator
WO2009070600A2 (en) 2007-11-27 2009-06-04 Ceramatec, Inc. Substantially solid, flexible electrolyte for alkili-metal-ion batteries
US8088270B2 (en) 2007-11-27 2012-01-03 Ceramatec, Inc. Process for recovering alkali metals and sulfur from alkali metal sulfides and polysulfides
US7985332B2 (en) * 2007-12-20 2011-07-26 Exxonmobil Research And Engineering Company Electrodesulfurization of heavy oils using a divided electrochemical cell
US8557101B2 (en) 2007-12-20 2013-10-15 Exxonmobil Research And Engineering Company Electrochemical treatment of heavy oil streams followed by caustic extraction
US8177963B2 (en) * 2007-12-20 2012-05-15 Exxonmobil Research And Engineering Company Partial electro-hydrogenation of sulfur containing feedstreams followed by sulfur removal
US8075762B2 (en) * 2007-12-20 2011-12-13 Exxonmobil Reseach And Engineering Company Electrodesulfurization of heavy oils
US20090159503A1 (en) * 2007-12-20 2009-06-25 Greaney Mark A Electrochemical treatment of heavy oil streams followed by caustic extraction or thermal treatment
US10320033B2 (en) 2008-01-30 2019-06-11 Enlighten Innovations Inc. Alkali metal ion battery using alkali metal conductive ceramic separator
US20090189567A1 (en) * 2008-01-30 2009-07-30 Joshi Ashok V Zinc Anode Battery Using Alkali Ion Conducting Separator
US8486251B2 (en) * 2008-08-05 2013-07-16 Exxonmobil Research And Engineering Company Process for regenerating alkali metal hydroxides by electrochemical means
US8323817B2 (en) 2008-09-12 2012-12-04 Ceramatec, Inc. Alkali metal seawater battery
US9475998B2 (en) 2008-10-09 2016-10-25 Ceramatec, Inc. Process for recovering alkali metals and sulfur from alkali metal sulfides and polysulfides
WO2010042874A2 (en) * 2008-10-09 2010-04-15 Ceramatec, Inc. Apparatus and method for reducing an alkali metal electrochemically at a temperature below the metal's melting temperature
JP5670997B2 (ja) * 2009-03-16 2015-02-18 セラマテック・インク ナトリウム−硫黄電池および２００℃未満の温度での電池の操作方法
US9546325B2 (en) 2009-11-02 2017-01-17 Field Upgrading Limited Upgrading platform using alkali metals
US9512368B2 (en) 2009-11-02 2016-12-06 Field Upgrading Limited Method of preventing corrosion of oil pipelines, storage structures and piping
US9441170B2 (en) 2012-11-16 2016-09-13 Field Upgrading Limited Device and method for upgrading petroleum feedstocks and petroleum refinery streams using an alkali metal conductive membrane
CN104818047A (zh) * 2009-11-02 2015-08-05 塞拉麦泰克股份有限公司 用碱金属和烃对石油原料的提质
US9688920B2 (en) 2009-11-02 2017-06-27 Field Upgrading Limited Process to separate alkali metal salts from alkali metal reacted hydrocarbons
JP5753852B2 (ja) 2009-11-05 2015-07-22 セラマテック・インク ナトリウムイオン伝導性セラミックセパレーターを有する固体ナトリウム系二次電池
WO2012021323A2 (en) 2010-08-11 2012-02-16 Ceramatec, Inc. Alkali metal aqueous battery
US10170798B2 (en) 2010-12-01 2019-01-01 Field Upgrading Usa, Inc. Moderate temperature sodium battery
WO2013012810A2 (en) * 2011-07-15 2013-01-24 Ceramatec, Inc. Upgrading platform using alkali metals
ES2650952T3 (es) 2012-02-03 2018-01-23 Field Upgrading Limited Proceso para desulfurar materias primas de petróleo
JP2015529745A (ja) * 2012-07-27 2015-10-08 ビーエーエスエフ ソシエタス・ヨーロピアＢａｓｆ Ｓｅ アルカリ金属の製造方法
MY173980A (en) * 2013-04-15 2020-03-02 Enlighten Innovations Inc Process to separate alkali metal salts from alkali metal reacted hydrocarbons
US10435631B2 (en) 2016-10-04 2019-10-08 Enlighten Innovations, Inc. Process for separating particles containing alkali metal salts from liquid hydrocarbons
EP3555232A1 (en) 2016-12-19 2019-10-23 ExxonMobil Research and Engineering Company Trim alkali metal desulfurization of refinery fractions
US12492125B2 (en) * 2021-08-09 2025-12-09 Phillips 66 Company Methods for preparing hard carbon products by sulfurization and oxidation processes
CN113881454A (zh) * 2021-09-30 2022-01-04 中国石油化工股份有限公司 一种从渣油中分离硫化钠的方法

Also Published As

Publication number Publication date
IT987858B (it) 1975-03-20
JPS5621782B2 (cg-RX-API-DMAC7.html) 1981-05-21
JPS4942702A (cg-RX-API-DMAC7.html) 1974-04-22
FR2185671B1 (cg-RX-API-DMAC7.html) 1978-09-29
NL7307131A (cg-RX-API-DMAC7.html) 1973-11-27
FR2185671A1 (cg-RX-API-DMAC7.html) 1974-01-04
US3788978A (en) 1974-01-29
GB1431491A (en) 1976-04-07
CA1001978A (en) 1976-12-21

Similar Documents

Publication Publication Date Title
DE2326696A1 (de) Verfahren zum entschwefeln von erdoelen mit alkalimetallen
US3785965A (en) Process for the desulfurization of petroleum oil fractions
US3788978A (en) Process for the desulfurization of petroleum oil stocks
US3791966A (en) Alkali metal desulfurization process for petroleum oil stocks
US4003824A (en) Desulfurization and hydroconversion of residua with sodium hydride and hydrogen
DE2436309C3 (de) Verfahren zum Reinigen von öl
US4120779A (en) Process for desulfurization of residua with sodamide-hydrogen and regeneration of sodamide
DE69205096T2 (de) Entfernung von Arsenverbindungen aus leichten Kohlenwasserstoffströmen.
DE3630986C2 (de) Verfahren zur Herstellung von hochreinem Koks
DE2558505A1 (de) Verfahren zur entschwefelung und hydrierung von kohlenwasserstoffen
DE69501891T2 (de) Verfahren zur verbesserung von rückstands-kohlen wasserstofföle
DE3025773A1 (de) Verfahren zur entschwefelung eines schwefel enthaltenden brenn- bzw. kraftstoffs
CH655737A5 (de) Verfahren zur gewinnung von kohlenwasserstoffen aus schieferoelgestein.
DE69800340T2 (de) Verfahren zur Reinigung von Naphthalin durch selektive Hydrierung und nachfolgende Trennung
DE1212662B (de) Verfahren zum Entfernen metallischer und stickstoffhaltiger Verunreinigungen aus Kohlenwasserstoffoelen
DE2210954A1 (de) Verfahren zum Gewinnen organischer Flüssigkeiten aus Kohleverflüssigungsprodukten
DE3208822A1 (de) Verfahren zur herstellung von entschwefelten, loesungsmittel-raffinierten produkten aus kohle
DD158794A5 (de) Verfahren zur herstellung einer normalerweise festen geloesten kohle
US4007110A (en) Residua desulfurization with sodium oxide and hydrogen
EP0209665B1 (de) Verfahren zur Kohlehydrierung mittels Sumpfphase- und katalysator-Festbetthydrierung
DE1645724A1 (de) Entschwefelungsverfahren fuer schwere Erdoelfraktionen
DE4411483A1 (de) Verfahren zur Entschwefelung von schwefelhaltigen Zusammensetzungen durch hydrothermale Reaktion und Verfahren zur Umwandlung vulkanisierter Kautschuke in Öle unter Verwendung überkritischer wäßriger Flüssigkeiten
CH663960A5 (de) Verfahren zum umwandeln kohlenstoffhaltiger ausgangsstoffe zu produkten niedriger viskositaet und/oder staerker hydrierten endprodukten.
DE3115111C2 (cg-RX-API-DMAC7.html)
DE1645726A1 (de) Entschwefelung von Erdoelfraktionen

Legal Events

Date Code Title Description
OHA Expiration of time for request for examination