CA1001978A - Process for the desulfurization of petroleum oil stocks - Google Patents

Process for the desulfurization of petroleum oil stocks

Info

Publication number
CA1001978A
CA1001978A CA171,995A CA171995A CA1001978A CA 1001978 A CA1001978 A CA 1001978A CA 171995 A CA171995 A CA 171995A CA 1001978 A CA1001978 A CA 1001978A
Authority
CA
Canada
Prior art keywords
desulfurization
petroleum oil
oil stocks
stocks
petroleum
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
CA171,995A
Inventor
Roby Bearden (Jr.)
Robert B. Macmullin
William E. Lewis
Albert B. Welty (Jr.)
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
ExxonMobil Technology and Engineering Co
Original Assignee
Exxon Research and Engineering Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Exxon Research and Engineering Co filed Critical Exxon Research and Engineering Co
Application granted granted Critical
Publication of CA1001978A publication Critical patent/CA1001978A/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G29/00—Refining of hydrocarbon oils, in the absence of hydrogen, with other chemicals
    • C10G29/02—Non-metals
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B17/00—Sulfur; Compounds thereof
    • C01B17/22—Alkali metal sulfides or polysulfides
    • C01B17/34—Polysulfides of sodium or potassium
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G29/00—Refining of hydrocarbon oils, in the absence of hydrogen, with other chemicals
    • C10G29/04—Metals, or metals deposited on a carrier
    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25C—PROCESSES FOR THE ELECTROLYTIC PRODUCTION, RECOVERY OR REFINING OF METALS; APPARATUS THEREFOR
    • C25C3/00—Electrolytic production, recovery or refining of metals by electrolysis of melts
    • C25C3/02—Electrolytic production, recovery or refining of metals by electrolysis of melts of alkali or alkaline earth metals
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2006/00—Physical properties of inorganic compounds
    • C01P2006/32—Thermal properties
    • C01P2006/33—Phase transition temperatures
    • C01P2006/34—Melting temperatures
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2006/00—Physical properties of inorganic compounds
    • C01P2006/80—Compositional purity
CA171,995A 1972-05-24 1973-05-23 Process for the desulfurization of petroleum oil stocks Expired CA1001978A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US25654772A 1972-05-24 1972-05-24

Publications (1)

Publication Number Publication Date
CA1001978A true CA1001978A (en) 1976-12-21

Family

ID=22972646

Family Applications (1)

Application Number Title Priority Date Filing Date
CA171,995A Expired CA1001978A (en) 1972-05-24 1973-05-23 Process for the desulfurization of petroleum oil stocks

Country Status (8)

Country Link
US (1) US3788978A (en)
JP (1) JPS5621782B2 (en)
CA (1) CA1001978A (en)
DE (1) DE2326236A1 (en)
FR (1) FR2185671B1 (en)
GB (1) GB1431491A (en)
IT (1) IT987858B (en)
NL (1) NL7307131A (en)

Families Citing this family (59)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4007111A (en) * 1975-04-28 1977-02-08 Exxon Research And Engineering Company Residua desulfurization and hydroconversion with sodamide and hydrogen
US4003824A (en) * 1975-04-28 1977-01-18 Exxon Research And Engineering Company Desulfurization and hydroconversion of residua with sodium hydride and hydrogen
US4076613A (en) * 1975-04-28 1978-02-28 Exxon Research & Engineering Co. Combined disulfurization and conversion with alkali metals
US4017381A (en) * 1975-04-28 1977-04-12 Exxon Research And Engineering Company Process for desulfurization of residua with sodamide-hydrogen and regeneration of sodamide
US3976559A (en) * 1975-04-28 1976-08-24 Exxon Research And Engineering Company Combined catalytic and alkali metal hydrodesulfurization and conversion process
US4127470A (en) * 1977-08-01 1978-11-28 Exxon Research & Engineering Company Hydroconversion with group IA, IIA metal compounds
US4119528A (en) * 1977-08-01 1978-10-10 Exxon Research & Engineering Co. Hydroconversion of residua with potassium sulfide
US4366045A (en) * 1980-01-22 1982-12-28 Rollan Swanson Process for conversion of coal to gaseous hydrocarbons
DE3114766A1 (en) * 1980-04-15 1982-06-16 Rollan Dr. 89316 Eureka Nev. Swanson METHOD FOR CONVERTING COAL OR Peat TO GASEOUS HYDROCARBONS OR VOLATILE DISTILLATES OR MIXTURES THEREOF
US4606812A (en) * 1980-04-15 1986-08-19 Chemroll Enterprises, Inc. Hydrotreating of carbonaceous materials
US4545891A (en) * 1981-03-31 1985-10-08 Trw Inc. Extraction and upgrading of fossil fuels using fused caustic and acid solutions
US5059307A (en) * 1981-03-31 1991-10-22 Trw Inc. Process for upgrading coal
US5085764A (en) * 1981-03-31 1992-02-04 Trw Inc. Process for upgrading coal
US4468316A (en) * 1983-03-03 1984-08-28 Chemroll Enterprises, Inc. Hydrogenation of asphaltenes and the like
JPS641981A (en) * 1987-06-25 1989-01-06 Fuji Electric Co Ltd Magnetic field detector
DE4034137C1 (en) * 1990-10-26 1991-10-10 Kernforschungszentrum Karlsruhe Gmbh, 7500 Karlsruhe, De
US5250181A (en) * 1991-06-17 1993-10-05 Exxon Research And Engineering Company Process for removing elemental sulfur from fluids
US5935421A (en) * 1995-05-02 1999-08-10 Exxon Research And Engineering Company Continuous in-situ combination process for upgrading heavy oil
US5695632A (en) * 1995-05-02 1997-12-09 Exxon Research And Engineering Company Continuous in-situ combination process for upgrading heavy oil
US6210564B1 (en) 1996-06-04 2001-04-03 Exxon Research And Engineering Company Process for desulfurization of petroleum feeds utilizing sodium metal
US5840450A (en) * 1996-12-24 1998-11-24 Samsung Display Devices Co., Ltd. Method for forming a black matrix on a faceplate panel for a color CRT
US7192516B2 (en) * 2003-04-17 2007-03-20 Trans Ionics Corporation Desulfurization of petroleum streams using metallic sodium
US7897028B2 (en) * 2004-01-26 2011-03-01 Ceramatec, Inc. Process for the recovery of materials from a desulfurization reaction
US7507327B2 (en) * 2004-09-30 2009-03-24 Exxonmobil Research And Engineering Company Desulfurizing organosulfur heterocycles in feeds with supported sodium
CA2531262A1 (en) * 2005-12-21 2007-06-21 Imperial Oil Resources Limited Very low sulfur heavy crude oil and process for the production thereof
US20100046825A1 (en) * 2006-02-10 2010-02-25 Parallel Synthesis Technologies, Inc. Authentication and anticounterfeiting methods and devices
EP2087540A4 (en) * 2006-10-13 2014-01-22 Ceramatec Inc Advanced metal-air battery having a ceramic membrane electrolyte
WO2009032313A1 (en) * 2007-09-05 2009-03-12 Ceramatec, Inc. Lithium-sulfur battery with a substantially non- porous membrane and enhanced cathode utilization
US8012621B2 (en) * 2007-11-26 2011-09-06 Ceramatec, Inc. Nickel-metal hydride battery using alkali ion conducting separator
US9209445B2 (en) 2007-11-26 2015-12-08 Ceramatec, Inc. Nickel-metal hydride/hydrogen hybrid battery using alkali ion conducting separator
WO2009070593A1 (en) 2007-11-27 2009-06-04 Ceramatec, Inc. Process for recovering alkali metals and sulfur from alkali metal sulfides and polysulfides
US8216722B2 (en) 2007-11-27 2012-07-10 Ceramatec, Inc. Solid electrolyte for alkali-metal-ion batteries
US8177963B2 (en) * 2007-12-20 2012-05-15 Exxonmobil Research And Engineering Company Partial electro-hydrogenation of sulfur containing feedstreams followed by sulfur removal
US20090159503A1 (en) * 2007-12-20 2009-06-25 Greaney Mark A Electrochemical treatment of heavy oil streams followed by caustic extraction or thermal treatment
US8075762B2 (en) * 2007-12-20 2011-12-13 Exxonmobil Reseach And Engineering Company Electrodesulfurization of heavy oils
US8557101B2 (en) 2007-12-20 2013-10-15 Exxonmobil Research And Engineering Company Electrochemical treatment of heavy oil streams followed by caustic extraction
US7985332B2 (en) * 2007-12-20 2011-07-26 Exxonmobil Research And Engineering Company Electrodesulfurization of heavy oils using a divided electrochemical cell
US20090189567A1 (en) * 2008-01-30 2009-07-30 Joshi Ashok V Zinc Anode Battery Using Alkali Ion Conducting Separator
US10320033B2 (en) 2008-01-30 2019-06-11 Enlighten Innovations Inc. Alkali metal ion battery using alkali metal conductive ceramic separator
US8486251B2 (en) * 2008-08-05 2013-07-16 Exxonmobil Research And Engineering Company Process for regenerating alkali metal hydroxides by electrochemical means
US8323817B2 (en) 2008-09-12 2012-12-04 Ceramatec, Inc. Alkali metal seawater battery
US9475998B2 (en) 2008-10-09 2016-10-25 Ceramatec, Inc. Process for recovering alkali metals and sulfur from alkali metal sulfides and polysulfides
WO2010042874A2 (en) * 2008-10-09 2010-04-15 Ceramatec, Inc. Apparatus and method for reducing an alkali metal electrochemically at a temperature below the metal's melting temperature
KR20110139197A (en) * 2009-03-16 2011-12-28 세라마테크, 인코오포레이티드 Sodium-sulfur battery with a substantially non-porous membrane and enhanced cathode utilization
US9512368B2 (en) 2009-11-02 2016-12-06 Field Upgrading Limited Method of preventing corrosion of oil pipelines, storage structures and piping
US9546325B2 (en) 2009-11-02 2017-01-17 Field Upgrading Limited Upgrading platform using alkali metals
US9441170B2 (en) 2012-11-16 2016-09-13 Field Upgrading Limited Device and method for upgrading petroleum feedstocks and petroleum refinery streams using an alkali metal conductive membrane
CA2769863C (en) * 2009-11-02 2017-02-28 Ceramatec, Inc. Upgrading of petroleum oil feedstocks using alkali metals and hydrocarbons
US9688920B2 (en) 2009-11-02 2017-06-27 Field Upgrading Limited Process to separate alkali metal salts from alkali metal reacted hydrocarbons
CA2770733C (en) 2009-11-05 2018-10-16 Ceramatec, Inc. Solid-state sodium-based secondary cell having a sodium ion conductive ceramic separator
WO2012021323A2 (en) 2010-08-11 2012-02-16 Ceramatec, Inc. Alkali metal aqueous battery
WO2012075079A2 (en) 2010-12-01 2012-06-07 Ceramatec, Inc. Moderate temperature sodium battery
EP2732010B1 (en) * 2011-07-15 2018-10-10 Field Upgrading Limited Upgrading platform using alkali metals
CA2863357C (en) 2012-02-03 2018-10-16 Ceramatec, Inc. Process for desulfurizing petroleum feedstocks
BR112015001713A2 (en) * 2012-07-27 2017-07-04 Basf Se process for the production of an alkali metal from a solvent-soluble salt of the alkali metal
SG11201508465WA (en) * 2013-04-15 2015-11-27 Field Upgrading Ltd Process to separate alkali metal salts from alkali metal reacted hydrocarbons
US10435631B2 (en) 2016-10-04 2019-10-08 Enlighten Innovations, Inc. Process for separating particles containing alkali metal salts from liquid hydrocarbons
EP3555232A1 (en) 2016-12-19 2019-10-23 ExxonMobil Research and Engineering Company Trim alkali metal desulfurization of refinery fractions
CN113881454A (en) * 2021-09-30 2022-01-04 中国石油化工股份有限公司 Method for separating sodium sulfide from residual oil

Also Published As

Publication number Publication date
DE2326236A1 (en) 1973-12-06
JPS4942702A (en) 1974-04-22
FR2185671B1 (en) 1978-09-29
NL7307131A (en) 1973-11-27
GB1431491A (en) 1976-04-07
IT987858B (en) 1975-03-20
US3788978A (en) 1974-01-29
JPS5621782B2 (en) 1981-05-21
FR2185671A1 (en) 1974-01-04

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