CA1003353A - Alkali metal desulfurization process for petroleum oil stocks using low pressure hydrogen - Google Patents
Alkali metal desulfurization process for petroleum oil stocks using low pressure hydrogenInfo
- Publication number
- CA1003353A CA1003353A CA170,511A CA170511A CA1003353A CA 1003353 A CA1003353 A CA 1003353A CA 170511 A CA170511 A CA 170511A CA 1003353 A CA1003353 A CA 1003353A
- Authority
- CA
- Canada
- Prior art keywords
- alkali metal
- low pressure
- pressure hydrogen
- desulfurization process
- petroleum oil
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B17/00—Sulfur; Compounds thereof
- C01B17/22—Alkali metal sulfides or polysulfides
- C01B17/34—Polysulfides of sodium or potassium
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G29/00—Refining of hydrocarbon oils, in the absence of hydrogen, with other chemicals
- C10G29/04—Metals, or metals deposited on a carrier
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G45/00—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds
- C10G45/02—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G67/00—Treatment of hydrocarbon oils by at least one hydrotreatment process and at least one process for refining in the absence of hydrogen only
- C10G67/02—Treatment of hydrocarbon oils by at least one hydrotreatment process and at least one process for refining in the absence of hydrogen only plural serial stages only
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2006/00—Physical properties of inorganic compounds
- C01P2006/32—Thermal properties
- C01P2006/33—Phase transition temperatures
- C01P2006/34—Melting temperatures
Landscapes
- Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Inorganic Chemistry (AREA)
- Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
- Electrolytic Production Of Metals (AREA)
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US25855572A | 1972-06-01 | 1972-06-01 |
Publications (1)
Publication Number | Publication Date |
---|---|
CA1003353A true CA1003353A (en) | 1977-01-11 |
Family
ID=22981078
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CA170,511A Expired CA1003353A (en) | 1972-06-01 | 1973-05-07 | Alkali metal desulfurization process for petroleum oil stocks using low pressure hydrogen |
Country Status (8)
Country | Link |
---|---|
US (1) | US3787315A (en) |
JP (1) | JPS5515514B2 (en) |
CA (1) | CA1003353A (en) |
DE (1) | DE2326696A1 (en) |
FR (1) | FR2186522B1 (en) |
GB (1) | GB1431190A (en) |
IT (1) | IT988819B (en) |
NL (1) | NL7307457A (en) |
Families Citing this family (64)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS51123161A (en) * | 1975-04-21 | 1976-10-27 | Hitachi Ltd | Electronic photograph device |
JPS51123160A (en) * | 1975-04-21 | 1976-10-27 | Hitachi Ltd | Electronic photograph device |
US4007111A (en) * | 1975-04-28 | 1977-02-08 | Exxon Research And Engineering Company | Residua desulfurization and hydroconversion with sodamide and hydrogen |
US4003824A (en) * | 1975-04-28 | 1977-01-18 | Exxon Research And Engineering Company | Desulfurization and hydroconversion of residua with sodium hydride and hydrogen |
US4003823A (en) * | 1975-04-28 | 1977-01-18 | Exxon Research And Engineering Company | Combined desulfurization and hydroconversion with alkali metal hydroxides |
US4017381A (en) * | 1975-04-28 | 1977-04-12 | Exxon Research And Engineering Company | Process for desulfurization of residua with sodamide-hydrogen and regeneration of sodamide |
US4007110A (en) * | 1975-04-28 | 1977-02-08 | Exxon Research And Engineering Company | Residua desulfurization with sodium oxide and hydrogen |
US4007109A (en) * | 1975-04-28 | 1977-02-08 | Exxon Research And Engineering Company | Combined desulfurization and hydroconversion with alkali metal oxides |
US4076613A (en) * | 1975-04-28 | 1978-02-28 | Exxon Research & Engineering Co. | Combined disulfurization and conversion with alkali metals |
US3976559A (en) * | 1975-04-28 | 1976-08-24 | Exxon Research And Engineering Company | Combined catalytic and alkali metal hydrodesulfurization and conversion process |
US4087348A (en) * | 1975-06-02 | 1978-05-02 | Exxon Research & Engineering Co. | Desulfurization and hydroconversion of residua with alkaline earth metal compounds and hydrogen |
US4018572A (en) * | 1975-06-23 | 1977-04-19 | Rollan Swanson | Desulfurization of fossil fuels |
JPS604464B2 (en) * | 1975-08-21 | 1985-02-04 | キヤノン株式会社 | image forming device |
US4366045A (en) * | 1980-01-22 | 1982-12-28 | Rollan Swanson | Process for conversion of coal to gaseous hydrocarbons |
DE3114766A1 (en) * | 1980-04-15 | 1982-06-16 | Rollan Dr. 89316 Eureka Nev. Swanson | METHOD FOR CONVERTING COAL OR Peat TO GASEOUS HYDROCARBONS OR VOLATILE DISTILLATES OR MIXTURES THEREOF |
DE3115111A1 (en) * | 1980-04-15 | 1982-02-04 | Rollan 10005 Santa Monica Calif. Swanson | METHOD FOR THE HYDROTREATMENT OF CARBONATED MATERIAL |
US4606812A (en) * | 1980-04-15 | 1986-08-19 | Chemroll Enterprises, Inc. | Hydrotreating of carbonaceous materials |
US4468316A (en) * | 1983-03-03 | 1984-08-28 | Chemroll Enterprises, Inc. | Hydrogenation of asphaltenes and the like |
JP2706994B2 (en) * | 1990-04-09 | 1998-01-28 | 行正 佐藤 | Method and apparatus for treating oil sludge and oil-containing wastewater |
US5935421A (en) * | 1995-05-02 | 1999-08-10 | Exxon Research And Engineering Company | Continuous in-situ combination process for upgrading heavy oil |
US5695632A (en) * | 1995-05-02 | 1997-12-09 | Exxon Research And Engineering Company | Continuous in-situ combination process for upgrading heavy oil |
US5602186A (en) * | 1995-10-27 | 1997-02-11 | Exxon Research And Engineering Company | Rubber devulcanization process |
US5798394A (en) * | 1995-10-27 | 1998-08-25 | Exxon Research And Engineering Company | Rubber devulcanization process |
US6210564B1 (en) | 1996-06-04 | 2001-04-03 | Exxon Research And Engineering Company | Process for desulfurization of petroleum feeds utilizing sodium metal |
US20040206670A1 (en) * | 2002-12-11 | 2004-10-21 | Paul Baskis | Carbon transforming process |
US7192516B2 (en) * | 2003-04-17 | 2007-03-20 | Trans Ionics Corporation | Desulfurization of petroleum streams using metallic sodium |
US7897028B2 (en) * | 2004-01-26 | 2011-03-01 | Ceramatec, Inc. | Process for the recovery of materials from a desulfurization reaction |
US7507327B2 (en) * | 2004-09-30 | 2009-03-24 | Exxonmobil Research And Engineering Company | Desulfurizing organosulfur heterocycles in feeds with supported sodium |
CA2531262A1 (en) * | 2005-12-21 | 2007-06-21 | Imperial Oil Resources Limited | Very low sulfur heavy crude oil and process for the production thereof |
US20100046825A1 (en) * | 2006-02-10 | 2010-02-25 | Parallel Synthesis Technologies, Inc. | Authentication and anticounterfeiting methods and devices |
US8012633B2 (en) * | 2006-10-13 | 2011-09-06 | Ceramatec, Inc. | Advanced metal-air battery having a ceramic membrane electrolyte |
US8771879B2 (en) * | 2007-09-05 | 2014-07-08 | Ceramatec, Inc. | Lithium—sulfur battery with a substantially non-porous lisicon membrane and porous lisicon layer |
US8012621B2 (en) | 2007-11-26 | 2011-09-06 | Ceramatec, Inc. | Nickel-metal hydride battery using alkali ion conducting separator |
US9209445B2 (en) | 2007-11-26 | 2015-12-08 | Ceramatec, Inc. | Nickel-metal hydride/hydrogen hybrid battery using alkali ion conducting separator |
US8088270B2 (en) | 2007-11-27 | 2012-01-03 | Ceramatec, Inc. | Process for recovering alkali metals and sulfur from alkali metal sulfides and polysulfides |
WO2009070600A2 (en) | 2007-11-27 | 2009-06-04 | Ceramatec, Inc. | Substantially solid, flexible electrolyte for alkili-metal-ion batteries |
WO2009073436A2 (en) * | 2007-11-28 | 2009-06-11 | Saudi Arabian Oil Company | Process for catalytic hydrotreating of sour crude oils |
US20090189567A1 (en) * | 2008-01-30 | 2009-07-30 | Joshi Ashok V | Zinc Anode Battery Using Alkali Ion Conducting Separator |
US10320033B2 (en) | 2008-01-30 | 2019-06-11 | Enlighten Innovations Inc. | Alkali metal ion battery using alkali metal conductive ceramic separator |
US8372267B2 (en) * | 2008-07-14 | 2013-02-12 | Saudi Arabian Oil Company | Process for the sequential hydroconversion and hydrodesulfurization of whole crude oil |
WO2010009077A2 (en) * | 2008-07-14 | 2010-01-21 | Saudi Arabian Oil Company | Process for the treatment of heavy oils using light hydrocarbon components as a diluent |
US20100018904A1 (en) * | 2008-07-14 | 2010-01-28 | Saudi Arabian Oil Company | Prerefining Process for the Hydrodesulfurization of Heavy Sour Crude Oils to Produce Sweeter Lighter Crudes Using Moving Catalyst System |
US8323817B2 (en) * | 2008-09-12 | 2012-12-04 | Ceramatec, Inc. | Alkali metal seawater battery |
US9475998B2 (en) | 2008-10-09 | 2016-10-25 | Ceramatec, Inc. | Process for recovering alkali metals and sulfur from alkali metal sulfides and polysulfides |
KR20110139197A (en) * | 2009-03-16 | 2011-12-28 | 세라마테크, 인코오포레이티드 | Sodium-sulfur battery with a substantially non-porous membrane and enhanced cathode utilization |
BRPI1012764A2 (en) * | 2009-06-22 | 2019-07-09 | Aramco Services Co | Alternative process for treating heavy crude oils in a coking refinery. |
WO2011053919A2 (en) * | 2009-11-02 | 2011-05-05 | Ceramatec, Inc. | Upgrading of petroleum oil feedstocks using alkali metals and hydrocarbons |
US9546325B2 (en) | 2009-11-02 | 2017-01-17 | Field Upgrading Limited | Upgrading platform using alkali metals |
US9441170B2 (en) | 2012-11-16 | 2016-09-13 | Field Upgrading Limited | Device and method for upgrading petroleum feedstocks and petroleum refinery streams using an alkali metal conductive membrane |
US9512368B2 (en) | 2009-11-02 | 2016-12-06 | Field Upgrading Limited | Method of preventing corrosion of oil pipelines, storage structures and piping |
US9688920B2 (en) * | 2009-11-02 | 2017-06-27 | Field Upgrading Limited | Process to separate alkali metal salts from alkali metal reacted hydrocarbons |
JP5753852B2 (en) | 2009-11-05 | 2015-07-22 | セラマテック・インク | Solid sodium secondary battery with sodium ion conductive ceramic separator |
WO2012021323A2 (en) | 2010-08-11 | 2012-02-16 | Ceramatec, Inc. | Alkali metal aqueous battery |
EP2647080B8 (en) | 2010-12-01 | 2019-05-22 | Field Upgrading USA, Inc. | Moderate temperature sodium battery |
EP2688984B1 (en) * | 2011-03-23 | 2018-05-02 | Aditya Birla Science & Technology CO. LTD. | A process for desulphurization of petroleum oil |
EP2732010B1 (en) | 2011-07-15 | 2018-10-10 | Field Upgrading Limited | Upgrading platform using alkali metals |
RU2578692C2 (en) | 2011-10-24 | 2016-03-27 | Адитиа Бирла Нуво Лимитед | Improved method for carbon ash production |
ES2650952T3 (en) | 2012-02-03 | 2018-01-23 | Field Upgrading Limited | Process to desulfurize petroleum raw materials |
WO2013175488A2 (en) * | 2012-03-30 | 2013-11-28 | Aditya Birla Science And Technology Company Ltd. | A process for obtaining carbon black powder with reduced sulfur content |
KR102090358B1 (en) * | 2013-04-15 | 2020-03-17 | 필드 업그레이딩 리미티드 | Process to separate alkali metal salts from alkali metal reacted hydrocarbons |
DE102014012110A1 (en) | 2014-08-19 | 2016-02-25 | Dr. Bilger Umweltconsulting Gmbh | Process for the removal of undesirable compounds from mineral oil and apparatus for carrying out the process |
WO2016191421A1 (en) * | 2015-05-25 | 2016-12-01 | Technology Holdings, Llc | Processing alkali metal-sulfide or alkaline earth metal-sulfide to obtain the alkali metal or alkaline earth metal |
US10435631B2 (en) | 2016-10-04 | 2019-10-08 | Enlighten Innovations, Inc. | Process for separating particles containing alkali metal salts from liquid hydrocarbons |
CN113881454A (en) * | 2021-09-30 | 2022-01-04 | 中国石油化工股份有限公司 | Method for separating sodium sulfide from residual oil |
Family Cites Families (12)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US213661A (en) * | 1879-03-25 | Improvement in plows | ||
US1729943A (en) * | 1921-06-14 | 1929-10-01 | Firm Of Internationale Bergin | Treatment by pressure and heat of heavy mineral oils and carbon material |
US2020661A (en) * | 1923-06-20 | 1935-11-12 | Phillips Petroleum Co | Process for treating hydrocarbon oils |
US3004912A (en) * | 1959-04-13 | 1961-10-17 | Nat Distillers Chem Corp | Desulfurization process utilizing metallic sodium and recycling of sludge |
US3093575A (en) * | 1959-11-25 | 1963-06-11 | Exxon Research Engineering Co | Treatment of petroleum residua with sodium alloys |
US3164545A (en) * | 1962-12-26 | 1965-01-05 | Exxon Research Engineering Co | Desulfurization process |
US3404036A (en) * | 1965-10-22 | 1968-10-01 | Ford Motor Co | Energy conversion device comprising a solid crystalline electrolyte and a solid reaction zone separator |
US3475225A (en) * | 1966-11-21 | 1969-10-28 | Ford Motor Co | Method for preparing solid state ionic conductor |
US3446677A (en) * | 1966-11-21 | 1969-05-27 | Ford Motor Co | Method of making a solid ionic conductor |
US3488271A (en) * | 1966-12-02 | 1970-01-06 | Ford Motor Co | Method for separating a metal from a salt thereof |
US3468709A (en) * | 1967-04-03 | 1969-09-23 | Ford Motor Co | Secondary battery employing an electronically - insulative,cationically-conductive solid electrolyte with anodic and cathodic feeder means |
US3565792A (en) * | 1968-06-07 | 1971-02-23 | Frank B Haskett | Cyclic process for desulfurizing crude petroleum fractions with sodium |
-
1972
- 1972-06-01 US US00258555A patent/US3787315A/en not_active Expired - Lifetime
-
1973
- 1973-05-07 CA CA170,511A patent/CA1003353A/en not_active Expired
- 1973-05-11 GB GB2261973A patent/GB1431190A/en not_active Expired
- 1973-05-25 DE DE2326696A patent/DE2326696A1/en active Pending
- 1973-05-29 NL NL7307457A patent/NL7307457A/xx unknown
- 1973-05-30 IT IT24851/73A patent/IT988819B/en active
- 1973-05-30 FR FR7319906A patent/FR2186522B1/fr not_active Expired
- 1973-06-01 JP JP6105073A patent/JPS5515514B2/ja not_active Expired
Also Published As
Publication number | Publication date |
---|---|
JPS4942703A (en) | 1974-04-22 |
GB1431190A (en) | 1976-04-07 |
DE2326696A1 (en) | 1973-12-20 |
FR2186522B1 (en) | 1978-09-29 |
FR2186522A1 (en) | 1974-01-11 |
NL7307457A (en) | 1973-12-04 |
IT988819B (en) | 1975-04-30 |
US3787315A (en) | 1974-01-22 |
JPS5515514B2 (en) | 1980-04-24 |
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