JP5670997B2 - ナトリウム−硫黄電池および200℃未満の温度での電池の操作方法 - Google Patents
ナトリウム−硫黄電池および200℃未満の温度での電池の操作方法 Download PDFInfo
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- BNOODXBBXFZASF-UHFFFAOYSA-N [Na].[S] Chemical compound [Na].[S] BNOODXBBXFZASF-UHFFFAOYSA-N 0.000 title claims description 48
- 238000000034 method Methods 0.000 title claims description 20
- 239000012528 membrane Substances 0.000 claims description 81
- 239000011734 sodium Substances 0.000 claims description 72
- 229910001415 sodium ion Inorganic materials 0.000 claims description 61
- FKNQFGJONOIPTF-UHFFFAOYSA-N Sodium cation Chemical compound [Na+] FKNQFGJONOIPTF-UHFFFAOYSA-N 0.000 claims description 42
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims description 39
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims description 34
- 229910052708 sodium Inorganic materials 0.000 claims description 34
- 239000002904 solvent Substances 0.000 claims description 34
- 239000002228 NASICON Substances 0.000 claims description 26
- 150000002500 ions Chemical class 0.000 claims description 11
- 239000002798 polar solvent Substances 0.000 claims description 10
- 229910052717 sulfur Inorganic materials 0.000 claims description 10
- 239000011593 sulfur Substances 0.000 claims description 10
- ZUHZGEOKBKGPSW-UHFFFAOYSA-N tetraglyme Chemical compound COCCOCCOCCOCCOC ZUHZGEOKBKGPSW-UHFFFAOYSA-N 0.000 claims description 10
- 239000003792 electrolyte Substances 0.000 claims description 8
- 239000011148 porous material Substances 0.000 claims description 6
- 239000012454 non-polar solvent Substances 0.000 claims description 5
- 239000003795 chemical substances by application Substances 0.000 claims description 4
- 238000007789 sealing Methods 0.000 claims description 4
- 238000000926 separation method Methods 0.000 claims description 4
- 239000005077 polysulfide Substances 0.000 description 14
- 229920001021 polysulfide Polymers 0.000 description 13
- 150000008117 polysulfides Polymers 0.000 description 13
- 239000000463 material Substances 0.000 description 9
- 239000000203 mixture Substances 0.000 description 7
- 238000009472 formulation Methods 0.000 description 5
- 239000007787 solid Substances 0.000 description 5
- KEAYESYHFKHZAL-UHFFFAOYSA-N Sodium Chemical compound [Na] KEAYESYHFKHZAL-UHFFFAOYSA-N 0.000 description 4
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 description 4
- 239000000919 ceramic Substances 0.000 description 4
- 238000010586 diagram Methods 0.000 description 4
- -1 sodium hexafluorophosphate Chemical compound 0.000 description 4
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 3
- JLTDJTHDQAWBAV-UHFFFAOYSA-N N,N-dimethylaniline Chemical compound CN(C)C1=CC=CC=C1 JLTDJTHDQAWBAV-UHFFFAOYSA-N 0.000 description 3
- 239000004698 Polyethylene Substances 0.000 description 3
- JDZCKJOXGCMJGS-UHFFFAOYSA-N [Li].[S] Chemical compound [Li].[S] JDZCKJOXGCMJGS-UHFFFAOYSA-N 0.000 description 3
- 229910052799 carbon Inorganic materials 0.000 description 3
- 239000010406 cathode material Substances 0.000 description 3
- 239000007795 chemical reaction product Substances 0.000 description 3
- 239000004020 conductor Substances 0.000 description 3
- 239000013078 crystal Substances 0.000 description 3
- 230000001351 cycling effect Effects 0.000 description 3
- 239000012046 mixed solvent Substances 0.000 description 3
- 239000004033 plastic Substances 0.000 description 3
- 229920003023 plastic Polymers 0.000 description 3
- 229920000573 polyethylene Polymers 0.000 description 3
- FVAUCKIRQBBSSJ-UHFFFAOYSA-M sodium iodide Chemical compound [Na+].[I-] FVAUCKIRQBBSSJ-UHFFFAOYSA-M 0.000 description 3
- GRVFOGOEDUUMBP-UHFFFAOYSA-N sodium sulfide (anhydrous) Chemical compound [Na+].[Na+].[S-2] GRVFOGOEDUUMBP-UHFFFAOYSA-N 0.000 description 3
- 229910000873 Beta-alumina solid electrolyte Inorganic materials 0.000 description 2
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 2
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 2
- 229910052782 aluminium Inorganic materials 0.000 description 2
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 2
- 239000011230 binding agent Substances 0.000 description 2
- 238000009835 boiling Methods 0.000 description 2
- 229910052802 copper Inorganic materials 0.000 description 2
- 239000010949 copper Substances 0.000 description 2
- 230000003247 decreasing effect Effects 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 230000002427 irreversible effect Effects 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- 239000012466 permeate Substances 0.000 description 2
- 150000003839 salts Chemical class 0.000 description 2
- HYHCSLBZRBJJCH-UHFFFAOYSA-N sodium polysulfide Chemical compound [Na+].S HYHCSLBZRBJJCH-UHFFFAOYSA-N 0.000 description 2
- 229910052979 sodium sulfide Inorganic materials 0.000 description 2
- YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 description 2
- YFNKIDBQEZZDLK-UHFFFAOYSA-N triglyme Chemical compound COCCOCCOCCOC YFNKIDBQEZZDLK-UHFFFAOYSA-N 0.000 description 2
- 229910014103 Na-S Inorganic materials 0.000 description 1
- 229910014147 Na—S Inorganic materials 0.000 description 1
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 1
- 150000001450 anions Chemical class 0.000 description 1
- 206010003549 asthenia Diseases 0.000 description 1
- 230000004888 barrier function Effects 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 238000002788 crimping Methods 0.000 description 1
- 238000007598 dipping method Methods 0.000 description 1
- VDQVEACBQKUUSU-UHFFFAOYSA-M disodium;sulfanide Chemical compound [Na+].[Na+].[SH-] VDQVEACBQKUUSU-UHFFFAOYSA-M 0.000 description 1
- 239000002019 doping agent Substances 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 239000011532 electronic conductor Substances 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 238000002955 isolation Methods 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 239000011244 liquid electrolyte Substances 0.000 description 1
- 239000011159 matrix material Substances 0.000 description 1
- 230000005012 migration Effects 0.000 description 1
- 238000013508 migration Methods 0.000 description 1
- 231100000252 nontoxic Toxicity 0.000 description 1
- 230000003000 nontoxic effect Effects 0.000 description 1
- 230000010287 polarization Effects 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 239000005518 polymer electrolyte Substances 0.000 description 1
- 239000011118 polyvinyl acetate Substances 0.000 description 1
- 239000002244 precipitate Substances 0.000 description 1
- 230000008569 process Effects 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 239000000565 sealant Substances 0.000 description 1
- 238000005245 sintering Methods 0.000 description 1
- 239000011780 sodium chloride Substances 0.000 description 1
- 235000009518 sodium iodide Nutrition 0.000 description 1
- 159000000000 sodium salts Chemical class 0.000 description 1
- 239000011877 solvent mixture Substances 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 239000010936 titanium Substances 0.000 description 1
- 229910052719 titanium Inorganic materials 0.000 description 1
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- H—ELECTRICITY
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- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/36—Accumulators not provided for in groups H01M10/05-H01M10/34
- H01M10/39—Accumulators not provided for in groups H01M10/05-H01M10/34 working at high temperature
-
- H—ELECTRICITY
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- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/05—Accumulators with non-aqueous electrolyte
- H01M10/052—Li-accumulators
- H01M10/0525—Rocking-chair batteries, i.e. batteries with lithium insertion or intercalation in both electrodes; Lithium-ion batteries
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/05—Accumulators with non-aqueous electrolyte
- H01M10/056—Accumulators with non-aqueous electrolyte characterised by the materials used as electrolytes, e.g. mixed inorganic/organic electrolytes
- H01M10/0561—Accumulators with non-aqueous electrolyte characterised by the materials used as electrolytes, e.g. mixed inorganic/organic electrolytes the electrolyte being constituted of inorganic materials only
- H01M10/0562—Solid materials
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- H01M10/42—Methods or arrangements for servicing or maintenance of secondary cells or secondary half-cells
- H01M10/44—Methods for charging or discharging
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- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
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- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/13—Electrodes for accumulators with non-aqueous electrolyte, e.g. for lithium-accumulators; Processes of manufacture thereof
- H01M4/136—Electrodes based on inorganic compounds other than oxides or hydroxides, e.g. sulfides, selenides, tellurides, halogenides or LiCoFy
-
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- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
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- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/36—Selection of substances as active materials, active masses, active liquids
- H01M4/58—Selection of substances as active materials, active masses, active liquids of inorganic compounds other than oxides or hydroxides, e.g. sulfides, selenides, tellurides, halogenides or LiCoFy; of polyanionic structures, e.g. phosphates, silicates or borates
- H01M4/581—Chalcogenides or intercalation compounds thereof
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- H01M50/463—Separators, membranes or diaphragms characterised by their shape
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- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
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- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
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Description
x=4、6又は8
x=4、6又は8、y=x−2
x=4、6又は8
Claims (19)
- ナトリウムを含有するアノードと、元素状硫黄を含有するカソードと、カソードからアノードを分離する非多孔性のナトリウムイオン伝導性膜とから成るナトリウム−硫黄電池であって、上記カソードは、元素状硫黄およびNa2Sx (ただし、x=1、2、4、6又は8)を少なくとも一部溶解する少なくとも1種の溶媒から成り、上記電池は、200℃未満の温度で操作されるように構成され、非多孔性のナトリウムイオン伝導性膜が、封孔剤で孔を充填処理しているNASICON膜であることを特徴とするナトリウム−硫黄電池。
- ナトリウムを含有するアノードと、元素状硫黄を含有するカソードと、カソードからアノードを分離する非多孔性のナトリウムイオン伝導性膜とから成るナトリウム−硫黄電池であって、上記カソードは、元素状硫黄およびNa2Sx (ただし、x=1、2、4、6又は8)を少なくとも一部溶解する少なくとも1種の溶媒から成り、上記電池は、200℃未満の温度で操作されるように構成され、上記少なくとも1種の溶媒が、元素状硫黄を溶解する無極性溶媒とNa2Sxを溶解する極性溶媒とから成ることを特徴とするナトリウム−硫黄電池。
- アノードが非多孔性のナトリウムイオン伝導性膜と反応しないように、アノードと非多孔性のナトリウムイオン伝導性膜との間にセパレーターを有する請求項1又は2に記載のナトリウム−硫黄電池。
- 上記セパレーターが多孔性セパレーターである請求項3に記載のナトリウム−硫黄電池。
- 多孔性セパレーターがナトリウムイオン伝導電解質を透過させる請求項4に記載のナトリウム−硫黄電池。
- 非多孔性のナトリウムイオン伝導性膜がNASICON膜である請求項2に記載のナトリウム−硫黄電池。
- 非多孔性のナトリウムイオン伝導性膜を支持するために、多孔性構造層が非多孔性のナトリウムイオン伝導性膜の少なくとも片面に接続されている請求項1又は2に記載のナトリウム−硫黄電池。
- 多孔性構造層が多孔性NASICON層である請求項7に記載のナトリウム−硫黄電池。
- 上記少なくとも1種の溶媒が、元素状硫黄およびNa2Sx (ただし、x=1、2、4、6又は8)を少なくとも一部溶解する少なくとも1種の極性溶媒から成る請求項1に記載のナトリウム−硫黄電池。
- 上記少なくとも1種の溶媒がテトラグリムから成る請求項1に記載のナトリウム−硫黄電池。
- ナトリウム含有アノードにおいてナトリウムイオンを発生させる工程と、非多孔性のイオン伝導性膜を介してナトリウムイオンをカソードに移送する工程と、カソードにおいてナトリウムイオンを元素状硫黄と反応させ、Na2Sx (ただし、x=1、2、4、6又は8)を発生させる工程とから成る200℃未満の温度での電池の操作方法であって、カソードにおける少なくとも1種の溶媒に元素状硫黄およびNa2Sx (ただし、x=1、2、4、6又は8)が少なくとも一部溶解し、非多孔性のナトリウムイオン伝導性膜がNASICON膜であり、NASICON膜の孔が封孔剤で充填されていることを特徴とする電池の操作方法。
- ナトリウム含有アノードにおいてナトリウムイオンを発生させる工程と、非多孔性のイオン伝導性膜を介してナトリウムイオンをカソードに移送する工程と、カソードにおいてナトリウムイオンを元素状硫黄と反応させ、Na2Sx (ただし、x=1、2、4、6又は8)を発生させる工程とから成る200℃未満の温度での電池の操作方法であって、カソードにおける少なくとも1種の溶媒に元素状硫黄およびNa2Sx (ただし、x=1、2、4、6又は8)が少なくとも一部溶解し、上記少なくとも1種の溶媒が、元素状硫黄を溶解する無極性溶媒とNa2Sx (ただし、x=1、2、4、6又は8)を溶解する極性溶媒とから成ることを特徴とする電池の操作方法。
- ナトリウム含有アノードが非多孔性のナトリウムイオン伝導性膜と反応しないように、ナトリウム含有アノードと非多孔性のナトリウムイオン伝導性膜との間が分離されている請求項11又は12に記載の方法。
- 上記のナトリウム含有アノードと非多孔性のナトリウムイオン伝導性膜との間の分離が、ナトリウム含有アノードと非多孔性のナトリウムイオン伝導性膜との間に多孔性セパレーターを配置することによって行われている請求項13に記載の方法。
- 上記多孔性セパレーターにナトリウムイオン移動電解質を透過させる工程を含む請求項14に記載の方法。
- 多孔性構造層によって非多孔性のイオン伝導性膜が支持されている請求項11又は12に記載の方法。
- 多孔性構造層が多孔性NASICON層である請求項16に記載の方法。
- 上記少なくとも1種の溶媒が、元素状硫黄およびNa2Sx (ただし、x=1、2、4、6又は8)を少なくとも一部溶解する少なくとも1種の極性溶媒から成る請求項11に記載の方法。
- 上記少なくとも1種の溶媒がテトラグリムから成る請求項11に記載の方法。
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Application Number | Priority Date | Filing Date | Title |
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US16062109P | 2009-03-16 | 2009-03-16 | |
US61/160,621 | 2009-03-16 | ||
PCT/US2010/027535 WO2010107833A2 (en) | 2009-03-16 | 2010-03-16 | Sodium-sulfur battery with a substantially non-porous membrane and enhanced cathode utilization |
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JP2012521073A JP2012521073A (ja) | 2012-09-10 |
JP5670997B2 true JP5670997B2 (ja) | 2015-02-18 |
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US (1) | US20100239893A1 (ja) |
EP (1) | EP2409354A4 (ja) |
JP (1) | JP5670997B2 (ja) |
KR (1) | KR20110139197A (ja) |
WO (1) | WO2010107833A2 (ja) |
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---|---|---|---|---|
US8771879B2 (en) * | 2007-09-05 | 2014-07-08 | Ceramatec, Inc. | Lithium—sulfur battery with a substantially non-porous lisicon membrane and porous lisicon layer |
US10320033B2 (en) | 2008-01-30 | 2019-06-11 | Enlighten Innovations Inc. | Alkali metal ion battery using alkali metal conductive ceramic separator |
US8323817B2 (en) * | 2008-09-12 | 2012-12-04 | Ceramatec, Inc. | Alkali metal seawater battery |
CA2770733C (en) | 2009-11-05 | 2018-10-16 | Ceramatec, Inc. | Solid-state sodium-based secondary cell having a sodium ion conductive ceramic separator |
WO2012021323A2 (en) | 2010-08-11 | 2012-02-16 | Ceramatec, Inc. | Alkali metal aqueous battery |
US10056651B2 (en) | 2010-11-05 | 2018-08-21 | Field Upgrading Usa, Inc. | Low temperature secondary cell with sodium intercalation electrode |
US10020543B2 (en) | 2010-11-05 | 2018-07-10 | Field Upgrading Usa, Inc. | Low temperature battery with molten sodium-FSA electrolyte |
US10170798B2 (en) | 2010-12-01 | 2019-01-01 | Field Upgrading Usa, Inc. | Moderate temperature sodium battery |
GB2493511B (en) * | 2011-07-29 | 2018-01-31 | Sondex Wireline Ltd | Downhole energy storage system |
US10224577B2 (en) | 2011-11-07 | 2019-03-05 | Field Upgrading Usa, Inc. | Battery charge transfer mechanisms |
JP2015515723A (ja) * | 2012-04-02 | 2015-05-28 | セラマテック・インク | 非極性アルカリ金属イオン伝導ハニカム構造セパレーターを有する電池 |
WO2013154349A1 (en) * | 2012-04-10 | 2013-10-17 | Sk Innovation Co.,Ltd. | Sodium secondary battery |
US20130288153A1 (en) * | 2012-04-30 | 2013-10-31 | Moris Technology Center LLC | Sodium-Sulfur Battery |
KR102114716B1 (ko) | 2012-09-06 | 2020-05-26 | 필드 업그레이딩 유에스에이, 인코포레이티드 | 나트륨-할로겐 2차 전지 |
US10854929B2 (en) | 2012-09-06 | 2020-12-01 | Field Upgrading Usa, Inc. | Sodium-halogen secondary cell |
KR102139516B1 (ko) | 2012-12-19 | 2020-07-30 | 필드 업그레이딩 유에스에이, 인코포레이티드 | 고체 알칼리 이온 전도성 전해질 멤브레인의 열화 방지 |
CN103116138B (zh) * | 2013-01-25 | 2015-06-17 | 南京工业大学 | 钠硫电池用三电极体系模拟电池装置 |
US9748544B2 (en) | 2013-11-12 | 2017-08-29 | Ceramatec, Inc. | Separator for alkali metal ion battery |
KR102356880B1 (ko) * | 2014-08-13 | 2022-02-03 | 에스케이이노베이션 주식회사 | 나트륨 이차전지 |
US10424803B2 (en) | 2014-09-15 | 2019-09-24 | Arizona Board Of Regents On Behalf Of Arizona State University | Ionic liquid catholytes and electrochemical devices containing same |
WO2017152171A1 (en) * | 2016-03-04 | 2017-09-08 | Cornell University | Stable room-temperature sodium-sulfur battery |
IL249526B (en) * | 2016-12-12 | 2019-08-29 | B C Energy Storage Ltd | Rechargeable lithium-free solid-state battery |
GB201716779D0 (en) * | 2017-10-13 | 2017-11-29 | Univ Lancaster | Electrolyte element and a cell incorporating the electrolyte element |
Family Cites Families (97)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US1501756A (en) * | 1922-08-18 | 1924-07-15 | Roessler & Hasslacher Chemical | Electrolytic process and cell |
US3660170A (en) * | 1970-04-08 | 1972-05-02 | Gen Electric | Dendrite-inhibiting additive for battery cell having zinc electrode |
US3785965A (en) * | 1971-10-28 | 1974-01-15 | Exxon Research Engineering Co | Process for the desulfurization of petroleum oil fractions |
US3788978A (en) * | 1972-05-24 | 1974-01-29 | Exxon Research Engineering Co | Process for the desulfurization of petroleum oil stocks |
US3791966A (en) * | 1972-05-24 | 1974-02-12 | Exxon Research Engineering Co | Alkali metal desulfurization process for petroleum oil stocks |
US3787315A (en) * | 1972-06-01 | 1974-01-22 | Exxon Research Engineering Co | Alkali metal desulfurization process for petroleum oil stocks using low pressure hydrogen |
US4076613A (en) * | 1975-04-28 | 1978-02-28 | Exxon Research & Engineering Co. | Combined disulfurization and conversion with alkali metals |
US3970472A (en) * | 1975-07-08 | 1976-07-20 | Mcgraw-Edison Company | Rechargeable battery with zinc negative and dendrite barrier |
US4041215A (en) * | 1976-04-05 | 1977-08-09 | Owens-Illinois, Inc. | Method for forming solid electrolyte composite |
US4053371A (en) * | 1976-06-01 | 1977-10-11 | The Dow Chemical Company | Cellular metal by electrolysis |
US4207391A (en) * | 1978-07-25 | 1980-06-10 | El-Chem Corporation | Rechargeable electrical storage battery with zinc anode and aqueous alkaline electrolyte |
US4244986A (en) * | 1979-04-24 | 1981-01-13 | Westinghouse Electric Corp. | Method of forming sodium beta-Al2 O3 films and coatings |
DE7913673U1 (de) * | 1979-05-11 | 1979-09-06 | Skf Kugellagerfabriken Gmbh, 8720 Schweinfurt | Ausruecker fuer kupplungen |
US4372823A (en) * | 1979-12-06 | 1983-02-08 | El-Chem Corporation | Rechargeable electrical storage battery with zinc anode and aqueous alkaline electrolyte |
ZA828603B (en) * | 1981-12-10 | 1983-09-28 | South African Inventions | Electrochemical cell |
JPS5928588A (ja) * | 1982-08-09 | 1984-02-15 | Meidensha Electric Mfg Co Ltd | 亜鉛―臭素二次電池 |
US4465744A (en) * | 1982-11-30 | 1984-08-14 | The United States Of America As Represented By The United States Department Of Energy | Super ionic conductive glass |
JPS6017872A (ja) * | 1983-07-11 | 1985-01-29 | Nippon Denso Co Ltd | 有機電池 |
US4542444A (en) * | 1983-12-27 | 1985-09-17 | The Standard Oil Company | Double layer energy storage device |
US4828939A (en) * | 1987-06-01 | 1989-05-09 | Eltech Systems Corporation | Bipolar metal/air battery |
US4842963A (en) * | 1988-06-21 | 1989-06-27 | The United States Of America As Represented By The United States Department Of Energy | Zinc electrode and rechargeable zinc-air battery |
US5057206A (en) * | 1988-08-25 | 1991-10-15 | Uop | Process for the production of white oils |
US5525442A (en) * | 1990-09-14 | 1996-06-11 | Westinghouse Electric Corporation | Alkali metal battery |
US5427873A (en) * | 1990-09-14 | 1995-06-27 | Westinghouse Electric Corporation | Lithium-water battery |
US5158840A (en) * | 1991-03-11 | 1992-10-27 | Hughes Aircraft Company | Glass sealing materials for sodium-sulfur batteries and batteries made therewith |
US5290405A (en) * | 1991-05-24 | 1994-03-01 | Ceramatec, Inc. | NaOH production from ceramic electrolytic cell |
US5208121A (en) * | 1991-06-18 | 1993-05-04 | Wisconsin Alumni Research Foundation | Battery utilizing ceramic membranes |
US5213908A (en) * | 1991-09-26 | 1993-05-25 | The United States Of America As Represented By The Administrator Of The National Aeronautics And Space Administration | Alkali metal carbon dioxide electrochemical system for energy storage and/or conversion of carbon dioxide to oxygen |
US5516598A (en) * | 1994-07-28 | 1996-05-14 | Polyplus Battery Company, Inc. | Secondary cell using organosulfur/metal charge transfer materials as positive electrode |
ZA958252B (en) * | 1994-10-13 | 1996-04-15 | Programme 3 Patent Holdings | Electrochemical cell |
US6017651A (en) * | 1994-11-23 | 2000-01-25 | Polyplus Battery Company, Inc. | Methods and reagents for enhancing the cycling efficiency of lithium polymer batteries |
US6025094A (en) * | 1994-11-23 | 2000-02-15 | Polyplus Battery Company, Inc. | Protective coatings for negative electrodes |
US5686201A (en) * | 1994-11-23 | 1997-11-11 | Polyplus Battery Company, Inc. | Rechargeable positive electrodes |
US6358643B1 (en) * | 1994-11-23 | 2002-03-19 | Polyplus Battery Company | Liquid electrolyte lithium-sulfur batteries |
US6030720A (en) * | 1994-11-23 | 2000-02-29 | Polyplus Battery Co., Inc. | Liquid electrolyte lithium-sulfur batteries |
US6376123B1 (en) * | 1994-11-23 | 2002-04-23 | Polyplus Battery Company | Rechargeable positive electrodes |
US5935421A (en) * | 1995-05-02 | 1999-08-10 | Exxon Research And Engineering Company | Continuous in-situ combination process for upgrading heavy oil |
US5541019A (en) * | 1995-11-06 | 1996-07-30 | Motorola, Inc. | Metal hydride electrochemical cell having a polymer electrolyte |
US5780186A (en) * | 1996-05-09 | 1998-07-14 | The United States Of America As Represented By The Administrator Of The National Aeronautics And Space Administration | High performance zinc anode for battery applications |
US6210564B1 (en) * | 1996-06-04 | 2001-04-03 | Exxon Research And Engineering Company | Process for desulfurization of petroleum feeds utilizing sodium metal |
US5882812A (en) * | 1997-01-14 | 1999-03-16 | Polyplus Battery Company, Inc. | Overcharge protection systems for rechargeable batteries |
US5856047A (en) * | 1997-01-31 | 1999-01-05 | Ovonic Battery Company, Inc. | High power nickel-metal hydride batteries and high power electrodes for use therein |
IL120784A (en) * | 1997-05-05 | 2000-08-31 | Chemergy Ltd | Iron based sulfur battery |
US6402795B1 (en) * | 1998-02-18 | 2002-06-11 | Polyplus Battery Company, Inc. | Plating metal negative electrodes under protective coatings |
US6265100B1 (en) * | 1998-02-23 | 2001-07-24 | Research International, Inc. | Rechargeable battery |
US6610440B1 (en) * | 1998-03-10 | 2003-08-26 | Bipolar Technologies, Inc | Microscopic batteries for MEMS systems |
US6214061B1 (en) * | 1998-05-01 | 2001-04-10 | Polyplus Battery Company, Inc. | Method for forming encapsulated lithium electrodes having glass protective layers |
US6416903B1 (en) * | 1998-08-17 | 2002-07-09 | Ovonic Battery Company, Inc. | Nickel hydroxide electrode material and method for making the same |
US6210832B1 (en) * | 1998-09-01 | 2001-04-03 | Polyplus Battery Company, Inc. | Mixed ionic electronic conductor coatings for redox electrodes |
US6200704B1 (en) * | 1998-09-01 | 2001-03-13 | Polyplus Battery Company, Inc. | High capacity/high discharge rate rechargeable positive electrode |
US6955866B2 (en) * | 1998-09-03 | 2005-10-18 | Polyplus Battery Company | Coated lithium electrodes |
US6537701B1 (en) * | 1998-09-03 | 2003-03-25 | Polyplus Battery Company, Inc. | Coated lithium electrodes |
US6110236A (en) * | 1998-09-11 | 2000-08-29 | Polyplus Battery Company, Inc. | Method of preparing electrodes having evenly distributed component mixtures |
US6291090B1 (en) * | 1998-09-17 | 2001-09-18 | Aer Energy Resources, Inc. | Method for making metal-air electrode with water soluble catalyst precursors |
US6355379B1 (en) * | 1999-02-03 | 2002-03-12 | Sanyo Electric Co., Ltd. | Polymer electrolyte batteries having improved electrode/electrolyte interface |
US6225002B1 (en) * | 1999-02-05 | 2001-05-01 | Polyplus Battery Company, Inc. | Dioxolane as a proctector for lithium electrodes |
CN2365765Y (zh) * | 1999-03-18 | 2000-02-23 | 孙法炯 | 一种新型的扣式金属空气电池 |
US6413285B1 (en) * | 1999-11-01 | 2002-07-02 | Polyplus Battery Company | Layered arrangements of lithium electrodes |
US6413284B1 (en) * | 1999-11-01 | 2002-07-02 | Polyplus Battery Company | Encapsulated lithium alloy electrodes having barrier layers |
MXPA02004947A (es) * | 1999-11-16 | 2002-09-18 | Rmg Services Pty Ltd | Tratamiento de aceites crudos. |
US20070221265A1 (en) * | 2006-03-22 | 2007-09-27 | Sion Power Corporation | Rechargeable lithium/water, lithium/air batteries |
US6368486B1 (en) * | 2000-03-28 | 2002-04-09 | E. I. Du Pont De Nemours And Company | Low temperature alkali metal electrolysis |
KR100326466B1 (ko) * | 2000-07-25 | 2002-02-28 | 김순택 | 리튬 설퍼 전지용 전해액 |
US6632573B1 (en) * | 2001-02-20 | 2003-10-14 | Polyplus Battery Company | Electrolytes with strong oxidizing additives for lithium/sulfur batteries |
US6653020B2 (en) * | 2001-04-12 | 2003-11-25 | Rutgers University Foundation | Metal nitride electrode materials for high capacity rechargeable lithium battery cells |
US7070632B1 (en) * | 2001-07-25 | 2006-07-04 | Polyplus Battery Company | Electrochemical device separator structures with barrier layer on non-swelling membrane |
US6787019B2 (en) * | 2001-11-21 | 2004-09-07 | E. I. Du Pont De Nemours And Company | Low temperature alkali metal electrolysis |
US6911280B1 (en) * | 2001-12-21 | 2005-06-28 | Polyplus Battery Company | Chemical protection of a lithium surface |
US7214443B2 (en) * | 2002-02-12 | 2007-05-08 | Plurion Limited | Secondary battery with autolytic dendrites |
KR100434189B1 (ko) * | 2002-03-21 | 2004-06-04 | 삼성전자주식회사 | 화학 기계적 연마장치 및 그 제어방법 |
US7645543B2 (en) * | 2002-10-15 | 2010-01-12 | Polyplus Battery Company | Active metal/aqueous electrochemical cells and systems |
US7390591B2 (en) * | 2002-10-15 | 2008-06-24 | Polyplus Battery Company | Ionically conductive membranes for protection of active metal anodes and battery cells |
US7482096B2 (en) * | 2003-06-04 | 2009-01-27 | Polyplus Battery Company | Alleviation of voltage delay in lithium-liquid depolarizer/electrolyte solvent battery cells |
US6881234B2 (en) * | 2003-08-08 | 2005-04-19 | Frank E. Towsley | Method for making electrodes for nickel-metal hydride batteries |
KR20050040714A (ko) * | 2003-10-28 | 2005-05-03 | 티디케이가부시기가이샤 | 다공질 기능성막, 센서, 다공질 기능성막의 제조방법,다공질 금속막의 제조방법 및 센서의 제조방법 |
US7491458B2 (en) * | 2003-11-10 | 2009-02-17 | Polyplus Battery Company | Active metal fuel cells |
US7824536B2 (en) * | 2003-12-11 | 2010-11-02 | Ceramatec, Inc. | Electrolytic method to make alkali alcoholates using ceramic ion conducting solid membranes |
US7282295B2 (en) * | 2004-02-06 | 2007-10-16 | Polyplus Battery Company | Protected active metal electrode and battery cell structures with non-aqueous interlayer architecture |
KR100651246B1 (ko) * | 2004-02-17 | 2006-11-29 | 경상대학교산학협력단 | 액체전해질을 사용한 나트륨/유황 전지 |
US7259126B2 (en) * | 2004-03-11 | 2007-08-21 | Ceramatec, Inc. | Gas diffusion electrode and catalyst for electrochemical oxygen reduction and method of dispersing the catalyst |
US7255961B2 (en) * | 2004-03-12 | 2007-08-14 | Trans Ionics Corporation | Thin film composite electrolyte |
JP2005290325A (ja) * | 2004-04-05 | 2005-10-20 | Toyota Motor Corp | 固体高分子電解質、固体高分子電解質膜、及びナトリウム硫黄電池 |
US7785461B2 (en) * | 2004-11-10 | 2010-08-31 | Petroleo Brasileiro S.A. - Petrobras | Process for selective hydrodesulfurization of naphtha |
US20060141346A1 (en) * | 2004-11-23 | 2006-06-29 | Gordon John H | Solid electrolyte thermoelectrochemical system |
US7413582B2 (en) * | 2005-08-29 | 2008-08-19 | Tsang Floris Y | Lithium battery |
JP5153065B2 (ja) * | 2005-08-31 | 2013-02-27 | 株式会社オハラ | リチウムイオン二次電池および固体電解質 |
US8182943B2 (en) * | 2005-12-19 | 2012-05-22 | Polyplus Battery Company | Composite solid electrolyte for protection of active metal anodes |
JP2009059505A (ja) * | 2007-08-30 | 2009-03-19 | Auto Network Gijutsu Kenkyusho:Kk | シールド導電体 |
US8771879B2 (en) * | 2007-09-05 | 2014-07-08 | Ceramatec, Inc. | Lithium—sulfur battery with a substantially non-porous lisicon membrane and porous lisicon layer |
US8012621B2 (en) * | 2007-11-26 | 2011-09-06 | Ceramatec, Inc. | Nickel-metal hydride battery using alkali ion conducting separator |
WO2009070593A1 (en) * | 2007-11-27 | 2009-06-04 | Ceramatec, Inc. | Process for recovering alkali metals and sulfur from alkali metal sulfides and polysulfides |
WO2009070600A2 (en) * | 2007-11-27 | 2009-06-04 | Ceramatec, Inc. | Substantially solid, flexible electrolyte for alkili-metal-ion batteries |
US20090189567A1 (en) * | 2008-01-30 | 2009-07-30 | Joshi Ashok V | Zinc Anode Battery Using Alkali Ion Conducting Separator |
US8323817B2 (en) * | 2008-09-12 | 2012-12-04 | Ceramatec, Inc. | Alkali metal seawater battery |
CA2770733C (en) * | 2009-11-05 | 2018-10-16 | Ceramatec, Inc. | Solid-state sodium-based secondary cell having a sodium ion conductive ceramic separator |
WO2012021323A2 (en) * | 2010-08-11 | 2012-02-16 | Ceramatec, Inc. | Alkali metal aqueous battery |
US10170798B2 (en) * | 2010-12-01 | 2019-01-01 | Field Upgrading Usa, Inc. | Moderate temperature sodium battery |
-
2010
- 2010-03-16 US US12/725,319 patent/US20100239893A1/en not_active Abandoned
- 2010-03-16 JP JP2012500901A patent/JP5670997B2/ja active Active
- 2010-03-16 WO PCT/US2010/027535 patent/WO2010107833A2/en active Application Filing
- 2010-03-16 EP EP10754004A patent/EP2409354A4/en not_active Withdrawn
- 2010-03-16 KR KR1020117018980A patent/KR20110139197A/ko not_active Application Discontinuation
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KR20110139197A (ko) | 2011-12-28 |
WO2010107833A3 (en) | 2011-01-13 |
WO2010107833A2 (en) | 2010-09-23 |
EP2409354A4 (en) | 2012-06-13 |
US20100239893A1 (en) | 2010-09-23 |
JP2012521073A (ja) | 2012-09-10 |
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