DE2262161C3 - Verfahren zur Herstellung nadeiförmiger Eisenpartikel - Google Patents
Verfahren zur Herstellung nadeiförmiger EisenpartikelInfo
- Publication number
- DE2262161C3 DE2262161C3 DE2262161A DE2262161A DE2262161C3 DE 2262161 C3 DE2262161 C3 DE 2262161C3 DE 2262161 A DE2262161 A DE 2262161A DE 2262161 A DE2262161 A DE 2262161A DE 2262161 C3 DE2262161 C3 DE 2262161C3
- Authority
- DE
- Germany
- Prior art keywords
- iron
- bismuth
- particles
- temperature
- iron oxide
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 title claims description 66
- 229910052742 iron Inorganic materials 0.000 title claims description 28
- 239000002245 particle Substances 0.000 title claims description 14
- 238000000034 method Methods 0.000 title claims description 12
- 238000004519 manufacturing process Methods 0.000 title claims description 8
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N iron oxide Inorganic materials [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 claims description 35
- 239000000243 solution Substances 0.000 claims description 24
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 22
- 229910052797 bismuth Inorganic materials 0.000 claims description 20
- JCXGWMGPZLAOME-UHFFFAOYSA-N bismuth atom Chemical compound [Bi] JCXGWMGPZLAOME-UHFFFAOYSA-N 0.000 claims description 20
- 229910052710 silicon Inorganic materials 0.000 claims description 7
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 claims description 6
- 239000010703 silicon Substances 0.000 claims description 6
- 150000003377 silicon compounds Chemical class 0.000 claims description 6
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims description 5
- 230000015572 biosynthetic process Effects 0.000 claims description 4
- 150000001621 bismuth Chemical class 0.000 claims description 4
- RXPAJWPEYBDXOG-UHFFFAOYSA-N hydron;methyl 4-methoxypyridine-2-carboxylate;chloride Chemical compound Cl.COC(=O)C1=CC(OC)=CC=N1 RXPAJWPEYBDXOG-UHFFFAOYSA-N 0.000 claims description 4
- 150000003839 salts Chemical class 0.000 claims description 4
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 3
- 238000006243 chemical reaction Methods 0.000 claims description 3
- 239000003795 chemical substances by application Substances 0.000 claims description 3
- 239000001257 hydrogen Substances 0.000 claims description 3
- 229910052739 hydrogen Inorganic materials 0.000 claims description 3
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 claims description 3
- 229910052757 nitrogen Inorganic materials 0.000 claims description 3
- 238000005245 sintering Methods 0.000 claims description 3
- 239000004115 Sodium Silicate Substances 0.000 claims description 2
- 239000012298 atmosphere Substances 0.000 claims description 2
- 239000007789 gas Substances 0.000 claims description 2
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 claims description 2
- 229910052911 sodium silicate Inorganic materials 0.000 claims description 2
- 239000007864 aqueous solution Substances 0.000 claims 3
- 238000002485 combustion reaction Methods 0.000 claims 1
- 150000001875 compounds Chemical class 0.000 claims 1
- 125000000118 dimethyl group Chemical group [H]C([H])([H])* 0.000 claims 1
- 239000002019 doping agent Substances 0.000 claims 1
- 230000000694 effects Effects 0.000 claims 1
- 239000006249 magnetic particle Substances 0.000 claims 1
- 239000002184 metal Substances 0.000 claims 1
- 229910052751 metal Inorganic materials 0.000 claims 1
- -1 polysiloxane Polymers 0.000 claims 1
- 229920001296 polysiloxane Polymers 0.000 claims 1
- 230000002269 spontaneous effect Effects 0.000 claims 1
- 239000000126 substance Substances 0.000 claims 1
- 239000000203 mixture Substances 0.000 description 13
- 239000000843 powder Substances 0.000 description 7
- FBPFZTCFMRRESA-KVTDHHQDSA-N D-Mannitol Chemical compound OC[C@@H](O)[C@@H](O)[C@H](O)[C@H](O)CO FBPFZTCFMRRESA-KVTDHHQDSA-N 0.000 description 6
- 229930195725 Mannitol Natural products 0.000 description 6
- 239000000594 mannitol Substances 0.000 description 6
- 235000010355 mannitol Nutrition 0.000 description 6
- 239000011734 sodium Substances 0.000 description 5
- 229910015902 Bi 2 O 3 Inorganic materials 0.000 description 4
- 239000008187 granular material Substances 0.000 description 4
- 238000002156 mixing Methods 0.000 description 3
- 239000000047 product Substances 0.000 description 3
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 2
- 229910002588 FeOOH Inorganic materials 0.000 description 2
- 239000002518 antifoaming agent Substances 0.000 description 2
- 239000002738 chelating agent Substances 0.000 description 2
- 238000001035 drying Methods 0.000 description 2
- 239000011259 mixed solution Substances 0.000 description 2
- NDLPOXTZKUMGOV-UHFFFAOYSA-N oxo(oxoferriooxy)iron hydrate Chemical compound O.O=[Fe]O[Fe]=O NDLPOXTZKUMGOV-UHFFFAOYSA-N 0.000 description 2
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 2
- 239000010802 sludge Substances 0.000 description 2
- 239000002002 slurry Substances 0.000 description 2
- 238000003786 synthesis reaction Methods 0.000 description 2
- FBPFZTCFMRRESA-FSIIMWSLSA-N D-Glucitol Natural products OC[C@H](O)[C@H](O)[C@@H](O)[C@H](O)CO FBPFZTCFMRRESA-FSIIMWSLSA-N 0.000 description 1
- FBPFZTCFMRRESA-JGWLITMVSA-N D-glucitol Chemical compound OC[C@H](O)[C@@H](O)[C@H](O)[C@H](O)CO FBPFZTCFMRRESA-JGWLITMVSA-N 0.000 description 1
- 229910002651 NO3 Inorganic materials 0.000 description 1
- NHNBFGGVMKEFGY-UHFFFAOYSA-N Nitrate Chemical compound [O-][N+]([O-])=O NHNBFGGVMKEFGY-UHFFFAOYSA-N 0.000 description 1
- VMHLLURERBWHNL-UHFFFAOYSA-M Sodium acetate Chemical compound [Na+].CC([O-])=O VMHLLURERBWHNL-UHFFFAOYSA-M 0.000 description 1
- 108700043492 SprD Proteins 0.000 description 1
- JCCZVLHHCNQSNM-UHFFFAOYSA-N [Na][Si] Chemical compound [Na][Si] JCCZVLHHCNQSNM-UHFFFAOYSA-N 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 229910002092 carbon dioxide Inorganic materials 0.000 description 1
- 239000001569 carbon dioxide Substances 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- BEQZMQXCOWIHRY-UHFFFAOYSA-H dibismuth;trisulfate Chemical compound [Bi+3].[Bi+3].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O BEQZMQXCOWIHRY-UHFFFAOYSA-H 0.000 description 1
- 239000012895 dilution Substances 0.000 description 1
- 238000010790 dilution Methods 0.000 description 1
- 239000004205 dimethyl polysiloxane Substances 0.000 description 1
- 235000013870 dimethyl polysiloxane Nutrition 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 238000005469 granulation Methods 0.000 description 1
- 230000003179 granulation Effects 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- YOBAEOGBNPPUQV-UHFFFAOYSA-N iron;trihydrate Chemical compound O.O.O.[Fe].[Fe] YOBAEOGBNPPUQV-UHFFFAOYSA-N 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 239000013528 metallic particle Substances 0.000 description 1
- 239000012299 nitrogen atmosphere Substances 0.000 description 1
- JCXJVPUVTGWSNB-UHFFFAOYSA-N nitrogen dioxide Inorganic materials O=[N]=O JCXJVPUVTGWSNB-UHFFFAOYSA-N 0.000 description 1
- 229910052697 platinum Inorganic materials 0.000 description 1
- 229920000435 poly(dimethylsiloxane) Polymers 0.000 description 1
- 239000002244 precipitate Substances 0.000 description 1
- 230000001105 regulatory effect Effects 0.000 description 1
- 230000000717 retained effect Effects 0.000 description 1
- 239000001632 sodium acetate Substances 0.000 description 1
- 235000017281 sodium acetate Nutrition 0.000 description 1
- VMSRVIHUFHQIAL-UHFFFAOYSA-M sodium;n,n-dimethylcarbamodithioate Chemical compound [Na+].CN(C)C([S-])=S VMSRVIHUFHQIAL-UHFFFAOYSA-M 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 239000000600 sorbitol Substances 0.000 description 1
- 229910001220 stainless steel Inorganic materials 0.000 description 1
- 239000010935 stainless steel Substances 0.000 description 1
- 239000007858 starting material Substances 0.000 description 1
- 238000009736 wetting Methods 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22F—WORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
- B22F9/00—Making metallic powder or suspensions thereof
- B22F9/16—Making metallic powder or suspensions thereof using chemical processes
- B22F9/18—Making metallic powder or suspensions thereof using chemical processes with reduction of metal compounds
- B22F9/20—Making metallic powder or suspensions thereof using chemical processes with reduction of metal compounds starting from solid metal compounds
- B22F9/22—Making metallic powder or suspensions thereof using chemical processes with reduction of metal compounds starting from solid metal compounds using gaseous reductors
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22F—WORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
- B22F1/00—Metallic powder; Treatment of metallic powder, e.g. to facilitate working or to improve properties
- B22F1/14—Treatment of metallic powder
- B22F1/145—Chemical treatment, e.g. passivation or decarburisation
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01F—MAGNETS; INDUCTANCES; TRANSFORMERS; SELECTION OF MATERIALS FOR THEIR MAGNETIC PROPERTIES
- H01F1/00—Magnets or magnetic bodies characterised by the magnetic materials therefor; Selection of materials for their magnetic properties
- H01F1/01—Magnets or magnetic bodies characterised by the magnetic materials therefor; Selection of materials for their magnetic properties of inorganic materials
- H01F1/03—Magnets or magnetic bodies characterised by the magnetic materials therefor; Selection of materials for their magnetic properties of inorganic materials characterised by their coercivity
- H01F1/032—Magnets or magnetic bodies characterised by the magnetic materials therefor; Selection of materials for their magnetic properties of inorganic materials characterised by their coercivity of hard-magnetic materials
- H01F1/04—Magnets or magnetic bodies characterised by the magnetic materials therefor; Selection of materials for their magnetic properties of inorganic materials characterised by their coercivity of hard-magnetic materials metals or alloys
- H01F1/06—Magnets or magnetic bodies characterised by the magnetic materials therefor; Selection of materials for their magnetic properties of inorganic materials characterised by their coercivity of hard-magnetic materials metals or alloys in the form of particles, e.g. powder
- H01F1/061—Magnets or magnetic bodies characterised by the magnetic materials therefor; Selection of materials for their magnetic properties of inorganic materials characterised by their coercivity of hard-magnetic materials metals or alloys in the form of particles, e.g. powder with a protective layer
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01F—MAGNETS; INDUCTANCES; TRANSFORMERS; SELECTION OF MATERIALS FOR THEIR MAGNETIC PROPERTIES
- H01F1/00—Magnets or magnetic bodies characterised by the magnetic materials therefor; Selection of materials for their magnetic properties
- H01F1/01—Magnets or magnetic bodies characterised by the magnetic materials therefor; Selection of materials for their magnetic properties of inorganic materials
- H01F1/03—Magnets or magnetic bodies characterised by the magnetic materials therefor; Selection of materials for their magnetic properties of inorganic materials characterised by their coercivity
- H01F1/032—Magnets or magnetic bodies characterised by the magnetic materials therefor; Selection of materials for their magnetic properties of inorganic materials characterised by their coercivity of hard-magnetic materials
- H01F1/04—Magnets or magnetic bodies characterised by the magnetic materials therefor; Selection of materials for their magnetic properties of inorganic materials characterised by their coercivity of hard-magnetic materials metals or alloys
- H01F1/06—Magnets or magnetic bodies characterised by the magnetic materials therefor; Selection of materials for their magnetic properties of inorganic materials characterised by their coercivity of hard-magnetic materials metals or alloys in the form of particles, e.g. powder
- H01F1/065—Magnets or magnetic bodies characterised by the magnetic materials therefor; Selection of materials for their magnetic properties of inorganic materials characterised by their coercivity of hard-magnetic materials metals or alloys in the form of particles, e.g. powder obtained by a reduction
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Power Engineering (AREA)
- Hard Magnetic Materials (AREA)
- Compounds Of Iron (AREA)
- Manufacture Of Metal Powder And Suspensions Thereof (AREA)
- Powder Metallurgy (AREA)
- Soft Magnetic Materials (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US21445271A | 1971-12-30 | 1971-12-30 |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| DE2262161A1 DE2262161A1 (de) | 1973-08-16 |
| DE2262161B2 DE2262161B2 (de) | 1975-01-23 |
| DE2262161C3 true DE2262161C3 (de) | 1980-01-24 |
Family
ID=22799142
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE2262161A Expired DE2262161C3 (de) | 1971-12-30 | 1972-12-19 | Verfahren zur Herstellung nadeiförmiger Eisenpartikel |
Country Status (8)
| Country | Link |
|---|---|
| US (1) | US3748119A (enExample) |
| JP (1) | JPS5219541B2 (enExample) |
| BE (1) | BE792840A (enExample) |
| DE (1) | DE2262161C3 (enExample) |
| FR (1) | FR2165967B1 (enExample) |
| GB (1) | GB1358118A (enExample) |
| IT (1) | IT973717B (enExample) |
| NL (1) | NL150938B (enExample) |
Families Citing this family (17)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3977985A (en) * | 1972-02-23 | 1976-08-31 | Tdk Electronics Company, Limited | Magnetic recording medium comprising cobalt or cobalt alloy coated particles of spicular magnetite |
| NL167729C (nl) * | 1973-05-03 | 1982-01-18 | Philips Nv | Werkwijze voor het bereiden van een hoofdzakelijk uit ijzer bestaand metaalpoeder. |
| JPS5631882B2 (enExample) * | 1973-11-16 | 1981-07-24 | ||
| DE2434096C2 (de) * | 1974-07-16 | 1985-10-17 | Basf Ag, 6700 Ludwigshafen | Nadelförmige, vorwiegend aus Eisen bestehende ferromagnetische Metallteilchen und Verfahren zu ihrer Herstellung |
| JPS6017802B2 (ja) * | 1975-09-05 | 1985-05-07 | 株式会社日立製作所 | 強磁性金属粉末の製造方法 |
| US4023989A (en) * | 1975-10-20 | 1977-05-17 | Monsanto Company | Method for producing corded steel wire |
| JPS52134858A (en) * | 1976-05-07 | 1977-11-11 | Kanto Denka Kogyo Kk | Method of making magnetic recording magnetic powder containing iron as main constituent |
| JPS534895A (en) * | 1976-06-16 | 1978-01-17 | Fujitsu Ltd | Manufacture of needle-shaped magnetic iron particles |
| US4222977A (en) * | 1978-05-16 | 1980-09-16 | Monsanto Company | Process to produce inorganic hollow fibers |
| JPS55114880A (en) * | 1979-02-28 | 1980-09-04 | Hitachi Ltd | Pulser for generating ignition signal |
| JPS5914081B2 (ja) * | 1979-10-05 | 1984-04-03 | 日立マクセル株式会社 | 耐蝕性に優れた金属磁性粉末の製造法 |
| DE3176436D1 (en) * | 1980-06-11 | 1987-10-15 | Hitachi Maxell | Process for preparing ferromagnetic particles comprising metallic iron |
| JPH0620008B2 (ja) * | 1987-08-24 | 1994-03-16 | チッソ株式会社 | 酸化皮膜を有する強磁性金属粉末の製造方法 |
| US5234489A (en) * | 1992-05-27 | 1993-08-10 | L'air Liquide | Process for reducing oxides contained in iron powder without substantial decarburization thereof |
| US7199077B2 (en) * | 2002-05-15 | 2007-04-03 | Sud-Chemie Inc. | Fischer-tropsch catalyst prepared with a high purity iron precursor |
| US7566680B2 (en) * | 2002-05-15 | 2009-07-28 | Sud-Chemie Inc. | High surface area iron material prepared from a low surface area iron metal precursor |
| US7939463B1 (en) * | 2002-05-15 | 2011-05-10 | Sud-Chemie Inc. | Preparation of iron oxides |
-
0
- BE BE792840D patent/BE792840A/xx not_active IP Right Cessation
-
1971
- 1971-12-30 US US00214452A patent/US3748119A/en not_active Expired - Lifetime
-
1972
- 1972-11-24 IT IT54261/72A patent/IT973717B/it active
- 1972-12-06 GB GB5633772A patent/GB1358118A/en not_active Expired
- 1972-12-14 JP JP47124857A patent/JPS5219541B2/ja not_active Expired
- 1972-12-19 DE DE2262161A patent/DE2262161C3/de not_active Expired
- 1972-12-20 FR FR7245379A patent/FR2165967B1/fr not_active Expired
- 1972-12-29 NL NL727217833A patent/NL150938B/xx not_active IP Right Cessation
Also Published As
| Publication number | Publication date |
|---|---|
| BE792840A (fr) | 1973-03-30 |
| US3748119A (en) | 1973-07-24 |
| FR2165967B1 (enExample) | 1976-06-04 |
| DE2262161A1 (de) | 1973-08-16 |
| DE2262161B2 (de) | 1975-01-23 |
| JPS4879153A (enExample) | 1973-10-24 |
| IT973717B (it) | 1974-06-10 |
| FR2165967A1 (enExample) | 1973-08-10 |
| NL150938B (nl) | 1976-09-15 |
| NL7217833A (enExample) | 1973-07-03 |
| JPS5219541B2 (enExample) | 1977-05-28 |
| GB1358118A (en) | 1974-06-26 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C3 | Grant after two publication steps (3rd publication) |