DE1667386C3 - Verfahren zur Herstellung von Wasserstoff und Kohlendioxid durch katalytische Umsetzung von Kohlenmonoxid mit Wasserdampf - Google Patents
Verfahren zur Herstellung von Wasserstoff und Kohlendioxid durch katalytische Umsetzung von Kohlenmonoxid mit WasserdampfInfo
- Publication number
- DE1667386C3 DE1667386C3 DE1667386A DE1667386A DE1667386C3 DE 1667386 C3 DE1667386 C3 DE 1667386C3 DE 1667386 A DE1667386 A DE 1667386A DE 1667386 A DE1667386 A DE 1667386A DE 1667386 C3 DE1667386 C3 DE 1667386C3
- Authority
- DE
- Germany
- Prior art keywords
- oxide
- catalyst
- conversion
- zinc
- aluminum
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 238000006243 chemical reaction Methods 0.000 title claims description 30
- 238000004519 manufacturing process Methods 0.000 title claims description 5
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 title claims description 3
- 229910002091 carbon monoxide Inorganic materials 0.000 title claims description 3
- 238000000034 method Methods 0.000 title description 11
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 title description 10
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 title description 7
- 230000003197 catalytic effect Effects 0.000 title description 7
- 229910052739 hydrogen Inorganic materials 0.000 title description 6
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 title description 2
- 229910002092 carbon dioxide Inorganic materials 0.000 title description 2
- 239000001569 carbon dioxide Substances 0.000 title description 2
- 239000001257 hydrogen Substances 0.000 title description 2
- 239000003054 catalyst Substances 0.000 claims description 44
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims description 12
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 claims description 10
- 239000000969 carrier Substances 0.000 claims description 7
- 229910017052 cobalt Inorganic materials 0.000 claims description 7
- 239000010941 cobalt Substances 0.000 claims description 7
- 230000000694 effects Effects 0.000 claims description 7
- CPLXHLVBOLITMK-UHFFFAOYSA-N magnesium oxide Inorganic materials [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 claims description 7
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 claims description 6
- 239000000395 magnesium oxide Substances 0.000 claims description 6
- AXZKOIWUVFPNLO-UHFFFAOYSA-N magnesium;oxygen(2-) Chemical compound [O-2].[Mg+2] AXZKOIWUVFPNLO-UHFFFAOYSA-N 0.000 claims description 6
- 229910052759 nickel Inorganic materials 0.000 claims description 6
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 claims description 5
- 239000011777 magnesium Substances 0.000 claims description 5
- 229910052749 magnesium Inorganic materials 0.000 claims description 5
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 claims description 5
- 239000011787 zinc oxide Substances 0.000 claims description 5
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 claims description 4
- 229910052782 aluminium Inorganic materials 0.000 claims description 4
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 4
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims description 4
- 239000011701 zinc Substances 0.000 claims description 4
- 229910052725 zinc Inorganic materials 0.000 claims description 4
- 229910000611 Zinc aluminium Inorganic materials 0.000 claims description 3
- HXFVOUUOTHJFPX-UHFFFAOYSA-N alumane;zinc Chemical compound [AlH3].[Zn] HXFVOUUOTHJFPX-UHFFFAOYSA-N 0.000 claims description 3
- 230000007704 transition Effects 0.000 claims description 3
- 229910052566 spinel group Inorganic materials 0.000 claims description 2
- 230000015572 biosynthetic process Effects 0.000 claims 1
- 239000007789 gas Substances 0.000 description 20
- 238000002474 experimental method Methods 0.000 description 9
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 8
- 239000000203 mixture Substances 0.000 description 7
- 229910052596 spinel Inorganic materials 0.000 description 6
- 239000011029 spinel Substances 0.000 description 6
- 239000000243 solution Substances 0.000 description 5
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 4
- 229910052742 iron Inorganic materials 0.000 description 4
- 150000004763 sulfides Chemical class 0.000 description 4
- RWSOTUBLDIXVET-UHFFFAOYSA-N Dihydrogen sulfide Chemical compound S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 description 3
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- APUPEJJSWDHEBO-UHFFFAOYSA-P ammonium molybdate Chemical compound [NH4+].[NH4+].[O-][Mo]([O-])(=O)=O APUPEJJSWDHEBO-UHFFFAOYSA-P 0.000 description 3
- 239000011609 ammonium molybdate Substances 0.000 description 3
- 235000018660 ammonium molybdate Nutrition 0.000 description 3
- 229940010552 ammonium molybdate Drugs 0.000 description 3
- 239000011230 binding agent Substances 0.000 description 3
- 229910002090 carbon oxide Inorganic materials 0.000 description 3
- 230000007423 decrease Effects 0.000 description 3
- MWUXSHHQAYIFBG-UHFFFAOYSA-N nitrogen oxide Inorganic materials O=[N] MWUXSHHQAYIFBG-UHFFFAOYSA-N 0.000 description 3
- 238000002360 preparation method Methods 0.000 description 3
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 2
- 239000003570 air Substances 0.000 description 2
- 229910021529 ammonia Inorganic materials 0.000 description 2
- 229910052799 carbon Inorganic materials 0.000 description 2
- 230000008021 deposition Effects 0.000 description 2
- 238000001035 drying Methods 0.000 description 2
- 238000001125 extrusion Methods 0.000 description 2
- 229910000037 hydrogen sulfide Inorganic materials 0.000 description 2
- 238000005984 hydrogenation reaction Methods 0.000 description 2
- 150000004679 hydroxides Chemical class 0.000 description 2
- 238000004898 kneading Methods 0.000 description 2
- 238000001556 precipitation Methods 0.000 description 2
- 239000012266 salt solution Substances 0.000 description 2
- 229910052717 sulfur Inorganic materials 0.000 description 2
- 239000011593 sulfur Substances 0.000 description 2
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 description 2
- 229910052721 tungsten Inorganic materials 0.000 description 2
- 239000010937 tungsten Substances 0.000 description 2
- 238000004438 BET method Methods 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 1
- PMVSDNDAUGGCCE-TYYBGVCCSA-L Ferrous fumarate Chemical compound [Fe+2].[O-]C(=O)\C=C\C([O-])=O PMVSDNDAUGGCCE-TYYBGVCCSA-L 0.000 description 1
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 description 1
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 description 1
- 239000011398 Portland cement Substances 0.000 description 1
- 241000212342 Sium Species 0.000 description 1
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 1
- 150000001242 acetic acid derivatives Chemical class 0.000 description 1
- 239000012190 activator Substances 0.000 description 1
- SNAAJJQQZSMGQD-UHFFFAOYSA-N aluminum magnesium Chemical compound [Mg].[Al] SNAAJJQQZSMGQD-UHFFFAOYSA-N 0.000 description 1
- ANBBXQWFNXMHLD-UHFFFAOYSA-N aluminum;sodium;oxygen(2-) Chemical compound [O-2].[O-2].[Na+].[Al+3] ANBBXQWFNXMHLD-UHFFFAOYSA-N 0.000 description 1
- 150000003863 ammonium salts Chemical class 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 235000021028 berry Nutrition 0.000 description 1
- 229910001593 boehmite Inorganic materials 0.000 description 1
- XFWJKVMFIVXPKK-UHFFFAOYSA-N calcium;oxido(oxo)alumane Chemical compound [Ca+2].[O-][Al]=O.[O-][Al]=O XFWJKVMFIVXPKK-UHFFFAOYSA-N 0.000 description 1
- 150000004649 carbonic acid derivatives Chemical class 0.000 description 1
- 239000004568 cement Substances 0.000 description 1
- 150000003841 chloride salts Chemical class 0.000 description 1
- 229910052804 chromium Inorganic materials 0.000 description 1
- 239000011651 chromium Substances 0.000 description 1
- 229910000423 chromium oxide Inorganic materials 0.000 description 1
- 239000003245 coal Substances 0.000 description 1
- UFMZWBIQTDUYBN-UHFFFAOYSA-N cobalt dinitrate Chemical compound [Co+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O UFMZWBIQTDUYBN-UHFFFAOYSA-N 0.000 description 1
- 229910001981 cobalt nitrate Inorganic materials 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 239000012141 concentrate Substances 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 238000009223 counseling Methods 0.000 description 1
- 238000005520 cutting process Methods 0.000 description 1
- 150000004675 formic acid derivatives Chemical class 0.000 description 1
- FAHBNUUHRFUEAI-UHFFFAOYSA-M hydroxidooxidoaluminium Chemical compound O[Al]=O FAHBNUUHRFUEAI-UHFFFAOYSA-M 0.000 description 1
- 238000011065 in-situ storage Methods 0.000 description 1
- 239000011261 inert gas Substances 0.000 description 1
- 230000000977 initiatory effect Effects 0.000 description 1
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 229910052750 molybdenum Inorganic materials 0.000 description 1
- 239000011733 molybdenum Substances 0.000 description 1
- 150000002823 nitrates Chemical class 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 230000000737 periodic effect Effects 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 239000002244 precipitate Substances 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- 229910001388 sodium aluminate Inorganic materials 0.000 description 1
- 235000011121 sodium hydroxide Nutrition 0.000 description 1
- 239000008279 sol Substances 0.000 description 1
- 238000007711 solidification Methods 0.000 description 1
- 230000008023 solidification Effects 0.000 description 1
- 239000007858 starting material Substances 0.000 description 1
- 150000003464 sulfur compounds Chemical class 0.000 description 1
- 150000003467 sulfuric acid derivatives Chemical class 0.000 description 1
- 229910052723 transition metal Inorganic materials 0.000 description 1
- 150000003624 transition metals Chemical class 0.000 description 1
- PBYZMCDFOULPGH-UHFFFAOYSA-N tungstate Chemical compound [O-][W]([O-])(=O)=O PBYZMCDFOULPGH-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/005—Spinels
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
- B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- B01J23/85—Chromium, molybdenum or tungsten
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
- C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
- C01B3/06—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of inorganic compounds containing electro-positively bound hydrogen, e.g. water, acids, bases, ammonia, with inorganic reducing agents
- C01B3/12—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of inorganic compounds containing electro-positively bound hydrogen, e.g. water, acids, bases, ammonia, with inorganic reducing agents by reaction of water vapour with carbon monoxide
- C01B3/16—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of inorganic compounds containing electro-positively bound hydrogen, e.g. water, acids, bases, ammonia, with inorganic reducing agents by reaction of water vapour with carbon monoxide using catalysts
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10K—PURIFYING OR MODIFYING THE CHEMICAL COMPOSITION OF COMBUSTIBLE GASES CONTAINING CARBON MONOXIDE
- C10K3/00—Modifying the chemical composition of combustible gases containing carbon monoxide to produce an improved fuel, e.g. one of different calorific value, which may be free from carbon monoxide
- C10K3/02—Modifying the chemical composition of combustible gases containing carbon monoxide to produce an improved fuel, e.g. one of different calorific value, which may be free from carbon monoxide by catalytic treatment
- C10K3/04—Modifying the chemical composition of combustible gases containing carbon monoxide to produce an improved fuel, e.g. one of different calorific value, which may be free from carbon monoxide by catalytic treatment reducing the carbon monoxide content, e.g. water-gas shift [WGS]
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/02—Impregnation, coating or precipitation
- B01J37/0201—Impregnation
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/50—Improvements relating to the production of bulk chemicals
- Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S502/00—Catalyst, solid sorbent, or support therefor: product or process of making
- Y10S502/524—Spinel
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Organic Chemistry (AREA)
- Combustion & Propulsion (AREA)
- Materials Engineering (AREA)
- General Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Health & Medical Sciences (AREA)
- General Health & Medical Sciences (AREA)
- Inorganic Chemistry (AREA)
- Catalysts (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DEB0092090 | 1967-04-15 |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| DE1667386A1 DE1667386A1 (de) | 1971-06-09 |
| DE1667386B2 DE1667386B2 (de) | 1975-04-30 |
| DE1667386C3 true DE1667386C3 (de) | 1975-12-11 |
Family
ID=6986195
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE1667386A Expired DE1667386C3 (de) | 1967-04-15 | 1967-04-15 | Verfahren zur Herstellung von Wasserstoff und Kohlendioxid durch katalytische Umsetzung von Kohlenmonoxid mit Wasserdampf |
Country Status (8)
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0096322A3 (en) * | 1982-06-08 | 1984-10-10 | Basf Aktiengesellschaft | Catalyst for the conversion of carbon monoxide and steam into sulfur-containing gases, process for the preparation of the catalyst and its use |
Families Citing this family (25)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB1281051A (en) * | 1968-06-18 | 1972-07-12 | Exxon Research Engineering Co | Low temperature shift reaction involving an alkali metal compound and a hydrogenation dehydrogenation component |
| BE758677A (fr) * | 1969-11-10 | 1971-05-10 | Exxon Research Engineering Co | Nouveau catalyseur pour la production de l'hydrogene par deplacement dugaz a l'eau |
| US3922337A (en) * | 1970-07-22 | 1975-11-25 | Ici Ltd | Hydrogen |
| US3974096A (en) * | 1972-03-16 | 1976-08-10 | Exxon Research And Engineering Company | Water gas shift catalyst |
| US4054644A (en) * | 1972-03-16 | 1977-10-18 | Exxon Research & Engineering Co. | Water gas shift process |
| NL175835B (nl) * | 1973-04-17 | 1984-08-01 | Shell Int Research | Werkwijze ter bereiding van een waterstofrijk gas uit een koolmonoxyde-bevattend gas met behulp van een nikkel en/of kobalt en molybdeen bevattende katalysator. |
| US4233180A (en) * | 1978-11-13 | 1980-11-11 | United Catalysts Inc. | Process for the conversion of carbon monoxide |
| US4604275A (en) * | 1980-10-24 | 1986-08-05 | National Distillers And Chemical Corporation | Selective catalytic oxidation of carbon monoxide in hydrocarbon stream to carbon dioxide |
| US4626521A (en) * | 1980-10-24 | 1986-12-02 | National Distillers And Chemical Corporation | Selective catalytic oxidation of carbon monoxide in hydrocarbon stream to carbon dioxide |
| US4452854A (en) * | 1981-04-14 | 1984-06-05 | United Catalysts, Inc. | Catalyst and process for carbon monoxide conversion in sour gas |
| US4389335A (en) * | 1981-04-14 | 1983-06-21 | United Catalysts Inc. | Catalyst for carbon monoxide conversion in sour gas |
| DE3318131A1 (de) * | 1983-05-18 | 1984-11-22 | Süd-Chemie AG, 8000 München | Eisenoxid-chromoxid-katalysator fuer die hochtemperatur-co-konvertierung |
| FR2554433B1 (fr) * | 1983-11-07 | 1986-03-14 | Shell Int Research | Procede de preparation d'un gaz riche en hydrogene |
| NL8402997A (nl) * | 1984-10-01 | 1986-05-01 | Unilever Nv | Katalysator materiaal. |
| US6019954A (en) * | 1994-12-16 | 2000-02-01 | China Petro-Chemical Corp | Catalyst and process for the conversion of carbon monoxide |
| CN101199933B (zh) * | 2006-12-16 | 2012-05-23 | 汤海溶 | 一种多元复合金属氧化物催化剂及其制备方法 |
| US8846564B2 (en) * | 2008-09-29 | 2014-09-30 | Clariant Corporation | Process for sulfiding catalysts for a sour gas shift process |
| GB0919385D0 (en) | 2009-11-05 | 2009-12-23 | Johnson Matthey Plc | Process |
| GB201109376D0 (en) | 2011-06-06 | 2011-07-20 | Johnson Matthey Plc | Water-gas shift catalyst |
| GB201400805D0 (en) | 2014-01-17 | 2014-03-05 | Johnson Matthey Plc | Method of loading a vessel |
| GB201519139D0 (en) | 2015-10-29 | 2015-12-16 | Johnson Matthey Plc | Process |
| UA123999C2 (uk) | 2015-10-29 | 2021-07-07 | Джонсон Метті Паблік Лімітед Компані | Каталізатор конверсії водяного газу |
| GB201519133D0 (en) | 2015-10-29 | 2015-12-16 | Johnson Matthey Plc | Process |
| US20210016258A1 (en) * | 2018-05-11 | 2021-01-21 | Sabic Global Technologies B.V. | Method for producing beta-cobalt molybdenum oxide catalyst having enhanced selectivity for the production of c3-c4 alcohols and catalyst obtained thereby |
| CN112844388B (zh) * | 2021-02-02 | 2022-11-29 | 新地能源工程技术有限公司 | 镁铝尖晶石型复合氧化物载体及其制备方法和蒸汽重整催化剂 |
Family Cites Families (14)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB279128A (en) * | 1926-10-16 | 1929-01-17 | Heinrich Bomke | A method of preparing hydrogen |
| DE630963C (de) * | 1933-06-13 | 1936-06-09 | Giulio Natta | Herstellung von Wasserstoff aus Wassergas |
| US2451041A (en) * | 1944-07-14 | 1948-10-12 | Standard Oil Dev Co | Catalytic cracking and reforming process for the production of aviation gasoline |
| US2459480A (en) * | 1945-08-11 | 1949-01-18 | Standard Oil Dev Co | Method of conditioning a catalyst for use in hydroforming of naphthas |
| US2474214A (en) * | 1946-05-22 | 1949-06-28 | Standard Oil Dev Co | Preparation of zinc aluminate spinel catalyst |
| US2474215A (en) * | 1947-12-31 | 1949-06-28 | Standard Oil Dev Co | Preparation of a zinc aluminategroup vi metal oxide catalyst |
| US2992191A (en) * | 1956-05-24 | 1961-07-11 | Sinclair Refining Co | Catalyst composition and preparation |
| US3061555A (en) * | 1958-12-15 | 1962-10-30 | Nalco Chemical Co | Stabilization of catalysts of molybdena-cobalt oxide on alumina hydrogel carriers |
| US3069250A (en) * | 1959-06-09 | 1962-12-18 | Metallgesellschaft Ag | Process for the conversion of gas produced by pressure gasification |
| US3170758A (en) * | 1960-09-01 | 1965-02-23 | Sinclair Research Inc | Method of purifying exhaust gases |
| NL131801C (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) * | 1964-02-10 | |||
| US3444099A (en) * | 1965-12-23 | 1969-05-13 | Exxon Research Engineering Co | Equilibration and steam-reforming catalysts |
| US3355249A (en) * | 1966-06-29 | 1967-11-28 | Arthur M Squires | Producing hydrogen and power |
| US3388972A (en) * | 1966-12-14 | 1968-06-18 | Catalysts & Chemicals Inc | Low temperature shift reaction catalysts and methods for their preparation |
-
1967
- 1967-04-15 DE DE1667386A patent/DE1667386C3/de not_active Expired
-
1968
- 1968-03-27 CH CH449568A patent/CH487070A/de not_active IP Right Cessation
- 1968-04-10 NL NL6805106.A patent/NL164248C/xx not_active IP Right Cessation
- 1968-04-10 US US720369A patent/US3529935A/en not_active Expired - Lifetime
- 1968-04-10 GB GB07188/68A patent/GB1213343A/en not_active Expired
- 1968-04-11 FR FR1566831D patent/FR1566831A/fr not_active Expired
- 1968-04-12 BE BE713658D patent/BE713658A/xx not_active IP Right Cessation
- 1968-04-12 AT AT363168A patent/AT289031B/de not_active IP Right Cessation
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0096322A3 (en) * | 1982-06-08 | 1984-10-10 | Basf Aktiengesellschaft | Catalyst for the conversion of carbon monoxide and steam into sulfur-containing gases, process for the preparation of the catalyst and its use |
Also Published As
| Publication number | Publication date |
|---|---|
| BE713658A (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) | 1968-10-14 |
| US3529935A (en) | 1970-09-22 |
| NL164248C (nl) | 1980-12-15 |
| NL164248B (nl) | 1980-07-15 |
| AT289031B (de) | 1971-03-25 |
| DE1667386B2 (de) | 1975-04-30 |
| FR1566831A (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) | 1969-05-09 |
| CH487070A (de) | 1970-03-15 |
| DE1667386A1 (de) | 1971-06-09 |
| NL6805106A (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) | 1968-10-16 |
| GB1213343A (en) | 1970-11-25 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C3 | Grant after two publication steps (3rd publication) | ||
| E77 | Valid patent as to the heymanns-index 1977 | ||
| 8330 | Complete disclaimer |