DE1592240B1 - Verfahren zur rueckextraktion von actiniden aus organi schen loesungsmitteln - Google Patents
Verfahren zur rueckextraktion von actiniden aus organi schen loesungsmittelnInfo
- Publication number
- DE1592240B1 DE1592240B1 DE19661592240 DE1592240A DE1592240B1 DE 1592240 B1 DE1592240 B1 DE 1592240B1 DE 19661592240 DE19661592240 DE 19661592240 DE 1592240 A DE1592240 A DE 1592240A DE 1592240 B1 DE1592240 B1 DE 1592240B1
- Authority
- DE
- Germany
- Prior art keywords
- extraction
- plutonium
- nitrous acid
- hno
- aqueous
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
- 238000000605 extraction Methods 0.000 title claims description 42
- 238000000034 method Methods 0.000 title claims description 10
- 239000003960 organic solvent Substances 0.000 title claims description 8
- 229910052768 actinide Inorganic materials 0.000 title claims description 6
- 150000001255 actinides Chemical class 0.000 title claims description 6
- IOVCWXUNBOPUCH-UHFFFAOYSA-N Nitrous acid Chemical group ON=O IOVCWXUNBOPUCH-UHFFFAOYSA-N 0.000 claims description 17
- 239000002904 solvent Substances 0.000 claims description 16
- 229910052778 Plutonium Inorganic materials 0.000 claims description 13
- OYEHPCDNVJXUIW-UHFFFAOYSA-N plutonium atom Chemical compound [Pu] OYEHPCDNVJXUIW-UHFFFAOYSA-N 0.000 claims description 13
- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 claims description 12
- 229910017604 nitric acid Inorganic materials 0.000 claims description 12
- MWUXSHHQAYIFBG-UHFFFAOYSA-N Nitric oxide Chemical compound O=[N] MWUXSHHQAYIFBG-UHFFFAOYSA-N 0.000 claims description 8
- 229910052770 Uranium Inorganic materials 0.000 claims description 8
- JFALSRSLKYAFGM-UHFFFAOYSA-N uranium(0) Chemical compound [U] JFALSRSLKYAFGM-UHFFFAOYSA-N 0.000 claims description 8
- 229910052781 Neptunium Inorganic materials 0.000 claims description 4
- LFNLGNPSGWYGGD-UHFFFAOYSA-N neptunium atom Chemical compound [Np] LFNLGNPSGWYGGD-UHFFFAOYSA-N 0.000 claims description 4
- ZLYXMBXMECZBSN-UHFFFAOYSA-N [Pu+3] Chemical compound [Pu+3] ZLYXMBXMECZBSN-UHFFFAOYSA-N 0.000 claims 1
- 239000003153 chemical reaction reagent Substances 0.000 claims 1
- 238000000354 decomposition reaction Methods 0.000 claims 1
- 239000000243 solution Substances 0.000 description 18
- SNRUBQQJIBEYMU-UHFFFAOYSA-N dodecane Chemical compound CCCCCCCCCCCC SNRUBQQJIBEYMU-UHFFFAOYSA-N 0.000 description 10
- STCOOQWBFONSKY-UHFFFAOYSA-N tributyl phosphate Chemical compound CCCCOP(=O)(OCCCC)OCCCC STCOOQWBFONSKY-UHFFFAOYSA-N 0.000 description 9
- 239000008346 aqueous phase Substances 0.000 description 8
- 238000006073 displacement reaction Methods 0.000 description 7
- 229910052751 metal Inorganic materials 0.000 description 7
- 239000002184 metal Substances 0.000 description 7
- SWZDQOUHBYYPJD-UHFFFAOYSA-N tridodecylamine Chemical compound CCCCCCCCCCCCN(CCCCCCCCCCCC)CCCCCCCCCCCC SWZDQOUHBYYPJD-UHFFFAOYSA-N 0.000 description 7
- 239000007864 aqueous solution Substances 0.000 description 5
- 239000002253 acid Substances 0.000 description 4
- 239000000203 mixture Substances 0.000 description 4
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 3
- 238000006243 chemical reaction Methods 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 150000002739 metals Chemical class 0.000 description 3
- 239000012071 phase Substances 0.000 description 3
- NHNBFGGVMKEFGY-UHFFFAOYSA-N Nitrate Chemical compound [O-][N+]([O-])=O NHNBFGGVMKEFGY-UHFFFAOYSA-N 0.000 description 2
- GQPLMRYTRLFLPF-UHFFFAOYSA-N Nitrous Oxide Chemical compound [O-][N+]#N GQPLMRYTRLFLPF-UHFFFAOYSA-N 0.000 description 2
- 230000009918 complex formation Effects 0.000 description 2
- 238000010790 dilution Methods 0.000 description 2
- 239000012895 dilution Substances 0.000 description 2
- 239000012074 organic phase Substances 0.000 description 2
- 238000005192 partition Methods 0.000 description 2
- XNGIFLGASWRNHJ-UHFFFAOYSA-L phthalate(2-) Chemical compound [O-]C(=O)C1=CC=CC=C1C([O-])=O XNGIFLGASWRNHJ-UHFFFAOYSA-L 0.000 description 2
- LPXPTNMVRIOKMN-UHFFFAOYSA-M sodium nitrite Chemical compound [Na+].[O-]N=O LPXPTNMVRIOKMN-UHFFFAOYSA-M 0.000 description 2
- 239000004215 Carbon black (E152) Substances 0.000 description 1
- CWYNVVGOOAEACU-UHFFFAOYSA-N Fe2+ Chemical compound [Fe+2] CWYNVVGOOAEACU-UHFFFAOYSA-N 0.000 description 1
- 229910002651 NO3 Inorganic materials 0.000 description 1
- NBSLIVIAZBZBFZ-UHFFFAOYSA-N [Np+4] Chemical compound [Np+4] NBSLIVIAZBZBFZ-UHFFFAOYSA-N 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 239000003638 chemical reducing agent Substances 0.000 description 1
- 230000002860 competitive effect Effects 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- -1 dodecane Chemical class 0.000 description 1
- 230000007717 exclusion Effects 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- 230000007062 hydrolysis Effects 0.000 description 1
- 238000006460 hydrolysis reaction Methods 0.000 description 1
- 239000012442 inert solvent Substances 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- 229910001960 metal nitrate Inorganic materials 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 150000002823 nitrates Chemical class 0.000 description 1
- ZQPKENGPMDNVKK-UHFFFAOYSA-N nitric acid;plutonium Chemical compound [Pu].O[N+]([O-])=O ZQPKENGPMDNVKK-UHFFFAOYSA-N 0.000 description 1
- 239000001272 nitrous oxide Substances 0.000 description 1
- 239000007800 oxidant agent Substances 0.000 description 1
- 230000001590 oxidative effect Effects 0.000 description 1
- 150000002978 peroxides Chemical class 0.000 description 1
- 238000001556 precipitation Methods 0.000 description 1
- 238000000746 purification Methods 0.000 description 1
- 230000001603 reducing effect Effects 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- 235000010288 sodium nitrite Nutrition 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- AAORDHMTTHGXCV-UHFFFAOYSA-N uranium(6+) Chemical compound [U+6] AAORDHMTTHGXCV-UHFFFAOYSA-N 0.000 description 1
- 229910002007 uranyl nitrate Inorganic materials 0.000 description 1
Classifications
-
- G—PHYSICS
- G21—NUCLEAR PHYSICS; NUCLEAR ENGINEERING
- G21C—NUCLEAR REACTORS
- G21C19/00—Arrangements for treating, for handling, or for facilitating the handling of, fuel or other materials which are used within the reactor, e.g. within its pressure vessel
- G21C19/42—Reprocessing of irradiated fuel
- G21C19/44—Reprocessing of irradiated fuel of irradiated solid fuel
- G21C19/46—Aqueous processes, e.g. by using organic extraction means, including the regeneration of these means
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
- C01G56/00—Compounds of transuranic elements
- C01G56/001—Preparation involving a liquid-liquid extraction, an adsorption or an ion-exchange
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B60/00—Obtaining metals of atomic number 87 or higher, i.e. radioactive metals
- C22B60/02—Obtaining thorium, uranium, or other actinides
- C22B60/0204—Obtaining thorium, uranium, or other actinides obtaining uranium
- C22B60/0217—Obtaining thorium, uranium, or other actinides obtaining uranium by wet processes
- C22B60/0252—Obtaining thorium, uranium, or other actinides obtaining uranium by wet processes treatment or purification of solutions or of liquors or of slurries
- C22B60/026—Obtaining thorium, uranium, or other actinides obtaining uranium by wet processes treatment or purification of solutions or of liquors or of slurries liquid-liquid extraction with or without dissolution in organic solvents
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B60/00—Obtaining metals of atomic number 87 or higher, i.e. radioactive metals
- C22B60/02—Obtaining thorium, uranium, or other actinides
- C22B60/0295—Obtaining thorium, uranium, or other actinides obtaining other actinides except plutonium
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B60/00—Obtaining metals of atomic number 87 or higher, i.e. radioactive metals
- C22B60/02—Obtaining thorium, uranium, or other actinides
- C22B60/04—Obtaining plutonium
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E30/00—Energy generation of nuclear origin
- Y02E30/30—Nuclear fission reactors
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02W—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
- Y02W30/00—Technologies for solid waste management
- Y02W30/50—Reuse, recycling or recovery technologies
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Organic Chemistry (AREA)
- General Life Sciences & Earth Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Mechanical Engineering (AREA)
- Manufacturing & Machinery (AREA)
- Materials Engineering (AREA)
- Geology (AREA)
- Metallurgy (AREA)
- Environmental & Geological Engineering (AREA)
- Physics & Mathematics (AREA)
- Inorganic Chemistry (AREA)
- Plasma & Fusion (AREA)
- General Engineering & Computer Science (AREA)
- High Energy & Nuclear Physics (AREA)
- Extraction Or Liquid Replacement (AREA)
- Inorganic Compounds Of Heavy Metals (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FR31858A FR1469488A (fr) | 1965-09-17 | 1965-09-17 | Procédé de réextraction d'actinides de solvants organiques |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| DE1592240B1 true DE1592240B1 (de) | 1971-07-01 |
Family
ID=8588609
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE19661592240 Withdrawn DE1592240B1 (de) | 1965-09-17 | 1966-09-13 | Verfahren zur rueckextraktion von actiniden aus organi schen loesungsmitteln |
Country Status (11)
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE3345199A1 (de) * | 1983-12-14 | 1985-06-27 | Kernforschungszentrum Karlsruhe Gmbh, 7500 Karlsruhe | Verfahren zur reduktiven plutonium-rueckextraktion aus einer organischen wiederaufarbeitungsloesung in eine waessrige, salpetersaure loesung unter anwendung eines elektrolysestromes |
Families Citing this family (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3450639A (en) * | 1967-02-20 | 1969-06-17 | Commissariat Energie Atomique | Process for the separation of molybdenum from fission product containing solutions |
| JPS5226318B2 (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) * | 1972-10-07 | 1977-07-13 | ||
| DE2838541A1 (de) * | 1977-09-16 | 1979-04-05 | British Nuclear Fuels Ltd | Verfahren zur reinigung einer plutonium enthaltenden phase |
| US4188361A (en) * | 1978-04-12 | 1980-02-12 | Davy International (Oil And Chemicals) Limited | Recovery of uranium values |
| EP0251399A1 (fr) * | 1986-06-23 | 1988-01-07 | "Centre d'Etude de l'Energie Nucléaire", "C.E.N." | Procédé de séparation ou de récupération de plutonium et plutonium ainsi obtenu |
| FR2682523B1 (fr) * | 1992-10-08 | 1994-08-12 | Japan Atomic Energy Res Inst | Methode de separation simultanee de l'uranium, du plutonium et du neptunium d'un combustible nucleaire epuise. |
| CN103714876B (zh) * | 2014-01-06 | 2016-09-14 | 中国原子能科学研究院 | 一种亚硝酸的脱除方法 |
| SE539432C2 (en) | 2015-12-21 | 2017-09-19 | Easymining Sweden Ab | Method and arrangement for recovery of salt |
| RU2765790C1 (ru) * | 2021-04-15 | 2022-02-03 | Российская Федерация, от имени которой выступает Государственная корпорация по атомной энергии "Росатом" | Способ разделения нептуния и плутония в азотнокислых растворах (варианты) |
-
1965
- 1965-09-17 FR FR31858A patent/FR1469488A/fr not_active Expired
-
1966
- 1966-08-30 BE BE686160D patent/BE686160A/fr unknown
- 1966-09-01 GB GB3901566A patent/GB1117385A/en not_active Expired
- 1966-09-04 IL IL2644966A patent/IL26449A/xx unknown
- 1966-09-08 US US57787966 patent/US3359079A/en not_active Expired - Lifetime
- 1966-09-13 DE DE19661592240 patent/DE1592240B1/de not_active Withdrawn
- 1966-09-14 NL NL6612960A patent/NL157060B/xx not_active IP Right Cessation
- 1966-09-15 ES ES331247A patent/ES331247A1/es not_active Expired
- 1966-09-16 LU LU51979A patent/LU51979A1/xx unknown
- 1966-09-16 CH CH1338566A patent/CH464159A/fr unknown
- 1966-09-16 BR BR18292766A patent/BR6682927D0/pt unknown
Non-Patent Citations (1)
| Title |
|---|
| None * |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE3345199A1 (de) * | 1983-12-14 | 1985-06-27 | Kernforschungszentrum Karlsruhe Gmbh, 7500 Karlsruhe | Verfahren zur reduktiven plutonium-rueckextraktion aus einer organischen wiederaufarbeitungsloesung in eine waessrige, salpetersaure loesung unter anwendung eines elektrolysestromes |
Also Published As
| Publication number | Publication date |
|---|---|
| ES331247A1 (es) | 1969-01-01 |
| IL26449A (en) | 1970-07-19 |
| CH464159A (fr) | 1968-10-31 |
| GB1117385A (en) | 1968-06-19 |
| FR1469488A (fr) | 1967-02-17 |
| NL6612960A (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) | 1967-03-20 |
| BR6682927D0 (pt) | 1973-05-03 |
| BE686160A (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) | 1967-02-01 |
| NL157060B (nl) | 1978-06-15 |
| LU51979A1 (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) | 1966-11-16 |
| US3359079A (en) | 1967-12-19 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| E77 | Valid patent as to the heymanns-index 1977 | ||
| 8339 | Ceased/non-payment of the annual fee |