DE1570586A1 - Verfahren zur Herstellung von festen Poly-2-vinylpyridin-N-oxyd - Google Patents
Verfahren zur Herstellung von festen Poly-2-vinylpyridin-N-oxydInfo
- Publication number
- DE1570586A1 DE1570586A1 DE19651570586 DE1570586A DE1570586A1 DE 1570586 A1 DE1570586 A1 DE 1570586A1 DE 19651570586 DE19651570586 DE 19651570586 DE 1570586 A DE1570586 A DE 1570586A DE 1570586 A1 DE1570586 A1 DE 1570586A1
- Authority
- DE
- Germany
- Prior art keywords
- oxide
- vinylpyridine
- poly
- acid
- solution
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- XWRBMHSLXKNRJX-UHFFFAOYSA-N 2-ethenyl-1-oxidopyridin-1-ium Chemical compound [O-][N+]1=CC=CC=C1C=C XWRBMHSLXKNRJX-UHFFFAOYSA-N 0.000 title claims description 23
- 238000000034 method Methods 0.000 title claims description 11
- 239000007787 solid Substances 0.000 title claims description 8
- 238000004519 manufacturing process Methods 0.000 title claims description 4
- 239000000243 solution Substances 0.000 claims description 27
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 claims description 20
- 239000002253 acid Substances 0.000 claims description 17
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 claims description 13
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 claims description 9
- 150000007513 acids Chemical class 0.000 claims description 8
- 238000001556 precipitation Methods 0.000 claims description 8
- 229920005989 resin Polymers 0.000 claims description 7
- 239000011347 resin Substances 0.000 claims description 7
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 claims description 6
- -1 aliphatic alcohols Chemical class 0.000 claims description 6
- 239000007864 aqueous solution Substances 0.000 claims description 3
- 150000002148 esters Chemical class 0.000 claims description 3
- 238000002156 mixing Methods 0.000 claims description 3
- 239000003960 organic solvent Substances 0.000 claims description 3
- 229910000147 aluminium phosphate Inorganic materials 0.000 claims description 2
- 238000010494 dissociation reaction Methods 0.000 claims description 2
- 230000005593 dissociations Effects 0.000 claims description 2
- 150000002170 ethers Chemical class 0.000 claims description 2
- 150000002576 ketones Chemical class 0.000 claims description 2
- 239000002244 precipitate Substances 0.000 claims 1
- 239000000126 substance Substances 0.000 claims 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Natural products CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 12
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 9
- 235000019441 ethanol Nutrition 0.000 description 9
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 description 8
- 239000000843 powder Substances 0.000 description 8
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 6
- 229960004756 ethanol Drugs 0.000 description 5
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 4
- 229960000583 acetic acid Drugs 0.000 description 4
- 230000003647 oxidation Effects 0.000 description 4
- 238000007254 oxidation reaction Methods 0.000 description 4
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 4
- ZWEHNKRNPOVVGH-UHFFFAOYSA-N 2-Butanone Chemical compound CCC(C)=O ZWEHNKRNPOVVGH-UHFFFAOYSA-N 0.000 description 3
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 3
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 description 3
- ZMXDDKWLCZADIW-UHFFFAOYSA-N N,N-Dimethylformamide Chemical compound CN(C)C=O ZMXDDKWLCZADIW-UHFFFAOYSA-N 0.000 description 3
- MUBZPKHOEPUJKR-UHFFFAOYSA-N Oxalic acid Chemical compound OC(=O)C(O)=O MUBZPKHOEPUJKR-UHFFFAOYSA-N 0.000 description 3
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- 238000003756 stirring Methods 0.000 description 3
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 2
- 150000001204 N-oxides Chemical class 0.000 description 2
- 201000010001 Silicosis Diseases 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 2
- 239000003054 catalyst Substances 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- 235000015165 citric acid Nutrition 0.000 description 2
- 238000001035 drying Methods 0.000 description 2
- 239000000945 filler Substances 0.000 description 2
- 238000001914 filtration Methods 0.000 description 2
- 239000012362 glacial acetic acid Substances 0.000 description 2
- 235000011007 phosphoric acid Nutrition 0.000 description 2
- 229910052697 platinum Inorganic materials 0.000 description 2
- 229920002717 polyvinylpyridine Polymers 0.000 description 2
- 235000011118 potassium hydroxide Nutrition 0.000 description 2
- 150000003839 salts Chemical class 0.000 description 2
- 239000002904 solvent Substances 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- KGIGUEBEKRSTEW-UHFFFAOYSA-N 2-vinylpyridine Chemical compound C=CC1=CC=CC=N1 KGIGUEBEKRSTEW-UHFFFAOYSA-N 0.000 description 1
- BVKZGUZCCUSVTD-UHFFFAOYSA-M Bicarbonate Chemical compound OC([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-M 0.000 description 1
- FEWJPZIEWOKRBE-JCYAYHJZSA-N Dextrotartaric acid Chemical compound OC(=O)[C@H](O)[C@@H](O)C(O)=O FEWJPZIEWOKRBE-JCYAYHJZSA-N 0.000 description 1
- JUJWROOIHBZHMG-UHFFFAOYSA-N Pyridine Chemical group C1=CC=NC=C1 JUJWROOIHBZHMG-UHFFFAOYSA-N 0.000 description 1
- 241000862969 Stella Species 0.000 description 1
- FEWJPZIEWOKRBE-UHFFFAOYSA-N Tartaric acid Natural products [H+].[H+].[O-]C(=O)C(O)C(O)C([O-])=O FEWJPZIEWOKRBE-UHFFFAOYSA-N 0.000 description 1
- 239000004840 adhesive resin Substances 0.000 description 1
- 229920006223 adhesive resin Polymers 0.000 description 1
- 125000001931 aliphatic group Chemical group 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 239000000356 contaminant Substances 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- 238000002845 discoloration Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 1
- 238000011049 filling Methods 0.000 description 1
- 229940093915 gynecological organic acid Drugs 0.000 description 1
- 238000010255 intramuscular injection Methods 0.000 description 1
- 239000007927 intramuscular injection Substances 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- STZCRXQWRGQSJD-GEEYTBSJSA-M methyl orange Chemical compound [Na+].C1=CC(N(C)C)=CC=C1\N=N\C1=CC=C(S([O-])(=O)=O)C=C1 STZCRXQWRGQSJD-GEEYTBSJSA-M 0.000 description 1
- 229940012189 methyl orange Drugs 0.000 description 1
- 229940032007 methylethyl ketone Drugs 0.000 description 1
- 150000007522 mineralic acids Chemical class 0.000 description 1
- 230000007935 neutral effect Effects 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 125000004433 nitrogen atom Chemical group N* 0.000 description 1
- 231100000252 nontoxic Toxicity 0.000 description 1
- 230000003000 nontoxic effect Effects 0.000 description 1
- 150000007524 organic acids Chemical class 0.000 description 1
- 235000005985 organic acids Nutrition 0.000 description 1
- 238000013021 overheating Methods 0.000 description 1
- 235000006408 oxalic acid Nutrition 0.000 description 1
- 150000002978 peroxides Chemical class 0.000 description 1
- 238000006116 polymerization reaction Methods 0.000 description 1
- 230000001376 precipitating effect Effects 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 238000010254 subcutaneous injection Methods 0.000 description 1
- 239000007929 subcutaneous injection Substances 0.000 description 1
- 235000002906 tartaric acid Nutrition 0.000 description 1
- 239000011975 tartaric acid Substances 0.000 description 1
- 239000004552 water soluble powder Substances 0.000 description 1
- 238000010626 work up procedure Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F6/00—Post-polymerisation treatments
- C08F6/06—Treatment of polymer solutions
- C08F6/12—Separation of polymers from solutions
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F8/00—Chemical modification by after-treatment
- C08F8/06—Oxidation
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Catalysts (AREA)
- Pyridine Compounds (AREA)
- Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DEF0046517 | 1965-07-03 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| DE1570586A1 true DE1570586A1 (de) | 1970-02-05 |
Family
ID=7101077
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE19651570586 Pending DE1570586A1 (de) | 1965-07-03 | 1965-07-03 | Verfahren zur Herstellung von festen Poly-2-vinylpyridin-N-oxyd |
Country Status (6)
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO1994020549A1 (de) * | 1993-03-03 | 1994-09-15 | Basf Aktiengesellschaft | Verfahren zur herstellung von polyvinylpyridin-n-oxiden |
Families Citing this family (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4853461A (en) * | 1988-06-13 | 1989-08-01 | Eastman Kodak Company | Method of isolating copolymers of vinylpyridine and styrene |
| US5906892A (en) * | 1993-08-09 | 1999-05-25 | The Trustees Of Princeton University | Electron acceptor compositions on polymer templates |
| EP2011099A4 (en) | 2006-04-06 | 2013-08-21 | Juniper Networks Inc | SYSTEM AND METHOD FOR DETECTING PROBLEMS FOR MOBILE PLATFORMS WITH LIMITED ACCESS |
| US8026306B2 (en) * | 2007-12-31 | 2011-09-27 | Pitney Bowes Inc. | Red-luminescent ink jet printing compositions and methods for improved waterfastness |
Family Cites Families (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2749349A (en) * | 1956-02-02 | 1956-06-05 | Reilly Tar & Chem Corp | Vinylpyridine-nu-oxides and process of making them |
| US2868797A (en) * | 1958-05-09 | 1959-01-13 | Reilly Tar & Chem Corp | 4-nitropyridine-alkanol, n-oxides |
| US3058959A (en) * | 1959-06-18 | 1962-10-16 | Union Carbide Corp | Acrylate ester-vinyl pyridine n-oxide copolymers |
| US3285892A (en) * | 1963-03-04 | 1966-11-15 | Cabot Corp | Polymerization of vinyl heterocyclic compounds |
-
1965
- 1965-07-03 DE DE19651570586 patent/DE1570586A1/de active Pending
-
1966
- 1966-06-28 CH CH933366A patent/CH476033A/de not_active IP Right Cessation
- 1966-06-30 US US574896A patent/US3501447A/en not_active Expired - Lifetime
- 1966-07-01 BE BE683531D patent/BE683531A/xx unknown
- 1966-07-01 NL NL6609254A patent/NL6609254A/xx unknown
- 1966-07-04 GB GB29934/66A patent/GB1113995A/en not_active Expired
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO1994020549A1 (de) * | 1993-03-03 | 1994-09-15 | Basf Aktiengesellschaft | Verfahren zur herstellung von polyvinylpyridin-n-oxiden |
Also Published As
| Publication number | Publication date |
|---|---|
| US3501447A (en) | 1970-03-17 |
| GB1113995A (en) | 1968-05-15 |
| BE683531A (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) | 1967-01-03 |
| CH476033A (de) | 1969-07-31 |
| NL6609254A (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) | 1967-01-04 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| DE2240782A1 (de) | Verfahren zur herstellung eines eisensaccharid-komplexes | |
| DE3446561A1 (de) | Verfahren zur herstellung von alkalimetallsalzen von polyethoxycarbonsaeuren | |
| DE1570586A1 (de) | Verfahren zur Herstellung von festen Poly-2-vinylpyridin-N-oxyd | |
| DE1300285B (de) | Verfahren zur Herstellung von Polyarylenaethern | |
| DE1119625B (de) | Verfahren zum AEtzen der Oberflaeche eines Halbleiterkoerpers | |
| DE121579C (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) | ||
| DE2360369A1 (de) | Verfahren zur oxydation von monosacchariden | |
| DE938668C (de) | Verfahren zur Herstellung von Aldehyden durch Anlagerung von CO und H an olefinischeKohlenstoffverbindungen | |
| DE891745C (de) | Verfahren zur Herstellung von Polyvinylacetalen | |
| DE888098C (de) | Verfahren zur Herstellung von hellfarbigen sauerstoffhaltigen Verbindungen, insbesondere Aldehyden | |
| DE1177639B (de) | Verfahren zur Herstellung von waessrigen Loesungen komplexer Organosiliciumverbindungen | |
| AT78217B (de) | Verfahren zur Darstellung neuer Zellulosederivate. | |
| DE1445304C (de) | Verfahren zur Aufarbeitung von Niederdruckpolyäthylen-Dispersionen | |
| DE711886C (de) | Verfahren zur Herstellung plastischer Massen | |
| DE511019C (de) | Verfahren zur Verbesserung von Celluloseaethern | |
| DE248885C (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) | ||
| DE694100C (de) | Verfahren zur Gewinnung von Metallverbindungen wasrodukte | |
| DE805720C (de) | Verfahren zur Polymerisation von Methylmethacrylat | |
| DE462994C (de) | Verfahren zur Gewinnung von Essigsaeure | |
| DE189959C (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) | ||
| DE703103C (de) | indungen aus Keratinabbauprodukten | |
| DE257015C (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) | ||
| DE2429425A1 (de) | Verfahren zur gewinnung von propylenoxid | |
| DE658767C (de) | Verfahren zur Herstellung von Alkaliperoxyden | |
| DE726640C (de) | Verfahren zum Regenerieren von Altkautschuk nach dem Alkaliverfahren |