DE1567788C3 - Verfahren zur Herstellung von Chlor aus Chlorwasserstoff - Google Patents
Verfahren zur Herstellung von Chlor aus ChlorwasserstoffInfo
- Publication number
- DE1567788C3 DE1567788C3 DE19651567788 DE1567788A DE1567788C3 DE 1567788 C3 DE1567788 C3 DE 1567788C3 DE 19651567788 DE19651567788 DE 19651567788 DE 1567788 A DE1567788 A DE 1567788A DE 1567788 C3 DE1567788 C3 DE 1567788C3
- Authority
- DE
- Germany
- Prior art keywords
- catalyst
- chlorine
- chloride
- oxygen
- ruthenium
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 title claims description 11
- 239000000460 chlorine Substances 0.000 title claims description 11
- 229910052801 chlorine Inorganic materials 0.000 title claims description 11
- 229910000041 hydrogen chloride Inorganic materials 0.000 title claims description 10
- IXCSERBJSXMMFS-UHFFFAOYSA-N hydrogen chloride Substances Cl.Cl IXCSERBJSXMMFS-UHFFFAOYSA-N 0.000 title claims description 10
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 title claims description 9
- 238000004519 manufacturing process Methods 0.000 title claims description 5
- 238000000034 method Methods 0.000 title claims 9
- 239000003054 catalyst Substances 0.000 claims description 18
- KJTLSVCANCCWHF-UHFFFAOYSA-N Ruthenium Chemical compound [Ru] KJTLSVCANCCWHF-UHFFFAOYSA-N 0.000 claims description 7
- 229910052707 ruthenium Inorganic materials 0.000 claims description 6
- 239000007789 gas Substances 0.000 claims description 5
- 229910052751 metal Inorganic materials 0.000 claims description 5
- 239000002184 metal Substances 0.000 claims description 5
- 238000006243 chemical reaction Methods 0.000 claims description 4
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 claims description 2
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims 8
- 239000001301 oxygen Substances 0.000 claims 8
- 229910052760 oxygen Inorganic materials 0.000 claims 8
- 150000003304 ruthenium compounds Chemical class 0.000 claims 6
- 229930195733 hydrocarbon Natural products 0.000 claims 5
- 150000002430 hydrocarbons Chemical class 0.000 claims 4
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims 3
- 239000010949 copper Substances 0.000 claims 3
- 239000000203 mixture Substances 0.000 claims 3
- 230000003647 oxidation Effects 0.000 claims 3
- 238000007254 oxidation reaction Methods 0.000 claims 3
- 229910052783 alkali metal Inorganic materials 0.000 claims 2
- 150000001340 alkali metals Chemical class 0.000 claims 2
- 239000012876 carrier material Substances 0.000 claims 2
- 125000004435 hydrogen atom Chemical group [H]* 0.000 claims 2
- 239000011148 porous material Substances 0.000 claims 2
- YBCAZPLXEGKKFM-UHFFFAOYSA-K ruthenium(iii) chloride Chemical compound [Cl-].[Cl-].[Cl-].[Ru+3] YBCAZPLXEGKKFM-UHFFFAOYSA-K 0.000 claims 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims 2
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims 1
- 239000005749 Copper compound Substances 0.000 claims 1
- 238000007138 Deacon process reaction Methods 0.000 claims 1
- MYMOFIZGZYHOMD-UHFFFAOYSA-N Dioxygen Chemical compound O=O MYMOFIZGZYHOMD-UHFFFAOYSA-N 0.000 claims 1
- 150000001338 aliphatic hydrocarbons Chemical class 0.000 claims 1
- 229910001514 alkali metal chloride Inorganic materials 0.000 claims 1
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims 1
- 125000003118 aryl group Chemical group 0.000 claims 1
- 229910010293 ceramic material Inorganic materials 0.000 claims 1
- 150000001875 compounds Chemical class 0.000 claims 1
- 229910052802 copper Inorganic materials 0.000 claims 1
- 150000001880 copper compounds Chemical class 0.000 claims 1
- ORTQZVOHEJQUHG-UHFFFAOYSA-L copper(II) chloride Chemical compound Cl[Cu]Cl ORTQZVOHEJQUHG-UHFFFAOYSA-L 0.000 claims 1
- 239000001257 hydrogen Substances 0.000 claims 1
- 229910052739 hydrogen Inorganic materials 0.000 claims 1
- -1 hydrogen chloride hydrocarbons Chemical class 0.000 claims 1
- 229910001510 metal chloride Inorganic materials 0.000 claims 1
- 150000002739 metals Chemical class 0.000 claims 1
- 229910052700 potassium Inorganic materials 0.000 claims 1
- 239000011591 potassium Substances 0.000 claims 1
- 239000008262 pumice Substances 0.000 claims 1
- 229920006395 saturated elastomer Polymers 0.000 claims 1
- 239000000741 silica gel Substances 0.000 claims 1
- 229910002027 silica gel Inorganic materials 0.000 claims 1
- 239000000377 silicon dioxide Substances 0.000 claims 1
- 229910052709 silver Inorganic materials 0.000 claims 1
- 239000004332 silver Substances 0.000 claims 1
- 239000007858 starting material Substances 0.000 claims 1
- 239000004575 stone Substances 0.000 claims 1
- HPGGPRDJHPYFRM-UHFFFAOYSA-J tin(iv) chloride Chemical compound Cl[Sn](Cl)(Cl)Cl HPGGPRDJHPYFRM-UHFFFAOYSA-J 0.000 claims 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B7/00—Halogens; Halogen acids
- C01B7/09—Bromine; Hydrogen bromide
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
- B01J27/06—Halogens; Compounds thereof
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B7/00—Halogens; Halogen acids
- C01B7/01—Chlorine; Hydrogen chloride
- C01B7/03—Preparation from chlorides
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B7/00—Halogens; Halogen acids
- C01B7/01—Chlorine; Hydrogen chloride
- C01B7/03—Preparation from chlorides
- C01B7/04—Preparation of chlorine from hydrogen chloride
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B7/00—Halogens; Halogen acids
- C01B7/13—Iodine; Hydrogen iodide
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Catalysts (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| NL6404460A NL6404460A (enExample) | 1964-04-23 | 1964-04-23 |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| DE1567788A1 DE1567788A1 (de) | 1970-05-27 |
| DE1567788B2 DE1567788B2 (de) | 1973-07-26 |
| DE1567788C3 true DE1567788C3 (de) | 1974-04-18 |
Family
ID=19789904
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE19651567788 Expired DE1567788C3 (de) | 1964-04-23 | 1965-04-21 | Verfahren zur Herstellung von Chlor aus Chlorwasserstoff |
Country Status (4)
| Country | Link |
|---|---|
| BE (1) | BE662847A (enExample) |
| DE (1) | DE1567788C3 (enExample) |
| GB (1) | GB1046313A (enExample) |
| NL (1) | NL6404460A (enExample) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US8889578B2 (en) | 2008-03-22 | 2014-11-18 | Bayer Materialscience Ag | Processes for regenerating sulfur-poisoned, ruthenium and/or ruthenium compound-containing catalysts |
Families Citing this family (42)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CA2176541A1 (en) * | 1995-05-18 | 1996-11-19 | Takuo Hibi | Process for producing chlorine |
| CN1150127C (zh) * | 1996-08-08 | 2004-05-19 | 住友化学工业株式会社 | 氯的生产方法 |
| US6852667B2 (en) | 1998-02-16 | 2005-02-08 | Sumitomo Chemical Company Limited | Process for producing chlorine |
| PT1506133E (pt) * | 2002-05-15 | 2011-11-10 | Basf Se | Processo para a preparação de cloro a partir de cloreto de hidrogénio |
| DE10244996A1 (de) * | 2002-09-26 | 2004-04-01 | Basf Ag | Katalysator für die katalytische Chlorwasserstoff-Oxidation |
| DE102005040286A1 (de) | 2005-08-25 | 2007-03-01 | Basf Ag | Mechanisch stabiler Katalysator auf Basis von alpha-Aluminiumoxid |
| DE102005061954A1 (de) | 2005-12-23 | 2007-07-05 | Basf Ag | Verfahren zur Wiedergewinnung von Ruthenium aus gebrauchten Rutheniumoxid-haltigen Katalysatoren |
| DE102006023261A1 (de) | 2006-05-18 | 2007-11-22 | Bayer Materialscience Ag | Verfahren zur Herstellung von Chlor aus Chlorwasserstoff und Sauerstoff |
| DE102007020154A1 (de) * | 2006-05-23 | 2007-11-29 | Bayer Materialscience Ag | Verfahren zur Herstellung von Chlor durch Gasphasenoxidation |
| DE102006024542A1 (de) | 2006-05-23 | 2007-11-29 | Bayer Materialscience Ag | Verfahren zur Abtrennung von Kohlenmonoxid aus einem chlorwasserstoffhaltigen Gas |
| DE102007020096A1 (de) | 2007-04-26 | 2008-10-30 | Bayer Materialscience Ag | Verfahren zur Oxidation von Kohlenmonoxid in einem HCI enthaltenden Gasstrom |
| DE102007020146A1 (de) | 2007-04-26 | 2008-10-30 | Bayer Materialscience Ag | Verfahren zur Reinigung und Oxidation eines Chlorwasserstoff enthaltenden Gases |
| DE102007020142A1 (de) * | 2007-04-26 | 2008-10-30 | Bayer Materialscience Ag | Verfahren zur Rückgewinnung von Ruthenium aus einem rutheniumhaltigen geträgerten Katalysatormaterial |
| DE102007020444A1 (de) | 2007-04-27 | 2008-11-06 | Bayer Materialscience Ag | Verfahren zur Oxidation eines Chlorwasserstoffenthaltenden Gasgemisches |
| DE102007033113A1 (de) | 2007-07-13 | 2009-01-15 | Bayer Technology Services Gmbh | Temperaturstabiler Katalysator für die Chlorwasserstoffgasphasenoxidation |
| DE102007033114A1 (de) | 2007-07-13 | 2009-01-15 | Bayer Technology Services Gmbh | Verfahren zur Herstellung von Chlor durch Gasphasenoxidation von Chlorwasserstoff |
| US7985395B2 (en) | 2007-07-13 | 2011-07-26 | Bayer Technology Services Gmbh | Thermally stable catalyst for hydrogen chloride gas phase oxidation |
| DE102008038032A1 (de) | 2008-08-16 | 2010-02-18 | Bayer Materialscience Ag | Katalytische Oxidation von Chlorwasserstoff mit Sauerstoff im nichtthermischen Plasma |
| DE102008038096A1 (de) | 2008-08-16 | 2010-02-18 | Bayer Materialscience Ag | Katalytische Oxidation von Chlorwasserstoff mit Ozon |
| DE102008050975A1 (de) | 2008-10-09 | 2010-04-15 | Bayer Technology Services Gmbh | Mehrstufiges Verfahren zur Herstellung von Chlor |
| DE102008051694A1 (de) | 2008-10-15 | 2010-04-22 | Bayer Materialscience Ag | Verfahren zur Abtrennung von Kohlenmonoxid aus einem HCI-Rohgas |
| DE102008052012A1 (de) | 2008-10-17 | 2010-04-22 | Bayer Materialscience Ag | Katalysator und Verfahren zur Herstellung von Chlor durch Gasphasenoxidation |
| DE102008063725A1 (de) | 2008-12-18 | 2010-06-24 | Bayer Materialscience Ag | Katalytische Oxidation von Chlorwasserstoff mit Sauerstoff im nichtthermischen Plasma |
| US20110268649A1 (en) | 2008-12-30 | 2011-11-03 | Basf Se | Catalyst comprising ruthenium and nickel for the oxidation of hydrogen chloride |
| KR101663334B1 (ko) | 2008-12-30 | 2016-10-06 | 바스프 에스이 | 사용된 산화루테늄 포함 촉매로부터 루테늄을 회수하는 방법 |
| WO2010097424A2 (de) | 2009-02-26 | 2010-09-02 | Basf Se | Katalysator für die chlorwasserstoffoxidation enthaltend ruthenium und silber und/oder calcium |
| DE102009021675A1 (de) | 2009-05-16 | 2010-11-18 | Bayer Technology Services Gmbh | Verfahren zur Herstellung von Chlor durch Gasphasenoxidation von Chlorwasserstoff in Gegenwart eines Ceroxid-Katalysators |
| DE102009033640A1 (de) | 2009-07-17 | 2011-03-03 | Bayer Technology Services Gmbh | Verfahren zur Herstellung von Chlor durch Gasphasenoxidation von Chlorwasserstoff in Anwesenheit von Schwefeloxiden |
| DE102009034773A1 (de) | 2009-07-25 | 2011-01-27 | Bayer Materialscience Ag | Verfahren zur Herstellung von Chlor durch Gasphasenoxidation an nanostrukturierten Rutheniumträgerkatalysatoren |
| US20120134913A1 (en) | 2009-08-05 | 2012-05-31 | Basf Se | Method for producing chlorine by gas phase oxidation of hydrogen chloride in a fluidized-bed reactor |
| EP2361682A1 (en) | 2010-02-23 | 2011-08-31 | Bayer MaterialScience AG | Catalyst for chlorine production |
| SG174715A1 (en) | 2010-03-30 | 2011-10-28 | Bayer Materialscience Ag | Process for preparing diaryl carbonates and polycarbonates |
| DE102010039735A1 (de) | 2010-08-25 | 2012-03-01 | Bayer Materialscience Aktiengesellschaft | Katalysator und Verfahren zur Herstellung von Chlor durch Gasphasenoxidation |
| DE102010039734A1 (de) | 2010-08-25 | 2012-03-01 | Bayer Materialscience Aktiengesellschaft | Katalysator und Verfahren zur Herstellung von Chlor durch Gasphasenoxidation |
| US20140241976A1 (en) | 2011-07-05 | 2014-08-28 | Bayer Intellectual Property Gmbh | Process for the production of chlorine using a cerium oxide catalyst in an isothermic reactor |
| KR20140048956A (ko) | 2011-07-05 | 2014-04-24 | 바이엘 인텔렉쳐 프로퍼티 게엠베하 | 단열 반응 캐스케이드에서 산화세륨 촉매를 사용한 염소의 제조 방법 |
| CN103889568B (zh) | 2011-10-24 | 2017-04-19 | 科思创德国股份有限公司 | 用于通过气相氧化制备氯的催化剂和方法 |
| EP3403723A1 (de) | 2017-05-19 | 2018-11-21 | Covestro Deutschland AG | Verfahren zur regeneration eines vergifteten, ruthenium oder rutheniumverbindungen enthaltenden katalysators |
| EP3421416A1 (de) | 2017-06-29 | 2019-01-02 | Covestro Deutschland AG | Photokatalytische oxidation von chlorwasserstoff mit kohlenstoffmonoxid |
| EP3670444A1 (de) | 2018-12-18 | 2020-06-24 | Covestro Deutschland AG | Photokatalytische oxidation von salzsäure mit sauerstoff |
| US11072528B2 (en) * | 2019-04-22 | 2021-07-27 | Fei Company | Halogen generator |
| WO2021198479A1 (en) | 2020-04-03 | 2021-10-07 | Total Se | Production of light olefins via oxychlorination |
-
1964
- 1964-04-23 NL NL6404460A patent/NL6404460A/xx unknown
-
1965
- 1965-04-21 GB GB1677665A patent/GB1046313A/en not_active Expired
- 1965-04-21 BE BE662847D patent/BE662847A/xx unknown
- 1965-04-21 DE DE19651567788 patent/DE1567788C3/de not_active Expired
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US8889578B2 (en) | 2008-03-22 | 2014-11-18 | Bayer Materialscience Ag | Processes for regenerating sulfur-poisoned, ruthenium and/or ruthenium compound-containing catalysts |
Also Published As
| Publication number | Publication date |
|---|---|
| DE1567788A1 (de) | 1970-05-27 |
| BE662847A (enExample) | 1965-10-21 |
| GB1046313A (en) | 1966-10-19 |
| NL6404460A (enExample) | 1965-10-25 |
| DE1567788B2 (de) | 1973-07-26 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C3 | Grant after two publication steps (3rd publication) |