DE1299875B - Verfahren zur Copolymerisation von Vinylchlorid und Vinylcarbazol - Google Patents
Verfahren zur Copolymerisation von Vinylchlorid und VinylcarbazolInfo
- Publication number
- DE1299875B DE1299875B DEC28136A DEC0028136A DE1299875B DE 1299875 B DE1299875 B DE 1299875B DE C28136 A DEC28136 A DE C28136A DE C0028136 A DEC0028136 A DE C0028136A DE 1299875 B DE1299875 B DE 1299875B
- Authority
- DE
- Germany
- Prior art keywords
- vinyl
- hours
- vinyl chloride
- carbazole
- monoamine
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- BZHJMEDXRYGGRV-UHFFFAOYSA-N Vinyl chloride Chemical compound ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 title claims description 23
- KKFHAJHLJHVUDM-UHFFFAOYSA-N n-vinylcarbazole Chemical compound C1=CC=C2N(C=C)C3=CC=CC=C3C2=C1 KKFHAJHLJHVUDM-UHFFFAOYSA-N 0.000 title claims description 20
- 238000000034 method Methods 0.000 title claims description 16
- 238000007334 copolymerization reaction Methods 0.000 title claims description 12
- 229920001577 copolymer Polymers 0.000 claims description 12
- 239000000203 mixture Substances 0.000 claims description 10
- 239000003054 catalyst Substances 0.000 claims description 8
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 claims description 8
- 229920002554 vinyl polymer Polymers 0.000 claims description 8
- 239000000178 monomer Substances 0.000 claims description 7
- UJOBWOGCFQCDNV-UHFFFAOYSA-N 9H-carbazole Chemical compound C1=CC=C2C3=CC=CC=C3NC2=C1 UJOBWOGCFQCDNV-UHFFFAOYSA-N 0.000 claims description 6
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 claims description 6
- LALRXNPLTWZJIJ-UHFFFAOYSA-N triethylborane Chemical group CCB(CC)CC LALRXNPLTWZJIJ-UHFFFAOYSA-N 0.000 claims description 6
- 238000002474 experimental method Methods 0.000 claims description 5
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 5
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 claims description 4
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 claims description 4
- 229910052796 boron Inorganic materials 0.000 claims description 4
- 230000000052 comparative effect Effects 0.000 claims description 4
- 239000000725 suspension Substances 0.000 claims description 4
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 claims description 3
- 229910000831 Steel Inorganic materials 0.000 claims description 3
- 239000000839 emulsion Substances 0.000 claims description 3
- 239000000843 powder Substances 0.000 claims description 3
- 239000010959 steel Substances 0.000 claims description 3
- 238000006243 chemical reaction Methods 0.000 claims description 2
- 238000001816 cooling Methods 0.000 claims description 2
- 238000010438 heat treatment Methods 0.000 claims description 2
- 239000000126 substance Substances 0.000 claims description 2
- JBANFLSTOJPTFW-UHFFFAOYSA-N azane;boron Chemical compound [B].N JBANFLSTOJPTFW-UHFFFAOYSA-N 0.000 claims 5
- 239000000047 product Substances 0.000 claims 3
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims 2
- 239000000460 chlorine Substances 0.000 claims 2
- 229910052801 chlorine Inorganic materials 0.000 claims 2
- 239000011521 glass Substances 0.000 claims 2
- QQZOPKMRPOGIEB-UHFFFAOYSA-N 2-Oxohexane Chemical compound CCCCC(C)=O QQZOPKMRPOGIEB-UHFFFAOYSA-N 0.000 claims 1
- 239000012736 aqueous medium Substances 0.000 claims 1
- 230000003197 catalytic effect Effects 0.000 claims 1
- BNIILDVGGAEEIG-UHFFFAOYSA-L disodium hydrogen phosphate Chemical compound [Na+].[Na+].OP([O-])([O-])=O BNIILDVGGAEEIG-UHFFFAOYSA-L 0.000 claims 1
- 239000003995 emulsifying agent Substances 0.000 claims 1
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 claims 1
- 239000000706 filtrate Substances 0.000 claims 1
- 239000008187 granular material Substances 0.000 claims 1
- 239000004816 latex Substances 0.000 claims 1
- 229920000126 latex Polymers 0.000 claims 1
- 239000007788 liquid Substances 0.000 claims 1
- 238000003760 magnetic stirring Methods 0.000 claims 1
- 229910052757 nitrogen Inorganic materials 0.000 claims 1
- 239000011541 reaction mixture Substances 0.000 claims 1
- 239000007787 solid Substances 0.000 claims 1
- 238000003756 stirring Methods 0.000 claims 1
- ZMPKTELQGVLZTD-UHFFFAOYSA-N tripropylborane Chemical compound CCCB(CCC)CCC ZMPKTELQGVLZTD-UHFFFAOYSA-N 0.000 claims 1
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 4
- 238000006116 polymerization reaction Methods 0.000 description 3
- 229910021529 ammonia Inorganic materials 0.000 description 2
- ZQMIGQNCOMNODD-UHFFFAOYSA-N diacetyl peroxide Chemical compound CC(=O)OOC(C)=O ZQMIGQNCOMNODD-UHFFFAOYSA-N 0.000 description 2
- 229920005862 polyol Polymers 0.000 description 2
- 150000003077 polyols Chemical class 0.000 description 2
- UAHNNBOKPMGCOS-UHFFFAOYSA-N (2-chloroacetyl) 2-chloroethaneperoxoate Chemical compound ClCC(=O)OOC(=O)CCl UAHNNBOKPMGCOS-UHFFFAOYSA-N 0.000 description 1
- 241000158147 Sator Species 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 125000000217 alkyl group Chemical group 0.000 description 1
- -1 alkyl radical Chemical class 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- 238000007872 degassing Methods 0.000 description 1
- 210000003608 fece Anatomy 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 125000004435 hydrogen atom Chemical class [H]* 0.000 description 1
- 239000010871 livestock manure Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 229910001510 metal chloride Inorganic materials 0.000 description 1
- 150000007530 organic bases Chemical class 0.000 description 1
- 230000001590 oxidative effect Effects 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 150000002978 peroxides Chemical class 0.000 description 1
- 238000010926 purge Methods 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F214/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen
- C08F214/02—Monomers containing chlorine
- C08F214/04—Monomers containing two carbon atoms
- C08F214/06—Vinyl chloride
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F14/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen
- C08F14/02—Monomers containing chlorine
- C08F14/04—Monomers containing two carbon atoms
- C08F14/06—Vinyl chloride
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F26/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a single or double bond to nitrogen or by a heterocyclic ring containing nitrogen
- C08F26/06—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a single or double bond to nitrogen or by a heterocyclic ring containing nitrogen by a heterocyclic ring containing nitrogen
- C08F26/12—N-Vinyl-carbazole
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FR830954A FR1268602A (fr) | 1960-06-23 | 1960-06-23 | Perfectionnement à la préparation de polymères et de copolymères à base de chlorure de vinyle |
| BE605181 | 1961-06-20 | ||
| FR875883A FR80489E (fr) | 1960-06-23 | 1961-10-13 | Perfectionnement à la préparation de polymères et de copolymères à base de chlorrue de vinyle |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| DE1299875B true DE1299875B (de) | 1969-07-24 |
Family
ID=27158861
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DEC28136A Pending DE1299875B (de) | 1960-06-23 | 1962-10-10 | Verfahren zur Copolymerisation von Vinylchlorid und Vinylcarbazol |
Country Status (7)
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4515927A (en) * | 1983-03-11 | 1985-05-07 | Gaylord Norman G | Process to copolymerize vinyl chloride and chlorotrifluoroethylene |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| BE562433A (US07816562-20101019-C00007.png) * | 1957-09-06 | |||
| DE664231C (de) * | 1934-07-25 | 1938-08-23 | I G Farbenindustrie Akt Ges | Verfahren zur Herstellung von Polyvinylverbindungen |
| DE1110420B (de) * | 1960-02-02 | 1961-07-06 | Bayer Ag | Verfahren zur Polymerisation ungesaettigter Verbindungen |
Family Cites Families (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2387517A (en) * | 1940-11-08 | 1945-10-23 | Jasco Inc | Process for copolymerization |
| DE1067215B (de) * | 1957-08-02 | 1959-10-15 | Farbenfabriken Bayer Aktiengesellschaft, Leverkusen-Bayerwerk | Verfahren zur Polymerisation von ungesättigten Verbindungen |
| NL109870C (US07816562-20101019-C00007.png) * | 1958-02-03 |
-
0
- NL NL282797D patent/NL282797A/xx unknown
- NL NL263966D patent/NL263966A/xx unknown
- BE BE605181D patent/BE605181A/xx unknown
- NL NL110546D patent/NL110546C/xx active
- NL NL122822D patent/NL122822C/xx active
- BE BE623422D patent/BE623422A/xx unknown
-
1961
- 1961-06-09 US US126756A patent/US3406157A/en not_active Expired - Lifetime
- 1961-06-21 GB GB22500/62A patent/GB947113A/en not_active Expired
- 1961-06-23 CH CH738361A patent/CH392894A/fr unknown
- 1961-10-13 FR FR875883A patent/FR80489E/fr not_active Expired
-
1962
- 1962-09-25 US US226149A patent/US3216984A/en not_active Expired - Lifetime
- 1962-10-01 CH CH1151562A patent/CH405717A/fr unknown
- 1962-10-10 DE DEC28136A patent/DE1299875B/de active Pending
- 1962-10-12 GB GB38379/62A patent/GB993183A/en not_active Expired
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE664231C (de) * | 1934-07-25 | 1938-08-23 | I G Farbenindustrie Akt Ges | Verfahren zur Herstellung von Polyvinylverbindungen |
| BE562433A (US07816562-20101019-C00007.png) * | 1957-09-06 | |||
| DE1110420B (de) * | 1960-02-02 | 1961-07-06 | Bayer Ag | Verfahren zur Polymerisation ungesaettigter Verbindungen |
Also Published As
| Publication number | Publication date |
|---|---|
| US3216984A (en) | 1965-11-09 |
| FR80489E (fr) | 1963-05-03 |
| NL263966A (US07816562-20101019-C00007.png) | |
| CH392894A (fr) | 1965-05-31 |
| CH405717A (fr) | 1966-01-15 |
| US3406157A (en) | 1968-10-15 |
| GB947113A (en) | 1964-01-22 |
| NL122822C (US07816562-20101019-C00007.png) | |
| BE623422A (US07816562-20101019-C00007.png) | |
| BE605181A (US07816562-20101019-C00007.png) | |
| NL282797A (US07816562-20101019-C00007.png) | |
| NL110546C (US07816562-20101019-C00007.png) | |
| GB993183A (en) | 1965-05-26 |
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