DE1238667B - Verfahren zur Herstellung von Polymeren von Vinylverbindungen - Google Patents
Verfahren zur Herstellung von Polymeren von VinylverbindungenInfo
- Publication number
- DE1238667B DE1238667B DEM60666A DEM0060666A DE1238667B DE 1238667 B DE1238667 B DE 1238667B DE M60666 A DEM60666 A DE M60666A DE M0060666 A DEM0060666 A DE M0060666A DE 1238667 B DE1238667 B DE 1238667B
- Authority
- DE
- Germany
- Prior art keywords
- compounds
- polymers
- metals
- catalysts
- compound
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 229920000642 polymer Polymers 0.000 title claims description 16
- 238000000034 method Methods 0.000 title claims description 8
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 title claims description 4
- 238000002360 preparation method Methods 0.000 title description 2
- 229910052751 metal Inorganic materials 0.000 claims description 10
- 239000002184 metal Substances 0.000 claims description 10
- 239000003054 catalyst Substances 0.000 claims description 8
- 150000002902 organometallic compounds Chemical class 0.000 claims description 8
- 150000002739 metals Chemical class 0.000 claims description 7
- 239000007795 chemical reaction product Substances 0.000 claims description 6
- 150000001875 compounds Chemical class 0.000 claims description 6
- 238000004519 manufacturing process Methods 0.000 claims description 5
- 150000003623 transition metal compounds Chemical class 0.000 claims description 5
- 229910052736 halogen Chemical group 0.000 claims description 3
- 150000002367 halogens Chemical group 0.000 claims description 3
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 claims description 2
- 125000000217 alkyl group Chemical group 0.000 claims description 2
- 125000003710 aryl alkyl group Chemical group 0.000 claims description 2
- 125000003118 aryl group Chemical group 0.000 claims description 2
- 229910052793 cadmium Inorganic materials 0.000 claims description 2
- BDOSMKKIYDKNTQ-UHFFFAOYSA-N cadmium atom Chemical compound [Cd] BDOSMKKIYDKNTQ-UHFFFAOYSA-N 0.000 claims description 2
- RCTYPNKXASFOBE-UHFFFAOYSA-M chloromercury Chemical compound [Hg]Cl RCTYPNKXASFOBE-UHFFFAOYSA-M 0.000 claims description 2
- 239000012442 inert solvent Substances 0.000 claims description 2
- 229910001510 metal chloride Inorganic materials 0.000 claims description 2
- 230000000737 periodic effect Effects 0.000 claims description 2
- 229910052725 zinc Inorganic materials 0.000 claims description 2
- 239000011701 zinc Substances 0.000 claims description 2
- IMNFDUFMRHMDMM-UHFFFAOYSA-N N-Heptane Chemical compound CCCCCCC IMNFDUFMRHMDMM-UHFFFAOYSA-N 0.000 description 26
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 8
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 8
- 238000006116 polymerization reaction Methods 0.000 description 8
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 8
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 8
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 6
- 239000001257 hydrogen Substances 0.000 description 5
- 229910052739 hydrogen Inorganic materials 0.000 description 5
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 4
- ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 description 4
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 4
- 239000012259 ether extract Substances 0.000 description 4
- 239000000284 extract Substances 0.000 description 4
- 238000000605 extraction Methods 0.000 description 4
- 229910052757 nitrogen Inorganic materials 0.000 description 4
- 229910010062 TiCl3 Inorganic materials 0.000 description 3
- -1 polypropylene Polymers 0.000 description 3
- YONPGGFAJWQGJC-UHFFFAOYSA-K titanium(iii) chloride Chemical compound Cl[Ti](Cl)Cl YONPGGFAJWQGJC-UHFFFAOYSA-K 0.000 description 3
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 2
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 2
- 229910052782 aluminium Inorganic materials 0.000 description 2
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 2
- YKYOUMDCQGMQQO-UHFFFAOYSA-L cadmium dichloride Chemical compound Cl[Cd]Cl YKYOUMDCQGMQQO-UHFFFAOYSA-L 0.000 description 2
- 230000003197 catalytic effect Effects 0.000 description 2
- 230000007423 decrease Effects 0.000 description 2
- 238000005194 fractionation Methods 0.000 description 2
- 150000004820 halides Chemical class 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- 229920001155 polypropylene Polymers 0.000 description 2
- 239000001294 propane Substances 0.000 description 2
- 229910052708 sodium Inorganic materials 0.000 description 2
- 239000011734 sodium Substances 0.000 description 2
- 229910001220 stainless steel Inorganic materials 0.000 description 2
- 239000010935 stainless steel Substances 0.000 description 2
- 239000004743 Polypropylene Substances 0.000 description 1
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 1
- 229910021551 Vanadium(III) chloride Inorganic materials 0.000 description 1
- 125000001931 aliphatic group Chemical group 0.000 description 1
- 229920006125 amorphous polymer Polymers 0.000 description 1
- 229910052790 beryllium Inorganic materials 0.000 description 1
- VRWRYXRXVZEJKF-UHFFFAOYSA-N beryllium;ethane Chemical compound [Be+2].[CH2-]C.[CH2-]C VRWRYXRXVZEJKF-UHFFFAOYSA-N 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- 229920006158 high molecular weight polymer Polymers 0.000 description 1
- 125000004435 hydrogen atom Chemical group [H]* 0.000 description 1
- 229920001580 isotactic polymer Polymers 0.000 description 1
- 125000002524 organometallic group Chemical group 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- 230000001105 regulatory effect Effects 0.000 description 1
- 238000012721 stereospecific polymerization Methods 0.000 description 1
- CXWXQJXEFPUFDZ-UHFFFAOYSA-N tetralin Chemical compound C1=CC=C2CCCCC2=C1 CXWXQJXEFPUFDZ-UHFFFAOYSA-N 0.000 description 1
- 229910052719 titanium Inorganic materials 0.000 description 1
- 239000010936 titanium Substances 0.000 description 1
- 229910052723 transition metal Inorganic materials 0.000 description 1
- 150000003624 transition metals Chemical class 0.000 description 1
- HQYCOEXWFMFWLR-UHFFFAOYSA-K vanadium(iii) chloride Chemical compound [Cl-].[Cl-].[Cl-].[V+3] HQYCOEXWFMFWLR-UHFFFAOYSA-K 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F110/04—Monomers containing three or four carbon atoms
- C08F110/06—Propene
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| IT1601057 | 1957-11-07 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| DE1238667B true DE1238667B (de) | 1967-04-13 |
Family
ID=11148436
Family Applications (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DEM60666A Pending DE1238667B (de) | 1957-11-07 | 1958-11-06 | Verfahren zur Herstellung von Polymeren von Vinylverbindungen |
| DEM39521A Pending DE1175437B (de) | 1957-11-07 | 1958-11-06 | Verfahren zur Herstellung von Polymeren von Vinylverbindungen |
Family Applications After (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DEM39521A Pending DE1175437B (de) | 1957-11-07 | 1958-11-06 | Verfahren zur Herstellung von Polymeren von Vinylverbindungen |
Country Status (7)
| Country | Link |
|---|---|
| US (1) | US3245973A (en, 2012) |
| BE (1) | BE572726A (en, 2012) |
| CH (1) | CH419613A (en, 2012) |
| DE (2) | DE1238667B (en, 2012) |
| GB (1) | GB890224A (en, 2012) |
| LU (1) | LU36565A1 (en, 2012) |
| NL (2) | NL106899C (en, 2012) |
Families Citing this family (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| BE593590A (en, 2012) * | 1959-07-31 | |||
| NL134018C (en, 2012) * | 1961-05-29 | |||
| BE624600A (en, 2012) * | 1961-10-31 | |||
| US3403140A (en) * | 1964-06-04 | 1968-09-24 | Phillips Petroleum Co | Polymerization process and catalyst |
| US3461083A (en) * | 1965-11-25 | 1969-08-12 | Montedison Spa | Crystalline ticl3 and method of preparing same |
| FR1602517A (en, 2012) * | 1968-08-14 | 1970-12-21 | ||
| US4136058A (en) * | 1977-02-28 | 1979-01-23 | Arco Polymers, Inc. | High efficiency catalysts for olefin polymerization |
| US4308369A (en) * | 1979-09-28 | 1981-12-29 | The Dow Chemical Company | High efficiency catalyst for polymerizing olefins |
Family Cites Families (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE1016022B (de) * | 1954-01-19 | 1957-09-19 | Dr Dr E H Karl Ziegler | Verfahren zur Herstellung von hochmolekularen Polyaethylenen |
| NL206073A (en, 2012) * | 1955-04-07 | 1900-01-01 | Hercules Powder Co Ltd | |
| NL213367A (en, 2012) * | 1955-12-30 | |||
| US2890187A (en) * | 1956-07-11 | 1959-06-09 | Exxon Research Engineering Co | Cured polypropylene |
-
0
- BE BE572726D patent/BE572726A/xx unknown
- NL NL232861D patent/NL232861A/xx unknown
- LU LU36565D patent/LU36565A1/xx unknown
- NL NL106899D patent/NL106899C/xx active
-
1958
- 1958-11-03 GB GB35170/58A patent/GB890224A/en not_active Expired
- 1958-11-03 US US771188A patent/US3245973A/en not_active Expired - Lifetime
- 1958-11-06 DE DEM60666A patent/DE1238667B/de active Pending
- 1958-11-06 CH CH6586658A patent/CH419613A/de unknown
- 1958-11-06 DE DEM39521A patent/DE1175437B/de active Pending
Also Published As
| Publication number | Publication date |
|---|---|
| NL232861A (en, 2012) | |
| BE572726A (en, 2012) | |
| GB890224A (en) | 1962-02-28 |
| LU36565A1 (en, 2012) | |
| NL106899C (en, 2012) | |
| US3245973A (en) | 1966-04-12 |
| CH419613A (de) | 1966-08-31 |
| DE1175437B (de) | 1964-08-06 |
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