DE1223557B - Verfahren zur Herstellung thixotroper Polyvinylester-Latices - Google Patents
Verfahren zur Herstellung thixotroper Polyvinylester-LaticesInfo
- Publication number
- DE1223557B DE1223557B DES83840A DES0083840A DE1223557B DE 1223557 B DE1223557 B DE 1223557B DE S83840 A DES83840 A DE S83840A DE S0083840 A DES0083840 A DE S0083840A DE 1223557 B DE1223557 B DE 1223557B
- Authority
- DE
- Germany
- Prior art keywords
- weight
- parts
- emulsifier
- dispersion
- och
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 238000000034 method Methods 0.000 title claims description 15
- 229920001290 polyvinyl ester Polymers 0.000 title claims description 9
- 229920000126 latex Polymers 0.000 title claims description 6
- 238000004519 manufacturing process Methods 0.000 title claims description 5
- 230000009974 thixotropic effect Effects 0.000 title claims description 5
- 239000006185 dispersion Substances 0.000 claims description 28
- 239000003995 emulsifying agent Substances 0.000 claims description 25
- 239000000203 mixture Substances 0.000 claims description 12
- 239000000084 colloidal system Substances 0.000 claims description 8
- 230000001681 protective effect Effects 0.000 claims description 8
- 239000000178 monomer Substances 0.000 claims description 7
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 claims description 5
- 239000004372 Polyvinyl alcohol Substances 0.000 claims description 5
- 229920002451 polyvinyl alcohol Polymers 0.000 claims description 5
- 239000001913 cellulose Substances 0.000 claims description 4
- 229920002678 cellulose Polymers 0.000 claims description 4
- 125000000217 alkyl group Chemical group 0.000 claims description 3
- 125000004432 carbon atom Chemical group C* 0.000 claims description 3
- 229920001567 vinyl ester resin Polymers 0.000 claims description 3
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 claims description 3
- 229910052783 alkali metal Inorganic materials 0.000 claims description 2
- 150000001340 alkali metals Chemical group 0.000 claims description 2
- 150000001875 compounds Chemical class 0.000 claims description 2
- 230000003472 neutralizing effect Effects 0.000 claims description 2
- 230000000379 polymerizing effect Effects 0.000 claims description 2
- 239000003973 paint Substances 0.000 description 15
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 8
- 239000004354 Hydroxyethyl cellulose Substances 0.000 description 7
- 229920000663 Hydroxyethyl cellulose Polymers 0.000 description 7
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 description 7
- 235000019447 hydroxyethyl cellulose Nutrition 0.000 description 7
- ROOXNKNUYICQNP-UHFFFAOYSA-N ammonium persulfate Chemical compound [NH4+].[NH4+].[O-]S(=O)(=O)OOS([O-])(=O)=O ROOXNKNUYICQNP-UHFFFAOYSA-N 0.000 description 6
- CQEYYJKEWSMYFG-UHFFFAOYSA-N butyl acrylate Chemical compound CCCCOC(=O)C=C CQEYYJKEWSMYFG-UHFFFAOYSA-N 0.000 description 6
- 239000000049 pigment Substances 0.000 description 6
- 239000011734 sodium Substances 0.000 description 6
- 238000006116 polymerization reaction Methods 0.000 description 4
- USHAGKDGDHPEEY-UHFFFAOYSA-L potassium persulfate Chemical compound [K+].[K+].[O-]S(=O)(=O)OOS([O-])(=O)=O USHAGKDGDHPEEY-UHFFFAOYSA-L 0.000 description 4
- 239000001488 sodium phosphate Substances 0.000 description 4
- RYFMWSXOAZQYPI-UHFFFAOYSA-K trisodium phosphate Chemical compound [Na+].[Na+].[Na+].[O-]P([O-])([O-])=O RYFMWSXOAZQYPI-UHFFFAOYSA-K 0.000 description 4
- 239000000654 additive Substances 0.000 description 3
- 229910001870 ammonium persulfate Inorganic materials 0.000 description 3
- 238000010586 diagram Methods 0.000 description 3
- 238000007720 emulsion polymerization reaction Methods 0.000 description 3
- 210000003739 neck Anatomy 0.000 description 3
- -1 nonylphenyl Chemical group 0.000 description 3
- 238000010992 reflux Methods 0.000 description 3
- 159000000000 sodium salts Chemical class 0.000 description 3
- 229910000406 trisodium phosphate Inorganic materials 0.000 description 3
- 235000019801 trisodium phosphate Nutrition 0.000 description 3
- 239000002699 waste material Substances 0.000 description 3
- UIIMBOGNXHQVGW-UHFFFAOYSA-M Sodium bicarbonate Chemical compound [Na+].OC([O-])=O UIIMBOGNXHQVGW-UHFFFAOYSA-M 0.000 description 2
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 2
- 238000005299 abrasion Methods 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- 230000007423 decrease Effects 0.000 description 2
- 239000000839 emulsion Substances 0.000 description 2
- BXWNKGSJHAJOGX-UHFFFAOYSA-N hexadecan-1-ol Chemical compound CCCCCCCCCCCCCCCCO BXWNKGSJHAJOGX-UHFFFAOYSA-N 0.000 description 2
- 239000004615 ingredient Substances 0.000 description 2
- 150000003839 salts Chemical class 0.000 description 2
- 238000004062 sedimentation Methods 0.000 description 2
- 150000003467 sulfuric acid derivatives Chemical class 0.000 description 2
- QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 description 1
- 241000270730 Alligator mississippiensis Species 0.000 description 1
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 1
- 235000010624 Medicago sativa Nutrition 0.000 description 1
- 240000004658 Medicago sativa Species 0.000 description 1
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 1
- 239000004159 Potassium persulphate Substances 0.000 description 1
- UIIMBOGNXHQVGW-DEQYMQKBSA-M Sodium bicarbonate-14C Chemical compound [Na+].O[14C]([O-])=O UIIMBOGNXHQVGW-DEQYMQKBSA-M 0.000 description 1
- 150000003863 ammonium salts Chemical class 0.000 description 1
- 229960000541 cetyl alcohol Drugs 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 229920001577 copolymer Polymers 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- 239000004815 dispersion polymer Substances 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 238000000265 homogenisation Methods 0.000 description 1
- 230000007062 hydrolysis Effects 0.000 description 1
- 238000006460 hydrolysis reaction Methods 0.000 description 1
- 230000001771 impaired effect Effects 0.000 description 1
- 239000011256 inorganic filler Substances 0.000 description 1
- 229910003475 inorganic filler Inorganic materials 0.000 description 1
- 239000004816 latex Substances 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 239000012875 nonionic emulsifier Substances 0.000 description 1
- 125000002347 octyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 229940055577 oleyl alcohol Drugs 0.000 description 1
- XMLQWXUVTXCDDL-UHFFFAOYSA-N oleyl alcohol Natural products CCCCCCC=CCCCCCCCCCCO XMLQWXUVTXCDDL-UHFFFAOYSA-N 0.000 description 1
- 125000001117 oleyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])/C([H])=C([H])\C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 238000010422 painting Methods 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 229920002689 polyvinyl acetate Polymers 0.000 description 1
- 239000011118 polyvinyl acetate Substances 0.000 description 1
- 235000019394 potassium persulphate Nutrition 0.000 description 1
- 150000003254 radicals Chemical class 0.000 description 1
- 230000000284 resting effect Effects 0.000 description 1
- 229910000030 sodium bicarbonate Inorganic materials 0.000 description 1
- 235000017557 sodium bicarbonate Nutrition 0.000 description 1
- 229910000162 sodium phosphate Inorganic materials 0.000 description 1
- 235000011008 sodium phosphates Nutrition 0.000 description 1
- 239000004408 titanium dioxide Substances 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
- 229920003176 water-insoluble polymer Polymers 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F283/00—Macromolecular compounds obtained by polymerising monomers on to polymers provided for in subclass C08G
- C08F283/06—Macromolecular compounds obtained by polymerising monomers on to polymers provided for in subclass C08G on to polyethers, polyoxymethylenes or polyacetals
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F18/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an acyloxy radical of a saturated carboxylic acid, of carbonic acid or of a haloformic acid
- C08F18/02—Esters of monocarboxylic acids
- C08F18/04—Vinyl esters
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F218/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an acyloxy radical of a saturated carboxylic acid, of carbonic acid or of a haloformic acid
- C08F218/02—Esters of monocarboxylic acids
- C08F218/04—Vinyl esters
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
- C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
- C08F220/10—Esters
- C08F220/12—Esters of monohydric alcohols or phenols
- C08F220/16—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms
- C08F220/18—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms with acrylic or methacrylic acids
- C08F220/1804—C4-(meth)acrylate, e.g. butyl (meth)acrylate, isobutyl (meth)acrylate or tert-butyl (meth)acrylate
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Paints Or Removers (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Emulsifying, Dispersing, Foam-Producing Or Wetting Agents (AREA)
- Polymerisation Methods In General (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| IT396162 | 1962-02-27 | ||
| IT2304662 | 1962-11-23 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| DE1223557B true DE1223557B (de) | 1966-08-25 |
Family
ID=26325502
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DES83840A Pending DE1223557B (de) | 1962-02-27 | 1963-02-21 | Verfahren zur Herstellung thixotroper Polyvinylester-Latices |
Country Status (7)
| Country | Link |
|---|---|
| US (1) | US3347805A (en, 2012) |
| BE (1) | BE628953A (en, 2012) |
| CH (1) | CH464523A (en, 2012) |
| DE (1) | DE1223557B (en, 2012) |
| DK (1) | DK105561C (en, 2012) |
| GB (1) | GB1034121A (en, 2012) |
| NL (2) | NL289459A (en, 2012) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3516975A (en) * | 1968-10-25 | 1970-06-23 | Gen Tire & Rubber Co | Ethylene-vinyl acetate polymers prepared with polyoxyalkylene compounds |
Families Citing this family (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE1260146B (de) * | 1965-02-12 | 1968-02-01 | Basf Ag | Verfahren zur Herstellung von waessrigen Dispersionen von Vinylesterpolymerisaten oder -copolymerisaten |
| JP3025763B1 (ja) * | 1999-03-04 | 2000-03-27 | 花王株式会社 | 乳化重合用界面活性剤組成物 |
| WO2008054614A1 (en) * | 2006-10-31 | 2008-05-08 | Dow Global Technologies Inc. | Carpet backing composition |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR977296A (fr) * | 1948-11-08 | 1951-03-29 | Belge Produits Chimiques Sa | Perfectionnements aux procédés de polymérisation en émulsion d'esters vinyliqueset autres composés organiques non saturés |
| CH307331A (de) * | 1952-08-25 | 1955-05-31 | Ciba Geigy | Verfahren zur Emulsionspolymerisation von ungesättigten polymerisierbaren Verbindungen. |
| DE1025144B (de) * | 1956-10-10 | 1958-02-27 | Basf Ag | Verfahren zur Herstellung stabiler, schwach schaeumender, waessriger Polymerisatdispersionen |
| US2998400A (en) * | 1958-05-15 | 1961-08-29 | Wyandotte Chemicals Corp | Floc-free polyvinyl acetate emulsions employing polyvinylmethyl ether copolymer as prtective colloid and process of preparation |
| BE603302A (fr) * | 1960-05-03 | 1961-11-03 | Basf Ag | Dispersions de polymeres et procédé pour leur production |
Family Cites Families (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US1970578A (en) * | 1930-11-29 | 1934-08-21 | Ig Farbenindustrie Ag | Assistants for the textile and related industries |
| US3150110A (en) * | 1958-02-14 | 1964-09-22 | Celanese Corp | High gloss latex paints |
| US3154510A (en) * | 1961-08-08 | 1964-10-27 | Fmc Corp | Polyvinyl acetate paints of increased adhesion containing barium compounds |
-
0
- NL NL136303D patent/NL136303C/xx active
- NL NL289459D patent/NL289459A/xx unknown
- BE BE628953D patent/BE628953A/xx unknown
-
1963
- 1963-02-20 GB GB6821/63A patent/GB1034121A/en not_active Expired
- 1963-02-21 DE DES83840A patent/DE1223557B/de active Pending
- 1963-02-21 US US260221A patent/US3347805A/en not_active Expired - Lifetime
- 1963-02-27 CH CH247563A patent/CH464523A/de unknown
- 1963-02-27 DK DK90363AA patent/DK105561C/da active
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR977296A (fr) * | 1948-11-08 | 1951-03-29 | Belge Produits Chimiques Sa | Perfectionnements aux procédés de polymérisation en émulsion d'esters vinyliqueset autres composés organiques non saturés |
| CH307331A (de) * | 1952-08-25 | 1955-05-31 | Ciba Geigy | Verfahren zur Emulsionspolymerisation von ungesättigten polymerisierbaren Verbindungen. |
| DE1025144B (de) * | 1956-10-10 | 1958-02-27 | Basf Ag | Verfahren zur Herstellung stabiler, schwach schaeumender, waessriger Polymerisatdispersionen |
| US2998400A (en) * | 1958-05-15 | 1961-08-29 | Wyandotte Chemicals Corp | Floc-free polyvinyl acetate emulsions employing polyvinylmethyl ether copolymer as prtective colloid and process of preparation |
| BE603302A (fr) * | 1960-05-03 | 1961-11-03 | Basf Ag | Dispersions de polymeres et procédé pour leur production |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3516975A (en) * | 1968-10-25 | 1970-06-23 | Gen Tire & Rubber Co | Ethylene-vinyl acetate polymers prepared with polyoxyalkylene compounds |
Also Published As
| Publication number | Publication date |
|---|---|
| US3347805A (en) | 1967-10-17 |
| NL136303C (en, 2012) | |
| NL289459A (en, 2012) | |
| GB1034121A (en) | 1966-06-29 |
| CH464523A (de) | 1968-10-31 |
| BE628953A (en, 2012) | |
| DK105561C (da) | 1966-10-10 |
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