DE1206148B - Verfahren zur Erhoehung der Festigkeit gegen Schnittausweitung von vulkanisiertem Butadien-Vinylpyridin-Kautschuk - Google Patents
Verfahren zur Erhoehung der Festigkeit gegen Schnittausweitung von vulkanisiertem Butadien-Vinylpyridin-KautschukInfo
- Publication number
- DE1206148B DE1206148B DEU7798A DEU0007798A DE1206148B DE 1206148 B DE1206148 B DE 1206148B DE U7798 A DEU7798 A DE U7798A DE U0007798 A DEU0007798 A DE U0007798A DE 1206148 B DE1206148 B DE 1206148B
- Authority
- DE
- Germany
- Prior art keywords
- rubber
- weight
- minutes
- butadiene
- vinylpyridine
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 229920001971 elastomer Polymers 0.000 title claims description 19
- 239000005060 rubber Substances 0.000 title claims description 19
- 238000000034 method Methods 0.000 title claims description 11
- JIAARYAFYJHUJI-UHFFFAOYSA-L zinc dichloride Chemical compound [Cl-].[Cl-].[Zn+2] JIAARYAFYJHUJI-UHFFFAOYSA-L 0.000 claims description 14
- 238000004073 vulcanization Methods 0.000 claims description 12
- VNDYJBBGRKZCSX-UHFFFAOYSA-L zinc bromide Chemical compound Br[Zn]Br VNDYJBBGRKZCSX-UHFFFAOYSA-L 0.000 claims description 8
- 239000000203 mixture Substances 0.000 claims description 7
- 239000011592 zinc chloride Substances 0.000 claims description 7
- 235000005074 zinc chloride Nutrition 0.000 claims description 7
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 claims description 6
- TWRXJAOTZQYOKJ-UHFFFAOYSA-L Magnesium chloride Chemical compound [Mg+2].[Cl-].[Cl-] TWRXJAOTZQYOKJ-UHFFFAOYSA-L 0.000 claims description 6
- 239000003795 chemical substances by application Substances 0.000 claims description 6
- 229920001577 copolymer Polymers 0.000 claims description 6
- KGIGUEBEKRSTEW-UHFFFAOYSA-N 2-vinylpyridine Chemical class C=CC1=CC=CC=N1 KGIGUEBEKRSTEW-UHFFFAOYSA-N 0.000 claims description 4
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 claims description 4
- 229940102001 zinc bromide Drugs 0.000 claims description 4
- UXVMQQNJUSDDNG-UHFFFAOYSA-L Calcium chloride Chemical compound [Cl-].[Cl-].[Ca+2] UXVMQQNJUSDDNG-UHFFFAOYSA-L 0.000 claims description 3
- 239000001110 calcium chloride Substances 0.000 claims description 3
- 229910001628 calcium chloride Inorganic materials 0.000 claims description 3
- 229910001629 magnesium chloride Inorganic materials 0.000 claims description 3
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 9
- 239000011593 sulfur Substances 0.000 description 9
- 229910052717 sulfur Inorganic materials 0.000 description 9
- 238000013459 approach Methods 0.000 description 8
- 238000005299 abrasion Methods 0.000 description 7
- 229910001507 metal halide Inorganic materials 0.000 description 7
- 150000005309 metal halides Chemical class 0.000 description 7
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 4
- 239000006229 carbon black Substances 0.000 description 4
- 229910001502 inorganic halide Inorganic materials 0.000 description 4
- 239000004014 plasticizer Substances 0.000 description 4
- KFDVPJUYSDEJTH-UHFFFAOYSA-N 4-ethenylpyridine Chemical compound C=CC1=CC=NC=C1 KFDVPJUYSDEJTH-UHFFFAOYSA-N 0.000 description 3
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
- 239000003963 antioxidant agent Substances 0.000 description 3
- 235000006708 antioxidants Nutrition 0.000 description 3
- 150000003839 salts Chemical class 0.000 description 3
- 239000004071 soot Substances 0.000 description 3
- 229920003051 synthetic elastomer Polymers 0.000 description 3
- 239000005061 synthetic rubber Substances 0.000 description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
- VJOWMORERYNYON-UHFFFAOYSA-N 5-ethenyl-2-methylpyridine Chemical compound CC1=CC=C(C=C)C=N1 VJOWMORERYNYON-UHFFFAOYSA-N 0.000 description 2
- 244000043261 Hevea brasiliensis Species 0.000 description 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
- 235000021355 Stearic acid Nutrition 0.000 description 2
- 230000003078 antioxidant effect Effects 0.000 description 2
- 238000005452 bending Methods 0.000 description 2
- MTAZNLWOLGHBHU-UHFFFAOYSA-N butadiene-styrene rubber Chemical compound C=CC=C.C=CC1=CC=CC=C1 MTAZNLWOLGHBHU-UHFFFAOYSA-N 0.000 description 2
- MZGNSEAPZQGJRB-UHFFFAOYSA-N dimethyldithiocarbamic acid Chemical compound CN(C)C(S)=S MZGNSEAPZQGJRB-UHFFFAOYSA-N 0.000 description 2
- 239000000945 filler Substances 0.000 description 2
- 150000004820 halides Chemical class 0.000 description 2
- 229920003052 natural elastomer Polymers 0.000 description 2
- 229920001194 natural rubber Polymers 0.000 description 2
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 2
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 description 2
- 239000008117 stearic acid Substances 0.000 description 2
- 238000010998 test method Methods 0.000 description 2
- 239000011787 zinc oxide Substances 0.000 description 2
- -1 -tert-butyl cresol Chemical compound 0.000 description 1
- YQUDMNIUBTXLSX-UHFFFAOYSA-N 2-ethenyl-5-ethylpyridine Chemical compound CCC1=CC=C(C=C)N=C1 YQUDMNIUBTXLSX-UHFFFAOYSA-N 0.000 description 1
- VMWGBWNAHAUQIO-UHFFFAOYSA-N 2-ethenyl-6-methylpyridine Chemical compound CC1=CC=CC(C=C)=N1 VMWGBWNAHAUQIO-UHFFFAOYSA-N 0.000 description 1
- KXDHJXZQYSOELW-UHFFFAOYSA-M Carbamate Chemical compound NC([O-])=O KXDHJXZQYSOELW-UHFFFAOYSA-M 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- 239000004606 Fillers/Extenders Substances 0.000 description 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical class Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 1
- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical class O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 description 1
- 239000006057 Non-nutritive feed additive Substances 0.000 description 1
- JUJWROOIHBZHMG-UHFFFAOYSA-N Pyridine Chemical group C1=CC=NC=C1 JUJWROOIHBZHMG-UHFFFAOYSA-N 0.000 description 1
- ADHMSYVDAOEEPZ-UHFFFAOYSA-N [dimethylcarbamothioylsulfanyl(phenyl)methyl] n,n-dimethylcarbamodithioate Chemical compound CN(C)C(=S)SC(SC(=S)N(C)C)C1=CC=CC=C1 ADHMSYVDAOEEPZ-UHFFFAOYSA-N 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 230000009918 complex formation Effects 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 229930003836 cresol Natural products 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000011156 evaluation Methods 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 239000006232 furnace black Substances 0.000 description 1
- 229910001504 inorganic chloride Inorganic materials 0.000 description 1
- 229920000126 latex Polymers 0.000 description 1
- 229920005610 lignin Polymers 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 229910017604 nitric acid Chemical class 0.000 description 1
- 150000001451 organic peroxides Chemical class 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 239000012763 reinforcing filler Substances 0.000 description 1
- 238000005096 rolling process Methods 0.000 description 1
- 238000010058 rubber compounding Methods 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
- 150000003751 zinc Chemical class 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/16—Halogen-containing compounds
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B60—VEHICLES IN GENERAL
- B60C—VEHICLE TYRES; TYRE INFLATION; TYRE CHANGING; CONNECTING VALVES TO INFLATABLE ELASTIC BODIES IN GENERAL; DEVICES OR ARRANGEMENTS RELATED TO TYRES
- B60C1/00—Tyres characterised by the chemical composition or the physical arrangement or mixture of the composition
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Tires In General (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US25523A US3087907A (en) | 1960-04-29 | 1960-04-29 | Vinylpyridine copolymer rubber composition containing metallic halide |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| DE1206148B true DE1206148B (de) | 1965-12-02 |
Family
ID=21826576
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DEU7798A Pending DE1206148B (de) | 1960-04-29 | 1961-02-15 | Verfahren zur Erhoehung der Festigkeit gegen Schnittausweitung von vulkanisiertem Butadien-Vinylpyridin-Kautschuk |
Country Status (7)
| Country | Link |
|---|---|
| US (1) | US3087907A (en, 2012) |
| BE (1) | BE602486A (en, 2012) |
| DE (1) | DE1206148B (en, 2012) |
| FR (1) | FR1284266A (en, 2012) |
| GB (1) | GB898239A (en, 2012) |
| LU (1) | LU40016A1 (en, 2012) |
| NL (2) | NL122894C (en, 2012) |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| NL302133A (en, 2012) * | 1963-01-31 | |||
| US3936429A (en) * | 1973-01-30 | 1976-02-03 | Fuji Photo Film Co., Ltd. | Reactive polymer |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2565812A (en) * | 1948-10-18 | 1951-08-28 | Phillips Petroleum Co | Production of rubber products |
Family Cites Families (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2434129A (en) * | 1945-01-17 | 1948-01-06 | Monsanto Chemicals | Vulcanizing butadiene polymers |
| US2473016A (en) * | 1945-01-29 | 1949-06-14 | American Cyanamid Co | Method of reducing cut-growth rate of rubberlike butadienestyrene copolymer |
| US2481810A (en) * | 1948-04-01 | 1949-09-13 | Us Rubber Co | Improving cut growth resistance of butadiene-vinyl pyridine rubbery copolymers |
| US2710287A (en) * | 1953-06-29 | 1955-06-07 | Us Rubber Co | Rubber treatment |
| US2825720A (en) * | 1955-09-27 | 1958-03-04 | Us Rubber Co | Vulcanization of butyl rubber by 2, 6-di(acyloxymethyl)-4-hydrocarbylphenyl acylates |
| US2927099A (en) * | 1956-08-02 | 1960-03-01 | Phillips Petroleum Co | Curing system for vinylpyridine rubbers |
| US3014005A (en) * | 1958-11-25 | 1961-12-19 | Us Rubber Co | Rubber-zinc silicate masterbatch, and process for preparing same |
-
0
- BE BE602486D patent/BE602486A/xx unknown
- NL NL263931D patent/NL263931A/xx unknown
- NL NL122894D patent/NL122894C/xx active
-
1960
- 1960-04-29 US US25523A patent/US3087907A/en not_active Expired - Lifetime
-
1961
- 1961-01-27 GB GB3199/61A patent/GB898239A/en not_active Expired
- 1961-02-15 DE DEU7798A patent/DE1206148B/de active Pending
- 1961-03-16 FR FR855878A patent/FR1284266A/fr not_active Expired
- 1961-04-13 LU LU40016D patent/LU40016A1/xx unknown
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2565812A (en) * | 1948-10-18 | 1951-08-28 | Phillips Petroleum Co | Production of rubber products |
Also Published As
| Publication number | Publication date |
|---|---|
| NL122894C (en, 2012) | |
| NL263931A (en, 2012) | |
| US3087907A (en) | 1963-04-30 |
| BE602486A (en, 2012) | |
| FR1284266A (fr) | 1962-02-09 |
| GB898239A (en) | 1962-06-06 |
| LU40016A1 (en, 2012) | 1961-06-13 |
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