DE1196467B - Verfahren zur Erzeugung von Oxalatueberzuegen erhoehter Schichtdicke auf Metallen - Google Patents
Verfahren zur Erzeugung von Oxalatueberzuegen erhoehter Schichtdicke auf MetallenInfo
- Publication number
- DE1196467B DE1196467B DEF33357A DEF0033357A DE1196467B DE 1196467 B DE1196467 B DE 1196467B DE F33357 A DEF33357 A DE F33357A DE F0033357 A DEF0033357 A DE F0033357A DE 1196467 B DE1196467 B DE 1196467B
- Authority
- DE
- Germany
- Prior art keywords
- acid
- solutions
- contain
- metals
- production
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- MUBZPKHOEPUJKR-UHFFFAOYSA-N Oxalic acid Chemical compound OC(=O)C(O)=O MUBZPKHOEPUJKR-UHFFFAOYSA-N 0.000 title claims description 20
- 238000000576 coating method Methods 0.000 title claims description 10
- 238000000034 method Methods 0.000 title claims description 8
- 229910052751 metal Inorganic materials 0.000 title claims description 7
- 239000002184 metal Substances 0.000 title claims description 7
- 150000002739 metals Chemical class 0.000 title claims description 5
- 238000004519 manufacturing process Methods 0.000 title claims description 4
- 239000002253 acid Substances 0.000 claims description 10
- 229920001577 copolymer Polymers 0.000 claims description 8
- ZTWTYVWXUKTLCP-UHFFFAOYSA-N vinylphosphonic acid Chemical compound OP(O)(=O)C=C ZTWTYVWXUKTLCP-UHFFFAOYSA-N 0.000 claims description 7
- 229910019142 PO4 Inorganic materials 0.000 claims description 6
- 235000021317 phosphate Nutrition 0.000 claims description 6
- 150000003013 phosphoric acid derivatives Chemical class 0.000 claims description 4
- 229920000642 polymer Polymers 0.000 claims description 4
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 claims description 3
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims description 3
- ABLZXFCXXLZCGV-UHFFFAOYSA-N Phosphorous acid Chemical compound OP(O)=O ABLZXFCXXLZCGV-UHFFFAOYSA-N 0.000 claims description 3
- 150000001242 acetic acid derivatives Chemical class 0.000 claims description 3
- 239000012190 activator Substances 0.000 claims description 3
- 150000001336 alkenes Chemical class 0.000 claims description 3
- 238000010348 incorporation Methods 0.000 claims description 3
- 150000002894 organic compounds Chemical class 0.000 claims description 3
- 235000006408 oxalic acid Nutrition 0.000 claims description 3
- 230000001590 oxidative effect Effects 0.000 claims description 3
- 150000003839 salts Chemical class 0.000 claims description 3
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 claims description 2
- 150000001408 amides Chemical class 0.000 claims description 2
- LDHQCZJRKDOVOX-NSCUHMNNSA-N crotonic acid Chemical compound C\C=C\C(O)=O LDHQCZJRKDOVOX-NSCUHMNNSA-N 0.000 claims description 2
- 150000002148 esters Chemical class 0.000 claims description 2
- FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 claims description 2
- 150000002825 nitriles Chemical class 0.000 claims description 2
- LDHQCZJRKDOVOX-UHFFFAOYSA-N trans-crotonic acid Natural products CC=CC(O)=O LDHQCZJRKDOVOX-UHFFFAOYSA-N 0.000 claims description 2
- 229920001567 vinyl ester resin Polymers 0.000 claims description 2
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 claims description 2
- 239000000243 solution Substances 0.000 description 15
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 6
- DHMQDGOQFOQNFH-UHFFFAOYSA-N Glycine Chemical compound NCC(O)=O DHMQDGOQFOQNFH-UHFFFAOYSA-N 0.000 description 6
- UEUXEKPTXMALOB-UHFFFAOYSA-J tetrasodium;2-[2-[bis(carboxylatomethyl)amino]ethyl-(carboxylatomethyl)amino]acetate Chemical compound [Na+].[Na+].[Na+].[Na+].[O-]C(=O)CN(CC([O-])=O)CCN(CC([O-])=O)CC([O-])=O UEUXEKPTXMALOB-UHFFFAOYSA-J 0.000 description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 4
- 239000004471 Glycine Substances 0.000 description 3
- 229910000831 Steel Inorganic materials 0.000 description 3
- 239000000203 mixture Substances 0.000 description 3
- 239000010959 steel Substances 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- BZSXEZOLBIJVQK-UHFFFAOYSA-N 2-methylsulfonylbenzoic acid Chemical compound CS(=O)(=O)C1=CC=CC=C1C(O)=O BZSXEZOLBIJVQK-UHFFFAOYSA-N 0.000 description 2
- KCXVZYZYPLLWCC-UHFFFAOYSA-N EDTA Chemical compound OC(=O)CN(CC(O)=O)CCN(CC(O)=O)CC(O)=O KCXVZYZYPLLWCC-UHFFFAOYSA-N 0.000 description 2
- PIICEJLVQHRZGT-UHFFFAOYSA-N Ethylenediamine Chemical compound NCCN PIICEJLVQHRZGT-UHFFFAOYSA-N 0.000 description 2
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- MVWDJLOUEUAWIE-UHFFFAOYSA-N O=C=O.O=C=O Chemical compound O=C=O.O=C=O MVWDJLOUEUAWIE-UHFFFAOYSA-N 0.000 description 2
- GEVPUGOOGXGPIO-UHFFFAOYSA-N oxalic acid;dihydrate Chemical compound O.O.OC(=O)C(O)=O GEVPUGOOGXGPIO-UHFFFAOYSA-N 0.000 description 2
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 2
- 239000010452 phosphate Substances 0.000 description 2
- 239000011550 stock solution Substances 0.000 description 2
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 1
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 description 1
- 230000002378 acidificating effect Effects 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 230000001464 adherent effect Effects 0.000 description 1
- 229910000318 alkali metal phosphate Inorganic materials 0.000 description 1
- 239000002738 chelating agent Substances 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 230000000536 complexating effect Effects 0.000 description 1
- 239000008139 complexing agent Substances 0.000 description 1
- 238000005237 degreasing agent Methods 0.000 description 1
- 239000013527 degreasing agent Substances 0.000 description 1
- MQIGTIFMSSGUBS-UHFFFAOYSA-N ethenylphosphinic acid Chemical compound OP(=O)C=C MQIGTIFMSSGUBS-UHFFFAOYSA-N 0.000 description 1
- 150000002505 iron Chemical class 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- SURQXAFEQWPFPV-UHFFFAOYSA-L iron(2+) sulfate heptahydrate Chemical compound O.O.O.O.O.O.O.[Fe+2].[O-]S([O-])(=O)=O SURQXAFEQWPFPV-UHFFFAOYSA-L 0.000 description 1
- 229910052700 potassium Inorganic materials 0.000 description 1
- 239000011591 potassium Substances 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C22/00—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals
- C23C22/05—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions
- C23C22/06—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous acidic solutions with pH less than 6
- C23C22/46—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous acidic solutions with pH less than 6 containing oxalates
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M173/00—Lubricating compositions containing more than 10% water
- C10M173/02—Lubricating compositions containing more than 10% water not containing mineral or fatty oils
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C22/00—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals
- C23C22/05—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions
- C23C22/06—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous acidic solutions with pH less than 6
- C23C22/46—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous acidic solutions with pH less than 6 containing oxalates
- C23C22/47—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous acidic solutions with pH less than 6 containing oxalates containing also phosphates
Landscapes
- Chemical & Material Sciences (AREA)
- General Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Chemical Treatment Of Metals (AREA)
- Paints Or Removers (AREA)
Priority Applications (8)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| NL125777D NL125777C (enrdf_load_stackoverflow) | 1961-03-07 | ||
| NL275308D NL275308A (enrdf_load_stackoverflow) | 1961-03-07 | ||
| DEF33357A DE1196467B (de) | 1961-03-07 | 1961-03-07 | Verfahren zur Erzeugung von Oxalatueberzuegen erhoehter Schichtdicke auf Metallen |
| LU41296D LU41296A1 (enrdf_load_stackoverflow) | 1961-03-07 | 1962-02-24 | |
| CH264562A CH411516A (de) | 1961-03-07 | 1962-03-05 | Verfahren zur Erzeugung von Oxalatüberzügen erhöhter Schichtdicke auf Metallen |
| FR890091A FR1316915A (fr) | 1961-03-07 | 1962-03-06 | Procédé de formation de revêtements d'oxalates sur métaux |
| BE614785A BE614785A (fr) | 1961-03-07 | 1962-03-07 | Procédé de formation de revêtements d'oxalates sur métaux |
| GB8839/62A GB941090A (en) | 1961-03-07 | 1962-03-07 | Process for the production of oxalate coatings on metals and solutions therefor |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DEF33357A DE1196467B (de) | 1961-03-07 | 1961-03-07 | Verfahren zur Erzeugung von Oxalatueberzuegen erhoehter Schichtdicke auf Metallen |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| DE1196467B true DE1196467B (de) | 1965-07-08 |
Family
ID=7095058
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DEF33357A Pending DE1196467B (de) | 1961-03-07 | 1961-03-07 | Verfahren zur Erzeugung von Oxalatueberzuegen erhoehter Schichtdicke auf Metallen |
Country Status (6)
| Country | Link |
|---|---|
| BE (1) | BE614785A (enrdf_load_stackoverflow) |
| CH (1) | CH411516A (enrdf_load_stackoverflow) |
| DE (1) | DE1196467B (enrdf_load_stackoverflow) |
| GB (1) | GB941090A (enrdf_load_stackoverflow) |
| LU (1) | LU41296A1 (enrdf_load_stackoverflow) |
| NL (2) | NL125777C (enrdf_load_stackoverflow) |
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4446046A (en) * | 1981-06-17 | 1984-05-01 | Betz Laboratories, Inc. | Poly (alkenyl) phosphonic acid and methods of use thereof |
| US4446028A (en) * | 1982-12-20 | 1984-05-01 | Betz Laboratories, Inc. | Isopropenyl phosphonic acid copolymers used to inhibit scale formation |
| WO2020165035A1 (de) * | 2019-02-14 | 2020-08-20 | Chemetall Gmbh | Vereinfachtes verfahren zur vorbehandlung von metallischen substraten für die kaltumformung und reaktiver schmierstoff hierzu |
| WO2021170706A1 (en) | 2020-02-25 | 2021-09-02 | Chemetall Gmbh | One-step pretreatment method of metallic substrates for metal cold forming |
| WO2021170707A1 (en) | 2020-02-25 | 2021-09-02 | Chemetall Gmbh | One-step pretreatment method of metallic substrates for metal cold forming |
| RU2809687C2 (ru) * | 2019-02-14 | 2023-12-14 | Хеметалл Гмбх | Способ предварительной обработки металлических основ для холодной формовки и химически активное смазывающее вещество для этой цели |
Families Citing this family (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS62174386A (ja) * | 1986-01-27 | 1987-07-31 | Nippon Parkerizing Co Ltd | しゆう酸塩皮膜化成処理液および該処理液によるステンレス鋼材の化成処理方法 |
| EP3828307A1 (de) * | 2019-11-26 | 2021-06-02 | Henkel AG & Co. KGaA | Ressourcenschonendes verfahren zur aktivierung einer metalloberfläche vor einer phosphatierung |
| CN117802498A (zh) * | 2023-12-29 | 2024-04-02 | 首钢集团有限公司 | 复合镀层、复合镀层钢板及其制备方法 |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR1174045A (fr) * | 1957-03-26 | 1959-03-05 | Pechiney | Protection des métaux |
-
0
- NL NL275308D patent/NL275308A/xx unknown
- NL NL125777D patent/NL125777C/xx active
-
1961
- 1961-03-07 DE DEF33357A patent/DE1196467B/de active Pending
-
1962
- 1962-02-24 LU LU41296D patent/LU41296A1/xx unknown
- 1962-03-05 CH CH264562A patent/CH411516A/de unknown
- 1962-03-07 BE BE614785A patent/BE614785A/fr unknown
- 1962-03-07 GB GB8839/62A patent/GB941090A/en not_active Expired
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR1174045A (fr) * | 1957-03-26 | 1959-03-05 | Pechiney | Protection des métaux |
Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4446046A (en) * | 1981-06-17 | 1984-05-01 | Betz Laboratories, Inc. | Poly (alkenyl) phosphonic acid and methods of use thereof |
| US4446028A (en) * | 1982-12-20 | 1984-05-01 | Betz Laboratories, Inc. | Isopropenyl phosphonic acid copolymers used to inhibit scale formation |
| WO2020165035A1 (de) * | 2019-02-14 | 2020-08-20 | Chemetall Gmbh | Vereinfachtes verfahren zur vorbehandlung von metallischen substraten für die kaltumformung und reaktiver schmierstoff hierzu |
| RU2809687C2 (ru) * | 2019-02-14 | 2023-12-14 | Хеметалл Гмбх | Способ предварительной обработки металлических основ для холодной формовки и химически активное смазывающее вещество для этой цели |
| US12139690B2 (en) | 2019-02-14 | 2024-11-12 | Chemetall Gmbh | Simplified method for pretreating metal substrates for cold forming and reactive lubricant therefor |
| WO2021170706A1 (en) | 2020-02-25 | 2021-09-02 | Chemetall Gmbh | One-step pretreatment method of metallic substrates for metal cold forming |
| WO2021170707A1 (en) | 2020-02-25 | 2021-09-02 | Chemetall Gmbh | One-step pretreatment method of metallic substrates for metal cold forming |
Also Published As
| Publication number | Publication date |
|---|---|
| GB941090A (en) | 1963-11-06 |
| NL275308A (enrdf_load_stackoverflow) | |
| BE614785A (fr) | 1962-09-07 |
| LU41296A1 (enrdf_load_stackoverflow) | 1962-04-24 |
| NL125777C (enrdf_load_stackoverflow) | |
| CH411516A (de) | 1966-04-15 |
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