DE1181217B - Verfahren zur Herstellung von Dialkyl-aluminiumhydriden mit Alkylresten mit mehr als2 C-Atomen - Google Patents
Verfahren zur Herstellung von Dialkyl-aluminiumhydriden mit Alkylresten mit mehr als2 C-AtomenInfo
- Publication number
- DE1181217B DE1181217B DEC32444A DEC0032444A DE1181217B DE 1181217 B DE1181217 B DE 1181217B DE C32444 A DEC32444 A DE C32444A DE C0032444 A DEC0032444 A DE C0032444A DE 1181217 B DE1181217 B DE 1181217B
- Authority
- DE
- Germany
- Prior art keywords
- aluminum
- alkyl radicals
- carbon atoms
- production
- dialkyl aluminum
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 238000000034 method Methods 0.000 title claims description 9
- AZDRQVAHHNSJOQ-UHFFFAOYSA-N alumane Chemical class [AlH3] AZDRQVAHHNSJOQ-UHFFFAOYSA-N 0.000 title description 5
- 238000004519 manufacturing process Methods 0.000 title description 4
- 125000004432 carbon atom Chemical group C* 0.000 title description 3
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 42
- 229910052782 aluminium Inorganic materials 0.000 claims description 41
- 229910000838 Al alloy Inorganic materials 0.000 claims description 12
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 7
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims description 7
- 229910052739 hydrogen Inorganic materials 0.000 claims description 7
- 239000001257 hydrogen Substances 0.000 claims description 7
- 239000010936 titanium Substances 0.000 claims description 6
- 229910052719 titanium Inorganic materials 0.000 claims description 6
- 229910052770 Uranium Inorganic materials 0.000 claims description 5
- 229910052735 hafnium Inorganic materials 0.000 claims description 5
- VBJZVLUMGGDVMO-UHFFFAOYSA-N hafnium atom Chemical compound [Hf] VBJZVLUMGGDVMO-UHFFFAOYSA-N 0.000 claims description 5
- 229910052758 niobium Inorganic materials 0.000 claims description 5
- 239000010955 niobium Substances 0.000 claims description 5
- GUCVJGMIXFAOAE-UHFFFAOYSA-N niobium atom Chemical compound [Nb] GUCVJGMIXFAOAE-UHFFFAOYSA-N 0.000 claims description 5
- 229910052706 scandium Inorganic materials 0.000 claims description 5
- SIXSYDAISGFNSX-UHFFFAOYSA-N scandium atom Chemical compound [Sc] SIXSYDAISGFNSX-UHFFFAOYSA-N 0.000 claims description 5
- 229910052720 vanadium Inorganic materials 0.000 claims description 5
- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 claims description 3
- 150000004678 hydrides Chemical class 0.000 claims description 3
- 229910052726 zirconium Inorganic materials 0.000 claims description 3
- 238000002360 preparation method Methods 0.000 claims description 2
- JFALSRSLKYAFGM-UHFFFAOYSA-N uranium(0) Chemical compound [U] JFALSRSLKYAFGM-UHFFFAOYSA-N 0.000 claims 1
- LEONUFNNVUYDNQ-UHFFFAOYSA-N vanadium atom Chemical compound [V] LEONUFNNVUYDNQ-UHFFFAOYSA-N 0.000 claims 1
- 230000003197 catalytic effect Effects 0.000 description 15
- 229910052845 zircon Inorganic materials 0.000 description 7
- GFQYVLUOOAAOGM-UHFFFAOYSA-N zirconium(iv) silicate Chemical compound [Zr+4].[O-][Si]([O-])([O-])[O-] GFQYVLUOOAAOGM-UHFFFAOYSA-N 0.000 description 7
- 229910045601 alloy Inorganic materials 0.000 description 6
- 239000000956 alloy Substances 0.000 description 6
- 150000001875 compounds Chemical class 0.000 description 6
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 4
- 239000007795 chemical reaction product Substances 0.000 description 4
- 238000002474 experimental method Methods 0.000 description 4
- 239000000203 mixture Substances 0.000 description 4
- DNYWZCXLKNTFFI-UHFFFAOYSA-N uranium Chemical compound [U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U] DNYWZCXLKNTFFI-UHFFFAOYSA-N 0.000 description 4
- GPPXJZIENCGNKB-UHFFFAOYSA-N vanadium Chemical compound [V]#[V] GPPXJZIENCGNKB-UHFFFAOYSA-N 0.000 description 4
- 238000006243 chemical reaction Methods 0.000 description 3
- 239000000047 product Substances 0.000 description 3
- 230000009257 reactivity Effects 0.000 description 3
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 2
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 description 2
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 2
- SIPUZPBQZHNSDW-UHFFFAOYSA-N bis(2-methylpropyl)aluminum Chemical compound CC(C)C[Al]CC(C)C SIPUZPBQZHNSDW-UHFFFAOYSA-N 0.000 description 2
- 229910052799 carbon Inorganic materials 0.000 description 2
- 229910052802 copper Inorganic materials 0.000 description 2
- 239000010949 copper Substances 0.000 description 2
- GNPSMYTXIPVJDU-UHFFFAOYSA-N dioctylalumane Chemical compound C(CCCCCCC)[AlH]CCCCCCCC GNPSMYTXIPVJDU-UHFFFAOYSA-N 0.000 description 2
- -1 dipentadecyl aluminum hydride Chemical compound 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 229910052742 iron Inorganic materials 0.000 description 2
- 229910052744 lithium Inorganic materials 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- 239000000843 powder Substances 0.000 description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- 229910052684 Cerium Inorganic materials 0.000 description 1
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 1
- 239000005977 Ethylene Substances 0.000 description 1
- 241001647090 Ponca Species 0.000 description 1
- 229910000831 Steel Inorganic materials 0.000 description 1
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 description 1
- 230000004913 activation Effects 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 125000005234 alkyl aluminium group Chemical group 0.000 description 1
- 229910052788 barium Inorganic materials 0.000 description 1
- DSAJWYNOEDNPEQ-UHFFFAOYSA-N barium atom Chemical compound [Ba] DSAJWYNOEDNPEQ-UHFFFAOYSA-N 0.000 description 1
- 229910002056 binary alloy Inorganic materials 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- ZMIGMASIKSOYAM-UHFFFAOYSA-N cerium Chemical compound [Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce] ZMIGMASIKSOYAM-UHFFFAOYSA-N 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 239000013068 control sample Substances 0.000 description 1
- HJXBDPDUCXORKZ-UHFFFAOYSA-N diethylalumane Chemical compound CC[AlH]CC HJXBDPDUCXORKZ-UHFFFAOYSA-N 0.000 description 1
- 238000005868 electrolysis reaction Methods 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 229910052746 lanthanum Inorganic materials 0.000 description 1
- FZLIPJUXYLNCLC-UHFFFAOYSA-N lanthanum atom Chemical compound [La] FZLIPJUXYLNCLC-UHFFFAOYSA-N 0.000 description 1
- 239000011133 lead Substances 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 229910052759 nickel Inorganic materials 0.000 description 1
- 230000003287 optical effect Effects 0.000 description 1
- 238000003825 pressing Methods 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 239000010935 stainless steel Substances 0.000 description 1
- 229910001220 stainless steel Inorganic materials 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- 239000011135 tin Substances 0.000 description 1
- 229910052718 tin Inorganic materials 0.000 description 1
- 238000012876 topography Methods 0.000 description 1
- MCULRUJILOGHCJ-UHFFFAOYSA-N triisobutylaluminium Chemical compound CC(C)C[Al](CC(C)C)CC(C)C MCULRUJILOGHCJ-UHFFFAOYSA-N 0.000 description 1
- LFXVBWRMVZPLFK-UHFFFAOYSA-N trioctylalumane Chemical compound CCCCCCCC[Al](CCCCCCCC)CCCCCCCC LFXVBWRMVZPLFK-UHFFFAOYSA-N 0.000 description 1
- 230000004580 weight loss Effects 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C21/00—Alloys based on aluminium
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
- B01J31/12—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides
- B01J31/14—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides of aluminium or boron
- B01J31/143—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides of aluminium or boron of aluminium
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F5/00—Compounds containing elements of Groups 3 or 13 of the Periodic Table
- C07F5/06—Aluminium compounds
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F5/00—Compounds containing elements of Groups 3 or 13 of the Periodic Table
- C07F5/06—Aluminium compounds
- C07F5/061—Aluminium compounds with C-aluminium linkage
- C07F5/065—Aluminium compounds with C-aluminium linkage compounds with an Al-H linkage
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Catalysts (AREA)
- Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US78320958A | 1958-12-29 | 1958-12-29 | |
| US58222A US3104252A (en) | 1958-12-29 | 1960-09-26 | Preparation of organoaluminum compounds in the presence of a catalytic amount of ti, zr, nb, v, sc, u, or hf |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| DE1181217B true DE1181217B (de) | 1964-11-12 |
Family
ID=26737371
Family Applications (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DEC32444A Pending DE1181217B (de) | 1958-12-29 | 1961-07-29 | Verfahren zur Herstellung von Dialkyl-aluminiumhydriden mit Alkylresten mit mehr als2 C-Atomen |
| DEC24749A Pending DE1185187B (de) | 1958-12-29 | 1961-07-29 | Verfahren zur Herstellung von aluminiumorganischen Verbindungen |
Family Applications After (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DEC24749A Pending DE1185187B (de) | 1958-12-29 | 1961-07-29 | Verfahren zur Herstellung von aluminiumorganischen Verbindungen |
Country Status (6)
| Country | Link |
|---|---|
| US (1) | US3104252A (fr) |
| BE (2) | BE594988A (fr) |
| DE (2) | DE1181217B (fr) |
| FR (1) | FR1243144A (fr) |
| GB (2) | GB932539A (fr) |
| NL (3) | NL246223A (fr) |
Families Citing this family (25)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3387949A (en) * | 1962-03-30 | 1968-06-11 | Hercules Inc | Preparation of metal hydrides |
| US3387948A (en) * | 1962-03-30 | 1968-06-11 | Hercules Inc | Preparation of alkaline earth metal aluminum hydrides |
| US3373179A (en) * | 1962-09-14 | 1968-03-12 | Continental Oil Co | Method for the manufacture of dialkyl aluminum hydride compounds |
| NL301775A (fr) * | 1962-12-28 | 1900-01-01 | ||
| US3388142A (en) * | 1963-07-12 | 1968-06-11 | Continental Oil Co | Method for producing dialkylaluminum hydride compounds |
| NL127426C (fr) * | 1963-08-30 | |||
| GB1064654A (en) * | 1963-10-02 | 1967-04-05 | Snam Spa | Process for preparing complex aluminium hydrides partly substituted with alcoholate groups and compounds so obtained |
| US3382269A (en) * | 1964-12-30 | 1968-05-07 | Continental Oil Co | Activation of aluminum in preparation of aluminum alkyls |
| US3428664A (en) * | 1965-01-27 | 1969-02-18 | Continental Oil Co | Distillative purification of aluminum alkyl |
| US3429695A (en) * | 1965-10-12 | 1969-02-25 | Ishikawajima Harima Heavy Ind | High strength aluminum alloy and its production method |
| US3505375A (en) * | 1966-11-01 | 1970-04-07 | Ethyl Corp | Process for producing alkyl aluminum compounds |
| US3470223A (en) * | 1967-02-02 | 1969-09-30 | Continental Oil Co | Solids purging from an aluminum alkyl stream |
| US3619181A (en) * | 1968-10-29 | 1971-11-09 | Aluminum Co Of America | Aluminum scandium alloy |
| FR2187928A2 (en) * | 1972-06-09 | 1974-01-18 | Ethyl Corp | Alkylaluminium cpds - from ternary or quaternary alloys contg aluminium,silicon,titanium and iron |
| US3853542A (en) * | 1973-01-08 | 1974-12-10 | Aluminum Co Of America | Process for promoting reactivity of aluminum |
| US3853931A (en) * | 1973-01-15 | 1974-12-10 | Aluminum Co Of America | Production of hydrocarbyl aluminum hydrides |
| US4528176A (en) * | 1982-12-15 | 1985-07-09 | Ethyl Corporation | Sodium aluminum hydride production |
| US4529580A (en) * | 1982-12-15 | 1985-07-16 | Ethyl Corporation | Alkali metal aluminum hydride production |
| US4512966A (en) * | 1983-12-02 | 1985-04-23 | Ethyl Corporation | Hydride production at moderate pressure |
| FR2607522B1 (fr) * | 1986-12-02 | 1992-04-30 | Cegedur | Procede permettant d'augmenter la temperature de recristallisation de l'aluminium et de ses alliages |
| US4882039A (en) * | 1986-12-04 | 1989-11-21 | Mobil Oil Corporation | Catalytic cracking of hydrocarbons with oxygen promoted alkali metal zeolite cracking catalyst |
| US5597529A (en) * | 1994-05-25 | 1997-01-28 | Ashurst Technology Corporation (Ireland Limited) | Aluminum-scandium alloys |
| CN102584879B (zh) * | 2012-01-19 | 2014-05-07 | 营口市向阳催化剂有限责任公司 | 一种三乙基铝的制备方法 |
| CN106467584B (zh) * | 2015-08-21 | 2019-08-20 | 中国石油化工股份有限公司 | 一种用于乙烯聚合的催化剂组分、其制备方法及应用 |
| US11471984B2 (en) | 2018-06-28 | 2022-10-18 | Scandium International Mining Corporation | Control of recrystallization in cold-rolled AlMn(Mg)ScZr sheets for brazing applications |
Family Cites Families (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2900402A (en) * | 1955-03-17 | 1959-08-18 | Monsanto Chemicals | Preparation of aluminum alkyls |
| LU34220A1 (fr) * | 1955-04-01 | |||
| US2787626A (en) * | 1955-06-07 | 1957-04-02 | Ethyl Corp | Manufacture of triethylaluminum |
| US2931722A (en) * | 1956-11-21 | 1960-04-05 | Nat Lead Co | Aluminum-titanium master alloys |
| US2922714A (en) * | 1957-04-03 | 1960-01-26 | Union Carbide Corp | Columbium-tantalum-aluminum alloy |
| BE577477A (fr) * | 1958-04-10 | |||
| AT215426B (de) * | 1958-04-10 | 1961-06-12 | Petrochemicals Ltd | Verfahren zur Herstellung von Aluminiumverbindungen |
| NL121526C (fr) * | 1959-04-16 | 1900-01-01 |
-
0
- BE BE614668D patent/BE614668A/xx unknown
- NL NL265774D patent/NL265774A/xx unknown
- NL NL120205D patent/NL120205C/xx active
- BE BE594988D patent/BE594988A/xx unknown
- NL NL246223D patent/NL246223A/xx unknown
-
1959
- 1959-11-30 GB GB40664/59A patent/GB932539A/en not_active Expired
- 1959-12-11 FR FR812849A patent/FR1243144A/fr not_active Expired
-
1960
- 1960-09-26 US US58222A patent/US3104252A/en not_active Expired - Lifetime
-
1961
- 1961-05-24 GB GB18796/61A patent/GB939824A/en not_active Expired
- 1961-07-29 DE DEC32444A patent/DE1181217B/de active Pending
- 1961-07-29 DE DEC24749A patent/DE1185187B/de active Pending
Also Published As
| Publication number | Publication date |
|---|---|
| GB939824A (en) | 1963-10-16 |
| NL246223A (fr) | |
| DE1185187B (de) | 1965-01-14 |
| BE614668A (fr) | |
| NL120205C (fr) | |
| FR1243144A (fr) | 1960-10-07 |
| GB932539A (en) | 1963-07-31 |
| NL265774A (fr) | |
| US3104252A (en) | 1963-09-17 |
| BE594988A (fr) |
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