GB939824A - Improvements in or relating to the preparation of organoaluminium compounds - Google Patents

Improvements in or relating to the preparation of organoaluminium compounds

Info

Publication number
GB939824A
GB939824A GB18796/61A GB1879661A GB939824A GB 939824 A GB939824 A GB 939824A GB 18796/61 A GB18796/61 A GB 18796/61A GB 1879661 A GB1879661 A GB 1879661A GB 939824 A GB939824 A GB 939824A
Authority
GB
United Kingdom
Prior art keywords
aluminium
elements
proportion
uranium
scandium
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB18796/61A
Inventor
Frederick John Radd
Warren Whitney Woods
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
ConocoPhillips Co
Original Assignee
Continental Oil Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Continental Oil Co filed Critical Continental Oil Co
Publication of GB939824A publication Critical patent/GB939824A/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22C—ALLOYS
    • C22C21/00—Alloys based on aluminium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/12—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides
    • B01J31/14—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides of aluminium or boron
    • B01J31/143—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides of aluminium or boron of aluminium
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F5/00—Compounds containing elements of Groups 3 or 13 of the Periodic Table
    • C07F5/06—Aluminium compounds
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F5/00—Compounds containing elements of Groups 3 or 13 of the Periodic Table
    • C07F5/06—Aluminium compounds
    • C07F5/061—Aluminium compounds with C-aluminium linkage
    • C07F5/065—Aluminium compounds with C-aluminium linkage compounds with an Al-H linkage

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Metallurgy (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)

Abstract

939,824. Organoaluminium compounds. CONTINENTAL OIL CO. May 24, 1961 [Sept. 26, 1960], No. 18796/61. Addition to 932,539. Class 2(3). In a process for preparing compounds of formula R<SP>1</SP>R<SP>2</SP>R<SP>3</SP>A1 in which R<SP>1</SP>, R<SP>2</SP> and R<SP>3</SP> are C 2 to C m alkyl radicals and may be the same or different, and in which R<SP>1</SP> may be hydrogen, which process comprises reacting a trialkyl aluminium compound or an olefin, aluminium and hydrogen at elevated temperature and superatmospheric pressure, the aluminium is replaced by an aluminium alloy containing a major proportion of aluminium and a minor and added proportion of at least one of the elements titanium, zirconium, niobium, vanadium, hafnium, scandium, and uranium : and where the compound to be produced is diethylaluminium hydride, the said alloy contains a minor proportion of at least one of the elements hafnium, scandium and uranium. The alloy may contain at least 98% by weight of aluminium and not more than 2% by weight of at least one of the said elements. The reaction is conducted at a temperature between 80‹ and 200‹C. and at a pressure of between 60 and 350 atmospheres. The mole ratio of aluminium to trialkylaluminium starting material is from 01:1 to to 10: 1 .
GB18796/61A 1958-12-29 1961-05-24 Improvements in or relating to the preparation of organoaluminium compounds Expired GB939824A (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US78320958A 1958-12-29 1958-12-29
US58222A US3104252A (en) 1958-12-29 1960-09-26 Preparation of organoaluminum compounds in the presence of a catalytic amount of ti, zr, nb, v, sc, u, or hf

Publications (1)

Publication Number Publication Date
GB939824A true GB939824A (en) 1963-10-16

Family

ID=26737371

Family Applications (2)

Application Number Title Priority Date Filing Date
GB40664/59A Expired GB932539A (en) 1958-12-29 1959-11-30 Preparation of diethylaluminium hydride
GB18796/61A Expired GB939824A (en) 1958-12-29 1961-05-24 Improvements in or relating to the preparation of organoaluminium compounds

Family Applications Before (1)

Application Number Title Priority Date Filing Date
GB40664/59A Expired GB932539A (en) 1958-12-29 1959-11-30 Preparation of diethylaluminium hydride

Country Status (6)

Country Link
US (1) US3104252A (en)
BE (2) BE594988A (en)
DE (2) DE1181217B (en)
FR (1) FR1243144A (en)
GB (2) GB932539A (en)
NL (3) NL265774A (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102584879A (en) * 2012-01-19 2012-07-18 营口市向阳催化剂有限责任公司 Preparation method of aluminium triethyl

Families Citing this family (24)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3387948A (en) * 1962-03-30 1968-06-11 Hercules Inc Preparation of alkaline earth metal aluminum hydrides
US3387949A (en) * 1962-03-30 1968-06-11 Hercules Inc Preparation of metal hydrides
US3373179A (en) * 1962-09-14 1968-03-12 Continental Oil Co Method for the manufacture of dialkyl aluminum hydride compounds
NL301775A (en) * 1962-12-28 1900-01-01
US3388142A (en) * 1963-07-12 1968-06-11 Continental Oil Co Method for producing dialkylaluminum hydride compounds
NL127426C (en) * 1963-08-30
GB1064654A (en) * 1963-10-02 1967-04-05 Snam Spa Process for preparing complex aluminium hydrides partly substituted with alcoholate groups and compounds so obtained
US3382269A (en) * 1964-12-30 1968-05-07 Continental Oil Co Activation of aluminum in preparation of aluminum alkyls
US3428664A (en) * 1965-01-27 1969-02-18 Continental Oil Co Distillative purification of aluminum alkyl
US3429695A (en) * 1965-10-12 1969-02-25 Ishikawajima Harima Heavy Ind High strength aluminum alloy and its production method
US3505375A (en) * 1966-11-01 1970-04-07 Ethyl Corp Process for producing alkyl aluminum compounds
US3470223A (en) * 1967-02-02 1969-09-30 Continental Oil Co Solids purging from an aluminum alkyl stream
US3619181A (en) * 1968-10-29 1971-11-09 Aluminum Co Of America Aluminum scandium alloy
FR2187928A2 (en) * 1972-06-09 1974-01-18 Ethyl Corp Alkylaluminium cpds - from ternary or quaternary alloys contg aluminium,silicon,titanium and iron
US3853542A (en) * 1973-01-08 1974-12-10 Aluminum Co Of America Process for promoting reactivity of aluminum
US3853931A (en) * 1973-01-15 1974-12-10 Aluminum Co Of America Production of hydrocarbyl aluminum hydrides
US4529580A (en) * 1982-12-15 1985-07-16 Ethyl Corporation Alkali metal aluminum hydride production
US4528176A (en) * 1982-12-15 1985-07-09 Ethyl Corporation Sodium aluminum hydride production
US4512966A (en) * 1983-12-02 1985-04-23 Ethyl Corporation Hydride production at moderate pressure
FR2607522B1 (en) * 1986-12-02 1992-04-30 Cegedur PROCESS FOR INCREASING THE TEMPERATURE OF RECRYSTALLIZATION OF ALUMINUM AND ITS ALLOYS
US4882039A (en) * 1986-12-04 1989-11-21 Mobil Oil Corporation Catalytic cracking of hydrocarbons with oxygen promoted alkali metal zeolite cracking catalyst
US5597529A (en) * 1994-05-25 1997-01-28 Ashurst Technology Corporation (Ireland Limited) Aluminum-scandium alloys
CN106467584B (en) * 2015-08-21 2019-08-20 中国石油化工股份有限公司 A kind of catalytic component, preparation method and application for vinyl polymerization
US11471984B2 (en) 2018-06-28 2022-10-18 Scandium International Mining Corporation Control of recrystallization in cold-rolled AlMn(Mg)ScZr sheets for brazing applications

Family Cites Families (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2900402A (en) * 1955-03-17 1959-08-18 Monsanto Chemicals Preparation of aluminum alkyls
NL109047C (en) * 1955-04-01
US2787626A (en) * 1955-06-07 1957-04-02 Ethyl Corp Manufacture of triethylaluminum
US2931722A (en) * 1956-11-21 1960-04-05 Nat Lead Co Aluminum-titanium master alloys
US2922714A (en) * 1957-04-03 1960-01-26 Union Carbide Corp Columbium-tantalum-aluminum alloy
BE577477A (en) * 1958-04-10
AT215426B (en) * 1958-04-10 1961-06-12 Petrochemicals Ltd Process for the production of aluminum compounds
BE593357A (en) * 1959-04-16 1900-01-01

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102584879A (en) * 2012-01-19 2012-07-18 营口市向阳催化剂有限责任公司 Preparation method of aluminium triethyl
CN102584879B (en) * 2012-01-19 2014-05-07 营口市向阳催化剂有限责任公司 Preparation method of aluminium triethyl

Also Published As

Publication number Publication date
GB932539A (en) 1963-07-31
BE614668A (en)
DE1185187B (en) 1965-01-14
US3104252A (en) 1963-09-17
DE1181217B (en) 1964-11-12
NL120205C (en)
FR1243144A (en) 1960-10-07
NL246223A (en)
NL265774A (en)
BE594988A (en)

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