GB1049035A - Method for manufacturing alkylaluminum compounds - Google Patents
Method for manufacturing alkylaluminum compoundsInfo
- Publication number
- GB1049035A GB1049035A GB25067/64A GB2506764A GB1049035A GB 1049035 A GB1049035 A GB 1049035A GB 25067/64 A GB25067/64 A GB 25067/64A GB 2506764 A GB2506764 A GB 2506764A GB 1049035 A GB1049035 A GB 1049035A
- Authority
- GB
- United Kingdom
- Prior art keywords
- aluminium
- alloy
- activator
- inactive
- suspension
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 125000005234 alkyl aluminium group Chemical group 0.000 title abstract 2
- 238000000034 method Methods 0.000 title abstract 2
- 238000004519 manufacturing process Methods 0.000 title 1
- 239000000956 alloy Substances 0.000 abstract 4
- 229910045601 alloy Inorganic materials 0.000 abstract 4
- 239000004411 aluminium Substances 0.000 abstract 4
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 abstract 4
- 229910052782 aluminium Inorganic materials 0.000 abstract 4
- 239000012190 activator Substances 0.000 abstract 3
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 abstract 2
- 230000003213 activating effect Effects 0.000 abstract 2
- 239000003795 chemical substances by application Substances 0.000 abstract 2
- 150000001875 compounds Chemical group 0.000 abstract 2
- 229910052739 hydrogen Inorganic materials 0.000 abstract 2
- 239000001257 hydrogen Substances 0.000 abstract 2
- 239000000725 suspension Substances 0.000 abstract 2
- 230000004913 activation Effects 0.000 abstract 1
- 125000003545 alkoxy group Chemical group 0.000 abstract 1
- 150000001398 aluminium Chemical class 0.000 abstract 1
- IZAOMHQHYCDRBR-UHFFFAOYSA-N butoxy-bis(2-methylpropyl)alumane Chemical compound CCCC[O-].CC(C)C[Al+]CC(C)C IZAOMHQHYCDRBR-UHFFFAOYSA-N 0.000 abstract 1
- 125000004432 carbon atom Chemical group C* 0.000 abstract 1
- WYBNVOBELAEJHI-UHFFFAOYSA-N dibutoxy(butyl)borane Chemical compound CCCCOB(CCCC)OCCCC WYBNVOBELAEJHI-UHFFFAOYSA-N 0.000 abstract 1
- 150000004678 hydrides Chemical class 0.000 abstract 1
- 239000011261 inert gas Substances 0.000 abstract 1
- 239000007788 liquid Substances 0.000 abstract 1
- HAUKUGBTJXWQMF-UHFFFAOYSA-N lithium;propan-2-olate Chemical compound [Li+].CC(C)[O-] HAUKUGBTJXWQMF-UHFFFAOYSA-N 0.000 abstract 1
- 229910052751 metal Inorganic materials 0.000 abstract 1
- 239000002184 metal Substances 0.000 abstract 1
- 125000002524 organometallic group Chemical group 0.000 abstract 1
- ZGJADVGJIVEEGF-UHFFFAOYSA-M potassium;phenoxide Chemical compound [K+].[O-]C1=CC=CC=C1 ZGJADVGJIVEEGF-UHFFFAOYSA-M 0.000 abstract 1
- 239000000376 reactant Substances 0.000 abstract 1
- 238000000926 separation method Methods 0.000 abstract 1
- QDRKDTQENPPHOJ-UHFFFAOYSA-N sodium ethoxide Chemical compound [Na+].CC[O-] QDRKDTQENPPHOJ-UHFFFAOYSA-N 0.000 abstract 1
- 239000000243 solution Substances 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F5/00—Compounds containing elements of Groups 3 or 13 of the Periodic Table
- C07F5/06—Aluminium compounds
- C07F5/061—Aluminium compounds with C-aluminium linkage
- C07F5/065—Aluminium compounds with C-aluminium linkage compounds with an Al-H linkage
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
Abstract
In the preparation of alkylaluminium compounds from aluminium or an alloy thereof with e.g. Fe, Ti or Si, the activating agent is an organometallic or organoboron compound bearing at least one alkoxy, aroxy, alkaroxy or aralkoxy group, the metal being mono-, di- or trivalent. Examples of activators, used in an amount of at least 0.01% by weight of the aluminium or alloy, are sodium ethoxide, lithium iso-propoxide, potassium phenoxide, n-butyl-di-n-butoxyboron and di-isobutyl-n-butoxyaluminium. The inactive aluminium or alloy is heated at 70-250 DEG C. directly with the activator, or preferably with a solution or suspension thereof in an inert liquid under an inert gas. The activated aluminium with or without separation from the activator or solution or suspension thereof, may be reacted with a trialkylaluminium compound or dialkyaluminium hydride containing 2 to 20 carbon atoms per alkyl radical, hydrogen and possibly an olefine by known methods at 100-200 DEG C. and under 100 atmospheres pressure of hydrogen. Alternatively, the activating agent, inactive aluminium or alloy and reactants may be charged to a single vessel and activation and reaction carried out at 100-200 DEG C.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP3210163 | 1963-06-18 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB1049035A true GB1049035A (en) | 1966-11-23 |
Family
ID=12349485
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB25067/64A Expired GB1049035A (en) | 1963-06-18 | 1964-06-17 | Method for manufacturing alkylaluminum compounds |
Country Status (4)
| Country | Link |
|---|---|
| US (1) | US3402190A (en) |
| CH (1) | CH484942A (en) |
| DE (2) | DE1221636B (en) |
| GB (1) | GB1049035A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102584879A (en) * | 2012-01-19 | 2012-07-18 | 营口市向阳催化剂有限责任公司 | Preparation method of aluminium triethyl |
Families Citing this family (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3505375A (en) * | 1966-11-01 | 1970-04-07 | Ethyl Corp | Process for producing alkyl aluminum compounds |
| US3687994A (en) * | 1970-12-16 | 1972-08-29 | Ethyl Corp | Method of manufacturing alkylaluminum compounds |
| US3853931A (en) * | 1973-01-15 | 1974-12-10 | Aluminum Co Of America | Production of hydrocarbyl aluminum hydrides |
Family Cites Families (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2845447A (en) * | 1954-04-08 | 1958-07-29 | Shell Dev | Production of aluminum alcoholates |
| US2831898A (en) * | 1954-04-29 | 1958-04-22 | Ethyl Corp | Phenol alkylation process |
| NL109047C (en) * | 1955-04-01 | |||
| BE549411A (en) * | 1955-07-13 | 1900-01-01 | ||
| NL100995C (en) * | 1956-09-26 | |||
| US2965663A (en) * | 1957-11-25 | 1960-12-20 | Anderson Chemical Company | Processes for preparing metal alkyls and alkoxides |
| US3050540A (en) * | 1958-07-30 | 1962-08-21 | Ethyl Corp | Manufacture of alkyl aluminum compounds |
| US3077490A (en) * | 1959-05-08 | 1963-02-12 | Goodrich Gulf Chem Inc | Preparation of aluminum hydrocarbyls |
| NL124863C (en) * | 1963-01-31 | |||
| US3324160A (en) * | 1963-04-12 | 1967-06-06 | Shell Oil Co | Oxidation of hydrocarbyl-metallo compounds |
-
1964
- 1964-06-16 US US375484A patent/US3402190A/en not_active Expired - Lifetime
- 1964-06-17 CH CH789264A patent/CH484942A/en not_active IP Right Cessation
- 1964-06-17 GB GB25067/64A patent/GB1049035A/en not_active Expired
- 1964-06-18 DE DES100271A patent/DE1221636B/en active Pending
- 1964-06-18 DE DES91575A patent/DE1216304B/en active Pending
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102584879A (en) * | 2012-01-19 | 2012-07-18 | 营口市向阳催化剂有限责任公司 | Preparation method of aluminium triethyl |
| CN102584879B (en) * | 2012-01-19 | 2014-05-07 | 营口市向阳催化剂有限责任公司 | Preparation method of aluminium triethyl |
Also Published As
| Publication number | Publication date |
|---|---|
| CH484942A (en) | 1970-01-31 |
| US3402190A (en) | 1968-09-17 |
| DE1216304B (en) | 1966-05-12 |
| DE1221636B (en) | 1966-07-28 |
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