GB1015227A - Process for making tetramethyl lead - Google Patents
Process for making tetramethyl leadInfo
- Publication number
- GB1015227A GB1015227A GB27569/64A GB2756964A GB1015227A GB 1015227 A GB1015227 A GB 1015227A GB 27569/64 A GB27569/64 A GB 27569/64A GB 2756964 A GB2756964 A GB 2756964A GB 1015227 A GB1015227 A GB 1015227A
- Authority
- GB
- United Kingdom
- Prior art keywords
- alloy
- methyl chloride
- per mole
- mole
- ammonia
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- XOOGZRUBTYCLHG-UHFFFAOYSA-N tetramethyllead Chemical compound C[Pb](C)(C)C XOOGZRUBTYCLHG-UHFFFAOYSA-N 0.000 title abstract 2
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 abstract 6
- NEHMKBQYUWJMIP-UHFFFAOYSA-N chloromethane Chemical compound ClC NEHMKBQYUWJMIP-UHFFFAOYSA-N 0.000 abstract 6
- 229910045601 alloy Inorganic materials 0.000 abstract 4
- 239000000956 alloy Substances 0.000 abstract 4
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 abstract 3
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 abstract 3
- 229910021529 ammonia Inorganic materials 0.000 abstract 3
- 229940050176 methyl chloride Drugs 0.000 abstract 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 abstract 1
- 239000004215 Carbon black (E152) Substances 0.000 abstract 1
- NHTMVDHEPJAVLT-UHFFFAOYSA-N Isooctane Chemical compound CC(C)CC(C)(C)C NHTMVDHEPJAVLT-UHFFFAOYSA-N 0.000 abstract 1
- 229910000978 Pb alloy Inorganic materials 0.000 abstract 1
- WBLCSWMHSXNOPF-UHFFFAOYSA-N [Na].[Pb] Chemical compound [Na].[Pb] WBLCSWMHSXNOPF-UHFFFAOYSA-N 0.000 abstract 1
- 125000004432 carbon atom Chemical group C* 0.000 abstract 1
- NEHMKBQYUWJMIP-NJFSPNSNSA-N chloro(114C)methane Chemical compound [14CH3]Cl NEHMKBQYUWJMIP-NJFSPNSNSA-N 0.000 abstract 1
- 239000003426 co-catalyst Substances 0.000 abstract 1
- 238000007796 conventional method Methods 0.000 abstract 1
- JVSWJIKNEAIKJW-UHFFFAOYSA-N dimethyl-hexane Natural products CCCCCC(C)C JVSWJIKNEAIKJW-UHFFFAOYSA-N 0.000 abstract 1
- 229910002804 graphite Inorganic materials 0.000 abstract 1
- 239000010439 graphite Substances 0.000 abstract 1
- 229930195733 hydrocarbon Natural products 0.000 abstract 1
- 150000002430 hydrocarbons Chemical group 0.000 abstract 1
- 239000012442 inert solvent Substances 0.000 abstract 1
- INQOMBQAUSQDDS-UHFFFAOYSA-N iodomethane Chemical compound IC INQOMBQAUSQDDS-UHFFFAOYSA-N 0.000 abstract 1
- 239000007788 liquid Substances 0.000 abstract 1
- 239000000314 lubricant Substances 0.000 abstract 1
- 239000000376 reactant Substances 0.000 abstract 1
- 239000003017 thermal stabilizer Substances 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic System
- C07F7/24—Lead compounds
Abstract
Tetramethyl lead is prepared by the reaction of a monosodium lead alloy with at least one mole of methyl chloride per mole of alloy at a temperature of from - 20 DEG to 120 DEG C. in the presence of from 0.01 to 1.5 moles of ammonia per mole of alloy. Advantageously there may also be present up to 0.04 moles of water per mole of alloy provided the amount of water does not exceed 0.3% by weight of the methyl chloride, and up to 0.04 moles per mole of alloy of a monohydroxylic organic compound ROH, wherein R is a hydrocarbon or oxahydrocarbon radical containing 1 to 18 carbon atoms. Preferably ROH is methanol. The methyl chloride may contain up to 5 mole per cent methyl iodide. The reactants may be introduced separately or together, all at once or gradually into the reaction vessel. The ammonia and co-catalyst components may be added as such or in a carrier which may be the methyl chloride or an inert solvent such as toluene or iso-octane which also acts as a thermal stabilizer. The ammonia may be gaseous or liquid. 1 to 5% of graphite may be present as a lubricant, and the reaction may take place under a pressure of 100-300 p.s.i.g. The product is recovered by conventional methods.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US293138A US3281442A (en) | 1963-07-05 | 1963-07-05 | Process for making tetramethyl lead |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB1015227A true GB1015227A (en) | 1965-12-31 |
Family
ID=23127806
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB27569/64A Expired GB1015227A (en) | 1963-07-05 | 1964-07-03 | Process for making tetramethyl lead |
Country Status (4)
| Country | Link |
|---|---|
| US (1) | US3281442A (en) |
| DE (1) | DE1234721B (en) |
| FR (1) | FR1406132A (en) |
| GB (1) | GB1015227A (en) |
Families Citing this family (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3426056A (en) * | 1965-02-24 | 1969-02-04 | Du Pont | Process for making tetramethyl lead |
| US3400143A (en) * | 1965-05-17 | 1968-09-03 | Du Pont | Process for making tetramethyl lead |
| US3408375A (en) * | 1965-05-17 | 1968-10-29 | Du Pont | Process for making tetramethyl lead |
| US3401187A (en) * | 1965-06-15 | 1968-09-10 | Du Pont | Process for making tetramethyl lead |
| US3401189A (en) * | 1966-02-07 | 1968-09-10 | Du Pont | Tetramethyl lead manufacture |
| US3413328A (en) * | 1966-06-01 | 1968-11-26 | Du Pont | Tetramethyl lead process |
| US3956176A (en) * | 1970-03-25 | 1976-05-11 | Ppg Industries, Inc. | Catalyst for preparation of tetramethyl lead in reaction of methyl halide and sodium-lead alloy |
Family Cites Families (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US1559405A (en) * | 1922-10-05 | 1925-10-27 | Du Pont | Process of making tetra-alkyl lead |
| US1622228A (en) * | 1923-05-19 | 1927-03-22 | Gen Motors Corp | Process of making organic lead compounds |
| US1661809A (en) * | 1924-03-25 | 1928-03-06 | Du Pont | Process of making tetra-alkyl lead |
| US3088920A (en) * | 1960-04-26 | 1963-05-07 | Du Pont | Process for treating tetraalkyllead compositions |
| US3072694A (en) * | 1960-11-15 | 1963-01-08 | Du Pont | Process for making tetramethyl lead |
| US3072695A (en) * | 1960-11-25 | 1963-01-08 | Du Pont | Process for making tetramethyl lead |
-
0
- DE DEP34616A patent/DE1234721B/en active Pending
-
1963
- 1963-07-05 US US293138A patent/US3281442A/en not_active Expired - Lifetime
-
1964
- 1964-07-03 GB GB27569/64A patent/GB1015227A/en not_active Expired
- 1964-07-03 FR FR980674A patent/FR1406132A/en not_active Expired
Also Published As
| Publication number | Publication date |
|---|---|
| FR1406132A (en) | 1965-07-16 |
| DE1234721B (en) | 1967-02-23 |
| US3281442A (en) | 1966-10-25 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| GB1015227A (en) | Process for making tetramethyl lead | |
| ES380594A1 (en) | Process for the polymerization of olefins | |
| GB923471A (en) | Organotin compounds | |
| ES382882A1 (en) | Procedure for the polymerization of alpha-olefins. (Machine-translation by Google Translate, not legally binding) | |
| GB933722A (en) | Manufacture of tetramethyllead | |
| KR850005838A (en) | Method for preparing 1,3,2-dioxaborinane | |
| ES385451A1 (en) | Process for polymerizing alpha-olefins | |
| ES396800A1 (en) | Catalyst suitable for use in the polymerization of unsaturated compounds the polymerization processes employing such catalysts and products obtained by the processes | |
| GB971598A (en) | Improvements in or relating to functional fluids | |
| ES386497A1 (en) | Process for polymerizing alpha-olefins | |
| KR840002340A (en) | Process for preparing 1- (3-benzyloxyphenyl) -1,1-dimethylheptane and related intermediates | |
| US2950304A (en) | Preparation of organomercury compounds | |
| ES390708A1 (en) | Procedure for the polymerization of suspension of vinyl chloride. (Machine-translation by Google Translate, not legally binding) | |
| ES387459A1 (en) | Catalytic isomerization process for the production of 5-ethylidenebicyclo(2.2.1) hept-2-enes | |
| US3090814A (en) | Process of making vinyl aryl ethers | |
| GB1474867A (en) | Process for the preparation of 2,2,2-trichloroethyl chloro formate | |
| GB894089A (en) | Process for the manufacture of alkyl aluminum compounds and dialkyl aluminum hydrides | |
| GB757524A (en) | Improvements in and relating to the production of complex metal alkyls | |
| ES394036A1 (en) | 17alpha-hydroxy and acyloxy substituted-9alpha-methyl-19-norprogesterones | |
| ES395715A1 (en) | Production of 1-aminoalkane 1,1-diphosphonic acids | |
| GB1019150A (en) | Improvements in or relating to the manufacture of 1,2,3,4-tetrachlorobutane | |
| US3686274A (en) | Process for preparing esters | |
| ES387606A1 (en) | Procedure for obtaining 17-alpha (lower alkin) alenil-carbinols. (Machine-translation by Google Translate, not legally binding) | |
| GB1098657A (en) | Process for making tetramethyl lead | |
| GB835847A (en) | Method of preparing boro-organic compounds |