DE1176128B - Verfahren zur Stabilisierung von Bis-(methoxy-thioformyl)-disulfid - Google Patents
Verfahren zur Stabilisierung von Bis-(methoxy-thioformyl)-disulfidInfo
- Publication number
- DE1176128B DE1176128B DEF34841A DEF0034841A DE1176128B DE 1176128 B DE1176128 B DE 1176128B DE F34841 A DEF34841 A DE F34841A DE F0034841 A DEF0034841 A DE F0034841A DE 1176128 B DE1176128 B DE 1176128B
- Authority
- DE
- Germany
- Prior art keywords
- disulfide
- bis
- stabilization
- methoxy
- thioformyl
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- FVCPXLWAKNJIKK-UHFFFAOYSA-N Dimexano Chemical compound COC(=S)SSC(=S)OC FVCPXLWAKNJIKK-UHFFFAOYSA-N 0.000 title claims description 15
- 238000000034 method Methods 0.000 title claims description 8
- 230000006641 stabilisation Effects 0.000 title claims description 7
- 238000011105 stabilization Methods 0.000 title claims description 7
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 claims description 15
- 150000007933 aliphatic carboxylic acids Chemical class 0.000 claims description 4
- XBDQKXXYIPTUBI-UHFFFAOYSA-N dimethylselenoniopropionate Natural products CCC(O)=O XBDQKXXYIPTUBI-UHFFFAOYSA-N 0.000 claims description 4
- BWGNESOTFCXPMA-UHFFFAOYSA-N Dihydrogen disulfide Chemical compound SS BWGNESOTFCXPMA-UHFFFAOYSA-N 0.000 claims description 3
- 125000000217 alkyl group Chemical group 0.000 claims description 2
- 125000004432 carbon atom Chemical group C* 0.000 claims description 2
- 235000019260 propionic acid Nutrition 0.000 claims description 2
- IUVKMZGDUIUOCP-BTNSXGMBSA-N quinbolone Chemical compound O([C@H]1CC[C@H]2[C@H]3[C@@H]([C@]4(C=CC(=O)C=C4CC3)C)CC[C@@]21C)C1=CCCC1 IUVKMZGDUIUOCP-BTNSXGMBSA-N 0.000 claims description 2
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 9
- 239000002253 acid Substances 0.000 description 5
- 239000000047 product Substances 0.000 description 5
- JUJWROOIHBZHMG-UHFFFAOYSA-N Pyridine Chemical compound C1=CC=NC=C1 JUJWROOIHBZHMG-UHFFFAOYSA-N 0.000 description 4
- 230000002363 herbicidal effect Effects 0.000 description 4
- QGJOPFRUJISHPQ-UHFFFAOYSA-N Carbon disulfide Chemical compound S=C=S QGJOPFRUJISHPQ-UHFFFAOYSA-N 0.000 description 3
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
- 239000000839 emulsion Substances 0.000 description 3
- 239000000203 mixture Substances 0.000 description 3
- 125000000896 monocarboxylic acid group Chemical group 0.000 description 3
- -1 polyethylene Polymers 0.000 description 3
- 239000004215 Carbon black (E152) Substances 0.000 description 2
- 150000007513 acids Chemical class 0.000 description 2
- 125000001931 aliphatic group Chemical group 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- 238000000354 decomposition reaction Methods 0.000 description 2
- JXTHNDFMNIQAHM-UHFFFAOYSA-N dichloroacetic acid Chemical compound OC(=O)C(Cl)Cl JXTHNDFMNIQAHM-UHFFFAOYSA-N 0.000 description 2
- 239000003995 emulsifying agent Substances 0.000 description 2
- 229930195733 hydrocarbon Natural products 0.000 description 2
- 150000002430 hydrocarbons Chemical class 0.000 description 2
- BDAGIHXWWSANSR-UHFFFAOYSA-N methanoic acid Natural products OC=O BDAGIHXWWSANSR-UHFFFAOYSA-N 0.000 description 2
- UMJSCPRVCHMLSP-UHFFFAOYSA-N pyridine Natural products COC1=CC=CN=C1 UMJSCPRVCHMLSP-UHFFFAOYSA-N 0.000 description 2
- 239000011734 sodium Substances 0.000 description 2
- 239000003381 stabilizer Substances 0.000 description 2
- 230000000087 stabilizing effect Effects 0.000 description 2
- HMZRYILWTIWFCZ-UHFFFAOYSA-N 2,2-dichloroacetic acid;formic acid Chemical compound OC=O.OC(=O)C(Cl)Cl HMZRYILWTIWFCZ-UHFFFAOYSA-N 0.000 description 1
- OSWFIVFLDKOXQC-UHFFFAOYSA-N 4-(3-methoxyphenyl)aniline Chemical compound COC1=CC=CC(C=2C=CC(N)=CC=2)=C1 OSWFIVFLDKOXQC-UHFFFAOYSA-N 0.000 description 1
- UXVMQQNJUSDDNG-UHFFFAOYSA-L Calcium chloride Chemical compound [Cl-].[Cl-].[Ca+2] UXVMQQNJUSDDNG-UHFFFAOYSA-L 0.000 description 1
- KZBUYRJDOAKODT-UHFFFAOYSA-N Chlorine Chemical compound ClCl KZBUYRJDOAKODT-UHFFFAOYSA-N 0.000 description 1
- 101710178035 Chorismate synthase 2 Proteins 0.000 description 1
- 101710152694 Cysteine synthase 2 Proteins 0.000 description 1
- 239000004698 Polyethylene Substances 0.000 description 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical group [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 1
- 239000013543 active substance Substances 0.000 description 1
- 150000008055 alkyl aryl sulfonates Chemical class 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 239000001110 calcium chloride Substances 0.000 description 1
- 229910001628 calcium chloride Inorganic materials 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- SKOLWUPSYHWYAM-UHFFFAOYSA-N carbonodithioic O,S-acid Chemical compound SC(S)=O SKOLWUPSYHWYAM-UHFFFAOYSA-N 0.000 description 1
- 239000007795 chemical reaction product Substances 0.000 description 1
- 239000000460 chlorine Substances 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 238000009833 condensation Methods 0.000 description 1
- 230000005494 condensation Effects 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- 230000008021 deposition Effects 0.000 description 1
- 229960005215 dichloroacetic acid Drugs 0.000 description 1
- 238000002845 discoloration Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 235000019253 formic acid Nutrition 0.000 description 1
- 125000002485 formyl group Chemical group [H]C(*)=O 0.000 description 1
- 239000004009 herbicide Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 150000007524 organic acids Chemical class 0.000 description 1
- 235000005985 organic acids Nutrition 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 239000011541 reaction mixture Substances 0.000 description 1
- 238000010992 reflux Methods 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 239000011593 sulfur Substances 0.000 description 1
- 229910052717 sulfur Inorganic materials 0.000 description 1
- 238000005987 sulfurization reaction Methods 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
- 239000008096 xylene Substances 0.000 description 1
- 150000003738 xylenes Chemical class 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C329/00—Thiocarbonic acids; Halides, esters or anhydrides thereof
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| NL255705 | 1960-09-08 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| DE1176128B true DE1176128B (de) | 1964-08-20 |
Family
ID=19752552
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DEF34841A Pending DE1176128B (de) | 1960-09-08 | 1961-09-02 | Verfahren zur Stabilisierung von Bis-(methoxy-thioformyl)-disulfid |
Country Status (7)
| Country | Link |
|---|---|
| US (1) | US3154401A (en, 2012) |
| BE (1) | BE607889A (en, 2012) |
| CH (1) | CH418055A (en, 2012) |
| DE (1) | DE1176128B (en, 2012) |
| ES (1) | ES270291A1 (en, 2012) |
| GB (1) | GB973702A (en, 2012) |
| NL (2) | NL107253C (en, 2012) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE2533989A1 (de) * | 1975-07-30 | 1977-02-24 | Bayer Ag | Verfahren zur herstellung von organischen sulfiden und disulfiden |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3235368A (en) * | 1962-04-25 | 1966-02-15 | Monsanto Co | Stabilization of herbicide |
| US5288753A (en) * | 1989-12-28 | 1994-02-22 | Union Oil Company Of California | Method of controlling animal and fungal pests with oligomeric thiocarbonates |
Family Cites Families (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2120285A (en) * | 1935-09-17 | 1938-06-14 | Merrill W Macafee | Secondary butyl and other dixanthogens |
| US2615804A (en) * | 1947-05-08 | 1952-10-28 | Goodrich Co B F | Herbicidal composition |
| US2615802A (en) * | 1948-10-23 | 1952-10-28 | Monsanto Chemicals | Herbicidal composition and method |
| US2600861A (en) * | 1949-12-28 | 1952-06-17 | Stauffer Chemical Co | Maturing cotton |
| US2813890A (en) * | 1954-10-15 | 1957-11-19 | Exxon Research Engineering Co | Manufacture of alkyl xanthogen sulfides |
-
0
- NL NL255705D patent/NL255705A/xx unknown
- BE BE607889D patent/BE607889A/xx unknown
- NL NL107253D patent/NL107253C/xx active
-
1961
- 1961-09-02 DE DEF34841A patent/DE1176128B/de active Pending
- 1961-09-07 ES ES0270291A patent/ES270291A1/es not_active Expired
- 1961-09-07 CH CH1040261A patent/CH418055A/de unknown
- 1961-09-08 GB GB32388/61A patent/GB973702A/en not_active Expired
- 1961-12-28 US US162967A patent/US3154401A/en not_active Expired - Lifetime
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE2533989A1 (de) * | 1975-07-30 | 1977-02-24 | Bayer Ag | Verfahren zur herstellung von organischen sulfiden und disulfiden |
Also Published As
| Publication number | Publication date |
|---|---|
| NL107253C (en, 2012) | |
| ES270291A1 (es) | 1962-05-01 |
| US3154401A (en) | 1964-10-27 |
| GB973702A (en) | 1964-10-28 |
| NL255705A (en, 2012) | |
| BE607889A (en, 2012) | |
| CH418055A (de) | 1966-07-31 |
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