DE1157027B - Fungizide Mittel - Google Patents
Fungizide MittelInfo
- Publication number
- DE1157027B DE1157027B DEF36152A DEF0036152A DE1157027B DE 1157027 B DE1157027 B DE 1157027B DE F36152 A DEF36152 A DE F36152A DE F0036152 A DEF0036152 A DE F0036152A DE 1157027 B DE1157027 B DE 1157027B
- Authority
- DE
- Germany
- Prior art keywords
- bis
- propylene
- dithiocarbamate
- iron
- ethylene
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000000417 fungicide Substances 0.000 title claims description 5
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims description 8
- CWYNVVGOOAEACU-UHFFFAOYSA-N Fe2+ Chemical compound [Fe+2] CWYNVVGOOAEACU-UHFFFAOYSA-N 0.000 claims description 6
- VTLYFUHAOXGGBS-UHFFFAOYSA-N Fe3+ Chemical compound [Fe+3] VTLYFUHAOXGGBS-UHFFFAOYSA-N 0.000 claims description 6
- 229910052788 barium Inorganic materials 0.000 claims description 5
- DSAJWYNOEDNPEQ-UHFFFAOYSA-N barium atom Chemical compound [Ba] DSAJWYNOEDNPEQ-UHFFFAOYSA-N 0.000 claims description 5
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 claims description 4
- 229910052749 magnesium Inorganic materials 0.000 claims description 4
- 239000011777 magnesium Substances 0.000 claims description 4
- 229910052759 nickel Inorganic materials 0.000 claims description 4
- -1 1,2-propylene-bis-dithiocarbamic acid Calcium Chemical compound 0.000 description 13
- 238000012360 testing method Methods 0.000 description 13
- 230000000855 fungicidal effect Effects 0.000 description 12
- 241000233622 Phytophthora infestans Species 0.000 description 11
- 238000002360 preparation method Methods 0.000 description 11
- 240000003768 Solanum lycopersicum Species 0.000 description 10
- 241000233866 Fungi Species 0.000 description 9
- 206010061217 Infestation Diseases 0.000 description 9
- 235000007688 Lycopersicon esculentum Nutrition 0.000 description 9
- 239000004480 active ingredient Substances 0.000 description 9
- 241000196324 Embryophyta Species 0.000 description 8
- IJIHYLHFNAWUGR-UHFFFAOYSA-N propylene 1,2-bis(dithiocarbamic acid) Chemical class SC(=S)NC(C)CNC(S)=S IJIHYLHFNAWUGR-UHFFFAOYSA-N 0.000 description 8
- QGJOPFRUJISHPQ-UHFFFAOYSA-N Carbon disulfide Chemical compound S=C=S QGJOPFRUJISHPQ-UHFFFAOYSA-N 0.000 description 6
- 239000012990 dithiocarbamate Substances 0.000 description 6
- 239000005977 Ethylene Substances 0.000 description 5
- 241001281803 Plasmopara viticola Species 0.000 description 5
- 239000000243 solution Substances 0.000 description 5
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 4
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 4
- DKVNPHBNOWQYFE-UHFFFAOYSA-N carbamodithioic acid Chemical compound NC(S)=S DKVNPHBNOWQYFE-UHFFFAOYSA-N 0.000 description 4
- 150000001875 compounds Chemical class 0.000 description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 4
- 229910052725 zinc Inorganic materials 0.000 description 4
- 239000011701 zinc Substances 0.000 description 4
- ZMXDDKWLCZADIW-UHFFFAOYSA-N N,N-Dimethylformamide Chemical compound CN(C)C=O ZMXDDKWLCZADIW-UHFFFAOYSA-N 0.000 description 3
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- AWYFNIZYMPNGAI-UHFFFAOYSA-N ethylenebis(dithiocarbamic acid) Chemical compound SC(=S)NCCNC(S)=S AWYFNIZYMPNGAI-UHFFFAOYSA-N 0.000 description 3
- 239000000203 mixture Substances 0.000 description 3
- KKMLIVYBGSAJPM-UHFFFAOYSA-L propineb Chemical compound [Zn+2].[S-]C(=S)NC(C)CNC([S-])=S KKMLIVYBGSAJPM-UHFFFAOYSA-L 0.000 description 3
- 150000003839 salts Chemical class 0.000 description 3
- 239000007787 solid Substances 0.000 description 3
- AMHNZOICSMBGDH-UHFFFAOYSA-L zineb Chemical compound [Zn+2].[S-]C(=S)NCCNC([S-])=S AMHNZOICSMBGDH-UHFFFAOYSA-L 0.000 description 3
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 2
- MDBPOWCTDFWMKB-UHFFFAOYSA-N C(N)(SCC(C)SC(N)=S)=S.[Mg] Chemical compound C(N)(SCC(C)SC(N)=S)=S.[Mg] MDBPOWCTDFWMKB-UHFFFAOYSA-N 0.000 description 2
- JPVYNHNXODAKFH-UHFFFAOYSA-N Cu2+ Chemical compound [Cu+2] JPVYNHNXODAKFH-UHFFFAOYSA-N 0.000 description 2
- QXNVGIXVLWOKEQ-UHFFFAOYSA-N Disodium Chemical compound [Na][Na] QXNVGIXVLWOKEQ-UHFFFAOYSA-N 0.000 description 2
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
- 239000003513 alkali Substances 0.000 description 2
- 229910052784 alkaline earth metal Inorganic materials 0.000 description 2
- 239000007864 aqueous solution Substances 0.000 description 2
- 159000000007 calcium salts Chemical class 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- 239000003085 diluting agent Substances 0.000 description 2
- 238000002474 experimental method Methods 0.000 description 2
- 229910001385 heavy metal Inorganic materials 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- 150000002815 nickel Chemical class 0.000 description 2
- 230000003032 phytopathogenic effect Effects 0.000 description 2
- 239000000725 suspension Substances 0.000 description 2
- 150000003751 zinc Chemical class 0.000 description 2
- ORTONXAAOVGKCC-UHFFFAOYSA-N 1-(dithiocarboxyamino)propan-2-ylcarbamodithioic acid zinc Chemical compound [Zn].SC(=S)NC(C)CNC(S)=S ORTONXAAOVGKCC-UHFFFAOYSA-N 0.000 description 1
- IHANVFPASHZZSU-UHFFFAOYSA-L 2-(dithiocarboxyamino)propyliminomethanedithiolate nickel(2+) Chemical compound C(C(C)NC([S-])=S)NC([S-])=S.[Ni+2] IHANVFPASHZZSU-UHFFFAOYSA-L 0.000 description 1
- JMZRZEXRYJUHEB-UHFFFAOYSA-N 2-carbamothioylsulfanylethyl carbamodithioate;zinc Chemical compound [Zn].NC(=S)SCCSC(N)=S JMZRZEXRYJUHEB-UHFFFAOYSA-N 0.000 description 1
- 235000001674 Agaricus brunnescens Nutrition 0.000 description 1
- 241000213004 Alternaria solani Species 0.000 description 1
- VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 description 1
- JHRSUWMRSMNFCA-UHFFFAOYSA-N C(N)(SCC(C)SC(N)=S)=S.[Ni] Chemical compound C(N)(SCC(C)SC(N)=S)=S.[Ni] JHRSUWMRSMNFCA-UHFFFAOYSA-N 0.000 description 1
- KXDHJXZQYSOELW-UHFFFAOYSA-M Carbamate Chemical compound NC([O-])=O KXDHJXZQYSOELW-UHFFFAOYSA-M 0.000 description 1
- 239000004606 Fillers/Extenders Substances 0.000 description 1
- 206010017533 Fungal infection Diseases 0.000 description 1
- 208000031888 Mycoses Diseases 0.000 description 1
- 241000222291 Passalora fulva Species 0.000 description 1
- 241001223281 Peronospora Species 0.000 description 1
- 244000046052 Phaseolus vulgaris Species 0.000 description 1
- 244000061456 Solanum tuberosum Species 0.000 description 1
- 235000002595 Solanum tuberosum Nutrition 0.000 description 1
- 244000269722 Thea sinensis Species 0.000 description 1
- 241000228452 Venturia inaequalis Species 0.000 description 1
- 241000607479 Yersinia pestis Species 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 230000004913 activation Effects 0.000 description 1
- 239000000853 adhesive Substances 0.000 description 1
- 230000001070 adhesive effect Effects 0.000 description 1
- 229910052783 alkali metal Inorganic materials 0.000 description 1
- 150000008044 alkali metal hydroxides Chemical class 0.000 description 1
- 239000000908 ammonium hydroxide Substances 0.000 description 1
- 239000002585 base Substances 0.000 description 1
- 235000012216 bentonite Nutrition 0.000 description 1
- 239000012876 carrier material Substances 0.000 description 1
- 239000007795 chemical reaction product Substances 0.000 description 1
- 239000012141 concentrate Substances 0.000 description 1
- 230000001687 destabilization Effects 0.000 description 1
- 239000012895 dilution Substances 0.000 description 1
- 238000010790 dilution Methods 0.000 description 1
- 201000010099 disease Diseases 0.000 description 1
- 208000037265 diseases, disorders, signs and symptoms Diseases 0.000 description 1
- 235000005489 dwarf bean Nutrition 0.000 description 1
- 235000013399 edible fruits Nutrition 0.000 description 1
- 239000000839 emulsion Substances 0.000 description 1
- OBWASNSCCRCAOI-UHFFFAOYSA-N ethenylideneiron Chemical group C(=C)=[Fe] OBWASNSCCRCAOI-UHFFFAOYSA-N 0.000 description 1
- 238000011156 evaluation Methods 0.000 description 1
- 238000001914 filtration Methods 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 230000002538 fungal effect Effects 0.000 description 1
- 244000053095 fungal pathogen Species 0.000 description 1
- 238000000338 in vitro Methods 0.000 description 1
- 238000011534 incubation Methods 0.000 description 1
- 239000002917 insecticide Substances 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 159000000014 iron salts Chemical class 0.000 description 1
- BAUYGSIQEAFULO-UHFFFAOYSA-L iron(2+) sulfate (anhydrous) Chemical compound [Fe+2].[O-]S([O-])(=O)=O BAUYGSIQEAFULO-UHFFFAOYSA-L 0.000 description 1
- 229910000359 iron(II) sulfate Inorganic materials 0.000 description 1
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 239000012669 liquid formulation Substances 0.000 description 1
- 159000000003 magnesium salts Chemical class 0.000 description 1
- LGQLOGILCSXPEA-UHFFFAOYSA-L nickel sulfate Chemical compound [Ni+2].[O-]S([O-])(=O)=O LGQLOGILCSXPEA-UHFFFAOYSA-L 0.000 description 1
- 229910000363 nickel(II) sulfate Inorganic materials 0.000 description 1
- 239000012875 nonionic emulsifier Substances 0.000 description 1
- 239000003973 paint Substances 0.000 description 1
- 235000012015 potatoes Nutrition 0.000 description 1
- 239000002244 precipitate Substances 0.000 description 1
- 238000001556 precipitation Methods 0.000 description 1
- ANGKWJAGTIYESY-UHFFFAOYSA-N propane-1,2-diamine Chemical compound CC(N)CN.CC(N)CN ANGKWJAGTIYESY-UHFFFAOYSA-N 0.000 description 1
- AOHJOMMDDJHIJH-UHFFFAOYSA-N propylenediamine Chemical compound CC(N)CN AOHJOMMDDJHIJH-UHFFFAOYSA-N 0.000 description 1
- 239000011541 reaction mixture Substances 0.000 description 1
- 239000000741 silica gel Substances 0.000 description 1
- 229910002027 silica gel Inorganic materials 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 239000000454 talc Substances 0.000 description 1
- 229910052623 talc Inorganic materials 0.000 description 1
- 239000000080 wetting agent Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C333/00—Derivatives of thiocarbamic acids, i.e. compounds containing any of the groups, the nitrogen atom not being part of nitro or nitroso groups
- C07C333/14—Dithiocarbamic acids; Derivatives thereof
- C07C333/16—Salts of dithiocarbamic acids
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
- A01N47/08—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having one or more single bonds to nitrogen atoms
- A01N47/10—Carbamic acid derivatives, i.e. containing the group —O—CO—N<; Thio analogues thereof
- A01N47/12—Carbamic acid derivatives, i.e. containing the group —O—CO—N<; Thio analogues thereof containing a —O—CO—N< group, or a thio analogue thereof, neither directly attached to a ring nor the nitrogen atom being a member of a heterocyclic ring
- A01N47/14—Di-thio analogues thereof
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C333/00—Derivatives of thiocarbamic acids, i.e. compounds containing any of the groups, the nitrogen atom not being part of nitro or nitroso groups
- C07C333/14—Dithiocarbamic acids; Derivatives thereof
- C07C333/18—Esters of dithiocarbamic acids
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Agronomy & Crop Science (AREA)
- Pest Control & Pesticides (AREA)
- Plant Pathology (AREA)
- Health & Medical Sciences (AREA)
- Engineering & Computer Science (AREA)
- Dentistry (AREA)
- General Health & Medical Sciences (AREA)
- Wood Science & Technology (AREA)
- Zoology (AREA)
- Environmental Sciences (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Priority Applications (10)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| NL289482D NL289482A (en, 2012) | 1962-03-01 | ||
| BE629022D BE629022A (en, 2012) | 1962-03-01 | ||
| DEF36152A DE1157027B (de) | 1962-03-01 | 1962-03-01 | Fungizide Mittel |
| CH202263A CH429287A (de) | 1962-03-01 | 1963-02-18 | Fungizide Mittel |
| US260037A US3326951A (en) | 1962-03-01 | 1963-02-20 | Propylene-(1, 2)-bis-dithiocarbamates |
| FR925856A FR1350244A (fr) | 1962-03-01 | 1963-02-25 | Nouveaux propylène-(1, 2)-bis-dithiocarbamates |
| GB7655/63A GB981680A (en) | 1962-03-01 | 1963-02-26 | Propylene-(1,2)-bis-dithiocarbamates |
| DK93963AA DK113992B (da) | 1962-03-01 | 1963-02-28 | Propylen-(1,2)-bis-dithiocarbamat-forbindelse til anvendelse i fungicider. |
| AT161863A AT255204B (de) | 1962-03-01 | 1963-03-01 | Fungizide Mittel |
| BR147300/63A BR6347300D0 (pt) | 1962-03-01 | 1963-03-01 | Composicoes fungicidas |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DEF36152A DE1157027B (de) | 1962-03-01 | 1962-03-01 | Fungizide Mittel |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| DE1157027B true DE1157027B (de) | 1963-11-07 |
Family
ID=7096333
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DEF36152A Pending DE1157027B (de) | 1962-03-01 | 1962-03-01 | Fungizide Mittel |
Country Status (9)
| Country | Link |
|---|---|
| US (1) | US3326951A (en, 2012) |
| AT (1) | AT255204B (en, 2012) |
| BE (1) | BE629022A (en, 2012) |
| BR (1) | BR6347300D0 (en, 2012) |
| CH (1) | CH429287A (en, 2012) |
| DE (1) | DE1157027B (en, 2012) |
| DK (1) | DK113992B (en, 2012) |
| GB (1) | GB981680A (en, 2012) |
| NL (1) | NL289482A (en, 2012) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3301747A (en) * | 1963-11-13 | 1967-01-31 | Bayer Ag | Fungicidal composition containing blasticidin s and metal salts of 1, 2-propylene-bis-dithiocarbamate |
| US3342670A (en) * | 1963-11-13 | 1967-09-19 | Bayer Ag | Combination of organic mercury compounds and 1, 2-propylene-bis-dithiocarbamic acid salts as fungicides for rice plants |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3880900A (en) * | 1971-07-28 | 1975-04-29 | Denki Kogaku Kogyo K K | Process for preparing metal complex of alkylene bisdithiocarbamate |
Family Cites Families (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2317765A (en) * | 1941-08-20 | 1943-04-27 | Rohm & Haas | Fungicidal composition |
| AT193891B (de) * | 1941-08-20 | 1957-12-10 | Rohm & Haas | Verfahren zur Herstellung neuer mehrwertiger Metallsalze von Alkylenbisdithiocarbaminsäuren |
| US2974082A (en) * | 1957-04-25 | 1961-03-07 | Alfred P Collins | Process of inhibiting microorganisms with alkylene bis-dithiocarbamate esters |
| US2983747A (en) * | 1958-07-28 | 1961-05-09 | Stauffer Chemical Co | Process for making thiolcarbamates |
| US3012053A (en) * | 1958-08-06 | 1961-12-05 | Monsanto Chemicals | Alkylenebis (thionocarbamates) |
| NL247712A (en, 2012) * | 1959-01-30 | |||
| US3082229A (en) * | 1959-09-24 | 1963-03-19 | Lawrence H Nash | Bimetallic salts of ethylene bis dithiocarbamic acid |
| US3085043A (en) * | 1961-10-26 | 1963-04-09 | Monsanto Chemicals | Methods and compositions for the treatment of soil |
-
0
- NL NL289482D patent/NL289482A/xx unknown
- BE BE629022D patent/BE629022A/xx unknown
-
1962
- 1962-03-01 DE DEF36152A patent/DE1157027B/de active Pending
-
1963
- 1963-02-18 CH CH202263A patent/CH429287A/de unknown
- 1963-02-20 US US260037A patent/US3326951A/en not_active Expired - Lifetime
- 1963-02-26 GB GB7655/63A patent/GB981680A/en not_active Expired
- 1963-02-28 DK DK93963AA patent/DK113992B/da unknown
- 1963-03-01 BR BR147300/63A patent/BR6347300D0/pt unknown
- 1963-03-01 AT AT161863A patent/AT255204B/de active
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3301747A (en) * | 1963-11-13 | 1967-01-31 | Bayer Ag | Fungicidal composition containing blasticidin s and metal salts of 1, 2-propylene-bis-dithiocarbamate |
| US3342670A (en) * | 1963-11-13 | 1967-09-19 | Bayer Ag | Combination of organic mercury compounds and 1, 2-propylene-bis-dithiocarbamic acid salts as fungicides for rice plants |
Also Published As
| Publication number | Publication date |
|---|---|
| GB981680A (en) | 1965-01-27 |
| CH429287A (de) | 1967-01-31 |
| US3326951A (en) | 1967-06-20 |
| NL289482A (en, 2012) | |
| DK113992B (da) | 1969-05-19 |
| BE629022A (en, 2012) | |
| BR6347300D0 (pt) | 1973-06-28 |
| AT255204B (de) | 1967-06-26 |
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