DE1133122B - Gegen Oxydation stabilisierte Formmasse - Google Patents
Gegen Oxydation stabilisierte FormmasseInfo
- Publication number
- DE1133122B DE1133122B DEW23556A DEW0023556A DE1133122B DE 1133122 B DE1133122 B DE 1133122B DE W23556 A DEW23556 A DE W23556A DE W0023556 A DEW0023556 A DE W0023556A DE 1133122 B DE1133122 B DE 1133122B
- Authority
- DE
- Germany
- Prior art keywords
- percent
- weight
- carbon black
- molding compound
- stabilizer
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 230000003647 oxidation Effects 0.000 title claims description 17
- 238000007254 oxidation reaction Methods 0.000 title claims description 17
- 150000001875 compounds Chemical class 0.000 title claims description 9
- 238000000465 moulding Methods 0.000 title claims description 9
- 239000006229 carbon black Substances 0.000 claims description 14
- 239000000203 mixture Substances 0.000 claims description 14
- 239000002245 particle Substances 0.000 claims description 11
- 239000003381 stabilizer Substances 0.000 claims description 9
- 125000004432 carbon atom Chemical group C* 0.000 claims description 6
- 125000004435 hydrogen atom Chemical group [H]* 0.000 claims description 6
- CSNJTIWCTNEOSW-UHFFFAOYSA-N carbamothioylsulfanyl carbamodithioate Chemical compound NC(=S)SSC(N)=S CSNJTIWCTNEOSW-UHFFFAOYSA-N 0.000 claims description 5
- 125000001424 substituent group Chemical group 0.000 claims description 4
- 125000001931 aliphatic group Chemical group 0.000 claims description 2
- AUZONCFQVSMFAP-UHFFFAOYSA-N disulfiram Chemical compound CCN(CC)C(=S)SSC(=S)N(CC)CC AUZONCFQVSMFAP-UHFFFAOYSA-N 0.000 claims 2
- 241000872198 Serjania polyphylla Species 0.000 claims 1
- 125000003698 tetramethyl group Chemical group [H]C([H])([H])* 0.000 claims 1
- 229920000642 polymer Polymers 0.000 description 20
- -1 ethylene, propylene, butene Chemical class 0.000 description 18
- 239000004698 Polyethylene Substances 0.000 description 12
- 229920000573 polyethylene Polymers 0.000 description 12
- 239000004071 soot Substances 0.000 description 12
- 150000005673 monoalkenes Chemical class 0.000 description 11
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 9
- 229910052760 oxygen Inorganic materials 0.000 description 9
- 239000001301 oxygen Substances 0.000 description 9
- 239000003963 antioxidant agent Substances 0.000 description 6
- BWGNESOTFCXPMA-UHFFFAOYSA-N Dihydrogen disulfide Chemical compound SS BWGNESOTFCXPMA-UHFFFAOYSA-N 0.000 description 5
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 4
- 238000010521 absorption reaction Methods 0.000 description 4
- 229910052717 sulfur Inorganic materials 0.000 description 4
- 239000011593 sulfur Substances 0.000 description 4
- KUAZQDVKQLNFPE-UHFFFAOYSA-N thiram Chemical compound CN(C)C(=S)SSC(=S)N(C)C KUAZQDVKQLNFPE-UHFFFAOYSA-N 0.000 description 4
- 229960002447 thiram Drugs 0.000 description 4
- UCKMPCXJQFINFW-UHFFFAOYSA-N Sulphide Chemical compound [S-2] UCKMPCXJQFINFW-UHFFFAOYSA-N 0.000 description 3
- 239000000654 additive Substances 0.000 description 3
- 238000009413 insulation Methods 0.000 description 3
- 229920006395 saturated elastomer Polymers 0.000 description 3
- 239000004743 Polypropylene Substances 0.000 description 2
- 238000007792 addition Methods 0.000 description 2
- 230000032683 aging Effects 0.000 description 2
- 230000003078 antioxidant effect Effects 0.000 description 2
- 125000003118 aryl group Chemical group 0.000 description 2
- QVQLCTNNEUAWMS-UHFFFAOYSA-N barium oxide Chemical compound [Ba]=O QVQLCTNNEUAWMS-UHFFFAOYSA-N 0.000 description 2
- 238000006243 chemical reaction Methods 0.000 description 2
- 239000004020 conductor Substances 0.000 description 2
- 230000001627 detrimental effect Effects 0.000 description 2
- 125000004177 diethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 2
- 238000002474 experimental method Methods 0.000 description 2
- 238000002844 melting Methods 0.000 description 2
- 230000008018 melting Effects 0.000 description 2
- 229920001155 polypropylene Polymers 0.000 description 2
- 230000005855 radiation Effects 0.000 description 2
- 125000000467 secondary amino group Chemical class [H]N([*:1])[*:2] 0.000 description 2
- 230000006641 stabilisation Effects 0.000 description 2
- 238000011105 stabilization Methods 0.000 description 2
- 230000000087 stabilizing effect Effects 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- LIKMAJRDDDTEIG-UHFFFAOYSA-N 1-hexene Chemical compound CCCCC=C LIKMAJRDDDTEIG-UHFFFAOYSA-N 0.000 description 1
- HIXDQWDOVZUNNA-UHFFFAOYSA-N 2-(3,4-dimethoxyphenyl)-5-hydroxy-7-methoxychromen-4-one Chemical compound C=1C(OC)=CC(O)=C(C(C=2)=O)C=1OC=2C1=CC=C(OC)C(OC)=C1 HIXDQWDOVZUNNA-UHFFFAOYSA-N 0.000 description 1
- LDTAOIUHUHHCMU-UHFFFAOYSA-N 3-methylpent-1-ene Chemical compound CCC(C)C=C LDTAOIUHUHHCMU-UHFFFAOYSA-N 0.000 description 1
- RZVAJINKPMORJF-UHFFFAOYSA-N Acetaminophen Chemical compound CC(=O)NC1=CC=C(O)C=C1 RZVAJINKPMORJF-UHFFFAOYSA-N 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- 239000004215 Carbon black (E152) Substances 0.000 description 1
- 230000002745 absorbent Effects 0.000 description 1
- 239000002250 absorbent Substances 0.000 description 1
- 150000001336 alkenes Chemical class 0.000 description 1
- 125000000217 alkyl group Chemical group 0.000 description 1
- 150000001491 aromatic compounds Chemical class 0.000 description 1
- 239000006231 channel black Substances 0.000 description 1
- UHZZMRAGKVHANO-UHFFFAOYSA-M chlormequat chloride Chemical compound [Cl-].C[N+](C)(C)CCCl UHZZMRAGKVHANO-UHFFFAOYSA-M 0.000 description 1
- 229920001577 copolymer Polymers 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- 230000006866 deterioration Effects 0.000 description 1
- 238000007865 diluting Methods 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- RTZKZFJDLAIYFH-UHFFFAOYSA-N ether Substances CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- 239000005357 flat glass Substances 0.000 description 1
- 239000011888 foil Substances 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 229920006158 high molecular weight polymer Polymers 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- QSHDDOUJBYECFT-UHFFFAOYSA-N mercury Chemical compound [Hg] QSHDDOUJBYECFT-UHFFFAOYSA-N 0.000 description 1
- 229910052753 mercury Inorganic materials 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
- 239000012778 molding material Substances 0.000 description 1
- 239000007800 oxidant agent Substances 0.000 description 1
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N phenol group Chemical group C1(=CC=CC=C1)O ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 1
- 150000002989 phenols Chemical class 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 description 1
- 230000001681 protective effect Effects 0.000 description 1
- 239000005297 pyrex Substances 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 150000004763 sulfides Chemical class 0.000 description 1
- 230000009044 synergistic interaction Effects 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/02—Elements
- C08K3/04—Carbon
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/36—Sulfur-, selenium-, or tellurium-containing compounds
- C08K5/39—Thiocarbamic acids; Derivatives thereof, e.g. dithiocarbamates
- C08K5/40—Thiurams, i.e. compounds containing groups
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Organic Insulating Materials (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US672062A US2889306A (en) | 1957-07-15 | 1957-07-15 | Stabilized straight chain hydrocarbons |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| DE1133122B true DE1133122B (de) | 1962-07-12 |
Family
ID=24697000
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DEW23556A Pending DE1133122B (de) | 1957-07-15 | 1958-06-23 | Gegen Oxydation stabilisierte Formmasse |
Country Status (6)
| Country | Link |
|---|---|
| US (1) | US2889306A (en, 2012) |
| BE (1) | BE565519A (en, 2012) |
| DE (1) | DE1133122B (en, 2012) |
| FR (1) | FR1240512A (en, 2012) |
| GB (1) | GB850499A (en, 2012) |
| NL (1) | NL104479C (en, 2012) |
Families Citing this family (14)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3089860A (en) * | 1958-12-03 | 1963-05-14 | Union Carbide Corp | Stabilized polyolefin compositions |
| US3082188A (en) * | 1959-02-24 | 1963-03-19 | Dow Chemical Co | Stabilized polyolefin compositions |
| BE595794A (en, 2012) * | 1959-09-02 | |||
| US3454522A (en) * | 1959-10-23 | 1969-07-08 | Eastman Kodak Co | Black polyethylene compositions stabilized against ultra-violet light degradation with a synergistic mixture of carbon black and a diester of 3,3-thiodipropionic acid |
| US3119783A (en) * | 1959-10-30 | 1964-01-28 | Union Carbide Corp | Polypropylene stabilized with a mixture of a para-tertiaryalkylphenol-formaldehyde resin and an organic phosphite |
| US3119784A (en) * | 1960-01-05 | 1964-01-28 | Union Carbide Corp | Propylene resin stabilized with a mixture of a para-tertiaryalkylphenolformaldehyde resin and an aminodithioformate |
| NL130213C (en, 2012) * | 1960-06-07 | |||
| GB1084336A (en, 2012) * | 1960-07-07 | |||
| US3216967A (en) * | 1961-01-09 | 1965-11-09 | Bell Telephone Labor Inc | Polyolefins stabilized with sulfides and thiobisphenols |
| NL286272A (en, 2012) * | 1961-12-05 | |||
| US3463731A (en) * | 1963-11-12 | 1969-08-26 | Ethyl Corp | Stabilization with phenolic type antioxidant |
| US3259604A (en) * | 1964-04-24 | 1966-07-05 | Bell Telephone Labor Inc | Stabilized long-chain polymers |
| US3304283A (en) * | 1964-04-24 | 1967-02-14 | Bell Telephone Labor Inc | Stabilized alpha-mono-olefinic polymers |
| US3522183A (en) * | 1968-05-07 | 1970-07-28 | Simplex Wire & Cable Co | Solid dielectric polyolefin compositions containing various voltage stabilizers |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB496966A (en) * | 1936-07-25 | 1938-12-09 | Standard Oil Dev Co | An improved manufacture of stabilised hydrocarbon polymers |
| US2582510A (en) * | 1947-12-05 | 1952-01-15 | Bell Telephone Labor Inc | Polyethylene stabilized with sulfur plus a vulcanization accelerator |
Family Cites Families (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2387518A (en) * | 1940-11-30 | 1945-10-23 | Jasco Inc | Stabilized polymer compositions |
-
0
- NL NL104479D patent/NL104479C/xx active
- BE BE565519D patent/BE565519A/xx unknown
-
1957
- 1957-07-15 US US672062A patent/US2889306A/en not_active Expired - Lifetime
-
1958
- 1958-06-16 FR FR768057A patent/FR1240512A/fr not_active Expired
- 1958-06-23 DE DEW23556A patent/DE1133122B/de active Pending
- 1958-07-08 GB GB21842/58A patent/GB850499A/en not_active Expired
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB496966A (en) * | 1936-07-25 | 1938-12-09 | Standard Oil Dev Co | An improved manufacture of stabilised hydrocarbon polymers |
| US2582510A (en) * | 1947-12-05 | 1952-01-15 | Bell Telephone Labor Inc | Polyethylene stabilized with sulfur plus a vulcanization accelerator |
Also Published As
| Publication number | Publication date |
|---|---|
| NL104479C (en, 2012) | |
| US2889306A (en) | 1959-06-02 |
| FR1240512A (fr) | 1960-09-09 |
| GB850499A (en) | 1960-10-05 |
| BE565519A (en, 2012) |
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