GB496966A - An improved manufacture of stabilised hydrocarbon polymers - Google Patents

An improved manufacture of stabilised hydrocarbon polymers

Info

Publication number
GB496966A
GB496966A GB16136/37A GB1613637A GB496966A GB 496966 A GB496966 A GB 496966A GB 16136/37 A GB16136/37 A GB 16136/37A GB 1613637 A GB1613637 A GB 1613637A GB 496966 A GB496966 A GB 496966A
Authority
GB
United Kingdom
Prior art keywords
disulphide
tertiary amyl
isobutylene
amyl phenol
hydrocarbon polymers
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB16136/37A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Standard Oil Development Co
Original Assignee
Standard Oil Development Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Standard Oil Development Co filed Critical Standard Oil Development Co
Publication of GB496966A publication Critical patent/GB496966A/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/0008—Organic ingredients according to more than one of the "one dot" groups of C08K5/01 - C08K5/59
    • C08K5/005—Stabilisers against oxidation, heat, light, ozone

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Polymerisation Methods In General (AREA)
  • Polyoxymethylene Polymers And Polymers With Carbon-To-Carbon Bonds (AREA)

Abstract

Natural or synthetic high molecular weight linear hydrocarbon polymers containing no acetylene groups, e.g. derived from olefines such as isobutylene, styrol, and indene, diolefines such as isoprene, or butadiene, or hydrogenated rubber, gutta or balata, are stabilized towards heating by incorporating therewith 0,1-5 per cent of an aromatic compound having attached to the ring an -XH group, which may be alkylated or esterified by an organic acid and in which X represents an atom of oxygen, sulphur, selenium or tellurium. The added substance may contain additional atoms of these elements which may also be present in either form or as disulphide. Typical additions are indicated. Examples are given of typical compounds and of the stabilization of polyisobutylene, obtained by the action of boron fluoride upon highly purified liquid isobutylene at a temperature of -100 DEG C., with tertiary amyl phenol, tertiary amyl phenol sulphide and disulphide and b -thionaphthol.ALSO:Natural or synthetic high molecular weight linear hydrocarbon polymers containing no acetylene groups, e.g. derived from olefines such as isobutylene, styrol, and indene, diolefines such as isoprene, or butadiene, or hydrogenated rubber, gutta or balata, are stabilized towards heating by incorporating therewith 0,1-5 per cent of an aromatic compound having attached to the ring a -XH, group, which may be alkylated or esterified by an organic acid and in which X represents an atom of oxygen, sulphur, selenium or tellurium. The added substance may contain additional atoms of these elements which may also be present in either form or as disulphide. Typical additions are indicated. Examples are given of typical compounds and of the stabilization of polyisobutylene, obtained by the action of boron fluoride upon highly purified liquid isobutylene at a temperature of -100 DEG C., with tertiary amyl phenol, tertiary amyl phenol sulphide and disulphide, and beta thionaphthol.
GB16136/37A 1936-07-25 1937-06-10 An improved manufacture of stabilised hydrocarbon polymers Expired GB496966A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US496966XA 1936-07-25 1936-07-25

Publications (1)

Publication Number Publication Date
GB496966A true GB496966A (en) 1938-12-09

Family

ID=21961185

Family Applications (1)

Application Number Title Priority Date Filing Date
GB16136/37A Expired GB496966A (en) 1936-07-25 1937-06-10 An improved manufacture of stabilised hydrocarbon polymers

Country Status (2)

Country Link
FR (1) FR823581A (en)
GB (1) GB496966A (en)

Cited By (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2458494A (en) * 1946-09-21 1949-01-11 Monsanto Chemicals Stabilization of vinyl compounds
DE1028774B (en) * 1955-12-15 1958-04-24 Hoechst Ag Process for the stabilization of low pressure polyethylene against the oxidative degradation by oxygen in the heat
DE1046306B (en) * 1956-08-25 1958-12-11 Hoechst Ag Stabilization of polyolefins against thermal oxidation
DE1096035B (en) * 1956-07-19 1960-12-29 Montedison Spa Process for the production of sheet material for sealing against water
DE1118450B (en) * 1956-11-29 1961-11-30 Western Electric Co Molding compound stabilized against oxidation
DE1118449B (en) * 1953-10-27 1961-11-30 Western Electric Co Molding compound stabilized against oxidation
DE1131007B (en) * 1956-11-29 1962-06-07 Western Electric Co Molding compound stabilized against oxidation
DE1133122B (en) * 1957-07-15 1962-07-12 Western Electric Co Molding compound stabilized against oxidation
DE1133884B (en) * 1958-03-24 1962-07-26 Ici Ltd Stabilized molding compound made from polyolefins
DE1133885B (en) * 1956-11-29 1962-07-26 Western Electric Co Molding compound stabilized against oxidation
DE1178590B (en) * 1958-03-27 1964-09-24 Hoechst Ag Process for stabilizing low pressure polyolefins
US3158615A (en) * 1960-07-20 1964-11-24 Union Carbide Corp Stabilized polymerizable vinyl pyridines
DE1191567B (en) * 1958-09-18 1965-04-22 Du Pont Molding compounds made from propylene polymers and a stabilizer combination

Cited By (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2458494A (en) * 1946-09-21 1949-01-11 Monsanto Chemicals Stabilization of vinyl compounds
DE1118449B (en) * 1953-10-27 1961-11-30 Western Electric Co Molding compound stabilized against oxidation
DE1028774B (en) * 1955-12-15 1958-04-24 Hoechst Ag Process for the stabilization of low pressure polyethylene against the oxidative degradation by oxygen in the heat
DE1096035B (en) * 1956-07-19 1960-12-29 Montedison Spa Process for the production of sheet material for sealing against water
DE1046306B (en) * 1956-08-25 1958-12-11 Hoechst Ag Stabilization of polyolefins against thermal oxidation
DE1131007B (en) * 1956-11-29 1962-06-07 Western Electric Co Molding compound stabilized against oxidation
DE1118450B (en) * 1956-11-29 1961-11-30 Western Electric Co Molding compound stabilized against oxidation
DE1133885B (en) * 1956-11-29 1962-07-26 Western Electric Co Molding compound stabilized against oxidation
DE1133122B (en) * 1957-07-15 1962-07-12 Western Electric Co Molding compound stabilized against oxidation
DE1133884B (en) * 1958-03-24 1962-07-26 Ici Ltd Stabilized molding compound made from polyolefins
DE1178590B (en) * 1958-03-27 1964-09-24 Hoechst Ag Process for stabilizing low pressure polyolefins
DE1191567B (en) * 1958-09-18 1965-04-22 Du Pont Molding compounds made from propylene polymers and a stabilizer combination
US3158615A (en) * 1960-07-20 1964-11-24 Union Carbide Corp Stabilized polymerizable vinyl pyridines

Also Published As

Publication number Publication date
FR823581A (en) 1938-01-22

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