DE10316662A1 - Reaktive Amino- und/oder Ammonium-Polysiloxanverbindungen - Google Patents

Reaktive Amino- und/oder Ammonium-Polysiloxanverbindungen Download PDF

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Publication number
DE10316662A1
DE10316662A1 DE10316662A DE10316662A DE10316662A1 DE 10316662 A1 DE10316662 A1 DE 10316662A1 DE 10316662 A DE10316662 A DE 10316662A DE 10316662 A DE10316662 A DE 10316662A DE 10316662 A1 DE10316662 A1 DE 10316662A1
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DE
Germany
Prior art keywords
groups
compound
formula
group
amino
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
DE10316662A
Other languages
German (de)
English (en)
Inventor
Horst Dr. Lange
Anita Witossek
Roland Dr. Wagner
Karl-Heinz Stachulla
Karl-Heinz Sockel
Annette MÖLLER
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Momentive Performance Materials GmbH
Original Assignee
GE Bayer Silicones GmbH and Co KG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by GE Bayer Silicones GmbH and Co KG filed Critical GE Bayer Silicones GmbH and Co KG
Priority to DE10316662A priority Critical patent/DE10316662A1/de
Priority to MXPA05010938A priority patent/MXPA05010938A/es
Priority to CA2563403A priority patent/CA2563403C/en
Priority to BRPI0409279-1A priority patent/BRPI0409279B1/pt
Priority to EP04726174.8A priority patent/EP1627008B1/de
Priority to JP2006505530A priority patent/JP4726234B2/ja
Priority to US10/552,558 priority patent/US7863397B2/en
Priority to KR1020057019350A priority patent/KR101232941B1/ko
Priority to PCT/EP2004/050472 priority patent/WO2004090007A2/de
Priority to CNB2004800163728A priority patent/CN100537641C/zh
Publication of DE10316662A1 publication Critical patent/DE10316662A1/de
Ceased legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/37—Polymers
    • C11D3/3703—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • C11D3/373—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds containing silicones
    • C11D3/3742—Nitrogen containing silicones
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
    • A61K8/04—Dispersions; Emulsions
    • A61K8/046—Aerosols; Foams
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
    • A61K8/86—Polyethers
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
    • A61K8/89—Polysiloxanes
    • A61K8/891—Polysiloxanes saturated, e.g. dimethicone, phenyl trimethicone, C24-C28 methicone or stearyl dimethicone
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
    • A61K8/89—Polysiloxanes
    • A61K8/896—Polysiloxanes containing atoms other than silicon, carbon, oxygen and hydrogen, e.g. dimethicone copolyol phosphate
    • A61K8/898—Polysiloxanes containing atoms other than silicon, carbon, oxygen and hydrogen, e.g. dimethicone copolyol phosphate containing nitrogen, e.g. amodimethicone, trimethyl silyl amodimethicone or dimethicone propyl PG-betaine
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q19/00—Preparations for care of the skin
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q19/00—Preparations for care of the skin
    • A61Q19/10—Washing or bathing preparations
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G77/00—Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule
    • C08G77/04—Polysiloxanes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G77/00—Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule
    • C08G77/04—Polysiloxanes
    • C08G77/38—Polysiloxanes modified by chemical after-treatment
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G77/00—Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule
    • C08G77/04—Polysiloxanes
    • C08G77/38—Polysiloxanes modified by chemical after-treatment
    • C08G77/382—Polysiloxanes modified by chemical after-treatment containing atoms other than carbon, hydrogen, oxygen or silicon
    • C08G77/388—Polysiloxanes modified by chemical after-treatment containing atoms other than carbon, hydrogen, oxygen or silicon containing nitrogen
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/643—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds containing silicon in the main chain
    • D06M15/6436—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds containing silicon in the main chain containing amino groups
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q5/00—Preparations for care of the hair
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q5/00—Preparations for care of the hair
    • A61Q5/004—Preparations used to protect coloured hair
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q5/00—Preparations for care of the hair
    • A61Q5/06—Preparations for styling the hair, e.g. by temporary shaping or colouring
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q5/00—Preparations for care of the hair
    • A61Q5/12—Preparations containing hair conditioners

Landscapes

  • Health & Medical Sciences (AREA)
  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Animal Behavior & Ethology (AREA)
  • General Health & Medical Sciences (AREA)
  • Public Health (AREA)
  • Veterinary Medicine (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Birds (AREA)
  • Epidemiology (AREA)
  • Organic Chemistry (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Engineering & Computer Science (AREA)
  • Dermatology (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Wood Science & Technology (AREA)
  • Dispersion Chemistry (AREA)
  • Textile Engineering (AREA)
  • Silicon Polymers (AREA)
  • Cosmetics (AREA)
  • Detergent Compositions (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
DE10316662A 2003-04-11 2003-04-11 Reaktive Amino- und/oder Ammonium-Polysiloxanverbindungen Ceased DE10316662A1 (de)

Priority Applications (10)

Application Number Priority Date Filing Date Title
DE10316662A DE10316662A1 (de) 2003-04-11 2003-04-11 Reaktive Amino- und/oder Ammonium-Polysiloxanverbindungen
MXPA05010938A MXPA05010938A (es) 2003-04-11 2004-04-07 Amino reactivo y/o compuestos de amino-polisiloxano.
CA2563403A CA2563403C (en) 2003-04-11 2004-04-07 Reactive amino- and/or ammonium-polysiloxane compounds
BRPI0409279-1A BRPI0409279B1 (pt) 2003-04-11 2004-04-07 Compostos de amino- e/ou amônio-polissiloxano reativos, suasaplicações, formulação compreendendo os mesmos, processos de preparaçãodos referidos compostos e tratamento e/ou acabamento de fibras, bem como asreferidas fibras
EP04726174.8A EP1627008B1 (de) 2003-04-11 2004-04-07 Reaktive amino- und/oder ammonium-polysiloxanverbindungen
JP2006505530A JP4726234B2 (ja) 2003-04-11 2004-04-07 反応性アミノ−及び/又はアンモニウム−ポリシロキサン化合物
US10/552,558 US7863397B2 (en) 2003-04-11 2004-04-07 Reactive amino-and/or ammonium polysiloxane compounds
KR1020057019350A KR101232941B1 (ko) 2003-04-11 2004-04-07 반응성 아미노- 및(또는) 암모늄-폴리실록산 화합물
PCT/EP2004/050472 WO2004090007A2 (de) 2003-04-11 2004-04-07 Reaktive amino- und/oder ammonium-polysiloxanverbindungen
CNB2004800163728A CN100537641C (zh) 2003-04-11 2004-04-07 活性的氨基和/或铵基聚硅氧烷化合物

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
DE10316662A DE10316662A1 (de) 2003-04-11 2003-04-11 Reaktive Amino- und/oder Ammonium-Polysiloxanverbindungen

Publications (1)

Publication Number Publication Date
DE10316662A1 true DE10316662A1 (de) 2004-11-11

Family

ID=33154161

Family Applications (1)

Application Number Title Priority Date Filing Date
DE10316662A Ceased DE10316662A1 (de) 2003-04-11 2003-04-11 Reaktive Amino- und/oder Ammonium-Polysiloxanverbindungen

Country Status (10)

Country Link
US (1) US7863397B2 (enExample)
EP (1) EP1627008B1 (enExample)
JP (1) JP4726234B2 (enExample)
KR (1) KR101232941B1 (enExample)
CN (1) CN100537641C (enExample)
BR (1) BRPI0409279B1 (enExample)
CA (1) CA2563403C (enExample)
DE (1) DE10316662A1 (enExample)
MX (1) MXPA05010938A (enExample)
WO (1) WO2004090007A2 (enExample)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE102005018315A1 (de) * 2005-04-20 2006-11-02 Rudolf Gmbh & Co. Kg Chemische Fabrik Zubereitungen auf Basis von carboxyfunktionellen Organopolysiloxan-Polyammonium-Copolymeren und deren Verwendung auf cellulosischen Substraten
WO2008095822A3 (en) * 2007-02-06 2008-11-27 Ciba Holding Inc Polysiloxane block copolymers

Families Citing this family (37)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE102005014311A1 (de) * 2005-03-30 2006-10-12 Ge Bayer Silicones Gmbh & Co. Kg Polyamino- und/oder Polyammonium-Polysiloxan-Colpolymer-Verbindungen mit kammartig angeordneten Polyalkylenonideinheiten
DE102005036602A1 (de) * 2005-08-01 2007-02-08 Ge Bayer Silicones Gmbh & Co. Kg Polyammonium-Polysiloxancopolymere
US20070286837A1 (en) * 2006-05-17 2007-12-13 Torgerson Peter M Hair care composition comprising an aminosilicone and a high viscosity silicone copolymer emulsion
DE102007012908A1 (de) 2007-03-19 2008-09-25 Momentive Performance Materials Gmbh Neue Polyamid-Polysiloxan-Verbindungen
US20080235879A1 (en) * 2007-03-28 2008-10-02 Ecolab Inc. Method of producing substantially wrinkle-free textile surfaces
DE102007023869A1 (de) 2007-05-21 2008-12-18 Momentive Performance Materials Gmbh & Co. Kg Neue Polycarbonat- und/oder Polyurethan-Polyorganosiloxan-Verbindungen
DE102007027027A1 (de) 2007-06-08 2008-12-11 Momentive Performance Materials Gmbh & Co. Kg Neue Polyharnstoff- und/oder Polyurethan-Polyorganosiloxan-Verbindungen
JP5484332B2 (ja) * 2007-08-14 2014-05-07 モーメンテイブ・パーフオーマンス・マテリアルズ・ゲゼルシヤフト・ミツト・ベシユレンクテル・ハフツング ポリ尿素ポリ有機シロキサン化合物、その生成方法、その使用、その一成分系または二成分系、およびそれによる硬化組成物
JP2010540789A (ja) * 2007-09-25 2010-12-24 モメンティブ パフォーマンス マテリアルズ インコーポレイテッド 合成繊維の表面を改質する方法
US8642022B2 (en) * 2007-11-02 2014-02-04 Momentive Performance Materials Inc. Copolymers of epoxy compounds and amino silanes
CN101970750B (zh) * 2007-11-02 2015-06-10 莫门蒂夫性能材料股份有限公司 用环氧化合物和氨基硅烷的共聚物处理的织物
PL2214633T3 (pl) * 2007-11-02 2012-01-31 Momentive Performance Mat Inc Kompozycja do pielęgnacji osobistej zawierająca produkt reakcji związku epoksydowego i aminosilanu
US20090118421A1 (en) * 2007-11-02 2009-05-07 Momentive Performance Materials Inc. Copolymer of epoxy compounds and amino silanes
DE102008013584A1 (de) 2008-03-11 2009-09-17 Momentive Performance Materials Gmbh Neue Polycarbonat-Polyorganosiloxan- und/oder Polyurethan-Polyorganosiloxan-Verbindungen
BRPI0910383A2 (pt) * 2008-03-11 2019-03-19 Momentive Performance Mat Gmbh compostos de poliuretano e/ou policarboanto de amônio
DE102008014762A1 (de) 2008-03-18 2009-09-24 Momentive Performance Materials Gmbh Verwendung von Polyamino- und/oder Polyammonium-Polysiloxan-Copolymer-Verbindungen
DE102008014761A1 (de) 2008-03-18 2009-12-10 Momentive Performance Materials Gmbh Verwendung von Polyamino- und/oder Polyammonium-Polysiloxan-Copolymer-Verbindungen
JP5640879B2 (ja) * 2011-04-22 2014-12-17 信越化学工業株式会社 シリコーンマイクロエマルション組成物
WO2013034705A1 (en) 2011-09-09 2013-03-14 Momentive Performance Materials Gmbh Use of ionic polysiloxanes as a solvent in organic reactions
US9403183B2 (en) 2011-12-07 2016-08-02 Samsung Electronics Co., Ltd. Methods of material hydrophilization by glycidol-containing siloxanes
JP6385284B2 (ja) 2012-03-01 2018-09-05 ダウ シリコーンズ コーポレーション 水中油型エマルションから粒子を形成する方法
JP2015519413A (ja) 2012-03-29 2015-07-09 モメンティブ パフォーマンス マテリアルズ ゲーエムベーハー 第四級アンモニウム基を含む低粘度ポリオルガノシロキサン、その製造方法および用途(ii)
WO2013148935A1 (en) * 2012-03-29 2013-10-03 Momentive Performance Materials Inc. Low viscosity polyorganosiloxanes comprising quaternary ammonium groups, methods for the production and the use thereof
DE102012207062A1 (de) * 2012-04-27 2013-10-31 Wacker Chemie Ag Verfahren zur Herstellung von Aminogruppen aufweisenden Organosiliciumverbindungen
US9198849B2 (en) 2013-07-03 2015-12-01 The Procter & Gamble Company Shampoo composition comprising low viscosity emulsified silicone polymers
EP3049050B1 (en) 2013-09-27 2018-10-24 The Procter and Gamble Company Hair conditioning compositions comprising low viscosity emulsified silicone polymers
CN105694065B (zh) * 2014-11-23 2021-05-14 上海墨城化工科技发展有限公司 无甲醛弹性硅树脂分散体
JP2017014408A (ja) 2015-07-02 2017-01-19 信越化学工業株式会社 オルガノポリシロキサン並びに毛髪化粧料及びその製造方法
US10954342B2 (en) * 2016-04-19 2021-03-23 Wacker Chemie Ag Amino-organopolysiloxanes and preparation method therefor
CN106977722B (zh) * 2017-04-01 2020-07-14 广州天赐有机硅科技有限公司 一种活性基团封端的改性聚硅氧烷及其制备方法和应用
US11179312B2 (en) 2017-06-05 2021-11-23 Momentive Performance Materials Inc. Aqueous compositions for the treatment of hair
US10982051B2 (en) 2017-06-05 2021-04-20 Momentive Performance Materials Inc. Aqueous compositions for hair treatment comprising polyorganosiloxanes with polyhydroxyaromatic moieties
EP3501488B1 (en) 2017-12-21 2021-04-14 Momentive Performance Materials GmbH Aqueous silicone polymer compositions
US20200163850A1 (en) 2018-11-24 2020-05-28 Momentive Performance Materials Gmbh Use of polyhydroxyaromatic compounds for the treatment of fibrous amino acid based substrates
US11090255B2 (en) 2018-12-04 2021-08-17 Momentive Performance Materials Inc. Use of polycarboxylic acid compounds for the treatment of fibrious amino acid based substrates, especially hair
US10617617B1 (en) 2018-12-04 2020-04-14 Momentive Performance Materials Inc. Polycarboxylic acid compounds for the treatment of fibrious amino acid based substrates, especially hair
CN116355222B (zh) * 2021-12-20 2025-05-13 山东东岳有机硅材料股份有限公司 一种耐水洗氨基、聚醚共改性聚硅氧烷及制备方法

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DE3803628A1 (de) * 1988-02-06 1989-08-17 Bayer Ag Verwendung von aminogruppen aufweisenden polysiloxanen als zusatzmittel in kunststofflacken
DE4208447C1 (en) * 1992-03-17 1993-06-03 Th. Goldschmidt Ag, 4300 Essen, De Silicone(s) with silicon-carbon linked residues contg. basic N and alkoxy gps. - by reacting silicone(s) contg. hydroxy-alkyl gps. with amino:alkyl-alkoxy-silane(s) in presence of non-equilibrating acid catalyst
US5276123A (en) * 1992-09-03 1994-01-04 Dow Corning Corporation Alkoxy endblocked polydiorganosiloxane and room temperature vulcanizable silicone elastomers made therefrom
DE19524816A1 (de) * 1995-07-07 1997-01-09 Bayer Ag Hydroxylierte Siloxanblockcopolymere
DE19852621A1 (de) * 1998-11-14 2000-05-18 Hansa Textilchemie Gmbh Permanentes Mittel zum Ausrüsten von Fasern oder aus Faser bestehenden Produkten
WO2003002809A1 (en) * 2000-11-16 2003-01-09 The Procter & Gamble Company Hydrophilic curable ethoxylated silicones

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US20070106045A1 (en) 2007-05-10
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CA2563403C (en) 2012-01-03
WO2004090007A3 (de) 2005-08-25
US7863397B2 (en) 2011-01-04
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