DE09829577T1 - Azeotrope zusammensetzungen mit 1-chlor-3,3,3-trifluorpropen - Google Patents

Azeotrope zusammensetzungen mit 1-chlor-3,3,3-trifluorpropen

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Publication number
DE09829577T1
DE09829577T1 DE9829577T DE09829577T DE09829577T1 DE 09829577 T1 DE09829577 T1 DE 09829577T1 DE 9829577 T DE9829577 T DE 9829577T DE 09829577 T DE09829577 T DE 09829577T DE 09829577 T1 DE09829577 T1 DE 09829577T1
Authority
DE
Germany
Prior art keywords
weight percent
chloro
trifluoropropene
azeotrope
composition
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
DE9829577T
Other languages
English (en)
Inventor
Rajiv R. Singh
Gary Knopeck
David J. Williams
Rajat Basu
Hang T. Pham
Ryan Hulse
Kane Cook
Leslie Bement
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Honeywell International Inc
Original Assignee
Honeywell International Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from US12/259,694 external-priority patent/US7935268B2/en
Application filed by Honeywell International Inc filed Critical Honeywell International Inc
Publication of DE09829577T1 publication Critical patent/DE09829577T1/de
Pending legal-status Critical Current

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    • A61K47/06—Organic compounds, e.g. natural or synthetic hydrocarbons, polyolefins, mineral oil, petrolatum or ozokerite
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Abstract

Zusammensetzung, umfassend eine binäre azeotropähnliche Mischung bestehend im Wesentlichen aus 1-Chlor-3,3,3-trifluorpropen und einem C1-C3-Alkohol, ausgewählt aus der Gruppe bestehend aus Methanol, Ethanol und Isopropanol.

Claims (35)

  1. Zusammensetzung, umfassend eine binäre azeotropähnliche Mischung bestehend im Wesentlichen aus 1-Chlor-3,3,3-trifluorpropen und einem C1-C3-Alkohol, ausgewählt aus der Gruppe bestehend aus Methanol, Ethanol und Isopropanol.
  2. Zusammensetzung nach Anspruch 1, wobei die azeotropähnliche Mischung im Wesentlichen aus etwa 70 bis etwa 99,9 Gewichtsprozent trans-1-Chlor-3,3,3-trifluorpropen und etwa 0,1 bis etwa 30 Gewichtsprozent Methanol besteht.
  3. Zusammensetzung nach Anspruch 1, wobei die azeotropähnliche Mischung im Wesentlichen aus etwa 78 bis etwa 99,9 Gewichtsprozent cis-1-Chlor-3,3,3-trifluorpropen und etwa 0,1 bis etwa 22 Gewichtsprozent Methanol besteht.
  4. Zusammensetzung nach Anspruch 1, wobei die azeotropähnliche Mischung im Wesentlichen aus etwa 85 bis etwa 99,9 Gewichtsprozent trans-1-Chlor-3,3,3-trifluorpropen und etwa 0,1 bis etwa 15 Gewichtsprozent Ethanol besteht.
  5. Zusammensetzung nach Anspruch 1, wobei die azeotropähnliche Mischung im Wesentlichen aus etwa 65 bis etwa 99,9 Gewichtsprozent cis-1-Chlor-3,3,3-trifluorpropen und etwa 0,1 bis etwa 35 Gewichtsprozent Ethanol besteht.
  6. Zusammensetzung nach Anspruch 1, wobei die azeotropähnliche Mischung im Wesentlichen aus etwa 90 bis etwa 99,9 Gewichtsprozent trans-1-Chlor-3,3,3-trifluorpropen und etwa 0,1 bis etwa 10 Gewichtsprozent Isopropanol besteht.
  7. Zusammensetzung nach Anspruch 1, wobei die azeotropähnliche Mischung im Wesentlichen aus etwa 85 bis etwa 99,9 Gewichtsprozent cis-1-Chlor-3,3,3-trifluorpropen und etwa 0,1 bis etwa 15 Gewichtsprozent Isopropanol besteht.
  8. Zusammensetzung, umfassend eine binäre azeotropähnliche Mischung bestehend im Wesentlichen aus 1-Chlor-3,3,3-trifluorpropen und einem C5-C6-Kohlenwasserstoff, ausgewählt aus der Gruppe bestehend aus n-Pentan, Isopentan, n-Hexan, Isohexan, Neopentan, Cyclopentan und Cyclopenten.
  9. Zusammensetzung nach Anspruch 8, wobei die azeotropähnliche Mischung im Wesentlichen aus etwa 65 bis etwa 99,9 Gewichtsprozent trans-1-Chlor-3,3,3-trifluorpropen und etwa 0,1 bis etwa 35 Gewichtsprozent n-Pentan besteht.
  10. Zusammensetzung nach Anspruch 8, wobei die azeotropähnliche Mischung im Wesentlichen aus etwa 20 bis etwa 99,5 Gewichtsprozent cis-1-Chlor-3,3,3-trifluorpropen und etwa 0,5 bis etwa 80 Gewichtsprozent n-Pentan besteht.
  11. Zusammensetzung nach Anspruch 8, wobei die azeotropähnliche Mischung im Wesentlichen aus etwa 60 bis etwa 99,95 Gewichtsprozent trans-1-Chlor-3,3,3-trifluorpropen und etwa 0,05 bis etwa 40 Gewichtsprozent Isopentan besteht.
  12. Zusammensetzung nach Anspruch 8, wobei die azeotropähnliche Mischung im Wesentlichen aus etwa 60 bis etwa 99,9 Gewichtsprozent trans-1-Chlor-3,3,3-trifluorpropen und etwa 0,1 bis etwa 40 Gewichtsprozent Neopentan besteht.
  13. Zusammensetzung nach Anspruch 8, wobei die azeotropähnliche Mischung im Wesentlichen aus etwa 5 bis etwa 50 Gewichtsprozent cis-1-Chlor-3,3,3-trifluorpropen und etwa 0,1 bis etwa 40 Gewichtsprozent Neopentan besteht.
  14. Zusammensetzung nach Anspruch 8, wobei die azeotropähnliche Mischung im Wesentlichen aus etwa 95 bis etwa 99,9 Gewichtsprozent trans-1-Chlor-3,3,3-trifluorpropen und etwa 0,1 bis etwa 5 Gewichtsprozent Cyclopentan besteht.
  15. Zusammensetzung nach Anspruch 8, wobei die azeotropähnliche Mischung im Wesentlichen aus etwa 42 bis etwa 99 Gewichtsprozent cis-1-Chlor-3,3,3-trifluorpropen und etwa 1 bis etwa 58 Gewichtsprozent Cyclopentan besteht.
  16. Zusammensetzung nach Anspruch 8, wobei die azeotropähnliche Mischung im Wesentlichen aus etwa 95 bis etwa 99,9 Gewichtsprozent trans-1-Chlor-3,3,3-trifluorpropen und etwa 0,1 bis etwa 5 Gewichtsprozent Cyclopenten besteht.
  17. Zusammensetzung nach Anspruch 8, wobei die azeotropähnliche Mischung im Wesentlichen aus etwa 95 bis etwa 99,99 Gewichtsprozent trans-1-Chlor-3,3,3-trifluorpropen und etwa 0,01 bis etwa 5 Gewichtsprozent n-Hexan besteht.
  18. Zusammensetzung nach Anspruch 8, wobei die azeotropähnliche Mischung im wesentlichen aus etwa 80 bis etwa 99,5 Gewichtsprozent cis-1-Chlor-3,3,3-trifluorpropen und etwa 0,5 bis etwa 20 Gewichtsprozent n-Hexan besteht.
  19. Zusammensetzung nach Anspruch 8, wobei die azeotropähnliche Mischung im Wesentlichen aus etwa 94,4 bis etwa 99,99 Gewichtsprozent trans-1-Chlor-3,3,3-trifluorpropen und etwa 0,01 bis etwa 5,6 Gewichtsprozent Isohexan besteht.
  20. Zusammensetzung nach Anspruch 8, wobei die azeotropähnliche Mischung im Wesentlichen aus etwa 70 bis etwa 99,5 Gewichtsprozent cis-1-Chlor-3,3,3-trifluorpropen und etwa 0,5 bis etwa 30 Gewichtsprozent Isohexan besteht.
  21. Zusammensetzung, umfassend eine binäre azeotropähnliche Mischung bestehend im Wesentlichen aus 1-Chlor-3,3,3-trifluorpropen und einem halogenierten Kohlenwasserstoff, ausgewählt aus der Gruppe bestehend aus 1-Chlorpropan, 2-Chlorpropan, 1,1,1,3,3-Pentafluorbutan und trans-1,2-Dichlorethylen, vorausgesetzt, dass, wenn der halogenierte Kohlenwasserstoff trans-1,2-Dichlorethylen ist und das 1-Chlor-3,3,3-Trifluorpropen trans-1-Chlor-3,3,3-trifluorpropen ist, die azeotropähnliche Mischung einen Siedepunkt von etwa 17°C bis etwa 19°C bei einem Druck von etwa 14,7 psia ± 0,5 psi aufweist.
  22. Zusammensetzung nach Anspruch 21, wobei die azeotropähnliche Mischung im Wesentlichen aus etwa 96 bis etwa 99,9 Gewichtsprozent trans-1-Chlor-3,3,3-trifluorpropen und etwa 0,1 bis etwa 4 Gewichtsprozent 1-Chlorpropan besteht.
  23. Zusammensetzung nach Anspruch 21, wobei die azeotropähnliche Mischung im Wesentlichen aus etwa 94 bis etwa 99,9 Gewichtsprozent trans-1-Chlor-3,3,3-trifluorpropen und etwa 0,1 bis etwa 6 Gewichtsprozent 2-Chlorpropan besteht.
  24. Zusammensetzung nach Anspruch 21, wobei die azeotropähnliche Mischung im Wesentlichen aus etwa 89 bis etwa 99,9 Gewichtsprozent trans-1-Chlor-3,3,3-trifluorpropen und etwa 0,1 bis etwa 11 Gewichtsprozent 1,1,1,3,3-Pentafluorbutan besteht.
  25. Zusammensetzung nach Anspruch 21, wobei die azeotropähnliche Mischung im Wesentlichen aus etwa 75 bis etwa 99,99 Gewichtsprozent trans-1-Chlor-3,3,3-trifluorpropen und etwa 0,01 bis etwa 25 Gewichtsprozent trans-1,2-Dichlorethylen besteht.
  26. Zusammensetzung nach Anspruch 21, wobei die azeotropähnliche Mischung im Wesentlichen aus etwa 42 bis etwa 99,9 Gewichtsprozent cis-1-Chlor-3,3,3-trifluorpropen und etwa 0,1 bis etwa 58 Gewichtsprozent trans-1,2-Dichlorethylen besteht.
  27. Zusammensetzung, umfassend eine binäre azeotropähnliche Mischung bestehend im Wesentlichen aus trans-1-Chlor-3,3,3-trifluorpropen und einer zweiten Komponente, ausgewählt aus der Gruppe bestehend aus Methylal und Methylaceton, vorausgesetzt, dass das trans-1-Chlor-3,3,3-trifluorpropen in einer Menge vorliegt, die mindestens 90 Gewichtsprozent der Mischung beträgt.
  28. Zusammensetzung nach Anspruch 27, wobei die azeotropähnliche Mischung im Wesentlichen aus etwa 95 bis etwa 99,9 Gewichtsprozent trans-1-Chlor-3,3,3-trifluorpropen und etwa 0,1 bis etwa 5 Gewichtsprozent Methylal besteht.
  29. Zusammensetzung nach Anspruch 27, wobei die azeotropähnliche Mischung im Wesentlichen aus etwa 90 bis etwa 99,9 Gewichtsprozent trans-1-Chlor-3,3,3-trifluorpropen und etwa 0,1 bis etwa 10 Gewichtsprozent Methylaceton besteht.
  30. Zusammensetzung, umfassend eine ternäre azeotropähnliche Mischung bestehend im Wesentlichen aus trans-1-Chlor-3,3,3-trifluorpropen, Methanol und einer dritten Komponente, ausgewählt unter n-Pentan und trans-1,2-Dichlorethylen.
  31. Zusammensetzung nach Anspruch 30, wobei die azeotropähnliche Mischung im Wesentlichen aus etwa 55 bis etwa 99,90 Gew.-% trans-1-Chlor-3,3,3-trifluorpropen, etwa 0,05 bis etwa 10 Gew.-% Methanol und etwa 0,05 bis etwa 35 Gew.-% n-Pentan besteht.
  32. Zusammensetzung nach Anspruch 30, wobei die azeotropähnliche Mischung im Wesentlichen aus etwa 80 bis etwa 99,90 Gew.-% trans-1-Chlor-3,3,3-trifluorpropen, etwa 0,05 bis etwa 15 Gew.-% Methanol und etwa 0,05 bis etwa 10 Gew.-% trans-1,2-Dichlorethylen besteht.
  33. Zusammensetzung, umfassend eine binäre azeotropähnliche Mischung bestehend im wesentlichen aus trans-1-Chlor-3,3,3-trifluorpropen und Wasser.
  34. Zusammensetzung, umfassend eine binäre azeotropähnliche Mischung bestehend im Wesentlichen aus cis-1-Chlor-3,3,3-trifluorpropen und Nitromethan.
  35. Zusammensetzung, umfassend eine binäre azeotropähnliche Mischung bestehend im Wesentlichen aus trans-1-Chlor-3,3,3-trifluorpropen und Nitromethan.
DE9829577T 2008-10-28 2009-10-27 Azeotrope zusammensetzungen mit 1-chlor-3,3,3-trifluorpropen Pending DE09829577T1 (de)

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US109007P 2008-10-28
US12/605,609 US8163196B2 (en) 2008-10-28 2009-10-26 Azeotrope-like compositions comprising 1-chloro-3,3,3-trifluoropropene
US605609 2009-10-26
PCT/US2009/062146 WO2010062572A2 (en) 2008-10-28 2009-10-27 Azeotrope-like compositions comprising 1-chloro-3,3,3-trifluoropropene
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