DD254015A5 - Fluessige, polymerisierbare masse fuer die herstellung von optischen kunstglaesern - Google Patents
Fluessige, polymerisierbare masse fuer die herstellung von optischen kunstglaesern Download PDFInfo
- Publication number
- DD254015A5 DD254015A5 DD86297900A DD29790086A DD254015A5 DD 254015 A5 DD254015 A5 DD 254015A5 DD 86297900 A DD86297900 A DD 86297900A DD 29790086 A DD29790086 A DD 29790086A DD 254015 A5 DD254015 A5 DD 254015A5
- Authority
- DD
- German Democratic Republic
- Prior art keywords
- component
- diethylene glycol
- weight
- tris
- allyl carbonate
- Prior art date
Links
- 239000007788 liquid Substances 0.000 title claims abstract description 23
- 230000003287 optical effect Effects 0.000 title claims abstract description 17
- 238000004519 manufacturing process Methods 0.000 title claims abstract description 7
- 239000005391 art glass Substances 0.000 title claims description 4
- 239000000203 mixture Substances 0.000 claims abstract description 41
- 238000006116 polymerization reaction Methods 0.000 claims abstract description 22
- JHQVCQDWGSXTFE-UHFFFAOYSA-N 2-(2-prop-2-enoxycarbonyloxyethoxy)ethyl prop-2-enyl carbonate Chemical compound C=CCOC(=O)OCCOCCOC(=O)OCC=C JHQVCQDWGSXTFE-UHFFFAOYSA-N 0.000 claims abstract description 18
- JKJWYKGYGWOAHT-UHFFFAOYSA-N bis(prop-2-enyl) carbonate Chemical compound C=CCOC(=O)OCC=C JKJWYKGYGWOAHT-UHFFFAOYSA-N 0.000 claims abstract description 18
- BPXVHIRIPLPOPT-UHFFFAOYSA-N 1,3,5-tris(2-hydroxyethyl)-1,3,5-triazinane-2,4,6-trione Chemical compound OCCN1C(=O)N(CCO)C(=O)N(CCO)C1=O BPXVHIRIPLPOPT-UHFFFAOYSA-N 0.000 claims abstract description 11
- 239000007983 Tris buffer Substances 0.000 claims abstract description 8
- 238000005266 casting Methods 0.000 claims abstract description 6
- 239000000178 monomer Substances 0.000 claims abstract description 5
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 claims description 29
- 239000000047 product Substances 0.000 claims description 17
- 239000007795 chemical reaction product Substances 0.000 claims description 9
- -1 allyl carbonates Chemical class 0.000 claims description 8
- 239000003505 polymerization initiator Substances 0.000 claims description 5
- 150000003254 radicals Chemical class 0.000 claims description 5
- BLCKNMAZFRMCJJ-UHFFFAOYSA-N cyclohexyl cyclohexyloxycarbonyloxy carbonate Chemical compound C1CCCCC1OC(=O)OOC(=O)OC1CCCCC1 BLCKNMAZFRMCJJ-UHFFFAOYSA-N 0.000 claims description 4
- 239000003999 initiator Substances 0.000 claims description 4
- 238000000034 method Methods 0.000 claims description 4
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 claims description 3
- OMPJBNCRMGITSC-UHFFFAOYSA-N Benzoylperoxide Chemical compound C=1C=CC=CC=1C(=O)OOC(=O)C1=CC=CC=C1 OMPJBNCRMGITSC-UHFFFAOYSA-N 0.000 claims description 2
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 claims description 2
- 239000006096 absorbing agent Substances 0.000 claims description 2
- NSGQRLUGQNBHLD-UHFFFAOYSA-N butan-2-yl butan-2-yloxycarbonyloxy carbonate Chemical compound CCC(C)OC(=O)OOC(=O)OC(C)CC NSGQRLUGQNBHLD-UHFFFAOYSA-N 0.000 claims description 2
- 239000003795 chemical substances by application Substances 0.000 claims description 2
- 239000000975 dye Substances 0.000 claims description 2
- 239000000049 pigment Substances 0.000 claims description 2
- BWJUFXUULUEGMA-UHFFFAOYSA-N propan-2-yl propan-2-yloxycarbonyloxy carbonate Chemical group CC(C)OC(=O)OOC(=O)OC(C)C BWJUFXUULUEGMA-UHFFFAOYSA-N 0.000 claims description 2
- 239000003381 stabilizer Substances 0.000 claims description 2
- GJBRNHKUVLOCEB-UHFFFAOYSA-N tert-butyl benzenecarboperoxoate Chemical compound CC(C)(C)OOC(=O)C1=CC=CC=C1 GJBRNHKUVLOCEB-UHFFFAOYSA-N 0.000 claims description 2
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 abstract description 4
- JHPBZFOKBAGZBL-UHFFFAOYSA-N (3-hydroxy-2,2,4-trimethylpentyl) 2-methylprop-2-enoate Chemical compound CC(C)C(O)C(C)(C)COC(=O)C(C)=C JHPBZFOKBAGZBL-UHFFFAOYSA-N 0.000 abstract description 2
- 150000001875 compounds Chemical class 0.000 description 6
- HECLRDQVFMWTQS-UHFFFAOYSA-N Dicyclopentadiene Chemical compound C1C2C3CC=CC3C1C=C2 HECLRDQVFMWTQS-UHFFFAOYSA-N 0.000 description 5
- 230000007935 neutral effect Effects 0.000 description 5
- 239000003054 catalyst Substances 0.000 description 3
- 230000007547 defect Effects 0.000 description 3
- 230000000379 polymerizing effect Effects 0.000 description 3
- 238000002834 transmittance Methods 0.000 description 3
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 2
- 230000000052 comparative effect Effects 0.000 description 2
- 239000011521 glass Substances 0.000 description 2
- 239000000654 additive Substances 0.000 description 1
- 235000019400 benzoyl peroxide Nutrition 0.000 description 1
- 238000012662 bulk polymerization Methods 0.000 description 1
- 238000012993 chemical processing Methods 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 238000004132 cross linking Methods 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- 230000009969 flowable effect Effects 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
- 239000011888 foil Substances 0.000 description 1
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 125000005395 methacrylic acid group Chemical group 0.000 description 1
- 239000005304 optical glass Substances 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 230000000717 retained effect Effects 0.000 description 1
- 229920002554 vinyl polymer Polymers 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- G—PHYSICS
- G02—OPTICS
- G02B—OPTICAL ELEMENTS, SYSTEMS OR APPARATUS
- G02B1/00—Optical elements characterised by the material of which they are made; Optical coatings for optical elements
- G02B1/04—Optical elements characterised by the material of which they are made; Optical coatings for optical elements made of organic materials, e.g. plastics
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F218/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an acyloxy radical of a saturated carboxylic acid, of carbonic acid or of a haloformic acid
- C08F218/24—Esters of carbonic or haloformic acids, e.g. allyl carbonate
Landscapes
- Physics & Mathematics (AREA)
- Chemical & Material Sciences (AREA)
- General Physics & Mathematics (AREA)
- Optics & Photonics (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Eyeglasses (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| IT8523289A IT1207518B (it) | 1985-12-19 | 1985-12-19 | Composizione liquida e polimerizzabile per la produzionedi sostituiti di vetri ottici. |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| DD254015A5 true DD254015A5 (de) | 1988-02-10 |
Family
ID=11205697
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DD86297900A DD254015A5 (de) | 1985-12-19 | 1986-12-18 | Fluessige, polymerisierbare masse fuer die herstellung von optischen kunstglaesern |
Country Status (10)
| Country | Link |
|---|---|
| US (1) | US4835233A (cs) |
| EP (1) | EP0227178A3 (cs) |
| JP (1) | JPH0627161B2 (cs) |
| CA (1) | CA1268287A (cs) |
| CS (1) | CS274286B2 (cs) |
| DD (1) | DD254015A5 (cs) |
| DK (1) | DK609786A (cs) |
| IE (1) | IE863291L (cs) |
| IT (1) | IT1207518B (cs) |
| NO (1) | NO166795C (cs) |
Families Citing this family (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| IT1228546B (it) * | 1987-07-31 | 1991-06-20 | Enichem Sintesi | Composizione liquida polimerizzabile in vetri organici dotati di elevata stabilita' termica |
| IT1223527B (it) * | 1987-12-18 | 1990-09-19 | Enichem Sintesi | Composizione liquida polimerizzabile in vetri organici dotati di basso assorbimento d'acqua e di elevata stabilita' termica |
| IT1217842B (it) * | 1988-06-17 | 1990-03-30 | Enichem Sintesi | Procedimento per la preparazione di vetri organici |
| US5286816A (en) * | 1991-03-28 | 1994-02-15 | Enichem Synthesis S.P.A. | Organic glass with improved impact strength and with a refractive index equal or similar to that of mineral glass |
| IT1245384B (it) * | 1991-03-28 | 1994-09-20 | Enichem Sintesi | Vetro organico con resistenza all'urto migliorata e con indice di rifrazione pari o simile a quello del vetro minerale |
| JPH089652B2 (ja) * | 1991-04-03 | 1996-01-31 | 竹本油脂株式会社 | ラジカル硬化性液状混合物、及びこれを含有するラジカル硬化性組成物、並びにこれらを硬化して得られる成形物 |
| US5237032A (en) * | 1992-09-30 | 1993-08-17 | Istituto Guido Donegani S.P.A. | Microwave processing of carbonate monomers |
| US5952441A (en) * | 1997-12-30 | 1999-09-14 | Ppg Industries Ohio, Inc. | Partially polymerized mixture of diethylene glycol (allyl carbonate) compounds |
| US7214754B2 (en) * | 1999-12-13 | 2007-05-08 | Ppg Industries Ohio, Inc. | Polymerizable polyol (allyl carbonate) compositions |
| MY127897A (en) * | 1999-12-13 | 2006-12-29 | Ppg Ind Ohio Inc | Polymerizable polyol(allyl carbonate) compositions |
| EP3500605B1 (en) | 2016-08-16 | 2020-05-20 | PPG Industries Ohio, Inc. | Polymerizable composition for optical articles |
Family Cites Families (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB1129688A (en) * | 1965-10-29 | 1968-10-09 | Bausch & Lomb | Diethylene glycol bis (allyl carbonate) terpolymer |
| US3658801A (en) * | 1969-06-10 | 1972-04-25 | Dart Ind Inc | Trisubstituted isocyanurates |
| US4205154A (en) * | 1977-10-05 | 1980-05-27 | Ppg Industries, Inc. | Triallyl carbonate polymers |
| JPS5661412A (en) * | 1979-10-25 | 1981-05-26 | Hoya Corp | High refractive-index terpolymer |
| IT1160172B (it) * | 1983-01-13 | 1987-03-04 | Anic Spa | Composizione liquida polimerizzabile, atta a produrre polimeri con elevate caratteristiche ottiche e meccaniche e polimeri e manufatti ottenuti da detta composizione |
| US4623708A (en) * | 1985-03-01 | 1986-11-18 | Coburn Optical Industries, Inc. | Prepolymerization of monomer compositions containing diethylene glycol bis(allyl carbonate) |
| US4622376A (en) * | 1985-06-27 | 1986-11-11 | Ppg Industries, Inc. | Composition of aromatic poly(allylcarbonate), styrene materials, and crosslinker containing three or more ethylenically unsaturated groups for producing polymer of high refractive index and low yellowness |
-
1985
- 1985-12-19 IT IT8523289A patent/IT1207518B/it active
-
1986
- 1986-12-15 EP EP86202268A patent/EP0227178A3/en not_active Withdrawn
- 1986-12-17 IE IE863291A patent/IE863291L/xx unknown
- 1986-12-17 DK DK609786A patent/DK609786A/da not_active Application Discontinuation
- 1986-12-17 NO NO865116A patent/NO166795C/no unknown
- 1986-12-18 DD DD86297900A patent/DD254015A5/de not_active IP Right Cessation
- 1986-12-18 CA CA000525756A patent/CA1268287A/en not_active Expired - Fee Related
- 1986-12-19 JP JP61301876A patent/JPH0627161B2/ja not_active Expired - Lifetime
- 1986-12-19 CS CS960786A patent/CS274286B2/cs unknown
-
1988
- 1988-08-25 US US07/237,664 patent/US4835233A/en not_active Expired - Fee Related
Also Published As
| Publication number | Publication date |
|---|---|
| CS274286B2 (en) | 1991-04-11 |
| JPS62156113A (ja) | 1987-07-11 |
| NO166795C (no) | 1991-09-04 |
| NO865116D0 (no) | 1986-12-17 |
| EP0227178A2 (en) | 1987-07-01 |
| CS960786A2 (en) | 1990-08-14 |
| IT8523289A0 (it) | 1985-12-19 |
| NO166795B (no) | 1991-05-27 |
| CA1268287A (en) | 1990-04-24 |
| DK609786A (da) | 1987-06-20 |
| EP0227178A3 (en) | 1988-12-21 |
| IE863291L (en) | 1987-06-19 |
| US4835233A (en) | 1989-05-30 |
| DK609786D0 (da) | 1986-12-17 |
| IT1207518B (it) | 1989-05-25 |
| NO865116L (no) | 1987-06-22 |
| JPH0627161B2 (ja) | 1994-04-13 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| ENJ | Ceased due to non-payment of renewal fee |