CN1864909B - 焊料合金和使用该焊料合金的半导体装置 - Google Patents
焊料合金和使用该焊料合金的半导体装置 Download PDFInfo
- Publication number
- CN1864909B CN1864909B CN2006100515427A CN200610051542A CN1864909B CN 1864909 B CN1864909 B CN 1864909B CN 2006100515427 A CN2006100515427 A CN 2006100515427A CN 200610051542 A CN200610051542 A CN 200610051542A CN 1864909 B CN1864909 B CN 1864909B
- Authority
- CN
- China
- Prior art keywords
- solder alloy
- weight
- antimony
- tin
- germanium
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- 229910045601 alloy Inorganic materials 0.000 title claims abstract description 86
- 239000000956 alloy Substances 0.000 title claims abstract description 86
- 229910000679 solder Inorganic materials 0.000 title claims abstract description 75
- 239000004065 semiconductor Substances 0.000 title claims abstract description 48
- 239000000758 substrate Substances 0.000 claims abstract description 47
- 229910052787 antimony Inorganic materials 0.000 claims abstract description 40
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 claims abstract description 34
- 229910052732 germanium Inorganic materials 0.000 claims abstract description 30
- GNPVGFCGXDBREM-UHFFFAOYSA-N germanium atom Chemical compound [Ge] GNPVGFCGXDBREM-UHFFFAOYSA-N 0.000 claims abstract description 30
- WATWJIUSRGPENY-UHFFFAOYSA-N antimony atom Chemical compound [Sb] WATWJIUSRGPENY-UHFFFAOYSA-N 0.000 claims abstract description 28
- 239000004020 conductor Substances 0.000 claims abstract description 12
- 238000003466 welding Methods 0.000 claims description 24
- 239000000919 ceramic Substances 0.000 claims description 12
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims description 11
- 239000010949 copper Substances 0.000 claims description 11
- 229910052802 copper Inorganic materials 0.000 claims description 10
- PNEYBMLMFCGWSK-UHFFFAOYSA-N Alumina Chemical compound [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims description 9
- 229910017083 AlN Inorganic materials 0.000 claims description 3
- PIGFYZPCRLYGLF-UHFFFAOYSA-N Aluminum nitride Chemical compound [Al]#N PIGFYZPCRLYGLF-UHFFFAOYSA-N 0.000 claims description 3
- 229910052581 Si3N4 Inorganic materials 0.000 claims description 3
- HQVNEWCFYHHQES-UHFFFAOYSA-N silicon nitride Chemical compound N12[Si]34N5[Si]62N3[Si]51N64 HQVNEWCFYHHQES-UHFFFAOYSA-N 0.000 claims description 3
- 230000000052 comparative effect Effects 0.000 description 10
- 239000000203 mixture Substances 0.000 description 9
- 238000002360 preparation method Methods 0.000 description 7
- 229910052751 metal Inorganic materials 0.000 description 6
- 239000002184 metal Substances 0.000 description 6
- 230000003647 oxidation Effects 0.000 description 6
- 238000007254 oxidation reaction Methods 0.000 description 6
- 230000032683 aging Effects 0.000 description 5
- 239000000843 powder Substances 0.000 description 5
- 238000000034 method Methods 0.000 description 4
- 238000006243 chemical reaction Methods 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 239000000463 material Substances 0.000 description 3
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- 230000004087 circulation Effects 0.000 description 2
- 238000001816 cooling Methods 0.000 description 2
- 230000004927 fusion Effects 0.000 description 2
- 235000011837 pasties Nutrition 0.000 description 2
- 239000002994 raw material Substances 0.000 description 2
- 238000010301 surface-oxidation reaction Methods 0.000 description 2
- 238000009736 wetting Methods 0.000 description 2
- 229910000838 Al alloy Inorganic materials 0.000 description 1
- 229910000881 Cu alloy Inorganic materials 0.000 description 1
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 description 1
- 208000037656 Respiratory Sounds Diseases 0.000 description 1
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 description 1
- 229910001128 Sn alloy Inorganic materials 0.000 description 1
- 230000003679 aging effect Effects 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 238000003912 environmental pollution Methods 0.000 description 1
- 239000008187 granular material Substances 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 230000005764 inhibitory process Effects 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 230000005499 meniscus Effects 0.000 description 1
- 229910052750 molybdenum Inorganic materials 0.000 description 1
- 239000011733 molybdenum Substances 0.000 description 1
- 229910052759 nickel Inorganic materials 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 229910052709 silver Inorganic materials 0.000 description 1
- 239000004332 silver Substances 0.000 description 1
- 238000005476 soldering Methods 0.000 description 1
- 230000008646 thermal stress Effects 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B23—MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
- B23K—SOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM
- B23K35/00—Rods, electrodes, materials, or media, for use in soldering, welding, or cutting
- B23K35/22—Rods, electrodes, materials, or media, for use in soldering, welding, or cutting characterised by the composition or nature of the material
- B23K35/24—Selection of soldering or welding materials proper
- B23K35/26—Selection of soldering or welding materials proper with the principal constituent melting at less than 400 degrees C
- B23K35/262—Sn as the principal constituent
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C13/00—Alloys based on tin
- C22C13/02—Alloys based on tin with antimony or bismuth as the next major constituent
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L24/00—Arrangements for connecting or disconnecting semiconductor or solid-state bodies; Methods or apparatus related thereto
- H01L24/01—Means for bonding being attached to, or being formed on, the surface to be connected, e.g. chip-to-package, die-attach, "first-level" interconnects; Manufacturing methods related thereto
- H01L24/26—Layer connectors, e.g. plate connectors, solder or adhesive layers; Manufacturing methods related thereto
- H01L24/31—Structure, shape, material or disposition of the layer connectors after the connecting process
- H01L24/33—Structure, shape, material or disposition of the layer connectors after the connecting process of a plurality of layer connectors
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L2924/00—Indexing scheme for arrangements or methods for connecting or disconnecting semiconductor or solid-state bodies as covered by H01L24/00
- H01L2924/01—Chemical elements
- H01L2924/01051—Antimony [Sb]
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L2924/00—Indexing scheme for arrangements or methods for connecting or disconnecting semiconductor or solid-state bodies as covered by H01L24/00
- H01L2924/01—Chemical elements
- H01L2924/01075—Rhenium [Re]
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L2924/00—Indexing scheme for arrangements or methods for connecting or disconnecting semiconductor or solid-state bodies as covered by H01L24/00
- H01L2924/013—Alloys
- H01L2924/014—Solder alloys
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L2924/00—Indexing scheme for arrangements or methods for connecting or disconnecting semiconductor or solid-state bodies as covered by H01L24/00
- H01L2924/15—Details of package parts other than the semiconductor or other solid state devices to be connected
- H01L2924/151—Die mounting substrate
- H01L2924/156—Material
- H01L2924/15786—Material with a principal constituent of the material being a non metallic, non metalloid inorganic material
- H01L2924/15787—Ceramics, e.g. crystalline carbides, nitrides or oxides
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L2924/00—Indexing scheme for arrangements or methods for connecting or disconnecting semiconductor or solid-state bodies as covered by H01L24/00
- H01L2924/30—Technical effects
- H01L2924/35—Mechanical effects
- H01L2924/351—Thermal stress
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Materials Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Computer Hardware Design (AREA)
- Microelectronics & Electronic Packaging (AREA)
- Power Engineering (AREA)
- Electric Connection Of Electric Components To Printed Circuits (AREA)
- Die Bonding (AREA)
- Cooling Or The Like Of Semiconductors Or Solid State Devices (AREA)
Abstract
Description
Sb(重量%) | Ge(重量%) | Sn | 湿强度(mN) | 湿润角(°) | 湿润区域的比率(%) | 氧化膜 | 1000次循环之后的裂纹长度(毫米) | |
对比例1 | 6.0 | - | 余量 | - | - | 83.6 | - | 3.0 |
对比例2 | 5.0 | - | 余量 | 14.4 | 9.7 | 100.0 | × | 3.0 |
实施例1 | 5.0 | 0.01 | 余量 | 15.2 | 3.3 | 100.0 | ◎ | - |
实施例2 | 5.0 | 0.05 | 余量 | 15.1 | 3.8 | 100.0 | ◎ | - |
实施例3 | 5.0 | 0.1 | 余量 | 15.1 | 4.2 | 100.0 | ◎ | - |
实施例4 | 5.0 | 0.2 | 余量 | 15.3 | 4.3 | 100.0 | ◎ | - |
对比例3 | 3.0 | - | 余量 | 14.5 | 9.5 | 84.0 | × | 3.4 |
实施例5 | 3.0 | 0.01 | 余量 | 15.2 | 3.1 | 100.0 | ◎ | - |
实施例6 | 3.0 | 0.05 | 余量 | 15.2 | 3.4 | 100.0 | ◎ | - |
实施例7 | 3.0 | 0.1 | 余量 | 15.3 | 3.5 | 100.0 | ◎ | - |
实施例8 | 3.0 | 0.2 | 余量 | 15.3 | 3.8 | 100.0 | ◎ | - |
对比例4 | 2.0 | - | 余量 | - | - | - | - | 9.1 |
Claims (5)
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2005148730A JP4635715B2 (ja) | 2005-05-20 | 2005-05-20 | はんだ合金およびそれを用いた半導体装置 |
JP2005148730 | 2005-05-20 | ||
JP2005-148730 | 2005-05-20 |
Related Child Applications (2)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN201210102888.0A Division CN102637662B (zh) | 2005-05-20 | 2006-02-28 | 使用焊料合金的半导体装置 |
CN2010102407673A Division CN101905388B (zh) | 2005-05-20 | 2006-02-28 | 一种制造半导体装置的方法 |
Publications (2)
Publication Number | Publication Date |
---|---|
CN1864909A CN1864909A (zh) | 2006-11-22 |
CN1864909B true CN1864909B (zh) | 2012-05-30 |
Family
ID=36061073
Family Applications (3)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN2006100515427A Active CN1864909B (zh) | 2005-05-20 | 2006-02-28 | 焊料合金和使用该焊料合金的半导体装置 |
CN2010102407673A Active CN101905388B (zh) | 2005-05-20 | 2006-02-28 | 一种制造半导体装置的方法 |
CN201210102888.0A Active CN102637662B (zh) | 2005-05-20 | 2006-02-28 | 使用焊料合金的半导体装置 |
Family Applications After (2)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN2010102407673A Active CN101905388B (zh) | 2005-05-20 | 2006-02-28 | 一种制造半导体装置的方法 |
CN201210102888.0A Active CN102637662B (zh) | 2005-05-20 | 2006-02-28 | 使用焊料合金的半导体装置 |
Country Status (5)
Country | Link |
---|---|
US (1) | US20060263235A1 (zh) |
JP (1) | JP4635715B2 (zh) |
CN (3) | CN1864909B (zh) |
DE (1) | DE102006005271B4 (zh) |
GB (1) | GB2426251B (zh) |
Families Citing this family (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2008221330A (ja) * | 2007-03-16 | 2008-09-25 | Fuji Electric Holdings Co Ltd | はんだ合金 |
CN101911232B (zh) * | 2008-02-22 | 2014-03-12 | 株式会社神户制钢所 | 触摸屏传感器 |
JP2009283741A (ja) * | 2008-05-23 | 2009-12-03 | Fuji Electric Device Technology Co Ltd | 半導体装置 |
TWI541488B (zh) * | 2011-08-29 | 2016-07-11 | 奇鋐科技股份有限公司 | 散熱裝置及其製造方法 |
CN102717201B (zh) * | 2012-07-04 | 2015-04-22 | 深圳市斯特纳新材料有限公司 | 具有耐腐蚀的高强度高温焊料 |
JP6713106B2 (ja) * | 2014-02-24 | 2020-06-24 | 株式会社弘輝 | 鉛フリーはんだ合金、はんだ材料及び接合構造体 |
CN108428682B (zh) * | 2018-04-13 | 2020-08-18 | 江西江铃集团新能源汽车有限公司 | 一种功率模组及其制备方法 |
Family Cites Families (16)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS62230493A (ja) * | 1986-03-31 | 1987-10-09 | Taruchin Kk | はんだ合金 |
JP3269745B2 (ja) * | 1995-01-17 | 2002-04-02 | 株式会社日立製作所 | モジュール型半導体装置 |
JPH09330941A (ja) * | 1996-06-13 | 1997-12-22 | Toshiba Corp | 高熱伝導ペースト半田および半導体デバイス |
JP3226213B2 (ja) * | 1996-10-17 | 2001-11-05 | 松下電器産業株式会社 | 半田材料及びそれを用いた電子部品 |
US6033488A (en) * | 1996-11-05 | 2000-03-07 | Samsung Electronics Co., Ltd. | Solder alloy |
KR19980068127A (ko) * | 1997-02-15 | 1998-10-15 | 김광호 | 납땜용 무연 합금 |
US6179935B1 (en) * | 1997-04-16 | 2001-01-30 | Fuji Electric Co., Ltd. | Solder alloys |
JP3353662B2 (ja) * | 1997-08-07 | 2002-12-03 | 富士電機株式会社 | はんだ合金 |
CA2340393A1 (en) * | 1999-06-11 | 2000-12-21 | Katsuaki Suganuma | Lead-free solder |
JP2002232022A (ja) * | 2001-01-31 | 2002-08-16 | Aisin Seiki Co Ltd | 熱電モジュール及びその製造方法 |
JP2002321084A (ja) * | 2001-04-26 | 2002-11-05 | Sumitomo Metal Mining Co Ltd | 電子部品接合用はんだ合金 |
US20030021718A1 (en) * | 2001-06-28 | 2003-01-30 | Osamu Munekata | Lead-free solder alloy |
JP2003094194A (ja) * | 2001-07-16 | 2003-04-02 | Uchihashi Estec Co Ltd | はんだ材及び電子部品における部材の固定方法 |
US20030178719A1 (en) * | 2002-03-22 | 2003-09-25 | Combs Edward G. | Enhanced thermal dissipation integrated circuit package and method of manufacturing enhanced thermal dissipation integrated circuit package |
JP2004017093A (ja) * | 2002-06-17 | 2004-01-22 | Toshiba Corp | 鉛フリーはんだ合金、及びこれを用いた鉛フリーはんだペースト |
CN1230567C (zh) * | 2003-07-02 | 2005-12-07 | 中国科学院金属研究所 | 一种抗液态表面氧化的工业纯锡及其应用 |
-
2005
- 2005-05-20 JP JP2005148730A patent/JP4635715B2/ja active Active
-
2006
- 2006-01-30 GB GB0601776A patent/GB2426251B/en not_active Expired - Fee Related
- 2006-02-02 US US11/345,516 patent/US20060263235A1/en not_active Abandoned
- 2006-02-06 DE DE102006005271A patent/DE102006005271B4/de active Active
- 2006-02-28 CN CN2006100515427A patent/CN1864909B/zh active Active
- 2006-02-28 CN CN2010102407673A patent/CN101905388B/zh active Active
- 2006-02-28 CN CN201210102888.0A patent/CN102637662B/zh active Active
Non-Patent Citations (1)
Title |
---|
JP平11-58066A 1999.03.02 |
Also Published As
Publication number | Publication date |
---|---|
CN101905388A (zh) | 2010-12-08 |
CN101905388B (zh) | 2012-05-30 |
CN102637662A (zh) | 2012-08-15 |
CN102637662B (zh) | 2014-09-24 |
US20060263235A1 (en) | 2006-11-23 |
JP4635715B2 (ja) | 2011-02-23 |
GB0601776D0 (en) | 2006-03-08 |
CN1864909A (zh) | 2006-11-22 |
GB2426251A (en) | 2006-11-22 |
DE102006005271A1 (de) | 2006-11-23 |
DE102006005271B4 (de) | 2012-12-06 |
GB2426251B (en) | 2007-10-10 |
JP2006320955A (ja) | 2006-11-30 |
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C10 | Entry into substantive examination | ||
SE01 | Entry into force of request for substantive examination | ||
ASS | Succession or assignment of patent right |
Owner name: FUJI MOTOR SYSTEM CO., LTD. Free format text: FORMER OWNER: FUJI MOTOR ELECTRONICS TECHNOLOGY CO., LTD. Effective date: 20100527 |
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C41 | Transfer of patent application or patent right or utility model | ||
TA01 | Transfer of patent application right |
Effective date of registration: 20100527 Address after: Tokyo, Japan Applicant after: Fuji Electric Systems Co., Ltd. Address before: Tokyo, Japan Applicant before: Fuji Electronic Device Technol |
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ASS | Succession or assignment of patent right |
Owner name: FUJI ELECTRIC CO., LTD. Free format text: FORMER OWNER: FUJI ELECTRIC SYSTEMS CO., LTD. Effective date: 20110921 |
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Effective date of registration: 20110921 Address after: Kanagawa Applicant after: Fuji Electric Co., Ltd. Address before: Tokyo, Japan Applicant before: Fuji Electric Systems Co., Ltd. |
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