CN1712199A - 再生回收光盘的方法、阻燃树脂组合物和阻燃树脂模制品 - Google Patents
再生回收光盘的方法、阻燃树脂组合物和阻燃树脂模制品 Download PDFInfo
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- CN1712199A CN1712199A CNA2005100837568A CN200510083756A CN1712199A CN 1712199 A CN1712199 A CN 1712199A CN A2005100837568 A CNA2005100837568 A CN A2005100837568A CN 200510083756 A CN200510083756 A CN 200510083756A CN 1712199 A CN1712199 A CN 1712199A
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- 125000002889 tridecyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 229910052905 tridymite Inorganic materials 0.000 description 1
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Abstract
再生一种回收光盘,所述光盘具有使用粘合剂将多个光盘基片粘结在一起的结构。为此,提供了一种用于回收光盘的再生方法,其中将回收光盘用作制备阻燃树脂组合物或树脂模制品的起始材料,所述回收光盘除了用于将多个光盘基片粘结在一起的粘合剂以外还含有至少一种沉积在光盘基片之上的选自反射膜、记录膜、保护膜和油墨膜的涂覆膜材料。
Description
相关申请的交叉引用
本发明包含与在2004.06.24向日本专利局提交的日本专利申请JP2004-186928相关的主题,在此将其全部内容引入作为参考。
技术领域
本发明涉及一种再生回收光盘如DVD(数字化多功能光盘)的方法、通过上述方法再生的阻燃树脂组合物和阻燃树脂模制品,其中每个光盘包括两个通过粘合剂粘结在一起的光盘基片。
背景技术
发现例如统称为DVD的DVD-Video、DVD-Audio、DVD-ROM、DVD±R、DVD±R/W或DVD-RAM广泛用作复制或记录图片、音乐或数据的介质。当然,所述DVD,如果被用完时,必须以与传统磁带型记录介质如VHS磁带、8mm磁带或音乐磁带相同的方式,作为废弃材料被大量处理。
同时,所述DVD具有通过粘合剂粘结在一起的两个光盘基片组成的结构。此外,在所述DVD中含有多种在光盘基片上形成的膜材料,例如反射膜、记录膜、或印刷油墨。因此,如果将DVD作为光盘用起始材料回收和再利用,则上述添加剂作为杂质混合,从而带来以下问题:可能不能实现高可靠性的光学性能。
因而,迄今为止提出了很多种技术,这些技术通过使用合适的化学品处理来剥离和除掉含在回收光盘中的上述添加剂(例如参见专利文献1~7)。
但是,这些传统方法使用了大量的化学品,并且产生大量液体,因而从节省资源和环境保护的观点来看存在一定问题。此外,这些技术大部分涉及包括单一光盘基片的光盘,例如CD-DA、CD-R、CD-ROM、CD-R/W或CD-RAM(以下统称为CD),并且不能直接应用于通过使用粘合剂将两个光盘基片牢固粘结在一起而获得的DVD。
在上述情形下,对于公共利益而言,强烈要求将未来预计大量回收的DVD有效再生。
[专利文献1]日本公开专利公报H7-205154
[专利文献2]日本公开专利公报2003-200133
[专利文献3]日本公开专利公报H5-217219
[专利文献4]日本公开专利公报2001-287225
[专利文献5]日本公开专利公报H11-57683
[专利文献6]日本公开专利公报H8-164524
[专利文献7]日本专利3270037
发明内容
考虑到上述相关技术的情况,需要提供一种再生回收光盘的方法、通过上述方法再生的阻燃树脂组合物和阻燃模制品,所述回收光盘具有由使用粘合剂将多个光盘基片粘结在一起组成的结构。
依据本发明,提供了一种回收光盘的再生方法,其中将回收光盘用作制备阻燃树脂组合物或树脂模制品的起始材料,所述回收光盘连同用于将多个光盘基片粘结在一起的粘合剂一起,还含有至少一种沉积于光盘基片之上的选自反射膜、记录膜、保护膜和油墨膜的涂覆膜材料。
本发明还提供了一种由回收光盘作为起始材料制备的阻燃树脂组合物,所述回收光盘连同用于将多个光盘基片粘结在一起的粘合剂一起,还含有至少一种形成于所述光盘基片之上的反射膜、记录膜、保护膜和油墨膜的涂覆材料。
本发明还提供了一种由回收光盘作为起始材料制备的阻燃树脂模制品,所述回收光盘连同用于将多个光盘基片粘结在一起的粘合剂一起,还含有至少一种形成于所述光盘基片之上的反射膜、记录膜、保护膜和油墨膜的涂覆材料。
依据本发明,将回收光盘用作制备阻燃树脂组合物或阻燃树脂模制品的起始材料,从而可将回收光盘在不使用大量药品或产生废液的情况下有效再生,所述回收光盘除了用于将多个光盘基片粘结一起的粘合剂之外,还含有至少一种形成于所述光盘基片之上的反射膜、记录膜、保护膜和油墨膜的涂覆材料。
附图说明
图1为表示一种DVD结构的横截面图。
图2为表示另一种DVD结构的横截面图。
具体实施方式
参考附图,依据本发明,现在将详细描述用于再生回收光盘的方法、阻燃树脂组合物和阻燃树脂模制品。
将要通过本发明所述再生方法回收的DVD,可通过例如分别在图1和2中所示的DVD(数字化多功能光盘)1、10举例说明。
参照图1,所述DVD 1通过使用透光粘合剂8将第一记录介质4粘结到第二记录介质7上来形成,所述第一记录介质4包括形成于所述第一光盘基片的一个表面之上的透光第一光盘基片2和第一记录膜3,所述第二记录介质7包括形成于所述第二光盘基片7的一个表面之上的透光第二光盘基片5和第二记录膜6,携带第一记录膜3的第一记录介质的表面与携带第二记录膜6的第二记录介质7的表面彼此面对。
参照图2,所述DVD 10通过使用透光粘合剂8将第一记录介质4粘结到第二记录介质7上来形成,所述第一记录介质4包括形成于所述第一光盘基片的一个表面之上的透光第一光盘基片2和第一记录膜3,所述第二记录介质7包括形成于所述第二光盘基片7的一个表面之上的透光第二光盘基片5和第二记录膜6,携带第一记录膜3的第一记录介质的表面与携带第二记录膜6的第二记录介质7的表面位于上述两个记录介质的相同侧。在所述第二记录膜6之上,形成用于保护第二记录膜6的保护膜9。
所述回收DVD不限定于上述DVD 1、10,并且可以列举为单侧单层光盘、双侧单层光盘、单侧双层光盘、和双侧双层光盘。
除了前面提到的上述DVD 1、10的第一和第二记录膜3、6之外,所述回收DVD可以含有一种或多种涂覆膜,例如反射膜、保护膜或油墨膜。
所述DVD 1、10可以列举为只能重放的DVD-5、-9、-10和-18,DVD-Video,DVD-Audio,DVD-ROM,单次写入DVD-R,DVD+R,可重写式DVD-RW,DVD+RW和DVD-RAM。
这些DVD 1、10通常可以通过二价酚和碳酸酯前体的反应生产。即,所述DVD 1、10通常通过溶液方法或熔融方法,即通过二价酚和光气的反应,或者通过二价酚和碳酸二苯酯的酯交换反应生产。
在此使用的所述二价酚,可以列举为对苯二酚、间苯二酚、4,4’-二苯酚、二(4-羟基苯基)甲烷、1,1-二(4-羟基苯酚)乙烷、2,2-二(4-羟基苯基)丙烷、2,2-二(3-甲基-4-羟基苯基)丙烷、2,2-二(3,5-二丁基-4-羟基苯基)丙烷、2,2-二(4-羟基苯基)丁烷、1,1-二(4-羟基苯基)-1-苯基乙烷、1,1-二(4-羟基苯基)环己烷、1,1-二(4-羟基苯基)-3,3,5-三甲基环己烷、2,2-二(4-羟基苯基)戊烷、4,4’-(间亚苯基异亚丙基)二苯酚、4,4’-(对亚苯基二异亚丙基)二苯酚、9,9-二(4-羟基苯基)芴、1,1-二(4-羟基苯基)-4-异丙基环己烷、二(4-羟基苯基)醚、二(4-羟基苯基)硫化物、和二(4-羟基苯基)砜。作为二价酚,优选使用2,2-二(4-羟基苯基)烷烃,并且特别是2,2-二(4-羟基苯基)丙烷。
作为碳酸酯前体,可以例如使用酰卤、碳酸酯或卤代甲酸酯。所述碳酸酯前体特定例子包括光气、碳酸二苯酯和二价苯酚的二卤代甲酸酯。
作为所述芳族聚碳酸酯,通常使用具有重均分子量(通过GPC测量且以聚苯乙烯来计算)为10,000~100,000,并且优选为30,000~60,000的芳族聚碳酸酯,或者使用具有粘均分子量为10,000~60,000,优选为14,000~20,000的芳族聚碳酸酯。需指出的是,所述粘均分子量可以通过使用Ubelode粘度计测量在20℃下在二氯甲烷溶液中的粘度和通过从极限粘度来计算。
同时,如果所述分子量不在上述范围之内,当使用的最终产品是树脂组合物或树脂模制品时,对于所述树脂来说,变得难以满足树脂特性。即,如果所述分子量偏低或偏高,分别使抗冲击性能降低,或者使流动性恶化。
在使用上述芳族聚碳酸酯模塑所述光盘基片之后,通过溅射将反射膜沉积在光盘基片之上,形成保护膜,并且使用粘结剂将两个光盘基片粘结在一起,以生产所述DVD 1和10。
同时,本发明用于再生所述回收DVD的方法,积极地利用含在所述回收DVD 1、10中的所述添加剂,以制备所述树脂阻燃剂。即,发明人已经发现,通过直接使用上述回收DVD,或者以预定用量与其它树脂在混合状态下使用,由作为起始材料的回收DVD制得的树脂组合物或树脂模制品可以在阻燃性能上得到改进。
含在这些回收DVD中的添加剂,可以列举为涂覆膜材料,例如粘合剂、反射膜、记录膜、保护模或油墨膜的材料。其中,用于粘结所述DVD 1或10的粘合剂有效地改进了树脂组合物或树脂模制品的阻燃性能。
特别地,在粘合剂中通常含有作为基本组份的UV射线可固化化合物和光聚合引发剂。作为UV射线可固化化合物组份,可将单官能或多官能(甲基)丙烯酸酯用作可聚合聚合物。它们可以单独或者组合使用。
本发明中需要的可聚合聚合物,可以例如定义如下:即,所述单官能(甲基)丙烯酸酯的取代基可以列举为烷基基团(甲基、乙基、丙基、丁基、异丁基、叔丁基、戊基、2-乙基己基、辛基、壬基、月桂基、十二烷基、十三烷基、十六烷基、十八烷基、甲氧基乙基、丁氧基乙基、苯氧基乙基、环己基、硬脂基、苯基或苄基),烷基醚基团(甲氧基乙基、丁氧基乙基、苯氧基乙基、壬基苯氧基乙基),羟烷基基团(2-羟基乙基、2-羟基丙基、3-氯-2-羟基丙基),氨基烷基基团(二甲基氨基乙基、二乙基氨基乙基、),缩水甘油基,四氢糠基、壬基苯氧基乙基四氢糠基,己内酯改性的四氢糠基,己内酯改性的二季戊四醇,二乙二醇乙氧基化合物,烷基改性的二季戊四醇,异冰片基,二环戊基,二环戊烯基和二环戊烯基氧乙基。
所述多官能(甲基)丙烯酸酯的取代基可以列举为烷基醚基团(乙二醇、聚乙二醇、聚丙二醇、丙二醇、三丙二醇、三丙二醇、1,3-丁二醇、新戊二醇),羟烷基基团(1,4-丁二醇、1,5-戊二醇、3-甲基-1,5-戊二醇、1,6-己二醇、1,8-辛二醇、1,9-壬二醇、三环癸烷二甲醇、三(2-羟基乙基)异氰脲酸酯、双酚A的环氧乙烷加成物的二醇、甘油、聚甘油、季戊四醇、或者二季戊四醇),二(甲基)丙烯酸酯(例如聚丙二醇的二烯丙基化合物、三(2-羟基乙基)异氰脲酸酯的二(甲基)丙烯酸酯、通过在1摩尔新戊二醇中加入不少于4摩尔环氧乙烷或环氧丙烷获得的二醇的二(甲基)丙烯酸酯、通过在1摩尔双酚A中加入2摩尔环氧乙烷或环氧丙烷获得的二醇的二(甲基)丙烯酸酯、通过在1摩尔三羟甲基丙烷中加入不少于3摩尔的环氧乙烷或环氧丙烷获得的三醇的二(甲基)丙烯酸酯、通过在1摩尔双酚A中加入不少于4摩尔环氧乙烷或环氧丙烷获得的二醇的二(甲基)丙烯酸酯、羟基新戊酸新戊二醇二丙烯酸酯、己内酯改性的羟基新戊酸新戊二醇二丙烯酸酯),三(甲基)丙烯酸酯(通过在1摩尔三羟甲基丙烷中加入不少于3摩尔的环氧乙烷或环氧丙烷获得的三醇的三(甲基)丙烯酸酯、三(2-羟基乙基)异氰脲酸酯三(甲基)丙烯酸酯、三羟甲基丙烷三(甲基)丙烯酸酯、季戊四醇三(甲基)丙烯酸酯、己内酯改性的三{(甲基)丙烯酰氧基乙基}异氰脲酸酯,聚(甲基)丙烯酸酯(二季戊四醇的聚(甲基)丙烯酸酯、烷基改性二季戊四醇的聚(甲基)丙烯酸酯),磷酸(甲基)丙烯酸酯(烷基化磷酸(甲基)丙烯酸酯、环氧乙烷改性的磷酸(甲基)丙烯酸酯、环氧乙烷改性的烷基化磷酸(甲基)丙烯酸酯),和氨基甲酸乙酯(甲基)丙烯酸酯(有机聚异氰酸酯与羟基(甲基)丙烯酸酯的反应产物,或多羟基化合物、有机聚异氰酸酯与羟基(甲基)丙烯酸酯的反应产物)。
上述取代基也可以是N-乙烯-2-吡咯烷酮、(甲基)丙烯酰胺、乙烯基咪唑、4-乙烯基吡啶、N-乙烯基甲酰胺、乙酸乙烯酯、丙烯酰吗啉、N-乙烯基己内酰胺、(甲基)丙烯酸、N-羟甲基丙烯酰胺或N-羟乙基丙烯酰胺和其烷基醚化合物。
可以组合使用可聚合的低聚物,例如聚酯(甲基)丙烯酸酯、聚醚(甲基)丙烯酸酯、环氧(甲基)丙烯酸酯和氨基甲酸乙酯(甲基)丙烯酸酯,作为可聚合的单体。
光聚合引发剂可以列举为1-羟基环己基苯基酮、苄基、安息香异丁醚、2,4-二甲基硫代呫吨酮、2,4-二乙基硫代呫吨酮、2,4-二异丙基硫代呫吨酮、2-异丙基硫代呫吨酮、2-氯硫代呫吨酮、2,4,6-三甲基苯甲酰基二苯基氧化膦、2-苄基-2,2-二甲基氨基-1-(4-吗啉代苯基)-丁酮-1、二(2,6-二甲氧基苯甲酰基)-2,2,2-三甲基戊基氧化膦、苯甲酰乙醚、苄基二甲基缩酮、2-羟基2-甲基1-苯基丙-1-酮、1-(4-异丙基苯基)-2-羟基2-甲基丙-酮、2-甲基-1-(4-甲基硫代苯基)-2-吗啉代-丙-1-酮、二苯酮、二乙氧基乙酰苯、4-苯基二苯酮、间苯二酰苯酮、2-羟基-2-甲基1-苯基丙酮、安息香异丁醚、安息香-正丁基醚、2,2-二甲氧基1,2-二苯基乙-1-酮、苯基乙醛酸甲酯、3,6-二(2-甲基-2-吗啉代-丙酮基)-9-丁基-咔唑、4-(二甲基氨基)苯甲酸异丙烯酰酯、4-(二甲基氨基)苯甲酸乙酯、[4-(4-甲基苯基硫代)苯基]苯基甲烷、4-苯甲酰基-4’-甲基-苯硫醚、(1-6-η-枯烯)(η-环戊二烯基)铁(1+)六氟化甲基磷酸盐(1-)、2,2-二甲氧基-2-2苯基乙酰苯、米蚩酮、2-甲基-[4-(甲基硫代)苯基]-2-吗啉代-1-丙酮、2-苄基-2-二甲基氨基1-(吗啉代苯基)-丁酮-1、2-氯呫吨酮、芳族重氮盐、芳族锍盐(4,4’-二[二(β-羟基乙氧基)苯基磺基]苯基硫化物-双六氟锑酸盐、2,4-二(三氯甲基)-6-(4-甲氧基苯基)-1,3,5-三嗪、三烯丙基锍六氟氨合物、三烯丙基锍六氟磷酸盐)、芳族碘鎓盐{甲苯基枯基碘鎓四(五氟苯基)硼酸盐}。
在上述粘合剂(UV射线可固化化合物+光聚合引发剂)之中,优选为具有羟基基团、磷酸(磷酸盐)基团、锍盐基团、重氮盐基团、碘鎓盐基团和羧基基团的那些。由于这些特定基团的存在,使所述树脂在燃烧时碳化,从而改进了树脂的阻燃性能。在这些特定基团之中,最优选的是羟基基团。这些特定基团的含量可以通过采用例如有关树脂的FT-IR测量来确定。
在所述阻燃树脂组合物或所述阻燃树脂模制品中,这些粘合剂的含量优选为0.005~20wt%,更优选为0.05~10wt%,并且最优选为0.5~5wt%。如果所述添加剂的含量小于这个范围,几乎不能实现在提高所述阻燃树脂阻燃性能上的有利效果,反之,如果所述添加剂的含量大于这个范围,则破坏了所述树脂的性能如机械性能。
可使用至少一种作为涂覆材料的膜的反射膜、记录膜、保护膜或油墨膜作为除了上述粘合剂之外的组份。
特别地,至少可将Al、Au和Si中的一种指定为反射膜材料。通常,并不特别限定,只要所述材料具有用于光盘的级别。因而,所述材料可以是未掺杂的物质或者与其它材料的混合物(合金)。
作为记录膜,有机染料如花青基、偶氮基或酞菁基染料,或由Te、Se、S、Ge、In、Sb、Fe、Tb、Co、Ag、Ce和Bi中至少一种组成的无机合金。
所述保护膜例如由(A)预聚物组份、(B)单体组份、(C)聚合引发剂组份和其它组份(D)组成。
所述组份(A)可以例如列举为聚酯丙烯酸酯、聚氨酯丙烯酸酯、环氧丙烯酸酯和聚醚丙烯酸酯。
所含有的所述组份(B)可以例如是一种改进所述组合物固化涂覆膜的强度的组份(B1),和一种有效降低所述组合物的浓度的稀释组合物(B2)。
在组份(B1)的分子中,可以优选含有两个或更多个,并且更优选含有三个或更多个(甲基)丙烯酰基团。例如,在分子中含有两个或更多个(甲基)丙烯酰基团的化合物可以是二环戊基二(甲基)丙烯酸酯或双酚A二(甲基)丙烯酸酯,其通过环氧烷烃来改性,例如环氧乙烷或环氧丙烷。在分子中含有三个或更多个(甲基)丙烯酰基团的化合物可以是三羟甲基丙烷三(甲基)丙烯酸酯、通过环氧烷烃如环氧乙烷或环氧丙烷改性的三羟甲基丙烷三(甲基)丙烯酸酯、二季戊四醇六(甲基)丙烯酸酯、二季戊四醇单羟基五(甲基)丙烯酸酯、烷基改性的二季戊四醇五(甲基)丙烯酸酯、烷基改性的二季戊四醇四(甲基)丙烯酸酯、季戊四醇三(甲基)丙烯酸酯、季戊四醇四(甲基)丙烯酸酯、三[(甲基)丙烯酰氧基乙基]异氰脲酸酯、己内酯改性的三[(甲基)丙烯酰氧基乙基]异氰脲酸酯和双三羟甲基丙烷四(甲基)丙烯酸酯。
所述组份(B2)优选在分子中包括至多两个(甲基)丙烯酰基基团。所述组份(B2)可以列举为三丙二醇二(甲基)丙烯酸酯、1,6-己二醇(甲基)丙烯酸酯、新戊二醇二(甲基)丙烯酸酯、二乙二醇二(甲基)丙烯酸酯、2-(2-乙氧基乙氧基)乙基(甲基)丙烯酸酯、(甲基)丙烯酸四氢糠酯、2-羟基(甲基)丙烯酸酯、(甲基)丙烯酸异冰片酯、(甲基)丙烯酸环己酯、(甲基)丙烯酸二环戊酯、(甲基)丙烯酸氨基酯:(甲基)丙烯酸N,N-二甲基氨基乙酯、(甲基)丙烯酸N,N-二乙基氨基乙酯、丙烯酰基吗啉、氨基丙烯酰胺(acrloamide):N-异丙基(甲基)丙烯酰胺、N,N-二甲基丙烯酰胺和N,N-二甲基氨基丙基(甲基)丙烯酰胺。
在上述保护膜中,使用的组份A1、B1和B2的比例依据所期望的涂覆膜强度来确定。同时,所述组份B2的比例越高,所述保护膜的粘度变得越低,但是,所述涂覆膜的强度变得越弱。
作为组份(C),可以使用例如在常规UV射线固化树脂中所用的各种光聚合引发剂和光聚合感光剂。所述组份(C)的例子包括安息香、安息香甲醚、安息香乙醚、安息香异丁醚、2-甲基安息香、苄基甲基缩酮、1-(4-异丙基)-2-羟基2-甲基丙-1-酮、1-(4-十二烷基苯基)-2-羟基-2-甲基丙-1-酮、1-羟基环己基苯基酮、2-羟基2-甲基1-苯基丙-1-酮、苯基乙醛酸甲酯、2-甲基1-[4-(甲基硫代)苯基]-2-吗啉代丙烷-1、2-苄基-2-二甲基氨基-1-(4-吗啉代苯基)-丁酮-1、2,4,4,6-三甲基苯甲酰基二苯基氧化膦、二苯酮、苯甲酰、苯甲酸甲酯、二苯酮基感光剂:受阻胺(HALS),例如三乙胺、甲基二乙醇胺、三乙醇胺、甲基二乙醇胺(diethanbolamine)、三乙醇胺、双(N-甲基2,2,6,6-四甲基-4-哌啶基)癸二酸酯、苯基斗哌啶基碳酸酯、苯甲酸2-二甲基氨基乙酯、对二甲基氨基乙酰苯、对二甲基氨基苯甲酸乙酯和对二甲基氨基苯甲酸异戊酯。
作为组份(D),如果必要可以使用各种添加剂,例如增粘剂、聚合抑制剂或表面活性剂。所述增粘剂的例子包括环氧乙烷改性的琥珀酸(甲基)丙烯酸酯、环氧乙烷改性的邻苯二甲酸(甲基)丙烯酸酯、环氧乙烷改性的磷酸(甲基)丙烯酸酯、和羟基萘氧基原(甲基)丙烯酸酯(hydroxynaphtoxy pro(meth)acrylate)。所述聚合抑制剂的例子包括氢醌、氢醌单甲基醚、叔丁基邻苯二酚、对苯醌、2,5-叔丁基氢醌和吩噻嗪。所述表面活性剂的例子包括如氟基非离子表面活性剂。
可将上述那些具有羟基基团、磷酸(磷酸盐)基团、锍盐基团、重氮盐基团、碘鎓酸和羧基基团的保护膜(预聚物组份+单体组份+聚合抑制剂组份+其它组份)与上述粘合剂组合使用,以有助于改进所讨论的树脂组合物或树脂模制品的阻燃性能。
通常,在油墨中含有颜料、(光)聚合引发剂、预聚物、多官能丙烯酸酯单体和各种助剂。除了所述颜料之外,上述试剂相等于或相似于上述添加剂。油墨中所述颜料的例子包括至少一种碳黑、二氧化钛、铜、其化合物、氧化铁、硅石、钼和其化合物。
上述添加剂,与聚碳酸酯一起混合在所述回收DVD中,作用是改进与其它树脂混合或未混合的回收DVD树脂的阻燃性能。
这些回收DVD可以是在工厂中生产并且回收的那些。包括流道(runners)、模塑边角料和原料颗粒边角料、预售不合格品或库存材料。所述回收DVD也可以从市场上回收。需指出的是,在工厂回收或销售之前回收的DVD通常较从市场上回收的那些更具有均一性能,并且因此更期望再次使用。同时,回收DVD也可以作为与其它种类树脂的混合物来使用,当然上述回收DVD可以单独作为树脂组合物或树脂模制品来使用。
可以与回收DVD混合的树脂可以列举为PC、ABS(丙烯腈丁二烯苯乙烯树脂)、AS(丙烯腈苯乙烯树脂)、PS(聚苯乙烯)、HIPS(高抗冲聚苯乙烯)、SPS(间规聚苯乙烯)、SBR(苯乙烯丁二烯橡胶)、SBS(苯乙烯丁二烯苯乙烯橡胶)、甲基丙烯酸甲酯苯乙烯树脂、MBS(甲基丙烯酸甲酯丁二烯苯乙烯树脂)、异戊二烯苯乙烯橡胶、异戊二烯橡胶、PB(聚丁二烯)、丁二烯丙烯酰基橡胶、异戊二烯丙烯酰基橡胶、乙烯丙烯橡胶、PMMA(聚甲基丙烯酸的酯)、PPS(聚苯硫醚)、PPE(聚苯醚)、PET(聚对苯二甲酸乙二醇酯)、PBT(聚对苯二甲酸丁二醇酯)、PP(聚丙烯)、PE(聚乙烯)、尼龙6、尼龙66、尼龙12、和PC/ABS、PC/PS、PC/HIPS、PC/PP、PC/PE、PC/PMMA、PC/PET和PC/PBT合金。其中最优选的是PC、ABS、AS、PS、HIPS、PC/ABS合金、PC/PS合金、PC/HIPS合金、PC/PP合金、PC/PE合金、PC/PMMA合金、PC/PET合金、PC/PBT合金和PC/尼龙合金。
上述树脂对于各种等级而言是用于通用目的用途而销售的那些,其显示高韧性、高抗冲击性能、高抗磨损性、高润滑性、高耐热性、高阻燃性能、高透明性、高光泽性、和高抗化学品性能、或者用于涂覆。上述树脂可以含有各种树脂用添加剂,例如抗静电剂、着色剂、颜料、抗氧化剂、阻燃剂、增塑剂、耐光性改进剂、增容剂、表面处理剂、改性剂、染料(如碳黑)、玻璃纤维、纸、或无纺布。所述树脂可以是在工厂中生产,但是不销售,例如流道或原料颗粒边角料、或从工厂回收的再生树脂。
如果使用再生树脂,则在工厂产生或来自标准产品(相同制品或相同的多个制品的产品)的回收树脂在多数情形下具有均一的物理性能,并且因此从再生的观点来看回收上述树脂是更期望的。
上述树脂可以与回收DVD混合以制备各种等级的阻燃树脂组合物或树脂模制品。
当然,如果将DVD本身用作所述树脂组合物或树脂模制品时,可以获得良好的阻燃性能效果。如果将回收DVD与上述其它树脂混合,则所述回收DVD的含量优选符合1~100wt%、更优选含量符合5~90wt%和最优选含量符合10~80wt%。这是因为采用低于上述限定值的共混比例,将不能获得所述阻燃性能。
当将回收DVD与其它树脂混合时,可以添加增容剂。增容剂的例子包括乙烯基单体与聚烯烃主链的环氧改性的嵌段共聚物和接枝聚合物(LDPE-g-PS、PP-g-PS、EGMA-g-PS、EEA-g-PS、EVA-g-PS、E/EA/MAH-g-PS、LDPE-g-PMMA、EGMA-g-PMMA、EEA-g-PMMA、EVA-g-PMMA、E/EA/MAH-g-PMMA、LDPE-g-AS、PP-g-AS、EGMA-g-AS、EEA-g-AS、EVA-g-AS、或E/EA/MAH-g-AS)。指出的是,EGMA、EEA、EVA、和E/EA/MAH代表乙烯-甲基丙烯酸缩水甘油酯共聚物、乙烯-丙烯酸乙酯共聚物、乙烯-乙酸乙烯酯共聚物和乙烯-乙酸乙酯-马来酸酐共聚物。虽然对于所述增容剂的添加量没有限制,但是基于所述树脂重量,其用量通常为0.1~20wt%,并且优选为1~10wt%。
虽然所述树脂的阻燃性能可以通过使用回收DVD来改进,但是也可以使用树脂用常规阻燃剂。由于回收DVD的基体材料是聚碳酸酯树脂,因此希望将常规用于PC的阻燃剂用作阻燃剂。例如,可以使用至少一种选自卤基阻燃剂、磷基阻燃剂、氮基阻燃剂、无机阻燃剂、硅基阻燃剂、金属盐基阻燃剂、或氟基阻燃剂的阻燃剂。
其中,所述卤基阻燃剂可以列举为卤代双酚、芳族卤素化合物、卤代聚碳酸酯、卤代芳族乙烯基聚合物、卤代异氰酸酯树脂、和卤代聚苯醚。优选的卤基阻燃剂可以列举为十溴二苯醚、四溴双酚A、四溴双酚A低聚物、溴代双酚基苯氧基树脂、溴代双酚基聚碳酸酯、溴代聚苯乙烯、溴代交联聚苯乙烯、溴代聚苯醚、聚二溴苯醚、十溴二苯醚双酚缩合物、含卤磷酸酯和氟基树脂。
上述卤基阻燃剂的添加量通常为0.1~30wt%,并且优选为1~20wt%。如果添加量超过了上述范围,将使所述树脂的性能降低。相反地,如果添加量低于上述范围,将降低所述卤基阻燃剂在改进阻燃性能上的有利效果。
所述磷基阻燃剂可以列举为,例如有机磷化合物、红磷和无机磷酸盐。
所述有机磷化合物可以列举为,例如膦、氧化膦、双膦、鏻盐、亚膦酸酯、磷酸酯、亚磷酸酯,并且更特别地为磷酸三苯酯、亚磷酸甲基新戊基酯、季戊四醇二乙基二亚磷酸酯、膦酸甲基新戊基酯、磷酸苯基新戊基酯、季戊四醇二苯基二磷酸酯、二环戊基次二磷酸酯、二新戊基次亚磷酸酯、苯基焦儿茶酚磷酸酯、乙基焦儿茶酚磷酸酯、双焦儿茶酚次二磷酸酯、苯氧基氨基膦腈(phosphasen)和苯氧基氟代烷基膦腈(phosphasen)。最优选的是芳族磷酸单体和缩合物。
作为红磷,可以使用的不仅是普通红磷,而且也可以是其表面涂覆了金属氢氧化物涂覆膜的普通红磷,所述金属氢氧化物选自氢氧化铝、氢氧化镁、氢氧化锌和氢氧化钛;其表面涂覆了热固性树脂和金属氢氧化物的涂覆膜的普通红磷,所述金属氢氧化物选自氢氧化铝、氢氧化镁、氢氧化锌和氢氧化钛;和其表面依次涂覆了金属氢氧化物涂覆膜和热固性树脂涂覆膜的普通红磷,所述金属氢氧化物选自氢氧化铝、氢氧化镁、氢氧化锌和氢氧化钛。
所述无机磷酸盐可以列举为多磷酸铵。
上述磷基阻燃剂的添加量通常为0.1~30wt%,并且优选为1~20wt%。如果添加量超过了上述范围,将损害所述树脂的性能如耐热性。相反地,如果添加量低于上述范围,将降低所述阻燃剂在改进阻燃性能上的有利效果。
所述氮基阻燃剂可以列举为,例如至少一种选自三嗪基化合物、三唑基化合物、四唑基化合物、膦腈(phosphasen)和重氮基化合物。氮基阻燃剂的特定例子包括蜜胺、蜜白胺、蜜勒胺、蜜弄、蜜胺氰脲酸酯、蜜胺磷酸酯、琥珀酰胍胺、己二酰胍胺、甲基戊二酰胍胺、蜜胺树脂和BT树脂,其中最优选的是蜜胺氰脲酸酯。
上述氮基阻燃剂的添加量通常为0.1~30wt%,并且优选为0.5~10wt%。如果添加量超过了上述范围,将损害所述树脂的性能。相反地,如果添加量低于上述范围,将降低所述阻燃剂在改进阻燃性能上的有利效果。
所述无机阻燃剂可以列举为硅石、硫酸钠、硫酸钙、硫酸钾、氢氧化铝、氢氧化镁、氢氧化锆、氢氧化钡、氢氧化钙、白云石、水滑石、碱式碳酸镁、水合氧化锡、、氧化铝、氧化铁、氧化钛、氧化锰、氧化镁、氧化锆、氧化锌、氧化钼、氧化钴、氧化铋、氧化铬、氧化锡、氧化锑、氧化镍、氧化铜、氧化钨、铝、铁、钛、锰、锌、钼、钴、铋、铬、镍、铜、钨、锡、锑、SUS、硼酸锌、偏硼酸锌、偏硼酸钡、碳酸锌、碳酸镁、碳酸钙、碳酸钡、和水合玻璃。这些阻燃剂可以单独或者组合使用。其中,最优选的是氢氧化铝、氢氧化镁、碱式碳酸镁、水滑石和水合玻璃。
上述无机阻燃剂的添加量通常为0.1~300wt%,并且优选为1~30wt%。如果添加量超过了上述范围,将损害所述树脂的性能如抗冲击性。相反地,如果添加量低于上述范围,将降低所述阻燃剂在改进阻燃性能上的有利效果。
所述硅基阻燃剂可以列举为硅氧烷化合物和硅烷化合物。其中,所述硅氧烷化合物可以列举为硅油、如聚二有机硅氧烷,和聚合物与共聚物的有机硅树脂,其由结构单元SiO2、RSiO3/2、R2SiO、R3SiO1/2或R1aR2bSiO(4-a-b)/2组合获得,其中R1为官能团、R2为具有1~12个碳原子的烃、并且a、b代表满足关系式0<a≤3、0≤b<3、或0<a+b≤3的数字。在上述分子式中,R可以列举为羟基、甲基、乙基、丙基、苯基、苄基、乙烯基、烷氧基、芳氧基、多氧亚烷基、羟基、羧基、苯胺基、氨基、巯基、和环氧基。其中,优选的是烷基基团(甲基和苯基)、烷氧基、羟基、羧基、氨基和环氧基。这些硅基树脂的数均分子量优选为200~5,000,000。所述硅基树脂可以呈油状、清漆状、胶状、粉状或颗粒状的任一种形式。
所述硅烷化合物可以列举为聚烷基硅烷化合物和聚碳硅烷化合物。其中,典型的化合物是聚甲基苯基硅烷、聚二苯基硅烷和聚苯基硅烷。这些化合物可以通过OH基团或烷基封端,或者可以具有环结构。
基于所述树脂部分的重量,上述硅基阻燃剂的添加量通常为0.01~10wt%,并且优选为0.1~5wt%。如果添加量超过了上述范围,将降低在改进阻燃性能上的有利效果。相反地,如果添加量低于上述范围,将倾向于降低所述树脂的外观或机械性能如抗冲击性能。
所述金属盐基阻燃剂可列举为无机酸(盐)或有机酸(盐)。有机酸(盐)可列举为有机磺酸(磺酸盐)、有机硫酸(硫酸盐)、有机磷酸(磷酸盐)、有机硼酸(硼酸盐)和有机碳酸(碳酸盐)。用于各种酸或盐的平衡离子(金属)可以优选为碱金属(钠、锂、钾或铯)、碱土金属(镁、钙、锶或钡)或Zn、Sn、Al或Sb。所述有机酸(盐)可被卤素如氟、氯或溴取代。
特别地,所述金属盐基阻燃剂可以列举为全氟烷烃磺酸盐(全氟甲烷磺酸盐、全氟乙烷磺酸盐、全氟丙烷磺酸盐、全氟丁烷磺酸盐、全氟甲基丁烷磺酸盐、全氟己烷磺酸盐、全氟庚烷磺酸盐、全氟辛烷磺酸盐)、烷基磺酸(磺酸盐)、苯磺酸(苯磺酸盐)、烷基苯磺酸(烷基苯磺酸盐)、二苯基磺酸(二苯基磺酸盐)、萘磺酸(萘磺酸盐)、二苯基砜-3-磺酸(磺酸盐)、2,5-二氯苯磺酸(磺酸盐)、2,4,5-三氯(trilolo)苯磺酸(磺酸盐)、二苯基砜-3,3-二磺酸(磺酸盐)、萘三磺酸(三磺酸盐)、芳族砜酰亚胺金属盐、其氟代化合物,和连接到苯乙烯(共)聚合物或含芳环的聚合物如聚苯醚、聚碳酸酯或聚对苯二甲酸乙二醇酯的芳环上的磺酸(磺酸盐)、硫酸(硫酸盐)、硼酸(硼酸盐)和羧酸(羧酸盐)。所述磺酸(磺酸盐),是典型的金属盐基阻燃剂,可以列举为磺酸金属盐,例如PS树脂(聚苯乙烯)、HIPS树脂(高抗冲聚苯乙烯)、AS树脂(丙烯腈-苯乙烯共聚物)、ABS树脂(丙烯腈-丁二烯-苯乙烯共聚物)、聚苯醚、聚碳酸酯或聚对苯二甲酸乙二醇酯,通过热的浓硫酸制造的AS树脂或ABS树脂水解产物的金属盐,和离子交换树脂。虽然对于引入由磺酸基团代表的酸(盐)的比率没有限定,但是其基于0.1~100mol%的取代。
所述有机羧酸(羧酸盐)可以列举为全氟蚁酸(蚁酸盐)、全氟甲烷羧酸(羧酸盐)、全氟乙烷羧酸(羧酸盐)、全氟丙烷羧酸(羧酸盐)、全氟丁烷羧酸(羧酸盐)、全氟甲基丁烷羧酸(羧酸盐)、全氟己烷羧酸(羧酸盐)、全氟庚烷羧酸(羧酸盐)和全氟辛烷羧酸(羧酸盐)。
上述金属盐基阻燃剂可以单独或者组合使用。
基于所述树脂组合物或所述树脂模制品的树脂部分的重量,上述金属盐基阻燃剂的添加量通常为0.0005~5wt%,优选0.001-2wt%,并且更优选为0.05~1wt%。由于无对应于增加添加量的阻燃效果可以因此而产生,因此经济地来说不期望增加添加量超过这个范围。
所述氟基阻燃剂是在树脂中含有氟原子的那些树脂,并且可以列举为聚单氟乙烯、聚二氟乙烯、聚三氟乙烯、聚四氟乙烯、和四氟/六氟丙烯共聚物。如果必要时,上述氟单体可以与能与其共聚的单体组合使用。这些氟基树脂的平均分子量优选为100,000~10,000,000。特别地,需要具有原纤维形成性能的树脂。
基于所述树脂组合物或树脂模制品的树脂部分的重量,所述氟基阻燃剂的添加量通常为0~5wt%,并且优选为0.1~2wt%。由于无对应于增加添加量的阻燃效果可以因此而产生,因此经济地来说不期望增加添加量超过这个范围。
需指出的是,在多数情形下上述氟基阻燃剂主要用于预防滴落。除了上述氟基阻燃剂之外,用于预防滴落的组份可以列举为上述有机硅树脂、酚树脂、芳族聚酰胺树脂(纤维)和聚丙烯腈树脂(纤维)。如果需要,也可以添加一种或多种热塑性弹性体材料,例如聚烯烃、聚酯、聚氨酯、1,2-聚丁二烯基或聚氯乙烯材料。
依据本发明,如果需要,也可以向所述阻燃树脂组合物或树脂模制品中添加有机填料。所述有机填料可以列举为,例如滑石、云母、硅灰石、高岭土、硅藻土、碳酸钙、硫酸钡、玻璃纤维、碳纤维、碳黑、钛酸钾和氧化钛。其中,优选的是滑石、云母和硅灰石。
作为无机填料,优选具有平均粒径范围在0.1~50μm,并且更加优选为0.2~20μm的无机填料。基于所讨论的所述树脂组合物或树脂模制品的树脂部分的重量,所述无机填料的添加量通常为0~30wt%,并且优选为0~15wt%。如果所述添加量超过上述范围,将降低抗冲击强度以及熔合强度。
依据本发明,如果需要,所述阻燃树脂组合物或树脂模制品可以与各种添加剂,例如颜料、染料、润滑剂、UV射线吸收剂、受阻胺基光稳定剂、抗氧化剂、卤素补充剂、遮光剂、金属钝化剂、焠灭剂、抗静电剂、增强剂或填料混合,只要它们不损害所述产品的物理性能。同时,模内铸塑可用于使所述树脂和金属结成一体。
上述材料可以以适当比例混合在一起、混合、熔融和捏合在一起,以获得阻燃树脂。此时,混合和捏合可以通过使用常规装置如带型共混器或鼓型转鼓预混合和使用班伯里密炼机混合器、单螺杆挤出机、双螺杆挤出机、多螺杆挤出机或共捏合器的方法进行。熔融和捏合期间的加热温度适当地为150~300℃,其取决于待混合的树脂种类。需指出的是,最初可将除了回收DVD之外的组份与聚碳酸酯或其它热塑性树脂一起熔融和捏合,并且以上述形式,即呈母料的形式加入。
依据注射模塑法、注射压模法、挤出模塑法、吹塑法、压塑法、真空模塑法和发泡模塑法,本发明所述阻燃树脂可以通过上述熔融-捏合-模塑装置,从作为起始材料的所获得的颗粒加工成各种模制品。如果必要,可对由回收DVD制得的所述树脂组合物或树脂模制品镀膜或者涂覆。
树脂用镀膜方法类似于常规树脂镀膜方法,并且可以通过脱脂、化学蚀刻、化学镀和电镀来进行,如果需要,任选与中和处理、催化剂处理或促进处理相结合。对于脱脂,使用表面活性剂,并且对于蚀刻,使用氧化剂和酸的混合溶液。在蚀刻之后,进行一系列的处理包括中和处理、催化剂处理、或促进处理,目的在于促进镀膜的光滑沉淀和改进镀层与树脂表面之间的粘结紧密度。随后,将所获得的产品浸渍在金属镀膜用化学金属镀浴中。通过上述方法将化学镀膜施用到所述模制品上之后,通过公知的方法使用用于电镀的铜、镍或铬使所述化学镀产品进行电镀,以制得镀膜产品。
树脂用涂覆材料可以列举为丙烯酸清漆基涂料、聚酯涂料、双液体组份环氧涂料(丙烯酸-环氧基涂料、环氧-聚酯基涂料)、丙烯酸涂料、双溶液丙烯酸-硅涂料、醇酸树脂涂料、蜜胺树脂基烘焙涂料、丙烯酸树脂基烘焙涂料、苯二甲酸树脂基涂料、氟基涂料、阳离子电涂底漆、聚氨酯树脂基涂料、丙烯酸聚氨酯树脂基涂料、聚酯改性的丙烯酸聚氨酯树脂基涂料、和烷基化氨基树脂基涂料。这些涂料可以通过喷雾或浸渍、或使用辊子或刷子,至少施涂一次用于涂覆所述树脂组合物或树脂模制品。
[实施例]
现在将解释本发明的几个实施例以及用于与所述实施例作比较的几个比较实施例,依据本发明,其中涉及本发明用于回收DVD的再生方法。
实施例1-6和比较实施例1-10涉及测试样品,所述样品通过将以下表1中所示比例的各种组份混合、随后捏合、造粒和彻底干燥,将所得到的物质送入挤出模塑装置中,并且将所获得的干燥产品注塑制备。
关于上述表1中所示测试样品的各种组份,所述树脂A和B的含量以wt%表示,并且其它组份,即阻燃剂、抗滴落剂和填料的添加量,通过相对于100重量份的由所述树脂A和B形成的树脂部分的物质重量份数来表示。
在表1所示的树脂部分,PC、HIPS和ABS分别代表光学级别(高流动性)聚碳酸酯、高耐震级别的高抗冲聚苯乙烯和具有普通流动性级别的ABS树脂。在表1所示阻燃剂之中,PSS-Na表示聚苯乙烯磺酸钠,其具有70,000的重均分子量,并且硫含量为14wt%;并且ASS-Na表示ABS树脂的磺酸钠,其硫含量为15wt%。所述磷基阻燃剂是三苯基磷酸酯,同时所述硅基阻燃剂为含有乙烯基和甲氧基的甲基苯基硅氧烷。在表1中,所述抗滴落剂是PTFE(聚四氟乙烯),同时所述填料是滑石,其平均粒径为3μm。
对于在这些实施例和比较实施例中所示的每个测试样品,对于阻燃性能进行测试用于评价性能。更特别地,遵照“Combustion Tests for Plastic Materials ofUL subject 94(Underwriter Laboratories Inc.)”,对每个测试样品进行垂直燃烧测试(UL94V-0、1、2)。此外,遵照日本工业标准JISK7201的“Combustion TestMethods for High Molecular Materials by Oxygen Index Method”进行燃烧测试,用于测量氧指数(O.I.)。同时,每个测试样品的厚度为0.1mm。
如表1中所示,从实施例1的测试样品与比较实施例1和2的测试样品比较,并且从实施例3的测试样品与比较实施例4和5的测试样品比较,可以看出的是,所述回收DVD在阻燃性能上优于原始PC树脂或回收CD。
此外,从实施例4的测试样品与比较实施例6和7的测试样品比较,并且从实施例5的测试样品与比较实施例9和10的测试样品比较,可以看出的是,通过混合其它树脂或其它阻燃剂,进一步改进了阻燃性能。
从上述可以看出的是,通过使用所述回收DVD作为原料,可以获得具有优良阻燃性能的树脂组合物。
本领域技术人员应该理解,根据设计要求和其它因素可进行各种改进、组合、子组合和替换,只要它们在所附权利要求或其同等物的范围之内。
表1
NO. | 树脂部分 | 阻燃剂 | 抗滴落剂 | 填料 | 阻燃性能 | |||||||
A组份 | B组份 | 类别 | 添加量(基于树脂的wt%) | 类别 | 添加量(基于树脂的wt%) | 类别 | 添加量(基于树脂的wt%) | UL94V | O.I.(%) | |||
类别 | (wt%) | 类别 | (wt%) | |||||||||
实施例1 | 回收DVD | 100 | - | - | - | - | - | - | - | - | V-2 | >27 |
实施例2 | 回收DVD | 90 | PC | 10 | - | - | - | - | - | - | V-2 | >27 |
实施例3 | 回收DVD | 100 | - | - | PSS-Na | 0.1 | PTFE | 0.2 | - | - | V-0 | >27 |
实施例4 | 回收DVD | 80 | ABS | 20 | TPP | 5 | PTFE | 0.2 | - | - | V-1 | >27 |
实施例5 | 回收DVD | 80 | ABS | 20 | ASS-Na/硅基阻燃剂 | 0.2/0.2 | PTFE | 0.2 | 滑石 | 2 | V-0 | >27 |
实施例6 | 回收DVD | 90 | HIPS | 10 | TPP | 0.5 | PTFE | 0.3 | - | - | V-1 | >27 |
比较实施例1 | PC | 100 | - | - | - | - | - | - | - | - | V-2NG | ≤25 |
比较实施例2 | 回收CD | 100 | - | - | - | - | - | - | - | - | V-2NG | ≤25 |
比较实施例3 | 回收CD | 90 | PC | 10 | - | - | - | - | - | - | V-2NG | ≤25 |
比较实施例4 | PC | 100 | - | - | PSS-Na | 0.1 | PTFE | 0.2 | - | - | V-2 | ≤25 |
比较实施例5 | 回收CD | 100 | - | - | PSS-Na | 0.1 | PTFE | 0.2 | - | - | V-2 | ≤25 |
比较实施例6 | PC | 80 | ABS | 20 | TPP | 5 | PTFE | 0.2 | - | - | V-2NG | ≤25 |
比较实施例7 | 回收CD | 80 | ABS | 20 | TPP | 5 | PTFE | 0.2 | - | - | V-2NG | ≤25 |
比较实施例8 | PC | 80 | ABS | 20 | ASS-Na/硅基阻燃剂 | 0.2/0.2 | PTFE | 0.2 | 滑石 | 2 | V-2 | ≤25 |
比较实施例9 | PC | 90 | HIPS | 10 | PSS-Na | 0.5 | PTFE | 0.3 | - | - | V-2NG | ≤25 |
比较实施例10 | 回收CD | 90 | HIPS | 10 | PSS-Na | 0.5 | PTFE | 0.3 | - | - | V-2NG | ≤25 |
Claims (18)
1.一种用于回收光盘的再生方法,其中
将回收光盘用作制备阻燃树脂组合物或树脂模制品的起始材料,所述回收光盘除了用于将多个光盘基片粘结在一起的粘合剂以外还含有至少一种沉积在光盘基片之上的选自反射膜、记录膜、保护膜和油墨膜的涂覆膜材料。
2.权利要求1的用于回收光盘的再生方法,其中在所述阻燃树脂组合物或树脂模制品中含有比例为5~90wt%的所述回收光盘。
3.权利要求1的用于回收光盘的再生方法,其中将所述回收光盘用作制备阻燃树脂组合物或树脂模制品的起始材料,所述回收光盘含有羟基基团、磷酸(磷酸盐)基团、重氮盐基团、碘鎓盐基团和羧基基团中的至少一种作为所述粘合剂。
4.权利要求3的用于回收光盘的再生方法,其中所述阻燃树脂组合物或树脂模制品中含有的所述粘合剂的比例范围为0.005wt%~20wt%。
5.权利要求1的用于回收光盘的再生方法,其中在所述阻燃树脂组合物或树脂模制品中包含作为阻燃剂的卤基阻燃剂、磷基阻燃剂、氮基阻燃剂、无机阻燃剂、硅基阻燃剂、金属盐基阻燃剂和氟基阻燃剂中的至少一种以及所述回收光盘。
6.权利要求1的用于回收光盘的再生方法,其中包含PC(聚碳酸酯)、ABS(丙烯腈丁二烯苯乙烯共聚物)、AS(丙烯腈苯乙烯共聚物)、PS(聚苯乙烯)、HIPS(高抗冲聚苯乙烯)、PC/ABS合金、PC/HIPS合金、PC/PP(聚丙烯)合金、PC/PE(聚乙烯)合金、PC/PMMA(聚甲基丙烯酸甲酯)合金、PC/PBT(聚对苯二甲酸丁二醇酯)合金和PC/尼龙合金中的至少一种以及所述回收光盘。
7.一种由回收光盘作为起始材料制备的阻燃树脂组合物,所述回收光盘包含至少一种在所述光盘基片上形成的反射膜、记录膜、保护膜和油墨膜的涂覆材料和用于将多个光盘基片粘结在一起的粘合剂。
8.权利要求7的阻燃树脂组合物,其中在起始材料中含有5~90wt%的所述回收光盘。
9.权利要求7的阻燃树脂组合物,其中将所述回收光盘用作起始材料,所述回收光盘含有羟基基团、磷酸(磷酸盐)基团、锍盐基团、重氮盐基团、碘鎓盐基团和羧基基团中的至少一种作为粘合剂。
10.权利要求9的阻燃树脂组合物,其中所述粘合剂的含量为0.005wt%~20wt%。
11.权利要求7的阻燃树脂组合物,其中包含作为阻燃剂的卤基阻燃剂、磷基阻燃剂、氮基阻燃剂、无机阻燃剂、硅基阻燃剂、金属盐基阻燃剂和氟基阻燃剂中的至少一种以及所述回收光盘。
12.权利要求7的阻燃树脂组合物,其中在用于所述阻燃树脂组合物或树脂模制品的起始材料中,包含PC(聚碳酸酯)、ABS(丙烯腈丁二烯苯乙烯共聚物)、AS(丙烯腈苯乙烯共聚物)、PS(聚苯乙烯)、HIPS(高抗冲聚苯乙烯)、PC/ABS合金、PC/PS合金、PC/HIPS合金、PC/PP(聚丙烯)合金、PC/PE(聚乙烯)合金、PC/PMMA(聚甲基丙烯酸甲酯)合金、PC/PET(聚对苯二甲酸乙二醇酯)合金、PC/PBT(聚对苯二甲酸丁二醇酯)合金和PC/尼龙合金中的至少一种以及所述回收光盘。
13.一种由回收光盘作为起始材料制备的阻燃树脂模制品,所述回收光盘包含至少一种在所述光盘基片上形成的反射膜、记录膜、保护膜和油墨膜的涂覆材料和用于将多个光盘基片粘结在一起的粘合剂。
14.权利要求13的阻燃树脂模制品,其中在起始材料中含有5~90wt%的所述回收光盘。
15.权利要求13的阻燃树脂模制品,其中将所述回收光盘用作起始材料,所述回收光盘含有羟基基团、磷酸(盐)基团、锍盐基团、重氮盐基团、碘鎓盐基团和羧基基团中的至少一种作为粘合剂。
16.权利要求15的阻燃树脂模制品,其中所述粘合剂的含量为0.005wt%~20wt%。
17.权利要求13的阻燃树脂模制品,其中包含作为阻燃剂的卤基阻燃剂、磷基阻燃剂、氮基阻燃剂、无机阻燃剂、硅基阻燃剂、金属盐基阻燃剂和氟基阻燃剂中的至少一种以及所述回收光盘。
18.权利要求13的阻燃树脂模制品,其中包含PC(聚碳酸酯)、ABS(丙烯腈丁二烯苯乙烯共聚物)、AS(丙烯腈苯乙烯共聚物)、PS(聚苯乙烯)、HIPS(高抗冲聚苯乙烯)、PC/ABS合金、PC/PS合金、PC/HIPS合金、PC/PP(聚丙烯)合金、PC/PE(聚乙烯)合金、PC/PMMA(聚甲基丙烯酸甲酯)合金、PC/PET(聚对苯二甲酸乙二醇酯)合金、PC/PBT(聚对苯二甲酸丁二醇酯)合金和PC/尼龙合金中的至少一种以及所述回收光盘。
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- 2005-06-23 KR KR20050054546A patent/KR20060048497A/ko not_active Application Discontinuation
- 2005-06-24 CN CN2005100837568A patent/CN1712199B/zh active Active
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CN104204093A (zh) * | 2012-03-19 | 2014-12-10 | 佳能株式会社 | 高分子组合物及其制造方法 |
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CN104941105B (zh) * | 2014-03-31 | 2018-10-30 | 文联煜 | 适用于舰船和航母的三嗪含氮杂环聚合物灭火剂 |
CN105739241A (zh) * | 2014-12-26 | 2016-07-06 | 太阳油墨制造株式会社 | 固化性树脂组合物、干膜、固化物和印刷电路板 |
CN113881183A (zh) * | 2021-11-09 | 2022-01-04 | 广东锦湖日丽高分子材料有限公司 | 一种低红外反射率的阻燃abs树脂组合物及其制备方法 |
CN113881183B (zh) * | 2021-11-09 | 2023-10-20 | 广东锦湖日丽高分子材料有限公司 | 一种低红外反射率的阻燃abs树脂组合物及其制备方法 |
Also Published As
Publication number | Publication date |
---|---|
JP2006008810A (ja) | 2006-01-12 |
JP5315583B2 (ja) | 2013-10-16 |
CN1712199B (zh) | 2010-12-08 |
US20050286397A1 (en) | 2005-12-29 |
KR20060048497A (ko) | 2006-05-18 |
US7868052B2 (en) | 2011-01-11 |
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