CN1670007A - 在双金属氰化物催化工艺中起始物进料流的酸化 - Google Patents

在双金属氰化物催化工艺中起始物进料流的酸化 Download PDF

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Publication number
CN1670007A
CN1670007A CNA2005100560038A CN200510056003A CN1670007A CN 1670007 A CN1670007 A CN 1670007A CN A2005100560038 A CNA2005100560038 A CN A2005100560038A CN 200510056003 A CN200510056003 A CN 200510056003A CN 1670007 A CN1670007 A CN 1670007A
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China
Prior art keywords
acid
molecular weight
starter
reactor
low molecular
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CNA2005100560038A
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English (en)
Chinese (zh)
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E·P·布劳内
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Covestro LLC
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Bayer MaterialScience LLC
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Publication of CN1670007A publication Critical patent/CN1670007A/zh
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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F8/00—Chemical modification by after-treatment
    • C08F8/02—Alkylation
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G65/00—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule
    • C08G65/02—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring
    • C08G65/26—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers and other compounds
    • C08G65/2696—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers and other compounds characterised by the process or apparatus used
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G2/00—Addition polymers of aldehydes or cyclic oligomers thereof or of ketones; Addition copolymers thereof with less than 50 molar percent of other substances
    • C08G2/30—Chemical modification by after-treatment
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G65/00—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G65/00—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule
    • C08G65/02—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring
    • C08G65/26—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers and other compounds
    • C08G65/2642—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers and other compounds characterised by the catalyst used
    • C08G65/2645—Metals or compounds thereof, e.g. salts
    • C08G65/2663—Metal cyanide catalysts, i.e. DMC's
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/24—Nitrogen compounds
    • B01J27/26—Cyanides

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Toxicology (AREA)
  • General Chemical & Material Sciences (AREA)
  • Polyethers (AREA)
  • Polyurethanes Or Polyureas (AREA)
  • Sealing Material Composition (AREA)
  • Heterocyclic Carbon Compounds Containing A Hetero Ring Having Oxygen Or Sulfur (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
CNA2005100560038A 2004-03-19 2005-03-21 在双金属氰化物催化工艺中起始物进料流的酸化 Pending CN1670007A (zh)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US10/804894 2004-03-19
US10/804,894 US20050209438A1 (en) 2004-03-19 2004-03-19 Starter feed stream acidification in DMC-catalyzed process

Related Child Applications (1)

Application Number Title Priority Date Filing Date
CN201010004910A Division CN101851329A (zh) 2004-03-19 2005-03-21 在双金属氰化物催化工艺中起始物进料流的酸化

Publications (1)

Publication Number Publication Date
CN1670007A true CN1670007A (zh) 2005-09-21

Family

ID=34838948

Family Applications (2)

Application Number Title Priority Date Filing Date
CNA2005100560038A Pending CN1670007A (zh) 2004-03-19 2005-03-21 在双金属氰化物催化工艺中起始物进料流的酸化
CN201010004910A Pending CN101851329A (zh) 2004-03-19 2005-03-21 在双金属氰化物催化工艺中起始物进料流的酸化

Family Applications After (1)

Application Number Title Priority Date Filing Date
CN201010004910A Pending CN101851329A (zh) 2004-03-19 2005-03-21 在双金属氰化物催化工艺中起始物进料流的酸化

Country Status (15)

Country Link
US (2) US20050209438A1 (https=)
EP (1) EP1577334B1 (https=)
JP (1) JP4912602B2 (https=)
KR (1) KR101156415B1 (https=)
CN (2) CN1670007A (https=)
AT (1) ATE386766T1 (https=)
BR (1) BRPI0500969B1 (https=)
CA (1) CA2500905C (https=)
DE (1) DE602005004821T2 (https=)
ES (1) ES2300889T3 (https=)
MX (1) MXPA05003008A (https=)
PL (1) PL1577334T3 (https=)
PT (1) PT1577334E (https=)
RU (1) RU2005107562A (https=)
SG (1) SG115771A1 (https=)

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102753603A (zh) * 2009-12-14 2012-10-24 陶氏环球技术有限责任公司 使用双金属氰化物催化剂连续制备低当量多元醇的方法
CN102858846A (zh) * 2010-02-25 2013-01-02 陶氏环球技术有限责任公司 多官能聚甘油引发的聚醚多元醇及由其得到的高回弹性聚氨酯板材
CN109071794A (zh) * 2016-04-20 2018-12-21 科思创有限公司 将反应器由碱催化的多元醇制备转换成dmc催化的多元醇制备的方法
CN109762123A (zh) * 2017-11-09 2019-05-17 山东蓝星东大有限公司 聚酯醚二醇及制法和由其制备的聚氨酯弹性体及制法
WO2020062816A1 (zh) 2018-09-29 2020-04-02 杭州普力材料科技有限公司 一种混合酸改性的锌钴双金属氰化物催化剂及其制备方法

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US20050209438A1 (en) * 2004-03-19 2005-09-22 Browne Edward P Starter feed stream acidification in DMC-catalyzed process
US7323605B2 (en) * 2005-11-09 2008-01-29 Bayer Materialscience Llc Double metal cyanide-catalyzed, low unsaturation polyethers from boron-containing starters
US20080021191A1 (en) * 2006-07-20 2008-01-24 Reese Jack R High water content tolerant process for the production of polyethers
DE102007057147A1 (de) 2007-11-28 2009-06-04 Evonik Goldschmidt Gmbh Verfahren zur Alkoxylierung mit DMC-Katalysatoren im Schlaufenreaktor mit Strahlsauger
WO2009077517A1 (de) * 2007-12-19 2009-06-25 Basf Se Verfahren zur herstellung von polyetheralkoholen
US20100324340A1 (en) * 2009-06-23 2010-12-23 Bayer Materialscience Llc Short chain polyether polyols prepared from ultra-low water-content starters via dmc catalysis
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SG190803A1 (en) * 2010-12-20 2013-07-31 Bayer Ip Gmbh Method for producing polyether polyols
KR101866599B1 (ko) 2010-12-27 2018-06-11 다우 글로벌 테크놀로지스 엘엘씨 이중 금속 시안화물 촉매 착물 및 마그네슘, 3족-15족 금속 또는 란탄 계열 금속 화합물을 사용한 알킬렌 옥시드 중합
BR112013025054B1 (pt) * 2011-03-31 2020-03-17 Dow Global Technologies Llc Método para produzir um poliéter poliol de cadeia curta
EP2543689B1 (en) 2011-07-04 2016-08-10 Repsol, S.A. Continuous method for the synthesis of polyols
US20130289150A1 (en) 2012-04-26 2013-10-31 Bayer Materialscience Ag Viscoelastic polyurethane foams
EP2671893A1 (de) 2012-06-06 2013-12-11 Bayer MaterialScience AG Verfahren zur Herstellung von Omega-Hydroxy-Aminopolymeren
US10358404B2 (en) 2012-06-21 2019-07-23 Covestro Llc Process for the production of low molecular weight impact polyethers
CN103525353B (zh) * 2012-07-01 2015-04-22 万华化学（北京）有限公司 一种聚氨酯复膜胶及其制备方法
US9890100B2 (en) 2013-03-14 2018-02-13 Covestro Llc Continuous process for the production of low molecular weight polyethers with a DMC catalyst
US9051412B2 (en) 2013-03-14 2015-06-09 Bayer Materialscience Llc Base-catalyzed, long chain, active polyethers from short chain DMC-catalyzed starters
US10669368B2 (en) * 2013-03-15 2020-06-02 Covestro Llc Method to increase the resistance of double metal cyanide catalysts to deactivation
BR112016006429B1 (pt) 2013-09-27 2021-08-17 Dow Global Technologies Llc Processo para produzir polímeros poli(óxido de 1,2- butileno) e polímero poli(óxido de 1,2- butileno)
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BR112017020478B1 (pt) 2015-03-31 2021-12-14 Dow Global Technologies Llc Composições de poliéter poliol, formulação de espuma semirrígida, espuma semirrígida e método para formar uma espuma semirrígida
WO2016160939A1 (en) 2015-03-31 2016-10-06 Dow Global Technologies Llc Semi-flexible foam formulations
EP3098251A1 (de) 2015-05-26 2016-11-30 Covestro Deutschland AG Einsatz von alkoholen, die mindestens zwei urethangruppen enthalten, zur herstellung von polyetherpolyolen
AR104981A1 (es) 2015-06-20 2017-08-30 Dow Global Technologies Llc Proceso continuo para producir polioles de poliéter que tienen un elevado contenido de óxido de etileno polimerizado, mediante el uso de un complejo catalizador de cianuro de metal doble y un compuesto metálico de la serie de lantanida o metal del grupo 3 - grupo 15, magnesio
CN107709405B (zh) * 2015-07-02 2020-02-07 科思创有限公司 使用dmc催化剂和连续加入起始剂制备聚醚多元醇的方法
WO2017006357A1 (en) 2015-07-06 2017-01-12 Dow Global Technologies Llc Polyurethane prepolymers
US9879114B2 (en) 2015-12-22 2018-01-30 Covestro Llc Process for the production of low molecular weight polyoxyalkylene polyols
CN107200837B (zh) * 2016-03-18 2019-10-18 淮安巴德聚氨酯科技有限公司 一种利用dmc催化剂循环制备聚醚多元醇的方法
US10961346B2 (en) 2016-05-13 2021-03-30 Covestro Deutschland Ag Method for the preparation of polyoxyalkylene polyols
US10258953B2 (en) 2016-08-05 2019-04-16 Covestro Llc Systems and processes for producing polyether polyols
PL3622003T3 (pl) 2017-05-10 2025-02-24 Dow Global Technologies Llc Proces polimeryzacji polieterowej
KR101950930B1 (ko) * 2017-05-26 2019-02-22 한국화학연구원 아연 산화물 및 알루미늄 산화물을 포함하는 히드록실기 알킬화용 다공성 촉매, 이의 비이온성 계면활성제를 사용한 제조방법 및 이를 이용한 폴리알킬렌 글리콜의 히드록실기의 알킬화 방법
PL3681925T3 (pl) 2017-09-15 2022-10-31 Dow Global Technologies Llc Ciągły sposób wytwarzania polieteropolioli
JP6510098B1 (ja) * 2018-02-14 2019-05-08 Ａｇｃ株式会社 ポリウレタンフォーム製造用組成物、ポリオールシステム液及びポリウレタンフォームの製造方法
CN110964192B (zh) * 2018-09-29 2022-05-17 杭州普力材料科技有限公司 一种用于制备二氧化碳基聚碳酸酯的混合酸改性双金属氰化物催化剂及其制备方法
CN110964191B (zh) * 2018-09-29 2021-02-02 杭州普力材料科技有限公司 一种混合酸改性的锌钴双金属氰化物催化剂及其制备方法
US10723829B2 (en) 2018-12-19 2020-07-28 Covestro Llc Product-to-product process for preparation of low viscosity polyoxyalkylene polyols
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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102753603A (zh) * 2009-12-14 2012-10-24 陶氏环球技术有限责任公司 使用双金属氰化物催化剂连续制备低当量多元醇的方法
CN102858846A (zh) * 2010-02-25 2013-01-02 陶氏环球技术有限责任公司 多官能聚甘油引发的聚醚多元醇及由其得到的高回弹性聚氨酯板材
CN102858846B (zh) * 2010-02-25 2015-10-07 陶氏环球技术有限责任公司 多官能聚甘油引发的聚醚多元醇及由其得到的高回弹性聚氨酯板材
CN109071794A (zh) * 2016-04-20 2018-12-21 科思创有限公司 将反应器由碱催化的多元醇制备转换成dmc催化的多元醇制备的方法
CN109071794B (zh) * 2016-04-20 2021-02-12 科思创有限公司 将反应器由碱催化的多元醇制备转换成dmc催化的多元醇制备的方法
CN109762123A (zh) * 2017-11-09 2019-05-17 山东蓝星东大有限公司 聚酯醚二醇及制法和由其制备的聚氨酯弹性体及制法
WO2020062816A1 (zh) 2018-09-29 2020-04-02 杭州普力材料科技有限公司 一种混合酸改性的锌钴双金属氰化物催化剂及其制备方法

Also Published As

Publication number Publication date
CN101851329A (zh) 2010-10-06
DE602005004821T2 (de) 2009-03-26
US20100234647A1 (en) 2010-09-16
BRPI0500969A (pt) 2005-11-08
US20050209438A1 (en) 2005-09-22
JP2005272838A (ja) 2005-10-06
KR101156415B1 (ko) 2012-06-13
KR20060044413A (ko) 2006-05-16
CA2500905C (en) 2012-11-20
DE602005004821D1 (de) 2008-04-03
BRPI0500969B1 (pt) 2015-08-11
SG115771A1 (en) 2005-10-28
ES2300889T3 (es) 2008-06-16
EP1577334B1 (en) 2008-02-20
RU2005107562A (ru) 2006-08-27
MXPA05003008A (es) 2005-09-22
PT1577334E (pt) 2008-04-28
US7919575B2 (en) 2011-04-05
JP4912602B2 (ja) 2012-04-11
ATE386766T1 (de) 2008-03-15
EP1577334A1 (en) 2005-09-21
CA2500905A1 (en) 2005-09-19
PL1577334T3 (pl) 2008-06-30

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