CN1568930A - Method for applying active constitutent of Bunge prickly ash to daily used chemical products - Google Patents

Method for applying active constitutent of Bunge prickly ash to daily used chemical products Download PDF

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CN1568930A
CN1568930A CN 03135418 CN03135418A CN1568930A CN 1568930 A CN1568930 A CN 1568930A CN 03135418 CN03135418 CN 03135418 CN 03135418 A CN03135418 A CN 03135418A CN 1568930 A CN1568930 A CN 1568930A
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pericarpium zanthoxyli
zanthoxyli
oil
surfactant
prescription
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郦安江
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Abstract

The invention discloses the method for applying active constitutent of Bunge prickly ash to daily used chemical products, wherein the zanthoxylum oil extracted from Chinese prickly ash fruit and the pricklyash peel concrete extracted from the leaf, stem, bark and root of the Chinese prickly ash are used as the active composition, and conventional methods are employed to prepare the line products containing pricklyash peel active compositions.

Description

The Pericarpium Zanthoxyli active component is applied in the method in the daily chemical products
Technical field
The present invention relates to the organic alcohol in the biology, relate to cosmetics or dressing preparation simultaneously, specifically, relate to the application process of Pericarpium Zanthoxyli active component in daily chemical products is produced.
Background technology
Pericarpium Zanthoxyli (Zanthoxylum bungeanum), rutaceae, shrub or dungarunga.The skin of Pericarpium Zanthoxyli fruit is rich in volatile oil, is the flavoring of using always; It is hyoscine also, its hot in nature, acrid in the mouth, and function warming middle-JIAO to relieve pain, parasite killing cure mainly coldness and pain in the epigastrium, vomiting and diarrhoea and ascariasis etc., and seed claims " Semen zanthoxyli ", can line water detumescence (seeing Shanghai Lexicographic Publishing House's " Ci hai " version in 1979,1274 pages).
The harm people of acarid are difficult for discovering, and harm is as the acne of adolescence, the acne rosacea of middle age etc. intuitively.But its harm is far above this.Such as anaphylaxis, demodicid mite class that demodicid mite class Excreta causes cause that diseases such as otitis media, rhinitis, bronchitis also constantly have report.Central television station on June 3rd, 2003 " road of health " column report, the crowd of demodicid mite harm accounts for the whole mankind's 97%, as seen its harm very.And the active substance that effectively suppresses the demodicid mite class is few, particularly can be used for human body to press down the demodicid mite material few.It is reported that but inorganic sulfur and zinc have certain the demodicid mite effect, and organic compound mostly is to be used for crops to kill demodicid mite, can not be used for the mankind.Therefore, the search natural constituent is used for pressing down demodicid mite in plant, is the extremely urgent task of scientific research personnel.Yet up to now, do not see the report that uses the Pericarpium Zanthoxyli active component to press down demodicid mite as yet, do not see the daily chemical product that uses the Pericarpium Zanthoxyli active component yet.
Summary of the invention
Purpose of the present invention just provides a kind of method that the Pericarpium Zanthoxyli active component can be applied to daily chemical product production, and the serial daily chemical product made from this method is provided.
The inventor is in the research that offsets the harm of acaricide class, from numerous natural plants, filter out the Pericarpium Zanthoxyli that China southwest abounds with, and extracted Fructus Zanthoxyli oil with its fruit, go out Pericarpium Zanthoxyli extractum with its leaf, stem, skin and root lixiviate, simultaneously, work out main chemical compositions mile any pure active component that kills demodicid mite just, presses down demodicid mite in Fructus Zanthoxyli oil and the Pericarpium Zanthoxyli extractum, obvious to fungus and the antibacterial effect of killing on the skin.The inventor points out: Pericarpium Zanthoxyli active component mile which alcohol has the effect of the demodicid mite of dispelling, bactericidal antiphlogistic, removing scurf and relieving itching, moistening skin, and nontoxic and no bad irritant reaction, is highly suitable among the daily chemical product.
For achieving the above object, the method that the Pericarpium Zanthoxyli active component is applied to serial daily chemical product production that the inventor provides comprises: (1) discards wherein black seed with fruit (being commonly called as Semen Pericarpium Zanthoxyli) roguing, the crushed after being dried of Pericarpium Zanthoxyli, makes the pricklyash hull powder; (2) the pricklyash hull powder is dropped in the supercritical fluid extraction equipment, add entrainer ethanol, use supercritical CO 2Extract Fructus Zanthoxyli oil; (3) no longer include after Fructus Zanthoxyli oil separates when supercritical fluid extraction equipment, add ethanol again and extract, obtain part Pericarpium Zanthoxyli extractum; (4) with branch and leaf, the roguing of rhizome skin, the drying of Pericarpium Zanthoxyli, be ground into coarse powder, use alcohol extraction, the extractum of extract and front is merged, obtain total Pericarpium Zanthoxyli extractum; (5) in serial daily chemical product is produced, the Fructus Zanthoxyli oil of interpolation 0.05%~20% or 0.05%~20% Pericarpium Zanthoxyli extractum, and make the serial daily chemical products that contains the Pericarpium Zanthoxyli active component according to a conventional method.
At above-mentioned supercritical CO 2In the extraction Fructus Zanthoxyli oil process, extraction conditions is: extracting pressure 12MPa; 35~65 ℃ of extraction temperature; Extraction time 1h.
Adopt the prescription of the producible serial daily chemical products of Pericarpium Zanthoxyli active component as follows:
(1) prescription of Pericarpium Zanthoxyli protective skin cream (mass fraction, %)
Fructus Zanthoxyli oil 0.5~2, high-carbon alcohols 3~7, esters 1~10, surfactant 3~5, wetting agent 1~5, D-panthenol 0.5~2, vitamins 0.1~1, antiseptic 0.2~1, essence 0.1~0.5, all the other are distilled water, various component sums are 100%.
In the said components, higher alcohols can be one or more in spermol, stearyl alcohol and the lauryl alcohol; Esters is methyl stearate or ethyl stearte; Surfactant is one or more in aliphatic alcohol polyethenoxy (25) ether, soil temperature-80, the soil temperature-60; Wetting agent is glycerol or propylene glycol; Vitamin is one or more among vitamin A, vitamin E, the vitamin O; Antiseptic is Nipagin ester or sodium benzoate.
(2) prescription of Pericarpium Zanthoxyli hair cream (mass fraction, %)
Fructus Zanthoxyli oil 2~4, surfactant 20~40, anti-dandruff dose 1~3, conditioner 0.5~3, natural essence 0.3~1, antiseptic sorbate 0.1~1, all the other are distilled water, various component sums are 100%.
Surfactant can be one or more in polyoxyethylene lauryl ether, sulfosuccinic acid monoesters disodium salt, cocamido propyl betaine, lauric acid diethyl amide, stearic acid monoethanolamide, lauryl alcohol sulphuric acid three ethanol etc. in the said components; Anti-dandruff dose is one or more in Zinc Pyrithione, active climbazole, the methylpyridone ethanolamine salt, and conditioner is a D-panthenol.
(3) prescription of Pericarpium Zanthoxyli bath gel (mass fraction, %)
Fructus Zanthoxyli oil 2~4, surfactant 30~50, wetting agent 4~10, lanoline 2~4, methyl hydroxybenzoate 0.1~0.5, sorbate 0.5~1, essence 0.5~3, other is a Purified Water, various component summations are 100%.
In the said components, surfactant is a lauryl alcohol sulphuric acid triethanolamine salt, one or more in ether alcohol sulfate, the lauric acid diethyl amide; Wetting agent is glycerol palmitate, glycerol or propylene glycol.
(4) prescription of Pericarpium Zanthoxyli fancy soap (mass fraction, %)
Soap base (Fructus Zanthoxyli oil/sulfur soap 3: 97) 2~72; Stearate 1~15; Surfactant 3~15; Essence 0.5~1; All the other are distilled water, and various component summations are 100%.
In the said components, surfactant is octyl group glycerin ether sodium sulfonate or sodium isethionate.
(5) the Pericarpium Zanthoxyli formulation of toothpaste (mass fraction, %)
Dibastic sodium phosphate 25~50, propylene glycol 10~26, Pericarpium Zanthoxyli extractum 0.08~0.3, sodium lauryl sulfate 2~10, methyl hydroxybenzoate 0.1~0.5, menthol and natural essence 0.1~0.5, aluminium-magnesium silicate 1~3, all the other are distilled water, various component summations are 100%.
(6) prescription of Pericarpium Zanthoxyli mosquito-repellent perfume (mass fraction, %)
Orange peel oil 2~3, Oleum Eucalypti 0.3~1, Pericarpium Zanthoxyli extractum 0.8~3, rose oil 0.2~0.4, benzoic acid 0.2~0.5, all the other are ethanol, various component summations are 100%.
In the said components, alcohol concentration is 75%, and other is the commercial goods.
The method that the Pericarpium Zanthoxyli active component is applied to serial daily chemical product production that provides of the present invention can be applied to produce a series of daily chemical products, and these products have good sterilizing and itch-relieving, acaricide presses down demodicid mite, antiinflammatory acne removing effect.Its manufacture method is easy, and is safe and effective.
The specific embodiment
Embodiment 1: preparation Pericarpium Zanthoxyli protective skin cream.Two material components that at first prepare protective skin cream, wherein:
A component: spermol 30g, stearyl alcohol 40g, butyl stearate 50g, glycerol 50g, aliphatic alcohol polyethenoxy (25) ether 30g, lanoline 40g, D-panthenol 10g, Fructus Zanthoxyli oil 10g;
B component: retinol1 g, vitamin E 3g, natural essence 1g, sodium benzoate 3g, methyl hydroxybenzoate 2g, distilled water 730g.
Second step slowly was heated to 75 ℃ with the A component in the rustless steel jacketed pan, make it miscible; Under constantly stirring, the sodium benzoate in the B component, methyl hydroxybenzoate and distilled water evenly added in the jacketed pan mix, make it to dissolve evenly after, be cooled to 40 ℃; The 3rd step added the vitamin A in the B component, vitamin E and natural essence in the jacketed pan respectively and mixes, and obtained the about 900g of good mastic behind the homogenizing, can divide and pack in 36 bottles, every bottle of 25g.
This product has good antiinflammatory, sterilization, itching-relieving action, and good nutrition Glycerin effect is arranged.
Embodiment 2 preparation Pericarpium Zanthoxyli hair creams.Get following raw material: polyoxyethylene lauryl ether 30g, sulfosuccinic acid monoesters disodium salt (30%) 250g, cocamido propyl betaine (30%) 30g, lauric acid diethyl amide 30g, stearic acid monoethanolamide 30g, Fructus Zanthoxyli oil 30g, D-panthenol 10g, natural essence 7g, sorbate 10g, distilled water 573g, the first step, heat water to 65 ℃, slowly add above-mentioned substance in the entry successively, after mixing, cooling gradually; Second step when treating that temperature is reduced to 45 ℃, added essence, behind the mix homogeneously, obtained the about 1000g of mastic, was cooled to the room temperature pack, every bag of 10g.
This product surface activity height has good anti-dandruff, itching-relieving action, and it is good to do wet combing character.
Embodiment 3 preparation Pericarpium Zanthoxyli bath gel.Get following raw material: lauryl alcohol sulphuric acid triethanolamine salt 40g, ether alcohol sulfate (30%, water dissolution) 20g, lauric acid diethyl amide 5g, glycerol palmitate 1g, lanoline (water solublity) 2g, glycerol 4g, Fructus Zanthoxyli oil 3g, orange bergamot essence 1g, sorbate 1g, distilled water 24g.The first step is heated to 50 ℃ with distilled water, successively above-mentioned substance slowly added in the entry, and after mixing, cooling gradually; Second step when treating that temperature is reduced to 40 ℃, added orange bergamot essence, after mixing, obtained the about 100g of bath gel, was cooled to the room temperature pack, every bag of 10g.
This product has good washes clean effect and good sterilization, the demodicid mite of dispelling, itching-relieving action, and washes the soft and smooth delicacy of clean back skin, feels more pleasant.
Embodiment 4 preparation Pericarpium Zanthoxyli fancy soaps.Get following raw material: soap base (Fructus Zanthoxyli oil/sulfur soap 3: 97) 8g, stearic acid 1g, fatty acid distribution of coconut oil 8g, Pericarpium Zanthoxyli extractum 5g, octyl group glycerin ether sodium sulfonate 60.5g, sodium isethionate 5g, sodium chloride 4g, titanium dioxide 0.5g, orange bergamot essence 1g, distilled water 4g.The first step with above-mentioned mixing of materials, is heated to molten condition and mix homogeneously; Second step will obtain the about 100g of soap powder after the material spray drying; The 3rd step added essence in the soap powder, stirred the back and ground evenly; The 4th step by printing shaping behind the vacuum press strip, made 1 in Pericarpium Zanthoxyli fancy soap with material.
This product has antipruritic skin moistening effect for the demodicid mite of dispelling removes the fancy soap of itching.
Embodiment 5 preparation Pericarpium Zanthoxyli toothpaste.Get following raw material: dibastic sodium phosphate 230g; Propylene glycol 250g; Pericarpium Zanthoxyli extractum 2g; Sodium lauryl sulfate 280g; Methyl hydroxybenzoate 1g; Menthol and natural essence 1g; Aluminium-magnesium silicate 12g; Water 213g.The first step is dissolved Pericarpium Zanthoxyli extractum with 10ml 95% ethanol, and is joined mixing in the material, obtains liquid material; Second goes on foot, and weighs after granular material is sieved respectively, joins mixing in the mixing and blending machine; The stirring of the 3rd step slowly joins in the granular material mixing with the liquid material of mixing down; The 4th step was ground cream with the back mixed material with colloid mill, adopted vacuum outgas at last, made about Pericarpium Zanthoxyli lotion of toothpaste 1000g, was delivered to filling machine and was fed into 5 dentifrice tubes, every pipe net weight 200g.
This product has good oral cavity antiinflammatory and removes the halitosis effect.
Embodiment 6 preparation Pericarpium Zanthoxyli mosquito-repellent perfumes.Get following raw material: Pericarpium Zanthoxyli extractum 25g, orange peel oil 30g, Oleum Eucalypti 10g, rose oil 4g, benzoic acid 5g, ethanol (75%) 926g.The first step adds ethanol in the rustless steel container, adds Pericarpium Zanthoxyli extractum, stirs it is dissolved fully; Second step under agitation added various essence successively, and mix homogeneously can make floral water 1000g, 20 tenuicollis bottles of packing into, every bottle of 50g.
The warmth of this product fragrance is pleasant, and indoor mosquito, acarid are had repellent, killing action.

Claims (10)

1 is applied to the method that serial daily chemical product is produced with the Pericarpium Zanthoxyli active component, and its feature comprises: (1) discards wherein black seed with fruit (being commonly called as Semen Pericarpium Zanthoxyli) roguing, the crushed after being dried of Pericarpium Zanthoxyli, makes the pricklyash hull powder; (2) the pricklyash hull powder is dropped in the supercritical fluid extraction equipment, add entrainer ethanol, use supercritical CO 2Under pressure 12MPa, 35~65 ℃ of conditions of temperature, extract 1h, extract Fructus Zanthoxyli oil; (3) no longer include after Fructus Zanthoxyli oil separates when supercritical fluid extraction equipment, add ethanol again and extract, obtain part Pericarpium Zanthoxyli extractum; (4) with branch and leaf, the roguing of rhizome skin, the drying of Pericarpium Zanthoxyli, be ground into coarse powder, use alcohol extraction, the extractum of extract and front is merged, obtain total Pericarpium Zanthoxyli extractum; (5) in serial daily chemical products is produced, the Fructus Zanthoxyli oil of interpolation 0.05%~20% or 0.05%~20% Pericarpium Zanthoxyli extractum, and make the series of products that contain the Pericarpium Zanthoxyli active component according to a conventional method.
The Pericarpium Zanthoxyli protective skin cream that 2 the method for claim 1 are produced is characterized in that the prescription of this protective skin cream is: in mass fraction, and Fructus Zanthoxyli oil 0.5~2, high-carbon alcohols 3~7, esters 1~10, surfactant 3~5, wetting agent 1~5, D-panthenol 0.5~2, vitamins 0.1~1, antiseptic 0.2~1, essence 0.1~0.5, all the other are distilled water, and various component sums are 100%.
3 Pericarpium Zanthoxyli protective skin cream as claimed in claim 2, the medium high carbon alcohol that it is characterized in that filling a prescription can be one or more in spermol, stearyl alcohol and the lauryl alcohol: esters is methyl stearate or ethyl stearte; Surfactant is one or more in aliphatic alcohol polyethenoxy (25) ether, soil temperature-80, the soil temperature-60; Wetting agent is glycerol or propylene glycol; Vitamin is one or more among vitamin A, vitamin E, the vitamin O; Antiseptic is Nipagin ester or sodium benzoate.
The Pericarpium Zanthoxyli hair cream that 4 the method for claim 1 are produced, the prescription that it is characterized in that this hair cream is: in mass fraction, Fructus Zanthoxyli oil 2~4, surfactant 20~40, anti-dandruff dose 1~3, conditioner 0.5~3, natural essence 0.3~1, antiseptic sorbate 0.1~1, all the other are distilled water, various component sums are 100%.
5 Pericarpium Zanthoxyli hair creams as claimed in claim 4 is characterized in that surfactant in the component can be one or more in polyoxyethylene lauryl ether, sulfosuccinic acid monoesters disodium salt, cocamido propyl betaine, lauric acid diethyl amide, stearic acid monoethanolamide, lauryl alcohol sulphuric acid three ethanol etc.; Anti-dandruff dose is one or more in Zinc Pyrithione, active climbazole, the methylpyridone ethanolamine salt, and conditioner is a D-panthenol.
The Pericarpium Zanthoxyli bath gel that 6 the method for claim 1 are produced, the prescription that it is characterized in that this bath gel is: in mass fraction, Fructus Zanthoxyli oil 2~4, surfactant 30~50, wetting agent 4~10, lanoline 2~4, methyl hydroxybenzoate 0.1~0.5, sorbate 0.5~1, essence 0.5~3, all the other are Purified Water, and various component summations are 100%.
7 Pericarpium Zanthoxyli bath gel as claimed in claim 6 is characterized in that surfactant is a lauryl alcohol sulphuric acid triethanolamine salt in the prescription, one or more in ether alcohol sulfate, the lauric acid diethyl amide; Wetting agent is glycerol palmitate, glycerol or propylene glycol.
The Pericarpium Zanthoxyli fancy soap that 8 the method for claim 1 are produced is characterized in that the prescription of this fancy soap is: in mass fraction, and soap base (Fructus Zanthoxyli oil/sulfur soap 3: 97) 2~72; Stearate 1~15; Surfactant octyl group glycerin ether sodium sulfonate or sodium isethionate 3~15; Essence 0.5~1; All the other are distilled water, and various component summations are 100%.
The Pericarpium Zanthoxyli toothpaste that 9 the method for claim 1 are produced, it is characterized in that this formulation of toothpaste is: in mass fraction, dibastic sodium phosphate 25~50, propylene glycol 10~26, Pericarpium Zanthoxyli extractum 0.08~0.3, sodium lauryl sulfate 2~10, methyl hydroxybenzoate 0.1~0.5, menthol and natural essence 0.1~0.5, aluminium-magnesium silicate 1~3, all the other are distilled water, and various component summations are 100%.
The Pericarpium Zanthoxyli mosquito-repellent perfume that 10 the method for claim 1 are produced is characterized in that the prescription of this floral water is: in mass fraction, and orange peel oil 2~3, Oleum Eucalypti 0.3~1, Pericarpium Zanthoxyli extractum 0.8~3, rose oil 0.2~0.4, benzoic acid 0.2~0.5; All the other are the ethanol of concentration 75%, and the summation of various components is 100%.
CN 03135418 2003-07-12 2003-07-12 Method for applying active constitutent of Bunge prickly ash to daily used chemical products Pending CN1568930A (en)

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CN100463667C (en) * 2005-02-04 2009-02-25 柳州两面针股份有限公司 Use of new stick shape pepper amide in oral health article
CN102727407A (en) * 2012-03-31 2012-10-17 重庆和信农业发展有限公司 Health-care toothpaste containing Chinese prickly ash extracts
CN102784350A (en) * 2012-08-07 2012-11-21 孙雅儒 Mite killing bactericide and preparation method of mite killing bactericide
CN102939998A (en) * 2012-11-28 2013-02-27 滨州职业学院 Mosquito repellent liquid and preparation method thereof
CN103099163A (en) * 2011-11-14 2013-05-15 长谷川香料株式会社 Manufacture method for extract comprising hydroxy sanshool
CN103284262A (en) * 2013-05-21 2013-09-11 湖北省农业科学院农产品加工与核农技术研究所 Production method for rose hydrosol-tremella sanguinea drink
US20140120190A1 (en) * 2012-10-20 2014-05-01 Dong-Qing WEI Methods of preparing prickly-ash peel extracts and cosmetic compositions incorporating prickly-ash peel extracts
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CN105685022A (en) * 2014-11-25 2016-06-22 金红叶纸业集团有限公司 Paraben composition water dispersion system and preparation method thereof
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CN108094571A (en) * 2017-11-23 2018-06-01 洪雅县和鑫农业科技发展有限公司 A kind of Chinese prickly ash active water production technology
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CN108938468A (en) * 2018-08-29 2018-12-07 陕西为康食品科技股份有限公司 A kind of Chinese prickly ash hand cleanser and preparation method thereof
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CN100463667C (en) * 2005-02-04 2009-02-25 柳州两面针股份有限公司 Use of new stick shape pepper amide in oral health article
CN103099163A (en) * 2011-11-14 2013-05-15 长谷川香料株式会社 Manufacture method for extract comprising hydroxy sanshool
CN102727407B (en) * 2012-03-31 2013-11-20 重庆和信农业发展有限公司 Health-care toothpaste containing Chinese prickly ash extracts
CN102727407A (en) * 2012-03-31 2012-10-17 重庆和信农业发展有限公司 Health-care toothpaste containing Chinese prickly ash extracts
CN102784350A (en) * 2012-08-07 2012-11-21 孙雅儒 Mite killing bactericide and preparation method of mite killing bactericide
US20140120190A1 (en) * 2012-10-20 2014-05-01 Dong-Qing WEI Methods of preparing prickly-ash peel extracts and cosmetic compositions incorporating prickly-ash peel extracts
CN102939998B (en) * 2012-11-28 2014-02-26 滨州职业学院 Mosquito repellent liquid and preparation method thereof
CN102939998A (en) * 2012-11-28 2013-02-27 滨州职业学院 Mosquito repellent liquid and preparation method thereof
CN103284262A (en) * 2013-05-21 2013-09-11 湖北省农业科学院农产品加工与核农技术研究所 Production method for rose hydrosol-tremella sanguinea drink
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CN105685022A (en) * 2014-11-25 2016-06-22 金红叶纸业集团有限公司 Paraben composition water dispersion system and preparation method thereof
CN105230685A (en) * 2015-11-06 2016-01-13 西南大学 Herbaceous plant essential oil composition with mosquito repelling effect
CN105230685B (en) * 2015-11-06 2018-04-03 西南大学 Herbaceous plant essential oil composition with repelling effect
CN105997675A (en) * 2016-06-22 2016-10-12 中华全国供销合作总社南京野生植物综合利用研究所 Mosquito repellent water containing green pepper extracts and preparation method of mosquito repellent water
CN106726871A (en) * 2016-11-18 2017-05-31 重庆市日用化学工业研究所 Sweet wormwood mosquito-expelling and antipruritic floral water and preparation method thereof
CN108094571A (en) * 2017-11-23 2018-06-01 洪雅县和鑫农业科技发展有限公司 A kind of Chinese prickly ash active water production technology
CN108653085A (en) * 2018-06-25 2018-10-16 济南瑞丰生物工程有限公司 A kind of facial mask and preparation method thereof of moisturizing whitening cell repair and suppression mite
CN108635310A (en) * 2018-08-14 2018-10-12 海南金香远药业科技有限公司 Inflammation-diminishing toothpaste and preparation method thereof
CN108938468A (en) * 2018-08-29 2018-12-07 陕西为康食品科技股份有限公司 A kind of Chinese prickly ash hand cleanser and preparation method thereof
CN109157435A (en) * 2018-09-28 2019-01-08 陕西为康食品科技股份有限公司 A kind of sterilization, the bacteriostatic hand sanitizer of Chinese prickly ash and Mongollian Thyme Herb essential oil
CN109097216A (en) * 2018-10-08 2018-12-28 陕西为康食品科技股份有限公司 A kind of Chinese prickly ash antibacterial toilet soap and preparation method thereof
CN109157424A (en) * 2018-10-12 2019-01-08 赵孔发 A kind of preparation method and applications of Japan pepper essential oil microcapsules
CN110772435A (en) * 2019-11-20 2020-02-11 曼真实业(广州)有限公司 Anti-dandruff shampoo and preparation method thereof
CN111904919A (en) * 2020-08-13 2020-11-10 广州广妆生物科技有限公司 Mite-killing conditioner, shower gel and preparation method thereof
CN111789786A (en) * 2020-08-13 2020-10-20 广州广妆生物科技有限公司 Mite-killing plant composition and preparation method and application thereof
CN111920733A (en) * 2020-08-13 2020-11-13 广州广妆生物科技有限公司 Mite-removing conditioner, facial cleanser and preparation method of mite-removing conditioner
CN111920732A (en) * 2020-08-13 2020-11-13 广州广妆生物科技有限公司 Mite-killing conditioner, shampoo and preparation method thereof
CN111789786B (en) * 2020-08-13 2022-11-11 广州极男化妆品有限公司 Mite-killing plant composition and preparation method and application thereof
CN111920733B (en) * 2020-08-13 2023-01-06 广州极男化妆品有限公司 Mite-removing conditioner, facial cleanser and preparation method of mite-removing conditioner
CN111920732B (en) * 2020-08-13 2023-01-06 广州极男化妆品有限公司 Mite-killing conditioner, shampoo and preparation method thereof
CN111904919B (en) * 2020-08-13 2023-04-07 广州极男化妆品有限公司 Mite-killing conditioner, shower gel and preparation method thereof
CN112262858A (en) * 2020-09-30 2021-01-26 深圳市妇幼保健院 Mosquito-repellent essential oil
CN114209619A (en) * 2021-11-30 2022-03-22 重庆创园生物科技有限公司 Liquid shampoo

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