CN1432569A - 吡唑衍生物的制备方法 - Google Patents
吡唑衍生物的制备方法 Download PDFInfo
- Publication number
- CN1432569A CN1432569A CN02143826A CN02143826A CN1432569A CN 1432569 A CN1432569 A CN 1432569A CN 02143826 A CN02143826 A CN 02143826A CN 02143826 A CN02143826 A CN 02143826A CN 1432569 A CN1432569 A CN 1432569A
- Authority
- CN
- China
- Prior art keywords
- alkyl
- haloalkyl
- halogen
- compound
- general formula
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D231/00—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings
- C07D231/02—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings not condensed with other rings
- C07D231/10—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members
- C07D231/14—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
- C07D231/38—Nitrogen atoms
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/48—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with two nitrogen atoms as the only ring hetero atoms
- A01N43/56—1,2-Diazoles; Hydrogenated 1,2-diazoles
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C255/00—Carboxylic acid nitriles
- C07C255/63—Carboxylic acid nitriles containing cyano groups and nitrogen atoms further bound to other hetero atoms, other than oxygen atoms of nitro or nitroso groups, bound to the same carbon skeleton
- C07C255/65—Carboxylic acid nitriles containing cyano groups and nitrogen atoms further bound to other hetero atoms, other than oxygen atoms of nitro or nitroso groups, bound to the same carbon skeleton with the nitrogen atoms further bound to nitrogen atoms
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C317/00—Sulfones; Sulfoxides
- C07C317/26—Sulfones; Sulfoxides having sulfone or sulfoxide groups and nitrogen atoms, not being part of nitro or nitroso groups, bound to the same carbon skeleton
- C07C317/30—Sulfones; Sulfoxides having sulfone or sulfoxide groups and nitrogen atoms, not being part of nitro or nitroso groups, bound to the same carbon skeleton with sulfone or sulfoxide groups bound to carbon atoms of rings other than six-membered aromatic rings of the carbon skeleton
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C317/00—Sulfones; Sulfoxides
- C07C317/44—Sulfones; Sulfoxides having sulfone or sulfoxide groups and carboxyl groups bound to the same carbon skeleton
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C317/00—Sulfones; Sulfoxides
- C07C317/44—Sulfones; Sulfoxides having sulfone or sulfoxide groups and carboxyl groups bound to the same carbon skeleton
- C07C317/48—Sulfones; Sulfoxides having sulfone or sulfoxide groups and carboxyl groups bound to the same carbon skeleton the carbon skeleton being further substituted by singly-bound nitrogen atoms, not being part of nitro or nitroso groups
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D231/00—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings
- C07D231/02—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings not condensed with other rings
- C07D231/10—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members
- C07D231/14—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D231/00—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings
- C07D231/02—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings not condensed with other rings
- C07D231/10—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members
- C07D231/14—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
- C07D231/16—Halogen atoms or nitro radicals
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D231/00—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings
- C07D231/02—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings not condensed with other rings
- C07D231/10—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members
- C07D231/14—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
- C07D231/44—Oxygen and nitrogen or sulfur and nitrogen atoms
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Dentistry (AREA)
- Wood Science & Technology (AREA)
- Plant Pathology (AREA)
- Health & Medical Sciences (AREA)
- Engineering & Computer Science (AREA)
- Agronomy & Crop Science (AREA)
- General Health & Medical Sciences (AREA)
- Pest Control & Pesticides (AREA)
- Zoology (AREA)
- Environmental Sciences (AREA)
- Plural Heterocyclic Compounds (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
- Nitrogen Condensed Heterocyclic Rings (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
Description
Ar | X | R3 | R4 | R5 | R6 | |
2,6-Cl2-4-CF3Ph | HSO4 | COCH3 | SO2(4-ClPh) | CN | NH2 | |
2,6-Cl2-4-CF3Ph | HSO4 | CN | SO2(4-ClPh) | CN | NH2 | |
2,6-Cl2-4-CF3Ph | HSO4 | CN | CO2Et | CN | NH2 | |
2,6-Cl2-4-CF3Ph | HSO4 | CN | SOCF3 | CN | NH2 | |
2,6-Cl2-4-CF3Ph | HSO4 | CN | SOCF3 | CN | NH2 | |
2,6-Cl2-4-OCF3Ph | Cl | Cl | SOCF3 | CN | NH2 | |
2,6-Cl2-4-CF3Ph | HSO4 | CN | SOEt | CN | NH2 | |
2,6-Cl2-4-CF3Ph | HSO4 | CN | P(O)(OEt)2 | CN | NH2 | |
2,6-Cl2-4-CF3Ph | Cl | CN | SOCF3 | CN | NH2 | |
2,6-Cl2-4-CF3Ph | HSO4 | SO(4-ClPh) | COCH3 | CN | NH2 | |
2,6-Cl2-4-CF3Ph | HSO4 | CN | COCF3 | CN | NH2 | |
2,6-Cl2-4-CF3Ph | HSO4 | CN | NO2 | CN | NH2 | |
2,6-Cl2-4-CF3Ph | HSO4 | NO2 | COCH3 | CN | NH2 | |
2,6-Cl2-4-CF3Ph | HSO4 | SO2(2-噻吩基) | COCH3 | CN | NH2 | |
2,6-Cl2-4-CF3Ph | HSO4 | COCH3 | SO2(2-噻吩基) | CN | NH2 | |
2,6-Cl2-4-(4-ClPh)Ph | HSO4 | CN | SOCF3 | CN | NH2 | |
2,6-Cl2-4-CF3Ph | HSO4 | Br | COCH3 | CN | NH2 | |
2,6-Cl2-4-CF3Ph | HSO4 | Br | COPh | CN | NH2 | |
2,6-Cl2-4-CF3Ph | HSO4 | CN | CO(2-呋喃基) | CN | NH2 | |
2,6-Cl2-4-CF3Ph | HSO4 | CN | SOCF3 | CN | NH2 | |
2,6-Cl2-4-SF3Ph | HSO4 | COCH3 | SO2(4-ClPh) | CN | NH2 | |
2,6-Cl2-4-SF3Ph | HSO4 | CN | SO2(4-ClPh) | CN | NH2 | |
2,6-Cl2-4-SF3Ph | HSO4 | CN | CO2Et | CN | NH2 | |
2,6-Cl2-4-SF3Ph | HSO4 | CN | SOCF3 | CN | NH2 | |
2,6-Cl2-4-SF3Ph | HSO4 | CN | SOCH3 | CN | NH2 | |
2,6-Cl2-4-SF3Ph | Cl | Cl | SOCF3 | CN | NH2 | |
2,6-Cl2-4-SF3Ph | HSO4 | CN | SOEt | CN | NH2 | |
2,6-Cl2-4-SF3Ph | HSO4 | CN | P(O)(OEt) | CN | NH2 | |
2,6-Cl2-4-(4CF3Ph)Ph | HSO4 | CN | SOCF3 | CN | NH2 | |
2,6-Cl2-4-(4-OCF3Ph)Ph | HSO4 | CN | SOCF3 | CN | NH2 | |
2,6-Cl2-4-OPh | HSO4 | CN | SOCF3 | CN | NH2 | |
2,6-Cl2-4-(4-SCF3Ph)Ph | HSO4 | CN | SOCF3 | CN | NH2 |
Claims (6)
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US08/815,848 US5907041A (en) | 1997-03-12 | 1997-03-12 | Process for preparing pyrazole derivatives |
US815,848 | 1997-03-12 |
Related Parent Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN98803283A Division CN1107672C (zh) | 1997-03-12 | 1998-03-05 | 用于制备吡唑衍生物的中间体 |
Publications (2)
Publication Number | Publication Date |
---|---|
CN1432569A true CN1432569A (zh) | 2003-07-30 |
CN1184206C CN1184206C (zh) | 2005-01-12 |
Family
ID=25219006
Family Applications (2)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN98803283A Expired - Lifetime CN1107672C (zh) | 1997-03-12 | 1998-03-05 | 用于制备吡唑衍生物的中间体 |
CNB021438269A Expired - Lifetime CN1184206C (zh) | 1997-03-12 | 1998-03-05 | 吡唑衍生物的制备方法 |
Family Applications Before (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN98803283A Expired - Lifetime CN1107672C (zh) | 1997-03-12 | 1998-03-05 | 用于制备吡唑衍生物的中间体 |
Country Status (25)
Country | Link |
---|---|
US (2) | US5907041A (zh) |
EP (1) | EP0966444B1 (zh) |
JP (1) | JP4429389B2 (zh) |
KR (1) | KR100536795B1 (zh) |
CN (2) | CN1107672C (zh) |
AR (1) | AR015108A1 (zh) |
AT (1) | ATE223382T1 (zh) |
AU (1) | AU750836B2 (zh) |
BG (1) | BG64648B1 (zh) |
BR (1) | BR9808854B1 (zh) |
CA (1) | CA2283507C (zh) |
CZ (1) | CZ296302B6 (zh) |
DE (1) | DE69807660T2 (zh) |
DK (1) | DK0966444T3 (zh) |
EA (1) | EA002086B1 (zh) |
ES (1) | ES2179476T3 (zh) |
HU (1) | HU229879B1 (zh) |
ID (1) | ID23447A (zh) |
IL (1) | IL131856A0 (zh) |
NZ (1) | NZ337766A (zh) |
PL (1) | PL196442B1 (zh) |
SK (1) | SK284800B6 (zh) |
TR (1) | TR199902213T2 (zh) |
WO (1) | WO1998040358A1 (zh) |
ZA (1) | ZA981875B (zh) |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN111592510A (zh) * | 2020-04-26 | 2020-08-28 | 衡水均凯化工有限公司 | 一种4,4-(六氟亚异丙烯基)二邻二甲酸酐的合成方法 |
CN111592511A (zh) * | 2020-04-26 | 2020-08-28 | 衡水均凯化工有限公司 | 一种4,4-(六氟亚异丙烯基)二邻二甲酸酐的制备工艺 |
Families Citing this family (12)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB9907458D0 (en) * | 1999-03-31 | 1999-05-26 | Rhone Poulenc Agrochimie | Processes for preparing pesticidal intermediates |
EP1264823A1 (en) * | 2001-06-08 | 2002-12-11 | Novartis AG | Process for the preparation of 2,3-dicyanopropionates |
WO2005023773A1 (en) * | 2003-09-04 | 2005-03-17 | Pfizer Limited | Process for the preparation of substituted aryl pyrazoles |
CA2573271C (en) | 2004-07-15 | 2015-10-06 | Amr Technology, Inc. | Aryl-and heteroaryl-substituted tetrahydroisoquinolines and use thereof to block reuptake of norepinephrine, dopamine, and serotonin |
JP5258561B2 (ja) | 2005-07-15 | 2013-08-07 | アルバニー モレキュラー リサーチ, インコーポレイテッド | アリール置換およびヘテロアリール置換テトラヒドロベンズアゼピンならびにノルエピネフリン、ドーパミンおよびセロトニンの再取り込みを遮断するためのその使用 |
US9156812B2 (en) | 2008-06-04 | 2015-10-13 | Bristol-Myers Squibb Company | Crystalline form of 6-[(4S)-2-methyl-4-(2-naphthyl)-1,2,3,4-tetrahydroisoquinolin-7-yl]pyridazin-3-amine |
WO2010132437A1 (en) | 2009-05-12 | 2010-11-18 | Albany Molecular Research, Inc. | Aryl, heteroaryl, and heterocycle substituted tetrahydroisoquinolines and use thereof |
KR20120023072A (ko) | 2009-05-12 | 2012-03-12 | 브리스톨-마이어스 스큅 컴퍼니 | (S)-7-(〔1,2,4〕트리아졸〔1,5-a〕피리딘-6-일)-4-(3,4-디클로로페닐)-1,2,3,4-테트라하이드로이소퀴놀린의 결정형 및 이의 용도 |
KR101939419B1 (ko) * | 2010-12-30 | 2019-01-16 | 바스프 에스이 | 표면-개질된 안료 제제 |
CN111825653A (zh) | 2019-04-19 | 2020-10-27 | 安道麦马克西姆有限公司 | 取代吡唑类化合物的制备及其作为邻氨基苯甲酰胺前体的用途 |
CN110483480A (zh) * | 2019-09-11 | 2019-11-22 | 江苏优普生物化学科技股份有限公司 | 2-(3-氯吡啶-2-基)-5-羟基-3-吡唑烷甲酸乙酯的合成方法 |
CN110981806A (zh) * | 2019-12-06 | 2020-04-10 | 江苏优普生物化学科技股份有限公司 | 合成芳基吡唑腈副产碳酸二酯的方法 |
Family Cites Families (14)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3140226A (en) * | 1957-05-01 | 1964-07-07 | Monsanto Co | Microorganism toxic alpha-chloro-betacyanoethylaryl sulfones |
US2978480A (en) * | 1957-05-08 | 1961-04-04 | Du Pont | Bis-(alkyl sulfonyl and sulfoxyl) aliphatic acid derivatives |
DE2928136A1 (de) * | 1979-07-12 | 1981-01-29 | Bayer Ag | Phosphorhaltige azoverbindungen sowie deren herstellung und verwendung als schaedlingsbekaempfungsmittel, lichtempfindliche materialien und als ausgangsstoffe zur synthese von pyrazolonen |
GB8713768D0 (en) * | 1987-06-12 | 1987-07-15 | May & Baker Ltd | Compositions of matter |
GB8531485D0 (en) * | 1985-12-20 | 1986-02-05 | May & Baker Ltd | Compositions of matter |
US5232940A (en) * | 1985-12-20 | 1993-08-03 | Hatton Leslie R | Derivatives of N-phenylpyrazoles |
DE3602524A1 (de) * | 1986-01-29 | 1987-07-30 | Bayer Ag | Verfahren zur herstellung konzentrierter loesungen von anionischen farbstoffen |
US4918085A (en) * | 1989-03-02 | 1990-04-17 | Rhone-Poulenc Ag Company | Pesticidal 3-cyano-5-alkoxy-1-arylpyrazoles, compositions and use |
GB8913866D0 (en) * | 1989-06-16 | 1989-08-02 | May & Baker Ltd | New compositions of matter |
US5236938A (en) * | 1991-04-30 | 1993-08-17 | Rhone-Poulenc Inc. | Pesticidal 1-aryl-5-(substituted alkylideneimino)pyrazoles |
GB9120641D0 (en) * | 1991-09-27 | 1991-11-06 | Ici Plc | Heterocyclic compounds |
GB9306184D0 (en) * | 1993-03-25 | 1993-05-19 | Zeneca Ltd | Heteroaromatic compounds |
DE19511269A1 (de) * | 1994-03-30 | 1995-10-05 | Ciba Geigy Ag | Pyrazole |
DE4414333A1 (de) * | 1994-04-25 | 1995-10-26 | Bayer Ag | Substituierte Pyridylpyrazole |
-
1997
- 1997-03-12 US US08/815,848 patent/US5907041A/en not_active Expired - Lifetime
-
1998
- 1998-03-05 CN CN98803283A patent/CN1107672C/zh not_active Expired - Lifetime
- 1998-03-05 ID IDW991018A patent/ID23447A/id unknown
- 1998-03-05 DK DK98913641T patent/DK0966444T3/da active
- 1998-03-05 CN CNB021438269A patent/CN1184206C/zh not_active Expired - Lifetime
- 1998-03-05 AU AU68270/98A patent/AU750836B2/en not_active Expired
- 1998-03-05 SK SK1231-99A patent/SK284800B6/sk not_active IP Right Cessation
- 1998-03-05 NZ NZ337766A patent/NZ337766A/xx not_active IP Right Cessation
- 1998-03-05 WO PCT/EP1998/001226 patent/WO1998040358A1/en active IP Right Grant
- 1998-03-05 ZA ZA981875A patent/ZA981875B/xx unknown
- 1998-03-05 AT AT98913641T patent/ATE223382T1/de not_active IP Right Cessation
- 1998-03-05 PL PL335610A patent/PL196442B1/pl unknown
- 1998-03-05 CZ CZ0319799A patent/CZ296302B6/cs not_active IP Right Cessation
- 1998-03-05 KR KR10-1999-7008197A patent/KR100536795B1/ko not_active IP Right Cessation
- 1998-03-05 EA EA199900821A patent/EA002086B1/ru not_active IP Right Cessation
- 1998-03-05 CA CA002283507A patent/CA2283507C/en not_active Expired - Lifetime
- 1998-03-05 JP JP53917298A patent/JP4429389B2/ja not_active Expired - Lifetime
- 1998-03-05 ES ES98913641T patent/ES2179476T3/es not_active Expired - Lifetime
- 1998-03-05 IL IL13185698A patent/IL131856A0/xx not_active IP Right Cessation
- 1998-03-05 BR BRPI9808854-8A patent/BR9808854B1/pt not_active IP Right Cessation
- 1998-03-05 HU HU0002931A patent/HU229879B1/hu unknown
- 1998-03-05 EP EP98913641A patent/EP0966444B1/en not_active Expired - Lifetime
- 1998-03-05 TR TR1999/02213T patent/TR199902213T2/xx unknown
- 1998-03-05 DE DE69807660T patent/DE69807660T2/de not_active Expired - Lifetime
- 1998-03-10 AR ARP980101070A patent/AR015108A1/es active IP Right Grant
-
1999
- 1999-02-16 US US09/249,798 patent/US6090927A/en not_active Expired - Lifetime
- 1999-10-04 BG BG103778A patent/BG64648B1/bg unknown
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN111592510A (zh) * | 2020-04-26 | 2020-08-28 | 衡水均凯化工有限公司 | 一种4,4-(六氟亚异丙烯基)二邻二甲酸酐的合成方法 |
CN111592511A (zh) * | 2020-04-26 | 2020-08-28 | 衡水均凯化工有限公司 | 一种4,4-(六氟亚异丙烯基)二邻二甲酸酐的制备工艺 |
Also Published As
Similar Documents
Publication | Publication Date | Title |
---|---|---|
CN1107672C (zh) | 用于制备吡唑衍生物的中间体 | |
DE60207416T2 (de) | Imidazotriazin-derivate als gaba-rezeptor-liganden | |
JP5603998B2 (ja) | ベンゾオキサボロールの調製方法 | |
EP0538080A1 (fr) | Dérivés de l'aminométhyl-4 pipéridine, leur préparation et leur application en thérapeutique | |
EP1087966B1 (en) | Chemical synthesis of morpholine derivatives | |
KR20020029917A (ko) | 치환된 피라졸로피리미딘의 합성 방법 | |
CN1182082A (zh) | 嘧啶衍生物制备方法 | |
CN101068812B (zh) | 4,5-二氢-吡唑并[3,4-c]吡啶-2-酮的有效合成 | |
Li et al. | Intramolecular. alpha.-amidoalkylation of an olefin for the synthesis of a useful prostaglandin intermediate | |
GB2116171A (en) | Benzothienylallylamines processes for their production and their use as pharmaceuticals | |
EP1233944A2 (de) | Kupplungs-kondensations-synthese von heterocyclen | |
Okuma et al. | Synthesis of 3, 1-benzothiazines from 2-alkenyl-and 2-alkynylanilides and lawesson reagent | |
CN1891688A (zh) | 芳基吡咯n-草酸酯类衍生物及制备和应用 | |
US5580989A (en) | Process for the preparation of N-4-[(substituted phenyl)alkylheterocyclic]-N | |
Zanatta et al. | Synthesis and characterization of new trifluoromethyl substituted 3‐ethoxycarbonyl‐and 3‐pyrimidin‐2‐yl)‐(1, 2, 3)‐oxathiazinane‐S‐oxides | |
CN1068882C (zh) | 5-(烷氧基甲基)-2,3-吡啶二甲酰亚胺化合物的制备方法 | |
de Jesús Cruz | Expanding the Synthetic Utility of β-Dicarbonyl Compounds in Stereoconvergent Reactions | |
Geffken et al. | Facile route to 1-alkoxy-3-pyrrolin-2-ones by cyclic sulphinylation of N-alkoxy-2-vinylglycolamides | |
CN103724340A (zh) | 一类具有苯并含氧杂环结构的噻唑类衍生物及其制法 | |
US7759492B2 (en) | Enantioselective synthesis of 13-oxotricyclo[8.2.1.0.3,8] trideca-3(8),4,6-triene-5-carboxylates | |
CN1704414A (zh) | 1-芳基吡唑肟类衍生物及其制备和应用 | |
JPH04243855A (ja) | フッ素含有化合物 | |
Noguchi et al. | Synthesis and antirheumatic activity of the metabolites of esonarimod | |
JPH0597735A (ja) | 光学活性二級アルコ−ルの製造方法 | |
CN1333741A (zh) | 1,4-二芳基-2-氟-1-丁烯-3-醇化合物和它们在制备1,4-二芳基-2-氟-1,3-丁二烯和1,4-二芳基-2-氟-2-丁烯化合物中的应用 |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
C06 | Publication | ||
PB01 | Publication | ||
C10 | Entry into substantive examination | ||
SE01 | Entry into force of request for substantive examination | ||
C14 | Grant of patent or utility model | ||
GR01 | Patent grant | ||
ASS | Succession or assignment of patent right |
Owner name: W DENSWIL BRANCH. Effective date: 20050527 Owner name: BASF AGRICULTURAL LTD. Free format text: FORMER OWNER: RHONE-POULENC AGROCH-IMIE |
|
C41 | Transfer of patent application or patent right or utility model | ||
TR01 | Transfer of patent right |
Effective date of registration: 20050527 Address after: Holland sea Wu Eminem Co-patentee after: Weiden Sverre branch Patentee after: BASF agriculture Ltd Address before: lyon Patentee before: Rhone-Poulenc Agrochimie |
|
CX01 | Expiry of patent term |
Granted publication date: 20050112 |
|
CX01 | Expiry of patent term |