CN1319924C - 环己烷的氧化方法 - Google Patents

环己烷的氧化方法 Download PDF

Info

Publication number
CN1319924C
CN1319924C CNB038215535A CN03821553A CN1319924C CN 1319924 C CN1319924 C CN 1319924C CN B038215535 A CNB038215535 A CN B038215535A CN 03821553 A CN03821553 A CN 03821553A CN 1319924 C CN1319924 C CN 1319924C
Authority
CN
China
Prior art keywords
chhp
pimelinketone
mixture
volatile residue
hexalin
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
CNB038215535A
Other languages
English (en)
Chinese (zh)
Other versions
CN1681759A (zh
Inventor
L·福多尔
B·C·苏特拉德哈
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
INVISTA TECHNOLOGIES Sarl
Original Assignee
INVISTA TECHNOLOGIES Sarl
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by INVISTA TECHNOLOGIES Sarl filed Critical INVISTA TECHNOLOGIES Sarl
Publication of CN1681759A publication Critical patent/CN1681759A/zh
Application granted granted Critical
Publication of CN1319924C publication Critical patent/CN1319924C/zh
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/132—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/74—Separation; Purification; Use of additives, e.g. for stabilisation
    • C07C29/76—Separation; Purification; Use of additives, e.g. for stabilisation by physical treatment
    • C07C29/80—Separation; Purification; Use of additives, e.g. for stabilisation by physical treatment by distillation
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C407/00—Preparation of peroxy compounds
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C407/00—Preparation of peroxy compounds
    • C07C407/003—Separation; Purification; Stabilisation; Use of additives
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C409/00—Peroxy compounds
    • C07C409/02—Peroxy compounds the —O—O— group being bound between a carbon atom, not further substituted by oxygen atoms, and hydrogen, i.e. hydroperoxides
    • C07C409/14—Peroxy compounds the —O—O— group being bound between a carbon atom, not further substituted by oxygen atoms, and hydrogen, i.e. hydroperoxides the carbon atom belonging to a ring other than a six-membered aromatic ring
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/27—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/27—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation
    • C07C45/32—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen
    • C07C45/33—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of CHx-moieties
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/51—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by pyrolysis, rearrangement or decomposition
    • C07C45/53—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by pyrolysis, rearrangement or decomposition of hydroperoxides
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/78—Separation; Purification; Stabilisation; Use of additives
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/78—Separation; Purification; Stabilisation; Use of additives
    • C07C45/81—Separation; Purification; Stabilisation; Use of additives by change in the physical state, e.g. crystallisation
    • C07C45/82—Separation; Purification; Stabilisation; Use of additives by change in the physical state, e.g. crystallisation by distillation
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2601/00—Systems containing only non-condensed rings
    • C07C2601/12—Systems containing only non-condensed rings with a six-membered ring
    • C07C2601/14—The ring being saturated

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
CNB038215535A 2002-09-12 2003-09-09 环己烷的氧化方法 Expired - Fee Related CN1319924C (zh)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US10/242,544 US6703529B1 (en) 2002-09-12 2002-09-12 Process for oxidation of cyclohexane
US10/242,544 2002-09-12

Publications (2)

Publication Number Publication Date
CN1681759A CN1681759A (zh) 2005-10-12
CN1319924C true CN1319924C (zh) 2007-06-06

Family

ID=31887781

Family Applications (1)

Application Number Title Priority Date Filing Date
CNB038215535A Expired - Fee Related CN1319924C (zh) 2002-09-12 2003-09-09 环己烷的氧化方法

Country Status (8)

Country Link
US (1) US6703529B1 (cg-RX-API-DMAC7.html)
EP (1) EP1539665B1 (cg-RX-API-DMAC7.html)
JP (1) JP2005539066A (cg-RX-API-DMAC7.html)
KR (1) KR20050044918A (cg-RX-API-DMAC7.html)
CN (1) CN1319924C (cg-RX-API-DMAC7.html)
AU (1) AU2003267072A1 (cg-RX-API-DMAC7.html)
TW (1) TW200410924A (cg-RX-API-DMAC7.html)
WO (1) WO2004024657A2 (cg-RX-API-DMAC7.html)

Families Citing this family (37)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6814867B2 (en) * 2002-09-12 2004-11-09 Inuista North America S.à.r.l. Process for reducing chromium in nonvolatile residue resulting from air oxidation of cyclohexane
FR2878847B1 (fr) 2004-12-07 2007-01-05 Rhodia Chimie Sa Procede de preparation de cyclohexanone
CN100460374C (zh) * 2006-01-06 2009-02-11 中国石油天然气股份有限公司 一种延长醇酮装置碱洗周期的方法
JP5350244B2 (ja) * 2006-08-18 2013-11-27 インヴィスタ テクノロジーズ エスアエルエル イオン性液体を用いた抽出方法
PL2384344T3 (pl) * 2009-01-30 2020-04-30 Invista Textiles (U.K.) Limited Aromatyczne poliestropoliole, pianki poliuretanowe modyfikowane izocyjanuratem i sposoby ich wytwarzania
RU2402520C1 (ru) * 2009-05-28 2010-10-27 Институт Катализа Им. Г.К. Борескова Сибирского Отделения Российской Академии Наук Способ получения смеси циклогексанола и циклогексанона
RU2409548C1 (ru) * 2009-05-28 2011-01-20 Институт Катализа Им. Г.К. Борескова Сибирского Отделения Российской Академии Наук Способ получения смеси циклогексанола и циклогексанона
RU2458903C1 (ru) * 2010-12-23 2012-08-20 Открытое акционерное общество "Щекиноазот" Способ получения циклогексанона и циклогексанола и установка для его осуществления
WO2012173938A1 (en) 2011-06-13 2012-12-20 Invista Technologies S.A.R.L. Aliphatic polyester polyols from cyclohexane oxidation byproduct streams as precursors for polyurethane and polyisocyanurate polymers
JP6058650B2 (ja) 2011-06-17 2017-01-11 インビスタ テクノロジーズ エス．アー．エール．エル． 廃棄流中のモノマー含有量を増大させるためのヒドロラーゼの使用
CN104011216A (zh) 2011-06-30 2014-08-27 英威达技术有限责任公司 用于生产尼龙-7、尼龙-7,7和聚酯的生物转化工艺
US9102960B2 (en) 2011-12-16 2015-08-11 Invista North America S.á.r.l. Methods of producing 6-carbon chemicals via CoA-dependent carbon chain elongation associated with carbon storage
US9102958B2 (en) 2011-12-16 2015-08-11 Invista North America S.á.r.l. Methods of producing 6-carbon chemicals via CoA-dependent carbon chain elongation associated with carbon storage
KR20150036439A (ko) 2012-07-19 2015-04-07 인비스타 테크놀러지스 에스.에이 알.엘. 사이클로헥산의 산화를 위한 공정
CN104583163A (zh) * 2012-07-19 2015-04-29 因温斯特技术公司 氧化环己烷的方法
CN104583164A (zh) 2012-07-19 2015-04-29 因温斯特技术公司 用于纯化环己烷空气氧化产物流的方法
KR20150036632A (ko) 2012-07-19 2015-04-07 인비스타 테크놀러지스 에스.에이 알.엘. 수소화 촉매의 재생
WO2014093847A2 (en) 2012-12-14 2014-06-19 Invista North America S.A.R.L. METHODS OF PRODUCING 7-CARBON CHEMICALS VIA CoA-DEPENDENT CARBON CHAIN ELONGATION ASSOCIATED WITH CARBON STORAGE
EP2935109A1 (en) 2012-12-18 2015-10-28 Invista Technologies S.à.r.l. Process for producing hydrogen cyanide and recovering hydrogen
US9617572B2 (en) 2012-12-31 2017-04-11 Invista North America S.A.R.L. Methods of producing 7-carbon chemicals via aromatic compounds
WO2014105790A2 (en) 2012-12-31 2014-07-03 Invista North America S.A.R.L. Methods of producing 7-carbon chemicals via c1 carbon chain elongation associated with coenzyme b synthesis
EP2938732A1 (en) 2012-12-31 2015-11-04 Invista Technologies S.à.r.l. Methods of producing 7-carbon chemicals from long chain fatty acids via oxidative cleavage
US9580733B2 (en) 2012-12-31 2017-02-28 Invista North America S.A.R.L. Methods of producing 6-carbon chemicals via methyl-ester shielded carbon chain elongation
EP2938731A2 (en) 2012-12-31 2015-11-04 Invista Technologies S.A R.L. Methods of producing 7-carbon chemicals via carbon chain elongation associated with cyclohexane carboxylate synthesis
WO2014105794A2 (en) 2012-12-31 2014-07-03 Invista North America S.A.R.L. Methods of producing 7-carbon chemicals via methyl-ester shielded carbon chain elongation
WO2014105797A2 (en) 2012-12-31 2014-07-03 Invista North America S.A.R.L. Methods of producing 7-carbon chemicals via pyruvate and succinate semialdehyde aldol condensation
CN104557497A (zh) * 2013-10-09 2015-04-29 中国石油化工股份有限公司 一种提高环己基过氧化氢分解酮醇比的方法
WO2015176026A1 (en) 2014-05-15 2015-11-19 Invista North America S.á.r.l. Methods of producing 6-carbon chemicals using 2,6-diaminopimelate as precursor to 2-aminopimelate
CN106795534A (zh) 2014-06-16 2017-05-31 英威达技术有限责任公司 用于生物合成化合物的方法、试剂和细胞
US9777302B2 (en) 2014-06-16 2017-10-03 Invista North America S.A.R.L. Methods, reagents and cells for biosynthesizing compounds
US20170152531A1 (en) 2014-06-16 2017-06-01 North America S.A.R.L. Process for producing glutarate and glutaric acid methyl ester
WO2015195654A1 (en) 2014-06-16 2015-12-23 Invista Technologies S.A R.L. Methods, reagents and cells for biosynthesizing compounds
CN104945213B (zh) * 2014-07-07 2017-01-11 山东勇智化工有限公司 干燥塔负压干燥工艺
RU2717342C1 (ru) 2015-10-01 2020-03-23 Эдвансикс Ресинс Энд Кемикалс Ллк Катализаторы на основе наночастиц для превращения циклогексанола в циклогексанон
CN105315128B (zh) * 2015-10-28 2017-04-12 江西科苑生物药业有限公司 一种环己烷氧化制备ka油的方法
CN106995463B (zh) * 2017-03-31 2019-11-08 中国石油化工股份有限公司 一种油溶性铬酸异辛酯催化体系
RU2673541C1 (ru) * 2017-10-13 2018-11-28 Открытое акционерное общество "Щекиноазот" Способ получения циклогексанона, циклогексанола и циклогексилгидропероксида, установка для его осуществления и устройство абсорбции реакционных газов и предварительного окисления циклогексана

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4720592A (en) * 1986-09-05 1988-01-19 E. I. Du Pont De Nemours And Company Preparation of cyclohexanone and cyclohexanol
US6008415A (en) * 1996-09-11 1999-12-28 Abb Lummus Global Inc. Cyclohexane oxidation

Family Cites Families (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB1590958A (en) * 1976-12-31 1981-06-10 Ici Ltd Oxidation of cyclohexane
SU1323537A1 (ru) 1982-01-22 1987-07-15 Рубежанский филиал Ворошиловградского машиностроительного института Способ очистки сточных вод от шестивалентного хрома
US4465861A (en) 1983-04-11 1984-08-14 E. I. Du Pont De Nemours And Company Process for producing a mixture containing cyclohexanol and cyclohexanone
RU2023674C1 (ru) 1991-07-15 1994-11-30 Ляпкин Александр Александрович Способ очистки сточных вод от соединений хрома
US5932109A (en) 1994-06-02 1999-08-03 Griffin Chemical Company Plating rinse water treatment
JP3632233B2 (ja) * 1995-03-10 2005-03-23 三菱化学株式会社 α−オレフイン低重合体の製造方法
JP3572811B2 (ja) * 1996-06-17 2004-10-06 東ソー株式会社 クロムを含有する廃触媒の処理方法
JP2001058192A (ja) 1999-08-23 2001-03-06 Matsushita Sangyo Kk 六価クロムの除去方法
US6814867B2 (en) * 2002-09-12 2004-11-09 Inuista North America S.à.r.l. Process for reducing chromium in nonvolatile residue resulting from air oxidation of cyclohexane

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4720592A (en) * 1986-09-05 1988-01-19 E. I. Du Pont De Nemours And Company Preparation of cyclohexanone and cyclohexanol
US6008415A (en) * 1996-09-11 1999-12-28 Abb Lummus Global Inc. Cyclohexane oxidation

Also Published As

Publication number Publication date
CN1681759A (zh) 2005-10-12
US6703529B1 (en) 2004-03-09
JP2005539066A (ja) 2005-12-22
AU2003267072A1 (en) 2004-04-30
WO2004024657A2 (en) 2004-03-25
KR20050044918A (ko) 2005-05-13
TW200410924A (en) 2004-07-01
US20040054235A1 (en) 2004-03-18
EP1539665A2 (en) 2005-06-15
AU2003267072A8 (en) 2004-04-30
WO2004024657A3 (en) 2004-08-05
EP1539665A4 (en) 2006-07-26
EP1539665B1 (en) 2011-11-09

Similar Documents

Publication Publication Date Title
US6703529B1 (en) Process for oxidation of cyclohexane
JP2009515967A (ja) クメンハイドロパーオキサイド分解生成物の蒸留による回収法
JP4001861B2 (ja) 水溶液からのギ酸の除去方法
KR100335515B1 (ko) 알돌화반응의폐수정제방법
US2083856A (en) Purification of organic oxy-compounds
JP3426213B2 (ja) シクロヘキサノールおよびシクロヘキサノンを製造する改良された方法
US3946077A (en) Process for oxidating hydrocarbons
CN102492845A (zh) 一种羰基合成反应废铑催化剂的消解方法
US7416645B2 (en) Continuous process for recovering acetone from a waste stream resulting from acetone purification
JP3367056B2 (ja) フェノール及びメチルエチルケトンの製造方法
CN101607875B (zh) 制造环烷酮的方法
EP1380561B1 (en) Continuous process for recovering acetone from a waste stream resulting from acetone purification
JP2713014B2 (ja) カプロラクタムの製法
JPS6034922A (ja) Ｋａ油精製廃液流の浄化方法
JP7771654B2 (ja) フェノールの製造方法
CN120717870A (zh) 一种分离环己烷氧化产物的方法
JP6321656B2 (ja) 精製残留物からのトリメチロールプロパンの回収
JPH06256238A (ja) フェノール及びメチルエチルケトンの製造方法
JPH0881407A (ja) シクロヘキサノン及びシクロヘキサノールの回収方法
JP6816724B2 (ja) ケトン及び／又はアルコールの製造方法及びそのシステム
KR830001083B1 (ko) 사이클로알칸(cycloalkanes)의 산화로 얻어진 사이클로 알카논(cycloalkanone) 혼합물의 정제방법
CN113651685A (zh) 环链烷两步氧化制备二羧酸的方法
JP2005162710A (ja) ジイソプロピルハイドロパーオキシベンゼンの製造方法
JP2003277765A (ja) タールの処理方法

Legal Events

Date Code Title Description
C06 Publication
PB01 Publication
C10 Entry into substantive examination
SE01 Entry into force of request for substantive examination
C14 Grant of patent or utility model
GR01 Patent grant
CF01 Termination of patent right due to non-payment of annual fee

Granted publication date: 20070606

Termination date: 20170909

CF01 Termination of patent right due to non-payment of annual fee