JP2005539066A - シクロヘキサンの酸化プロセス - Google Patents

シクロヘキサンの酸化プロセス Download PDF

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JP2005539066A
JP2005539066A JP2004536396A JP2004536396A JP2005539066A JP 2005539066 A JP2005539066 A JP 2005539066A JP 2004536396 A JP2004536396 A JP 2004536396A JP 2004536396 A JP2004536396 A JP 2004536396A JP 2005539066 A JP2005539066 A JP 2005539066A
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decomposition
cyclohexanol
cyclohexanone
phase
process according
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JP2004536396A
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JP2005539066A5 (cg-RX-API-DMAC7.html
Inventor
フォダー ラドビック
チャンドラ ストラダー バジャ
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インヴィスタ テクノロジーズ エス．アー．アール．エル
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Publication of JP2005539066A publication Critical patent/JP2005539066A/ja
Publication of JP2005539066A5 publication Critical patent/JP2005539066A5/ja
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    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/132—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/74—Separation; Purification; Use of additives, e.g. for stabilisation
    • C07C29/76—Separation; Purification; Use of additives, e.g. for stabilisation by physical treatment
    • C07C29/80—Separation; Purification; Use of additives, e.g. for stabilisation by physical treatment by distillation
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C407/00—Preparation of peroxy compounds
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C407/00—Preparation of peroxy compounds
    • C07C407/003—Separation; Purification; Stabilisation; Use of additives
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C409/00—Peroxy compounds
    • C07C409/02—Peroxy compounds the —O—O— group being bound between a carbon atom, not further substituted by oxygen atoms, and hydrogen, i.e. hydroperoxides
    • C07C409/14—Peroxy compounds the —O—O— group being bound between a carbon atom, not further substituted by oxygen atoms, and hydrogen, i.e. hydroperoxides the carbon atom belonging to a ring other than a six-membered aromatic ring
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/27—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/27—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation
    • C07C45/32—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen
    • C07C45/33—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of CHx-moieties
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/51—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by pyrolysis, rearrangement or decomposition
    • C07C45/53—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by pyrolysis, rearrangement or decomposition of hydroperoxides
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/78—Separation; Purification; Stabilisation; Use of additives
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/78—Separation; Purification; Stabilisation; Use of additives
    • C07C45/81—Separation; Purification; Stabilisation; Use of additives by change in the physical state, e.g. crystallisation
    • C07C45/82—Separation; Purification; Stabilisation; Use of additives by change in the physical state, e.g. crystallisation by distillation
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2601/00—Systems containing only non-condensed rings
    • C07C2601/12—Systems containing only non-condensed rings with a six-membered ring
    • C07C2601/14—The ring being saturated

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
JP2004536396A 2002-09-12 2003-09-09 シクロヘキサンの酸化プロセス Pending JP2005539066A (ja)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US10/242,544 US6703529B1 (en) 2002-09-12 2002-09-12 Process for oxidation of cyclohexane
PCT/US2003/028261 WO2004024657A2 (en) 2002-09-12 2003-09-09 Process for oxidation of cyclohexane

Publications (2)

Publication Number Publication Date
JP2005539066A true JP2005539066A (ja) 2005-12-22
JP2005539066A5 JP2005539066A5 (cg-RX-API-DMAC7.html) 2006-09-28

Family

ID=31887781

Family Applications (1)

Application Number Title Priority Date Filing Date
JP2004536396A Pending JP2005539066A (ja) 2002-09-12 2003-09-09 シクロヘキサンの酸化プロセス

Country Status (8)

Country Link
US (1) US6703529B1 (cg-RX-API-DMAC7.html)
EP (1) EP1539665B1 (cg-RX-API-DMAC7.html)
JP (1) JP2005539066A (cg-RX-API-DMAC7.html)
KR (1) KR20050044918A (cg-RX-API-DMAC7.html)
CN (1) CN1319924C (cg-RX-API-DMAC7.html)
AU (1) AU2003267072A1 (cg-RX-API-DMAC7.html)
TW (1) TW200410924A (cg-RX-API-DMAC7.html)
WO (1) WO2004024657A2 (cg-RX-API-DMAC7.html)

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US6814867B2 (en) * 2002-09-12 2004-11-09 Inuista North America S.à.r.l. Process for reducing chromium in nonvolatile residue resulting from air oxidation of cyclohexane
FR2878847B1 (fr) 2004-12-07 2007-01-05 Rhodia Chimie Sa Procede de preparation de cyclohexanone
CN100460374C (zh) * 2006-01-06 2009-02-11 中国石油天然气股份有限公司 一种延长醇酮装置碱洗周期的方法
JP5350244B2 (ja) * 2006-08-18 2013-11-27 インヴィスタ テクノロジーズ エスアエルエル イオン性液体を用いた抽出方法
PL2384344T3 (pl) * 2009-01-30 2020-04-30 Invista Textiles (U.K.) Limited Aromatyczne poliestropoliole, pianki poliuretanowe modyfikowane izocyjanuratem i sposoby ich wytwarzania
RU2402520C1 (ru) * 2009-05-28 2010-10-27 Институт Катализа Им. Г.К. Борескова Сибирского Отделения Российской Академии Наук Способ получения смеси циклогексанола и циклогексанона
RU2409548C1 (ru) * 2009-05-28 2011-01-20 Институт Катализа Им. Г.К. Борескова Сибирского Отделения Российской Академии Наук Способ получения смеси циклогексанола и циклогексанона
RU2458903C1 (ru) * 2010-12-23 2012-08-20 Открытое акционерное общество "Щекиноазот" Способ получения циклогексанона и циклогексанола и установка для его осуществления
WO2012173938A1 (en) 2011-06-13 2012-12-20 Invista Technologies S.A.R.L. Aliphatic polyester polyols from cyclohexane oxidation byproduct streams as precursors for polyurethane and polyisocyanurate polymers
JP6058650B2 (ja) 2011-06-17 2017-01-11 インビスタ テクノロジーズ エス．アー．エール．エル． 廃棄流中のモノマー含有量を増大させるためのヒドロラーゼの使用
CN104011216A (zh) 2011-06-30 2014-08-27 英威达技术有限责任公司 用于生产尼龙-7、尼龙-7,7和聚酯的生物转化工艺
US9102960B2 (en) 2011-12-16 2015-08-11 Invista North America S.á.r.l. Methods of producing 6-carbon chemicals via CoA-dependent carbon chain elongation associated with carbon storage
US9102958B2 (en) 2011-12-16 2015-08-11 Invista North America S.á.r.l. Methods of producing 6-carbon chemicals via CoA-dependent carbon chain elongation associated with carbon storage
KR20150036439A (ko) 2012-07-19 2015-04-07 인비스타 테크놀러지스 에스.에이 알.엘. 사이클로헥산의 산화를 위한 공정
CN104583163A (zh) * 2012-07-19 2015-04-29 因温斯特技术公司 氧化环己烷的方法
CN104583164A (zh) 2012-07-19 2015-04-29 因温斯特技术公司 用于纯化环己烷空气氧化产物流的方法
KR20150036632A (ko) 2012-07-19 2015-04-07 인비스타 테크놀러지스 에스.에이 알.엘. 수소화 촉매의 재생
WO2014093847A2 (en) 2012-12-14 2014-06-19 Invista North America S.A.R.L. METHODS OF PRODUCING 7-CARBON CHEMICALS VIA CoA-DEPENDENT CARBON CHAIN ELONGATION ASSOCIATED WITH CARBON STORAGE
EP2935109A1 (en) 2012-12-18 2015-10-28 Invista Technologies S.à.r.l. Process for producing hydrogen cyanide and recovering hydrogen
US9617572B2 (en) 2012-12-31 2017-04-11 Invista North America S.A.R.L. Methods of producing 7-carbon chemicals via aromatic compounds
WO2014105790A2 (en) 2012-12-31 2014-07-03 Invista North America S.A.R.L. Methods of producing 7-carbon chemicals via c1 carbon chain elongation associated with coenzyme b synthesis
EP2938732A1 (en) 2012-12-31 2015-11-04 Invista Technologies S.à.r.l. Methods of producing 7-carbon chemicals from long chain fatty acids via oxidative cleavage
US9580733B2 (en) 2012-12-31 2017-02-28 Invista North America S.A.R.L. Methods of producing 6-carbon chemicals via methyl-ester shielded carbon chain elongation
EP2938731A2 (en) 2012-12-31 2015-11-04 Invista Technologies S.A R.L. Methods of producing 7-carbon chemicals via carbon chain elongation associated with cyclohexane carboxylate synthesis
WO2014105794A2 (en) 2012-12-31 2014-07-03 Invista North America S.A.R.L. Methods of producing 7-carbon chemicals via methyl-ester shielded carbon chain elongation
WO2014105797A2 (en) 2012-12-31 2014-07-03 Invista North America S.A.R.L. Methods of producing 7-carbon chemicals via pyruvate and succinate semialdehyde aldol condensation
CN104557497A (zh) * 2013-10-09 2015-04-29 中国石油化工股份有限公司 一种提高环己基过氧化氢分解酮醇比的方法
WO2015176026A1 (en) 2014-05-15 2015-11-19 Invista North America S.á.r.l. Methods of producing 6-carbon chemicals using 2,6-diaminopimelate as precursor to 2-aminopimelate
CN106795534A (zh) 2014-06-16 2017-05-31 英威达技术有限责任公司 用于生物合成化合物的方法、试剂和细胞
US9777302B2 (en) 2014-06-16 2017-10-03 Invista North America S.A.R.L. Methods, reagents and cells for biosynthesizing compounds
US20170152531A1 (en) 2014-06-16 2017-06-01 North America S.A.R.L. Process for producing glutarate and glutaric acid methyl ester
WO2015195654A1 (en) 2014-06-16 2015-12-23 Invista Technologies S.A R.L. Methods, reagents and cells for biosynthesizing compounds
CN104945213B (zh) * 2014-07-07 2017-01-11 山东勇智化工有限公司 干燥塔负压干燥工艺
RU2717342C1 (ru) 2015-10-01 2020-03-23 Эдвансикс Ресинс Энд Кемикалс Ллк Катализаторы на основе наночастиц для превращения циклогексанола в циклогексанон
CN105315128B (zh) * 2015-10-28 2017-04-12 江西科苑生物药业有限公司 一种环己烷氧化制备ka油的方法
CN106995463B (zh) * 2017-03-31 2019-11-08 中国石油化工股份有限公司 一种油溶性铬酸异辛酯催化体系
RU2673541C1 (ru) * 2017-10-13 2018-11-28 Открытое акционерное общество "Щекиноазот" Способ получения циклогексанона, циклогексанола и циклогексилгидропероксида, установка для его осуществления и устройство абсорбции реакционных газов и предварительного окисления циклогексана

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5384941A (en) * 1976-12-31 1978-07-26 Ici Ltd Method for production of cyclohexanol and cyclohexanone
JPH08245429A (ja) * 1995-03-10 1996-09-24 Mitsubishi Chem Corp α−オレフイン低重合体の製造方法
JPH108149A (ja) * 1996-06-17 1998-01-13 Tosoh Corp クロムを含有する廃触媒の処理方法

Family Cites Families (8)

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SU1323537A1 (ru) 1982-01-22 1987-07-15 Рубежанский филиал Ворошиловградского машиностроительного института Способ очистки сточных вод от шестивалентного хрома
US4465861A (en) 1983-04-11 1984-08-14 E. I. Du Pont De Nemours And Company Process for producing a mixture containing cyclohexanol and cyclohexanone
US4720592A (en) 1986-09-05 1988-01-19 E. I. Du Pont De Nemours And Company Preparation of cyclohexanone and cyclohexanol
RU2023674C1 (ru) 1991-07-15 1994-11-30 Ляпкин Александр Александрович Способ очистки сточных вод от соединений хрома
US5932109A (en) 1994-06-02 1999-08-03 Griffin Chemical Company Plating rinse water treatment
US5780683A (en) * 1996-09-11 1998-07-14 Abb Lummus Global Inc. Cyclohexane oxidation
JP2001058192A (ja) 1999-08-23 2001-03-06 Matsushita Sangyo Kk 六価クロムの除去方法
US6814867B2 (en) * 2002-09-12 2004-11-09 Inuista North America S.à.r.l. Process for reducing chromium in nonvolatile residue resulting from air oxidation of cyclohexane

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5384941A (en) * 1976-12-31 1978-07-26 Ici Ltd Method for production of cyclohexanol and cyclohexanone
JPH08245429A (ja) * 1995-03-10 1996-09-24 Mitsubishi Chem Corp α−オレフイン低重合体の製造方法
JPH108149A (ja) * 1996-06-17 1998-01-13 Tosoh Corp クロムを含有する廃触媒の処理方法

Also Published As

Publication number Publication date
CN1681759A (zh) 2005-10-12
US6703529B1 (en) 2004-03-09
AU2003267072A1 (en) 2004-04-30
WO2004024657A2 (en) 2004-03-25
KR20050044918A (ko) 2005-05-13
TW200410924A (en) 2004-07-01
US20040054235A1 (en) 2004-03-18
EP1539665A2 (en) 2005-06-15
AU2003267072A8 (en) 2004-04-30
CN1319924C (zh) 2007-06-06
WO2004024657A3 (en) 2004-08-05
EP1539665A4 (en) 2006-07-26
EP1539665B1 (en) 2011-11-09

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