CN1317955A - 紫外线防护镜和含苯并三唑和二苯酮的材料 - Google Patents
紫外线防护镜和含苯并三唑和二苯酮的材料 Download PDFInfo
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- CN1317955A CN1317955A CN99811027A CN99811027A CN1317955A CN 1317955 A CN1317955 A CN 1317955A CN 99811027 A CN99811027 A CN 99811027A CN 99811027 A CN99811027 A CN 99811027A CN 1317955 A CN1317955 A CN 1317955A
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- lens
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- ultraviolet absorber
- aryl
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- 239000000463 material Substances 0.000 title claims description 23
- 239000012965 benzophenone Substances 0.000 title claims description 12
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- 229920000642 polymer Polymers 0.000 claims abstract description 31
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- 239000006097 ultraviolet radiation absorber Substances 0.000 claims description 55
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- 229910052739 hydrogen Inorganic materials 0.000 claims description 35
- 239000001257 hydrogen Substances 0.000 claims description 32
- 150000002431 hydrogen Chemical group 0.000 claims description 28
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 claims description 27
- 125000000217 alkyl group Chemical group 0.000 claims description 27
- 125000003118 aryl group Chemical group 0.000 claims description 25
- QRUDEWIWKLJBPS-UHFFFAOYSA-N benzotriazole Chemical compound C1=CC=C2N[N][N]C2=C1 QRUDEWIWKLJBPS-UHFFFAOYSA-N 0.000 claims description 25
- 239000012964 benzotriazole Substances 0.000 claims description 24
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- 238000000862 absorption spectrum Methods 0.000 description 2
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 2
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- 125000002947 alkylene group Chemical group 0.000 description 2
- 235000013405 beer Nutrition 0.000 description 2
- OCWYEMOEOGEQAN-UHFFFAOYSA-N bumetrizole Chemical compound CC(C)(C)C1=CC(C)=CC(N2N=C3C=C(Cl)C=CC3=N2)=C1O OCWYEMOEOGEQAN-UHFFFAOYSA-N 0.000 description 2
- 125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 2
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- NUHSROFQTUXZQQ-UHFFFAOYSA-N isopentenyl diphosphate Chemical compound CC(=C)CCO[P@](O)(=O)OP(O)(O)=O NUHSROFQTUXZQQ-UHFFFAOYSA-N 0.000 description 2
- VLCAYQIMSMPEBW-UHFFFAOYSA-N methyl 3-hydroxy-2-methylidenebutanoate Chemical compound COC(=O)C(=C)C(C)O VLCAYQIMSMPEBW-UHFFFAOYSA-N 0.000 description 2
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- XUDBVJCTLZTSDC-UHFFFAOYSA-N 2-ethenylbenzoic acid Chemical compound OC(=O)C1=CC=CC=C1C=C XUDBVJCTLZTSDC-UHFFFAOYSA-N 0.000 description 1
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- OMIHGPLIXGGMJB-UHFFFAOYSA-N 7-oxabicyclo[4.1.0]hepta-1,3,5-triene Chemical compound C1=CC=C2OC2=C1 OMIHGPLIXGGMJB-UHFFFAOYSA-N 0.000 description 1
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- IEQIEDJGQAUEQZ-UHFFFAOYSA-N phthalocyanine Chemical compound N1C(N=C2C3=CC=CC=C3C(N=C3C4=CC=CC=C4C(=N4)N3)=N2)=C(C=CC=C2)C2=C1N=C1C2=CC=CC=C2C4=N1 IEQIEDJGQAUEQZ-UHFFFAOYSA-N 0.000 description 1
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Images
Classifications
-
- G—PHYSICS
- G02—OPTICS
- G02B—OPTICAL ELEMENTS, SYSTEMS OR APPARATUS
- G02B1/00—Optical elements characterised by the material of which they are made; Optical coatings for optical elements
- G02B1/04—Optical elements characterised by the material of which they are made; Optical coatings for optical elements made of organic materials, e.g. plastics
- G02B1/041—Lenses
- G02B1/043—Contact lenses
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US09/121,071 | 1998-07-21 | ||
US09/121,071 US6244707B1 (en) | 1998-07-21 | 1998-07-21 | UV blocking lenses and material containing benzotriazoles and benzophenones |
Publications (1)
Publication Number | Publication Date |
---|---|
CN1317955A true CN1317955A (zh) | 2001-10-17 |
Family
ID=22394323
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN99811027A Pending CN1317955A (zh) | 1998-07-21 | 1999-07-13 | 紫外线防护镜和含苯并三唑和二苯酮的材料 |
Country Status (12)
Cited By (14)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1321964C (zh) * | 2003-05-27 | 2007-06-20 | 三星电子株式会社 | 具有紫外线吸收部分的耐光添加剂及包含该添加剂的油墨组合物 |
CN1884364B (zh) * | 2005-06-23 | 2010-08-25 | 上海伟星光学有限公司 | 一种用于制造光致变色树脂镜片的组合物 |
CN101068869B (zh) * | 2004-12-03 | 2010-11-03 | 西巴特殊化学品控股有限公司 | 紫外光吸收剂稳定剂组合 |
CN1849531B (zh) * | 2003-09-08 | 2011-11-16 | 博士伦公司 | 具有蓝光吸收特性的人工晶状体的制备方法 |
CN101318029B (zh) * | 2008-06-20 | 2012-02-01 | 周辉 | 眼用可塑性高分子聚合材料及其应用 |
CN103026267A (zh) * | 2010-04-29 | 2013-04-03 | 诺华公司 | 具有uv吸收剂和蓝光生色团的组合的眼内透镜 |
CN103917899A (zh) * | 2011-10-12 | 2014-07-09 | 诺华股份有限公司 | 通过涂布制备uv吸收性眼用透镜的方法 |
CN103009737B (zh) * | 2006-01-13 | 2015-05-20 | 圣戈本操作塑料有限公司 | 耐候性多层膜 |
CN109789241A (zh) * | 2016-06-23 | 2019-05-21 | 麦迪凯姆研究所有限股份公司 | 可调光的水凝胶和生物模拟人工晶状体 |
CN111430550A (zh) * | 2020-03-26 | 2020-07-17 | 杭州纤纳光电科技有限公司 | 带紫外保护层的钙钛矿电池组件及其制备方法 |
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CN112930487A (zh) * | 2018-08-10 | 2021-06-08 | 鲍希与洛姆伯股份有限公司 | 眼科装置 |
CN114994953A (zh) * | 2015-09-29 | 2022-09-02 | 视觉缓解公司 | Uv和高能可见吸收验眼透镜 |
Families Citing this family (53)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US6329485B1 (en) * | 1998-12-11 | 2001-12-11 | Bausch & Lomb Incorporated | High refractive index hydrogel compositions for ophthalmic implants |
US7879288B2 (en) | 1999-03-01 | 2011-02-01 | Johnson & Johnson Vision Care, Inc. | Method and apparatus of sterilization using monochromatic UV radiation source |
JP3676138B2 (ja) | 1999-09-20 | 2005-07-27 | Hoya株式会社 | 紫外線吸収性に優れたプラスチック眼鏡レンズ及びその製造方法 |
JP3547662B2 (ja) * | 1999-09-20 | 2004-07-28 | Hoya株式会社 | 紫外線吸収性に優れたプラスチック眼鏡レンズ及びその製造方法 |
US20030234459A1 (en) * | 2000-05-19 | 2003-12-25 | Nandu Mahendra P. | Method for the manufacture of molded polymeric devices using variable frequency microwaves |
JP4152732B2 (ja) * | 2001-12-27 | 2008-09-17 | 株式会社トクヤマ | 樹脂組成物 |
US6851804B2 (en) * | 2001-12-28 | 2005-02-08 | Jagdish M. Jethmalani | Readjustable optical elements |
US20040186241A1 (en) * | 2003-03-20 | 2004-09-23 | Gemert Barry Van | Photochromic ocular devices |
DE10349254A1 (de) * | 2003-10-20 | 2005-05-12 | Transmit Technologietransfer | Intraokulare Linseneinrichtung zur Verbesserung des Sehvermögens bei Netzhauterkrankungen |
WO2005066694A2 (en) | 2003-12-29 | 2005-07-21 | Advanced Medical Optics, Inc. | Intraocular lenses having a visible light-selective-transmissive-region |
US20060083940A1 (en) * | 2004-04-30 | 2006-04-20 | Solomon Bekele | Ultraviolet light absorbing composition |
EP2574976B1 (en) | 2004-04-30 | 2021-08-11 | Johnson & Johnson Surgical Vision, Inc. | Ophthalmic devices having a highly selective violet light transmissive filter |
JP2006011131A (ja) * | 2004-06-28 | 2006-01-12 | Asahi Kasei Aimii Kk | 色付きコンタクトレンズ |
JP5264177B2 (ja) | 2004-11-22 | 2013-08-14 | アボット・メディカル・オプティクス・インコーポレイテッド | 共重合性メチンおよびアントラキノン化合物およびそれらを含有する物品 |
US7326423B2 (en) * | 2004-11-22 | 2008-02-05 | Advanced Medical Optics, Inc. | Copolymerizable azo compounds and articles containing them |
US20060197067A1 (en) * | 2005-03-04 | 2006-09-07 | Erning Xia | Radiation-absorbing materials, ophthalmic compositions containing same, and method of treating ophthalmic devices |
EP2568573A3 (en) | 2005-03-07 | 2014-06-04 | Black & Decker Inc. | Power Tools with Motor Having a Multi-Piece Stator |
US20060252850A1 (en) * | 2005-05-04 | 2006-11-09 | Bausch & Lomb Incorporated | Radiation-absorbing polymeric materials and ophthalmic devices comprising same |
US7842367B2 (en) | 2005-05-05 | 2010-11-30 | Key Medical Technologies, Inc. | Ultra violet, violet, and blue light filtering polymers for ophthalmic applications |
US7163446B1 (en) * | 2005-06-20 | 2007-01-16 | John Ray Cole | Vehicle headlight restoration |
CN101321505B (zh) * | 2005-09-08 | 2015-12-02 | 卡尔豪恩视觉公司 | 具有增强紫外保护的新型可调节光学元件 |
US20070092830A1 (en) * | 2005-10-24 | 2007-04-26 | Bausch & Lomb Incorporated | Polymeric radiation-absorbing materials and ophthalmic devices comprising same |
US20070092831A1 (en) * | 2005-10-24 | 2007-04-26 | Bausch & Lomb Incorporated | Radiation-absorbing polymeric materials and ophthalmic devices comprising same |
US7691918B2 (en) | 2006-10-13 | 2010-04-06 | Alcon, Inc. | Intraocular lenses with unique blue-violet cutoff and blue light transmission characteristics |
US20080259617A1 (en) * | 2007-04-19 | 2008-10-23 | Wayne M. Torcivia | Transportation system and method or methods for the restoration,re-manufacturing and re-conditioning or any combination thereof,of a vehicle headlight fixture or headlight fixture lens or any combination thereof |
TWI435915B (zh) | 2007-08-09 | 2014-05-01 | Alcon Inc | 含有吸收紫外光(uv)及短波長可見光二者的發色團之眼科鏡體材料(一) |
TW200916531A (en) | 2007-08-09 | 2009-04-16 | Alcon Inc | Ophthalmic lens materials containing chromophores that absorb both UV and short wavelength visible light |
US8394906B2 (en) * | 2008-02-12 | 2013-03-12 | Aaren Scientific Inc. | Ophthalmic lens having a yellow dye light blocking component |
AU2009228847B2 (en) * | 2008-03-27 | 2014-08-07 | Alcon, Inc. | Hydrogel intraocular lens and method of forming same |
US8236053B1 (en) | 2008-10-08 | 2012-08-07 | Novartis Ag | 2-amino benzophenone UV-absorbers for ophthalmic lens materials |
TWI453199B (zh) | 2008-11-04 | 2014-09-21 | Alcon Inc | 用於眼用鏡片材料之紫外光/可見光吸收劑 |
JP5597647B2 (ja) * | 2008-12-30 | 2014-10-01 | ノバルティス アーゲー | 3官能uv吸収性化合物およびその用途 |
HUE038021T2 (hu) * | 2010-07-30 | 2018-09-28 | Novartis Ag | Eljárás UV-abszorbeáló szemészeti lencsék elõállítására |
US8740382B1 (en) | 2010-09-30 | 2014-06-03 | Cognex Corporation | System and method for automatically tracking a contact lens in a wearer's eye |
US9427778B2 (en) | 2010-10-20 | 2016-08-30 | Search Automotive Technologies, Llc | Headlight restoration kit |
MY158272A (en) | 2010-12-13 | 2016-09-30 | Novartis Ag | Ophthalmic lenses modified with functional groups and methods of making thereof |
US20130313733A1 (en) * | 2012-05-25 | 2013-11-28 | Ivan Nunez | Method of making a fully polymerized uv blocking silicone hydrogel lens |
PL2875091T3 (pl) * | 2012-07-23 | 2017-04-28 | Bausch & Lomb Incorporated | Związki absorbujące światło do polimerów optycznych |
US10338408B2 (en) * | 2012-12-17 | 2019-07-02 | Novartis Ag | Method for making improved UV-absorbing ophthalmic lenses |
US10441676B2 (en) * | 2013-01-15 | 2019-10-15 | Medicem Institute s.r.o. | Light-adjustable hydrogel and bioanalogic intraocular lens |
ES2693335T3 (es) | 2013-01-15 | 2018-12-11 | Medicem Institute s.r.o. | Lente intraocular bioanalógica |
US20160221281A1 (en) | 2013-09-12 | 2016-08-04 | Battelle Memorial Institute | Lens modification methods |
JP6516147B2 (ja) * | 2015-03-03 | 2019-05-22 | 株式会社 アイレ | 抗菌性コンタクトレンズ及びその使用方法並びにその製造方法 |
CN108431147B (zh) | 2016-01-21 | 2021-02-26 | 罗门哈斯公司 | 用于耐久涂料的聚合物分散体和包含所述聚合物分散体的涂料 |
US10752720B2 (en) | 2017-06-26 | 2020-08-25 | Johnson & Johnson Vision Care, Inc. | Polymerizable blockers of high energy light |
US10723732B2 (en) | 2017-06-30 | 2020-07-28 | Johnson & Johnson Vision Care, Inc. | Hydroxyphenyl phenanthrolines as polymerizable blockers of high energy light |
US10526296B2 (en) | 2017-06-30 | 2020-01-07 | Johnson & Johnson Vision Care, Inc. | Hydroxyphenyl naphthotriazoles as polymerizable blockers of high energy light |
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EP3960831A4 (en) * | 2019-04-26 | 2023-01-11 | Miyoshi Oil & Fat Co., Ltd. | ULTRAVIOLET ABSORBER WITH EXCELLENT HEAT RESISTANCE AND EXCELLENT WAVELENGTH ABSORPTION |
US11958824B2 (en) | 2019-06-28 | 2024-04-16 | Johnson & Johnson Vision Care, Inc. | Photostable mimics of macular pigment |
US11543683B2 (en) | 2019-08-30 | 2023-01-03 | Johnson & Johnson Vision Care, Inc. | Multifocal contact lens displaying improved vision attributes |
US20240004105A1 (en) * | 2020-09-23 | 2024-01-04 | Griffith Altmann | Refractive-index adustable lens |
Family Cites Families (54)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2962533A (en) | 1958-01-20 | 1960-11-29 | American Cyanamid Co | Ortho-hydroxybenzophenones with unsaturated ether substituents |
US3072585A (en) | 1960-01-13 | 1963-01-08 | American Cyanamid Co | Vinylbenzyloxy phenylbenzotriazoles |
US3133042A (en) | 1960-09-09 | 1964-05-12 | Du Pont | Polymeric compositions and process |
NL279774A (US06244707-20010612-C00010.png) | 1961-06-16 | |||
US3162676A (en) | 1962-06-18 | 1964-12-22 | Nat Starch Chem Corp | Ethylenically unsaturated derivatives of 2, 4-dihydroxybenzophenone |
US3328491A (en) | 1964-05-01 | 1967-06-27 | Nat Starch Chem Corp | Uv light absorbing copolymers of acryloxymethyl benzoates and dihydroxybenzophenone derivatives |
US3493539A (en) | 1968-11-13 | 1970-02-03 | Nat Starch Chem Corp | Ethylenically unsaturated derivatives of 2-(2-hydroxyphenyl) benzotriazole and polymers therefrom |
USRE33477E (en) | 1973-06-20 | 1990-12-04 | Wesley-Jessen, Inc. | Ultraviolet absorbing hydrophilic corneal contact lenses |
US4390676A (en) | 1976-11-15 | 1983-06-28 | Schering Corporation | Ultraviolet absorbing lenses |
US4321396A (en) | 1980-01-17 | 1982-03-23 | Gaf Corporation | Copolymerizable, ultraviolet light absorber allyloxy-2-(2H-benzotriazol-2-yl)-4-alkylbenzenes |
US4260768A (en) | 1980-01-17 | 1981-04-07 | Gaf Corporation | Copolymerizable, ultraviolet light absorber 2-(2H-benzotriazol-2-yl)-4-alkylphenol acrylic acid esters |
US4310687A (en) | 1980-07-10 | 1982-01-12 | Gaf Corporation | Copolymerizable ultraviolet light absorber monomers which are acrylate esters of 2-hydroxy, alkoxy, methylol benzophenones |
US4508882A (en) | 1981-08-24 | 1985-04-02 | Asahi Glass Company Ltd. | Benzotriazole compound and homopolymer or copolymers thereof |
US4636212A (en) | 1982-05-10 | 1987-01-13 | Optical Radiation Corporation | Ultraviolet radiation absorbing intraocular lens |
US4528311A (en) | 1983-07-11 | 1985-07-09 | Iolab Corporation | Ultraviolet absorbing polymers comprising 2-hydroxy-5-acrylyloxyphenyl-2H-benzotriazoles |
DE3475617D1 (en) | 1983-07-26 | 1989-01-19 | Ciba Geigy Ag | Compounds which can be copolymerised |
US4740070A (en) | 1984-06-05 | 1988-04-26 | Ppg Industries, Inc. | Optical filter |
US5187207A (en) | 1984-06-08 | 1993-02-16 | Photoprotective Technologies, Inc. | Melanin hydrophilic contact lenses |
US5036115A (en) | 1984-06-08 | 1991-07-30 | Photoprotective Technologies, Inc. | Optical lens system incorporating melanin as an absorbing pigment for protection against electromagnetic radiation |
US4783361A (en) | 1984-09-10 | 1988-11-08 | Ovonic Synthetic Materials Company, Inc. | Coated lenses |
DE3439483A1 (de) | 1984-10-27 | 1986-05-07 | Röhm GmbH, 6100 Darmstadt | Radikalisch polymerisierbarer uv-absorber, verfahren zu seiner herstellung und seine polymere |
US5135965A (en) | 1984-12-18 | 1992-08-04 | T. R. Developments, Ltd. | Hydrogel-forming polymers used in intraocular lenses |
US5002979A (en) | 1985-01-29 | 1991-03-26 | Bausch & Lomb Incorporated | Extended-wear lenses |
US5084537A (en) | 1985-01-29 | 1992-01-28 | Bausch & Lomb, Incorporated | UV-absorbing extended-wear Lenses |
US4753654A (en) | 1985-03-18 | 1988-06-28 | Optical Radiation Corporation | Ultraviolet radiation absorbing intraocular lens |
SE8503522D0 (sv) | 1985-07-19 | 1985-07-19 | Pharmacia Ab | Uv-absorberande linsmaterial |
US4719248A (en) | 1985-08-08 | 1988-01-12 | Bausch & Lomb Incorporated | Ultraviolet blocking agents for contact lenses |
US4716234A (en) | 1986-12-01 | 1987-12-29 | Iolab Corporation | Ultraviolet absorbing polymers comprising 2-(2'-hydroxy-5'-acryloyloxyalkoxyphenyl)-2H-benzotriazole |
US4868251A (en) * | 1986-12-24 | 1989-09-19 | Allergan, Inc. | Ultraviolet light absorbing silicone compositions |
US4872877A (en) | 1987-03-17 | 1989-10-10 | Dennis T. Grendahl | Intraocular lens with ultraviolet screening agent |
US4853374A (en) | 1987-06-09 | 1989-08-01 | M.D.R. Group, Inc. | Viscoelastic vitreous substitute with UV blocker |
US5099027A (en) | 1987-08-12 | 1992-03-24 | Ppg Industries, Inc. | 2(2-hydroxyphenyl)2H-benzotriazole compounds and homopolymers or copolymers thereof |
US5194544A (en) | 1987-10-15 | 1993-03-16 | University Of Florida | UV absorbing vinyl monomers and polymers and ocular implants prepared therefrom |
US5374663A (en) | 1988-03-03 | 1994-12-20 | Hoya Corporation | Process for producing cyanopsia-correctable intraocular lens |
US4845180A (en) | 1988-03-21 | 1989-07-04 | Allergan, Inc. | Ultraviolet light absorbing compounds, compositions and methods for making same |
JPH0761357B2 (ja) | 1988-03-28 | 1995-07-05 | ホーヤ株式会社 | 眼内レンズ |
US5133745A (en) | 1988-05-26 | 1992-07-28 | Alcon Laboratories, Inc. | Ultraviolet absorbing hydrogels |
US5106930A (en) | 1988-09-28 | 1992-04-21 | Ioptex Research Inc. | Contact lenses |
DE3837884A1 (de) | 1988-11-08 | 1990-05-10 | Mutzhas Maximilian F | Lichtfilter zur verbesserung des sehens |
US4929250A (en) | 1989-03-14 | 1990-05-29 | Ciba-Geigy Corporation | Ultraviolet absorbing lenses and method of making the same |
US4963160A (en) | 1989-03-14 | 1990-10-16 | Ciba-Geigy Corporation | Reactive uv absorbing compositions and method of preparing lenses therefrom |
US5298033A (en) | 1989-03-14 | 1994-03-29 | Ciba-Geigy Corporation | Ultraviolet absorbing lenses and methods of manufacturing thereof |
US5194456A (en) | 1989-12-04 | 1993-03-16 | Ioptex Research, Inc. | Uv absorbers and pmma material containing such absorbers |
US5252628A (en) | 1989-12-07 | 1993-10-12 | Lions Eye Institute Of Western Australia, Inc. | Method of making photoprotective hydrophilic polymers and ocular devices thereof |
JP2613486B2 (ja) | 1990-03-30 | 1997-05-28 | 旭光学工業株式会社 | 貼り合わせ眼鏡レンズ及びその製造方法 |
US5290892A (en) | 1990-11-07 | 1994-03-01 | Nestle S.A. | Flexible intraocular lenses made from high refractive index polymers |
JP2685980B2 (ja) | 1990-11-26 | 1997-12-08 | 株式会社メニコン | 紫外線吸収性眼内レンズ |
US5164462A (en) | 1991-04-25 | 1992-11-17 | Allergan, Inc. | Ultraviolet light absorbing compounds and silicone compositions |
JP3195662B2 (ja) | 1992-08-24 | 2001-08-06 | 株式会社メニコン | 眼用レンズ材料 |
DE69406914T2 (de) | 1993-04-22 | 1998-05-28 | Jessen Wesley Corp | Eine styren-gruppe enthaltende uv-absorbierende benzotriazole |
US5480927A (en) | 1994-05-20 | 1996-01-02 | Ciba Geigy Corporation | Method of increasing the concentration of radiation-absorbing agents in optical and ophthalmic lenses |
JP3444660B2 (ja) | 1994-07-15 | 2003-09-08 | Hoya株式会社 | ハードコンタクトレンズ材料およびハードコンタクトレンズ |
US5910537A (en) * | 1994-07-22 | 1999-06-08 | Staar Surgical Company Inc. | Biocompatible, optically transparent, ultraviolet light absorbing, polymeric material based upon collagen and method of making |
EP0786675B1 (en) * | 1996-01-26 | 2002-11-06 | Teijin Chemicals, Ltd. | Spectacle lens |
-
1998
- 1998-07-21 US US09/121,071 patent/US6244707B1/en not_active Expired - Lifetime
-
1999
- 1999-07-13 WO PCT/US1999/015804 patent/WO2000004848A1/en active IP Right Grant
- 1999-07-13 CN CN99811027A patent/CN1317955A/zh active Pending
- 1999-07-13 MX MXPA01000783A patent/MXPA01000783A/es unknown
- 1999-07-13 CA CA002338245A patent/CA2338245C/en not_active Expired - Fee Related
- 1999-07-13 AU AU52117/99A patent/AU757384B2/en not_active Ceased
- 1999-07-13 EP EP99937242A patent/EP1096905B1/en not_active Expired - Lifetime
- 1999-07-13 DE DE69929798T patent/DE69929798T2/de not_active Expired - Lifetime
- 1999-07-13 BR BR9912324-0A patent/BR9912324A/pt not_active IP Right Cessation
- 1999-07-13 JP JP2000560842A patent/JP2002521705A/ja active Pending
- 1999-07-13 KR KR1020017000701A patent/KR20010084879A/ko not_active Application Discontinuation
- 1999-07-13 AT AT99937242T patent/ATE317250T1/de not_active IP Right Cessation
-
2001
- 2001-04-20 US US09/838,992 patent/US20010025198A1/en not_active Abandoned
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Also Published As
Publication number | Publication date |
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JP2002521705A (ja) | 2002-07-16 |
BR9912324A (pt) | 2001-04-24 |
US20010025198A1 (en) | 2001-09-27 |
EP1096905A1 (en) | 2001-05-09 |
AU5211799A (en) | 2000-02-14 |
US6244707B1 (en) | 2001-06-12 |
WO2000004848A1 (en) | 2000-02-03 |
CA2338245A1 (en) | 2000-02-03 |
AU757384B2 (en) | 2003-02-20 |
MXPA01000783A (es) | 2003-03-12 |
DE69929798T2 (de) | 2006-10-12 |
EP1096905A4 (en) | 2001-09-26 |
DE69929798D1 (de) | 2006-04-20 |
KR20010084879A (ko) | 2001-09-06 |
EP1096905B1 (en) | 2006-02-08 |
ATE317250T1 (de) | 2006-02-15 |
CA2338245C (en) | 2005-04-12 |
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