CN1188387C - 通过乙烷或乙烯氧化生产乙酸乙烯酯单体的方法 - Google Patents
通过乙烷或乙烯氧化生产乙酸乙烯酯单体的方法 Download PDFInfo
- Publication number
- CN1188387C CN1188387C CNB008101868A CN00810186A CN1188387C CN 1188387 C CN1188387 C CN 1188387C CN B008101868 A CNB008101868 A CN B008101868A CN 00810186 A CN00810186 A CN 00810186A CN 1188387 C CN1188387 C CN 1188387C
- Authority
- CN
- China
- Prior art keywords
- ethane
- ethylene
- catalyst
- oxygen
- catalyzer
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C67/00—Preparation of carboxylic acid esters
- C07C67/04—Preparation of carboxylic acid esters by reacting carboxylic acids or symmetrical anhydrides onto unsaturated carbon-to-carbon bonds
- C07C67/05—Preparation of carboxylic acid esters by reacting carboxylic acids or symmetrical anhydrides onto unsaturated carbon-to-carbon bonds with oxidation
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C67/00—Preparation of carboxylic acid esters
- C07C67/04—Preparation of carboxylic acid esters by reacting carboxylic acids or symmetrical anhydrides onto unsaturated carbon-to-carbon bonds
- C07C67/05—Preparation of carboxylic acid esters by reacting carboxylic acids or symmetrical anhydrides onto unsaturated carbon-to-carbon bonds with oxidation
- C07C67/055—Preparation of carboxylic acid esters by reacting carboxylic acids or symmetrical anhydrides onto unsaturated carbon-to-carbon bonds with oxidation in the presence of platinum group metals or their compounds
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/50—Improvements relating to the production of bulk chemicals
- Y02P20/582—Recycling of unreacted starting or intermediate materials
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
- Catalysts (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US09/312,683 | 1999-05-14 | ||
| US09/312683 | 1999-05-14 | ||
| US09/312,683 US6143921A (en) | 1999-05-14 | 1999-05-14 | Method for producing vinyl acetate monomer from ethane or ethylene oxidation |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1360565A CN1360565A (zh) | 2002-07-24 |
| CN1188387C true CN1188387C (zh) | 2005-02-09 |
Family
ID=23212532
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CNB008101868A Expired - Fee Related CN1188387C (zh) | 1999-05-14 | 2000-05-09 | 通过乙烷或乙烯氧化生产乙酸乙烯酯单体的方法 |
Country Status (10)
| Country | Link |
|---|---|
| US (3) | US6143921A (https=) |
| EP (1) | EP1180092B1 (https=) |
| JP (1) | JP2002544250A (https=) |
| KR (1) | KR100609203B1 (https=) |
| CN (1) | CN1188387C (https=) |
| AT (1) | ATE306467T1 (https=) |
| DE (1) | DE60023132T2 (https=) |
| ES (1) | ES2250137T3 (https=) |
| SA (1) | SA99200395B1 (https=) |
| WO (1) | WO2000069802A1 (https=) |
Families Citing this family (39)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US7189377B1 (en) * | 1996-08-07 | 2007-03-13 | Bp Chemicals Limited | Apparatus for performing integrated process for reproduction of vinyl acetate and/or acetic acid using a fluidized bed |
| US6143921A (en) | 1999-05-14 | 2000-11-07 | Saudi Basic Industries Corporation | Method for producing vinyl acetate monomer from ethane or ethylene oxidation |
| US6258992B1 (en) * | 1999-09-17 | 2001-07-10 | Saudi Basic Industries Corporation | Gas phase catalytic oxidation of hydrocarbons to carboxylic acids and dehydrogenated products |
| DK1286945T3 (da) * | 2000-05-19 | 2005-05-09 | Celanese Int Corp | Integreret fremgangsmåde til fremstilling af vinylacetat |
| DE50102496D1 (de) * | 2000-10-10 | 2004-07-08 | Basf Ag | Verfahren zur herstellung eines ringförmigen schalenkatalysators und verwendung davon zur herstellung von acrolein |
| GB0026241D0 (en) | 2000-10-26 | 2000-12-13 | Bp Chem Int Ltd | Process |
| GB0026243D0 (en) * | 2000-10-26 | 2000-12-13 | Bp Chem Int Ltd | Process |
| MXPA03008716A (es) * | 2001-03-30 | 2003-12-11 | Shell Int Research | Proceso para preparacion de catalizador que contiene metal del grupo viii y uso del mismo para preparar carboxilato de alquenilo. |
| US6642173B2 (en) * | 2001-04-25 | 2003-11-04 | Rohm And Haas Company | Catalyst |
| US6656873B2 (en) * | 2001-06-14 | 2003-12-02 | Sanjay Chaturvedi | Mixed metal oxide catalyst |
| RU2184725C1 (ru) * | 2001-10-26 | 2002-07-10 | Государственное образовательное учреждение Воронежская государственная технологическая академия | Способ автоматического контроля и управления процессом получения винилацетата на основе этилена |
| GB0200021D0 (en) * | 2002-01-02 | 2002-02-13 | Bp Chem Int Ltd | Process |
| GB0205016D0 (en) * | 2002-03-04 | 2002-04-17 | Bp Chem Int Ltd | Process |
| GB0205014D0 (en) * | 2002-03-04 | 2002-04-17 | Bp Chem Int Ltd | Process |
| JP4421201B2 (ja) * | 2002-03-27 | 2010-02-24 | シエル・インターナシヨナル・リサーチ・マートスハツペイ・ベー・ヴエー | 触媒を調製する方法、触媒、および触媒の使用 |
| US7038082B2 (en) | 2002-10-17 | 2006-05-02 | Basf Aktiengesellschaft | Preparation of a multimetal oxide material |
| US7294734B2 (en) * | 2003-05-02 | 2007-11-13 | Velocys, Inc. | Process for converting a hydrocarbon to an oxygenate or a nitrile |
| US7220390B2 (en) | 2003-05-16 | 2007-05-22 | Velocys, Inc. | Microchannel with internal fin support for catalyst or sorption medium |
| GB0312965D0 (en) | 2003-06-05 | 2003-07-09 | Bp Chem Int Ltd | Process |
| TW201236754A (en) * | 2003-12-19 | 2012-09-16 | Celanese Int Corp | Zirconia containing support materials for catalysts |
| US7465823B2 (en) * | 2004-03-17 | 2008-12-16 | Celanese International Corporation | Utilization of acetic acid reaction heat in other process plants |
| WO2006068764A2 (en) * | 2004-12-20 | 2006-06-29 | Celanese International Corporation | Modified support materials for catalysts |
| US8227369B2 (en) * | 2005-05-25 | 2012-07-24 | Celanese International Corp. | Layered composition and processes for preparing and using the composition |
| DE602006009107D1 (de) * | 2005-06-01 | 2009-10-22 | Celanese Int Corp | Verfahen zur selektiven oxidierung von ethan zu ethylen |
| DE102007025315A1 (de) * | 2007-05-31 | 2008-12-11 | Süd-Chemie AG | Katalysator zur selektiven Hydrierung acetylenischer Kohlenwasserstoffe und Verfahren zu seiner Herstellung |
| DE102007025442B4 (de) * | 2007-05-31 | 2023-03-02 | Clariant International Ltd. | Verwendung einer Vorrichtung zur Herstellung eines Schalenkatalysators und Schalenkatalysator |
| DE102007025223A1 (de) * | 2007-05-31 | 2008-12-04 | Süd-Chemie AG | Zirkoniumoxid-dotierter VAM-Schalenkatalysator, Verfahren zu dessen Herstellung sowie dessen Verwendung |
| DE102007025443A1 (de) | 2007-05-31 | 2008-12-04 | Süd-Chemie AG | Pd/Au-Schalenkatalysator enthaltend HfO2, Verfahren zu dessen Herstellung sowie dessen Verwendung |
| DE102007025362A1 (de) * | 2007-05-31 | 2008-12-11 | Süd-Chemie AG | Dotierter Pd/Au-Schalenkatalysator, Verfahren zu dessen Herstellung sowie dessen Verwendung |
| DE102007025444A1 (de) * | 2007-05-31 | 2008-12-11 | Süd-Chemie AG | VAM-Schalenkatalysator, Verfahren zu dessen Herstellung sowie dessen Verwendung |
| DE202008017277U1 (de) | 2008-11-30 | 2009-04-30 | Süd-Chemie AG | Katalysatorträger |
| US9676695B2 (en) | 2011-03-02 | 2017-06-13 | Aither Chemical LLC | Methods for integrated natural gas purification and products produced therefrom |
| DE102012205444A1 (de) | 2012-04-03 | 2013-10-10 | Wacker Chemie Ag | Verfahren zur Herstellung von Vinylacetat |
| WO2018114747A1 (en) | 2016-12-19 | 2018-06-28 | Shell Internationale Research Maatschappij B.V. | Ethane oxidative dehydrogenation with co-production of vinyl acetate |
| PL3555037T3 (pl) | 2016-12-19 | 2021-05-17 | Shell Internationale Research Maatschappij B.V. | Utleniające odwodornienie etanu ze współprodukcją octanu winylu |
| CN112703055A (zh) * | 2018-09-17 | 2021-04-23 | 沙特基础工业全球技术公司 | 选择性氧化催化剂和在选择性氧化催化剂的存在下氧化c2烃的方法 |
| CN113613781A (zh) * | 2019-03-26 | 2021-11-05 | 沙特基础全球技术有限公司 | 催化剂再活化方法 |
| EP4059916A1 (de) | 2021-03-15 | 2022-09-21 | Linde GmbH | Verfahren und anlage zur erzeugung eines produktkohlenwasserstoffs |
| EP4116283A1 (de) | 2021-07-06 | 2023-01-11 | Linde GmbH | Verfahren und anlage zur herstellung von vinylacetat |
Family Cites Families (19)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3190912A (en) * | 1962-05-02 | 1965-06-22 | Nat Distillers Chem Corp | Process for preparing esters |
| US3637819A (en) * | 1967-12-30 | 1972-01-25 | Knapsack Ag | Process for the manufacture of unsaturated esters of carboxylic acids |
| US3650896A (en) * | 1969-10-09 | 1972-03-21 | Atomic Energy Commission | Nuclear fuel particles |
| US3792087A (en) * | 1971-11-10 | 1974-02-12 | Nat Distillers Chem Corp | Vapor phase oxidation of ethylene to acetic acid |
| US3970697A (en) * | 1974-07-01 | 1976-07-20 | National Distillers And Chemical Corporation | Oxidation of ethylene to acetic acid |
| US4188490A (en) * | 1977-05-27 | 1980-02-12 | National Distillers And Chemical Corporation | Catalytic oxidation of ethylene to mixtures of acetic acid and vinyl acetate |
| DE2811115A1 (de) * | 1978-03-15 | 1979-09-27 | Hoechst Ag | Traeger-katalysator fuer die herstellung von vinylacetat aus ethylen, essigsaeure und sauerstoff in der gasphase |
| DE3803900A1 (de) * | 1988-02-09 | 1989-08-17 | Hoechst Ag | Verfahren zur herstellung von vinylacetat |
| US5185308A (en) * | 1991-05-06 | 1993-02-09 | Bp Chemicals Limited | Catalysts and processes for the manufacture of vinyl acetate |
| DE19630832A1 (de) * | 1996-07-31 | 1998-02-05 | Hoechst Ag | Verfahren zur selektiven Herstellung von Essigsäure |
| GB9616573D0 (en) * | 1996-08-07 | 1996-09-25 | Bp Chem Int Ltd | Process |
| US7189377B1 (en) * | 1996-08-07 | 2007-03-13 | Bp Chemicals Limited | Apparatus for performing integrated process for reproduction of vinyl acetate and/or acetic acid using a fluidized bed |
| DE19717075A1 (de) | 1997-04-23 | 1998-10-29 | Hoechst Ag | Verfahren zur Herstellung von Essigsäure in einer Reaktorkaskade |
| US6013597A (en) | 1997-09-17 | 2000-01-11 | Saudi Basic Industries Corporation | Catalysts for the oxidation of ethane to acetic acid processes of making same and, processes of using same |
| DE19745902A1 (de) | 1997-10-17 | 1999-04-22 | Hoechst Ag | Verfahren zur selektiven Herstellung von Essigsäure durch katalytische Oxidation von Ethan |
| US6030920A (en) | 1997-12-24 | 2000-02-29 | Saudi Basic Industries Corporation | Catalysts for producing acetic acid from ethane oxidation, processes of making same and method of using same |
| US6028221A (en) | 1998-06-29 | 2000-02-22 | Saudi Basic Industries Corporation | Catalyst systems for the one step gas phase production of acetic acid from ethylene and methods of making and using the same |
| US6060421A (en) | 1998-12-23 | 2000-05-09 | Saudi Basic Industries Corporation | Catalysts for the oxidation of ethane to acetic acid, methods of making and using the same |
| US6143921A (en) | 1999-05-14 | 2000-11-07 | Saudi Basic Industries Corporation | Method for producing vinyl acetate monomer from ethane or ethylene oxidation |
-
1999
- 1999-05-14 US US09/312,683 patent/US6143921A/en not_active Ceased
- 1999-07-28 SA SA99200395A patent/SA99200395B1/ar unknown
-
2000
- 2000-05-09 AT AT00936733T patent/ATE306467T1/de not_active IP Right Cessation
- 2000-05-09 DE DE60023132T patent/DE60023132T2/de not_active Expired - Lifetime
- 2000-05-09 US US10/031,808 patent/US6605739B1/en not_active Expired - Lifetime
- 2000-05-09 ES ES00936733T patent/ES2250137T3/es not_active Expired - Lifetime
- 2000-05-09 JP JP2000618222A patent/JP2002544250A/ja active Pending
- 2000-05-09 WO PCT/EP2000/004234 patent/WO2000069802A1/en not_active Ceased
- 2000-05-09 CN CNB008101868A patent/CN1188387C/zh not_active Expired - Fee Related
- 2000-05-09 EP EP00936733A patent/EP1180092B1/en not_active Revoked
- 2000-05-09 KR KR1020017014540A patent/KR100609203B1/ko not_active Expired - Fee Related
-
2006
- 2006-02-08 US US11/363,148 patent/USRE43859E1/en not_active Expired - Lifetime
Also Published As
| Publication number | Publication date |
|---|---|
| US6605739B1 (en) | 2003-08-12 |
| JP2002544250A (ja) | 2002-12-24 |
| WO2000069802A1 (en) | 2000-11-23 |
| KR100609203B1 (ko) | 2006-08-02 |
| WO2000069802A9 (en) | 2001-11-29 |
| ES2250137T3 (es) | 2006-04-16 |
| EP1180092B1 (en) | 2005-10-12 |
| ATE306467T1 (de) | 2005-10-15 |
| KR20020015689A (ko) | 2002-02-28 |
| US6143921A (en) | 2000-11-07 |
| DE60023132D1 (de) | 2006-02-23 |
| CN1360565A (zh) | 2002-07-24 |
| USRE43859E1 (en) | 2012-12-11 |
| EP1180092A1 (en) | 2002-02-20 |
| SA99200395B1 (ar) | 2006-04-04 |
| DE60023132T2 (de) | 2006-06-29 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C06 | Publication | ||
| PB01 | Publication | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| CF01 | Termination of patent right due to non-payment of annual fee | ||
| CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20050209 Termination date: 20180509 |