CN1140577C - 耐磨性硅烷可交联聚合物和聚合物共混组合物 - Google Patents
耐磨性硅烷可交联聚合物和聚合物共混组合物 Download PDFInfo
- Publication number
- CN1140577C CN1140577C CNB971817820A CN97181782A CN1140577C CN 1140577 C CN1140577 C CN 1140577C CN B971817820 A CNB971817820 A CN B971817820A CN 97181782 A CN97181782 A CN 97181782A CN 1140577 C CN1140577 C CN 1140577C
- Authority
- CN
- China
- Prior art keywords
- composition
- grafting
- ethylene
- alpha
- crosslinked
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L51/00—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
- C08L51/06—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers grafted on to homopolymers or copolymers of aliphatic hydrocarbons containing only one carbon-to-carbon double bond
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F255/00—Macromolecular compounds obtained by polymerising monomers on to polymers of hydrocarbons as defined in group C08F10/00
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F255/00—Macromolecular compounds obtained by polymerising monomers on to polymers of hydrocarbons as defined in group C08F10/00
- C08F255/02—Macromolecular compounds obtained by polymerising monomers on to polymers of hydrocarbons as defined in group C08F10/00 on to polymers of olefins having two or three carbon atoms
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F255/00—Macromolecular compounds obtained by polymerising monomers on to polymers of hydrocarbons as defined in group C08F10/00
- C08F255/08—Macromolecular compounds obtained by polymerising monomers on to polymers of hydrocarbons as defined in group C08F10/00 on to polymers of olefins having four or more carbon atoms
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F257/00—Macromolecular compounds obtained by polymerising monomers on to polymers of aromatic monomers as defined in group C08F12/00
- C08F257/02—Macromolecular compounds obtained by polymerising monomers on to polymers of aromatic monomers as defined in group C08F12/00 on to polymers of styrene or alkyl-substituted styrenes
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Silicon Polymers (AREA)
Abstract
Description
聚合物定义 | 密度(g/cm3) | MI(g/10min) | %结晶度 |
A | 0.910 | 3.5 | 33 |
B | 0.896 | 1.6 | 27 |
C | 0.858 | 1.7 | 3 |
D | 0.870 | 5.0 | 10 |
装置区段 | 第一(接枝)通过温度(℃) | 第二次(油引入)通过温度(℃) |
1 | 140 | 164 |
2 | 160 | 68 |
3 | 180 | 102 |
4 | 205 | 137 |
5 | 206 | 145 |
口模 | 190 | 142 |
水浴 | 13 | 13 |
参数 | 设定值 |
区段I温度(°F/℃) | 385/196 |
区段2-4的温度(°F/℃) | 400/204 |
区段5的温度(°F/℃) | 410/210 |
注射量 | 58.3-58.8cc |
注射压力(巴/MPa) | 700/70 |
保持压(巴/MPa) | 150-190/15-19 |
注塑时间 | 1.95-2.3秒 |
冷却时间 | 30-40秒 |
螺杆注射速度 | 25米/分钟 |
组分 | Ex.1 | Ex.2 | Ex.3 | Ex.4 | Ex.5 | Ex.6 | Ex.7 | Ex.8 | Ex.9 | Ex.10 | Ex.11 | Ex.12 |
聚合物A | -- | -- | -- | 20 | 14 | 20 | 14 | -- | -- | -- | -- | -- |
聚合物C | 100 | -- | -- | -- | -- | 80 | 56 | 95 | 72 | 60 | -- | -- |
聚合物D | -- | 100 | 90 | 80 | 56 | -- | -- | -- | -- | -- | 90 | 63 |
PP | -- | -- | 10 | -- | -- | -- | -- | 5 | 13 | 10 | 10 | 7 |
油 | -- | -- | -- | -- | 30 | -- | 30 | -- | 15 | 30 | -- | 30 |
实例 | 拉伸强度(psi/MPa) | 伸长率(%) | 凝胶(wt%) | 硬度(肖氏A) | NBS磨损 | COF(干瓷砖) | COF(湿瓷砖) |
1 | 490/3.4 | 140 | 98 | 62 | 40 | 1.07 | 0.70 |
2 | 690/4.8 | 320 | 84 | 73 | 80 | 0.77 | 0.47 |
A | 669/4.6 | 755 | 0 | 76 | 48 | 0.69 | 0.46 |
3 | 790/5.4 | 280 | 91 | 78 | 140 | 0.90 | 0.49 |
4 | 780/5.4 | 240 | 96 | 80 | 165 | N.D. | N.D. |
5 | 370/2.6 | 240 | 57 | 58 | 75 | N.D. | N.D. |
6 | 680/4.7 | 180 | 94 | 72 | 75 | N.D. | N.D. |
7 | 360/2.5 | 170 | 60 | 58 | 62 | N.D. | N.D. |
8 | 530/3.7 | 141 | 96 | 64 | 155 | 0.91 | 0.59 |
9 | 373/2.6 | 131 | 83 | 56 | 124 | 1.16 | 0.57 |
10 | 549/3.8 | 186 | 76 | 64 | 143 | 1.05 | 0.56 |
11 | 793/5.5 | 276 | 91 | 78 | 143 | 0.90 | 0.49 |
B | 878/6.1 | 990 | 0 | 80 | 60 | 0.89 | 0.49 |
12 | 501/3.5 | 347 | 63 | 59 | 96 | 1.02 | 0.45 |
C | 393/2.7 | 815 | 0 | 60 | 67 | 0.82 | 0.42 |
13 | 680/4.7 | 689 | 43 | 57 | 56 | 1.50 | 0.38 |
14 | 618/4.3 | >1000 | 24 | 56 | 47 | 1.38 | 0.32 |
Claims (13)
Applications Claiming Priority (4)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US3464896P | 1996-12-13 | 1996-12-13 | |
US60/034,648 | 1996-12-13 | ||
US96590197A | 1997-11-07 | 1997-11-07 | |
US08/965,901 | 1997-11-07 |
Publications (2)
Publication Number | Publication Date |
---|---|
CN1246135A CN1246135A (zh) | 2000-03-01 |
CN1140577C true CN1140577C (zh) | 2004-03-03 |
Family
ID=26711205
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CNB971817820A Expired - Lifetime CN1140577C (zh) | 1996-12-13 | 1997-11-13 | 耐磨性硅烷可交联聚合物和聚合物共混组合物 |
Country Status (8)
Country | Link |
---|---|
EP (1) | EP0944670B1 (zh) |
JP (1) | JP2002514244A (zh) |
KR (1) | KR100580409B1 (zh) |
CN (1) | CN1140577C (zh) |
AU (1) | AU743999B2 (zh) |
CA (1) | CA2274667A1 (zh) |
DE (1) | DE69721042T2 (zh) |
WO (1) | WO1998026001A1 (zh) |
Families Citing this family (26)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
AR018359A1 (es) * | 1998-05-18 | 2001-11-14 | Dow Global Technologies Inc | Articulo resistente al calor , configurado, irradiado y reticulado, libre de un agente de reticulacion de silano |
US6709742B2 (en) | 1998-05-18 | 2004-03-23 | Dow Global Technologies Inc. | Crosslinked elastic fibers |
EP1086188B1 (en) * | 1998-06-01 | 2006-09-13 | Dow Global Technologies Inc. | Method of making washable, dryable elastic articles |
RU2233847C2 (ru) * | 1999-03-02 | 2004-08-10 | Эксонмобил Кемикэл Пейтентс Инк. | Сополимеры альфа-олефина и винилового ароматического мономера с привитым силаном |
FR2828198B1 (fr) * | 2001-07-31 | 2007-02-23 | Atofina | Polypropylene isotactique obtenu par catalyse metallocene greffe |
DE10154303A1 (de) * | 2001-11-05 | 2003-05-15 | Rehau Ag & Co | Vernetzte Profile |
US20050279779A1 (en) * | 2004-06-03 | 2005-12-22 | Gerondale Scott J | Controlled drop dispensing tip |
ES2398109T3 (es) | 2005-07-11 | 2013-03-13 | Dow Global Technologies Llc | Composiciones que comprenden polímeros de olefinas injertados con silano y artículos fabricados a partir de las mismas |
KR100853430B1 (ko) * | 2006-01-24 | 2008-08-21 | 주식회사 엘지화학 | 복원력이 향상된 열가소성 엘라스토머 |
CN109320664A (zh) | 2006-06-15 | 2019-02-12 | 陶氏环球技术有限责任公司 | 官能化烯烃共聚体、组合物和由其制成的制品及其制法 |
KR101005691B1 (ko) * | 2006-10-26 | 2011-01-05 | 주식회사 엘지화학 | 신규한 실란화합물로부터 유도된 브리지 구조를 가지는폴리프로필렌계 수지 및 그 폴리프로필렌계 수지의제조방법 |
DE102008039218A1 (de) | 2008-08-22 | 2010-02-25 | Woco Industrietechnik Gmbh | Vulkanisierbare Kautschukmischungen sowie Elastomerformteile, erhältlich aus diesen Kautschukmischungen |
KR101448314B1 (ko) | 2009-05-15 | 2014-10-08 | 주식회사 엘지화학 | 봉지재 시트, 이의 제조방법 및 이를 포함하는 태양전지 모듈 |
CN102464767B (zh) * | 2010-11-04 | 2014-08-06 | 中国石油天然气股份有限公司 | 一种原位制备硅橡胶复合材料的方法 |
CN104114592A (zh) * | 2012-02-03 | 2014-10-22 | 陶氏环球技术有限责任公司 | 包括含硅烷的乙烯互聚物配方的膜和包括其的电子设备模块 |
US10040888B1 (en) | 2013-06-14 | 2018-08-07 | Cooper-Standard Automotive Inc. | Composition including silane-grafted polyolefin |
US10100139B2 (en) | 2013-08-01 | 2018-10-16 | Cooper-Standard Automotive Inc. | Hose, composition including silane-grafted polyolefin, and process of making a hose |
CN103694411B (zh) * | 2013-12-24 | 2016-05-18 | 上海高分子功能材料研究所 | 一种硅烷接枝聚烯烃弹性体的接枝方法及硅烷接枝交联聚烯烃弹性体的制备方法 |
US10371292B2 (en) | 2014-07-02 | 2019-08-06 | Cooper-Standard Automotive Inc. | Hose, abrasion resistant composition, and process of making a hose |
KR102003451B1 (ko) | 2016-06-30 | 2019-07-24 | 코오롱인더스트리 주식회사 | 경화 가능한 석유수지, 이의 제조방법 및 이의 용도 |
KR102291384B1 (ko) | 2016-09-27 | 2021-08-20 | 코오롱인더스트리 주식회사 | 경화 가능한 변성 석유수지, 이의 제조방법 및 이의 용도 |
EP3551453A1 (en) | 2016-12-10 | 2019-10-16 | Cooper-Standard Automotive, Inc. | Roofing membranes, compositions, and methods of making the same |
EP3551715B1 (en) | 2016-12-10 | 2023-11-08 | Cooper-Standard Automotive, Inc. | Microdense seals, compositions, and methods of making the same |
KR102343368B1 (ko) | 2017-06-30 | 2021-12-24 | 코오롱인더스트리 주식회사 | 경화 가능한 석유수지, 이의 제조방법 및 이의 용도 |
JP7083723B2 (ja) * | 2018-08-07 | 2022-06-13 | リケンテクノス株式会社 | 摺動材料組成物、摺動性成形物、および摺動性部材 |
WO2020070034A1 (en) | 2018-10-02 | 2020-04-09 | Borealis Ag | Cross-linked plastomers as a replacement for rubber |
Family Cites Families (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4058583A (en) * | 1975-03-10 | 1977-11-15 | Kabel-Und Metallwerke Gutehoffnungshutte Ag. | Grafting of silane on thermoplastics or elastomers for purposes of cross-linking |
AR218611A1 (es) * | 1975-06-23 | 1980-06-30 | Kabel Metallwerke Ghh | Procedimiento para la elaboracion de termoplasticos o elastomeros reticulables por injerto de un compuesto de silano en presencia de humedad |
DE2736003C2 (de) * | 1977-08-10 | 1985-10-03 | kabelmetal electro GmbH, 3000 Hannover | Verfahren zur Herstellung extrudierfähiger und feuchtigkeitsvernetzbarer gummiähnlicher Thermoplaste |
DE3107907C2 (de) * | 1981-03-02 | 1984-06-07 | kabelmetal electro GmbH, 3000 Hannover | Verfahren zur Herstellung von Schrumpfschläuchen, -manschetten und -kappen |
GB2116986A (en) * | 1982-03-18 | 1983-10-05 | Exxon Research Engineering Co | Method for producing polymer mouldings |
DE3688897D1 (de) * | 1985-06-05 | 1993-09-23 | Dynamit Nobel Ag | Vernetzte formkoerper mit erhoehter schlagzaehigkeit aus ternaeren polyolefin-formmassen und deren herstellung. |
CA1280528C (en) * | 1986-06-16 | 1991-02-19 | Barry Topcik | Elastomer polyolefin blends |
CN1111551C (zh) * | 1994-04-20 | 2003-06-18 | 陶氏化学公司 | 硅烷可交联的基本线型乙烯聚合物及其用途 |
NO309384B1 (no) * | 1995-01-16 | 2001-01-22 | Borealis Holding As | Polyolefinlegering med forbedret overflatehårdhet og ripefasthet |
-
1997
- 1997-11-13 JP JP52666098A patent/JP2002514244A/ja not_active Ceased
- 1997-11-13 DE DE69721042T patent/DE69721042T2/de not_active Expired - Lifetime
- 1997-11-13 EP EP97948188A patent/EP0944670B1/en not_active Expired - Lifetime
- 1997-11-13 CA CA002274667A patent/CA2274667A1/en not_active Abandoned
- 1997-11-13 KR KR1019997005271A patent/KR100580409B1/ko not_active IP Right Cessation
- 1997-11-13 AU AU54303/98A patent/AU743999B2/en not_active Ceased
- 1997-11-13 WO PCT/US1997/020220 patent/WO1998026001A1/en active IP Right Grant
- 1997-11-13 CN CNB971817820A patent/CN1140577C/zh not_active Expired - Lifetime
Also Published As
Publication number | Publication date |
---|---|
DE69721042T2 (de) | 2004-02-05 |
WO1998026001A1 (en) | 1998-06-18 |
KR20000057549A (ko) | 2000-09-25 |
CN1246135A (zh) | 2000-03-01 |
JP2002514244A (ja) | 2002-05-14 |
KR100580409B1 (ko) | 2006-05-16 |
CA2274667A1 (en) | 1998-06-18 |
DE69721042D1 (de) | 2003-05-22 |
AU5430398A (en) | 1998-07-03 |
EP0944670A1 (en) | 1999-09-29 |
AU743999B2 (en) | 2002-02-14 |
EP0944670B1 (en) | 2003-04-16 |
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Legal Events
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C06 | Publication | ||
PB01 | Publication | ||
C10 | Entry into substantive examination | ||
SE01 | Entry into force of request for substantive examination | ||
C14 | Grant of patent or utility model | ||
GR01 | Patent grant | ||
ASS | Succession or assignment of patent right |
Owner name: WERBEN COMPANY Free format text: FORMER OWNER: DUPONT SPECILA ELASTOMER CO., LTD. Effective date: 20060310 Owner name: DOW GLOBAL TECHNICAL COMPANY Free format text: FORMER OWNER: WERBEN COMPANY Effective date: 20060310 |
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Owner name: DUPONT SPECILA ELASTOMER CO., LTD. Free format text: FORMER NAME OR ADDRESS: DUPONT DOW ELASTOMERS LLC |
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CP03 | Change of name, title or address |
Address after: Delaware, USA Patentee after: DuPont characteristic elastomers Inc. Address before: Delaware, USA Patentee before: DUPONT DOW ELASTOMERS LLC |
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Effective date of registration: 20060310 Address after: Michigan, USA Patentee after: Wen Ben Address before: Delaware, USA Patentee before: DuPont characteristic elastomers Inc. Effective date of registration: 20060310 Address after: Michigan, USA Patentee after: Dow Global Technologies Inc. Address before: Michigan, USA Patentee before: Wen Ben |
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